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Dissertations / Theses on the topic 'Cycloaddition reactions'

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1

Boyd, Susan Mary. "Asymmetric cycloaddition reactions." Thesis, University of Oxford, 1991. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.293374.

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2

Paramasivam, Indrani. "Alkyne cycloaddition reactions." Thesis, Imperial College London, 1990. http://hdl.handle.net/10044/1/46486.

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3

Moore, Jane Elizabeth. "Cycloaddition reactions of alkynylboronates." Thesis, University of Sheffield, 2005. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.420776.

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4

Ghose, S. "Cycloaddition reactions of nitroalkenes." Thesis, University of Liverpool, 1988. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.384381.

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5

Bragdon, Jason Paul. "Metal-Catalyzed Cycloaddition Reactions." The Ohio State University, 2009. http://rave.ohiolink.edu/etdc/view?acc_num=osu1244575259.

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6

姚大源 and Tai-yuen Yue. "Cycloaddition reactions of 2-vinylchromones." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 1992. http://hub.hku.hk/bib/B31210661.

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7

Leslie, Morag Garden. "Cycloaddition reactions of jojoba oil." Thesis, University of Edinburgh, 1990. http://hdl.handle.net/1842/12407.

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The cycloaddition reactions of nitrile oxides with jojoba oil have been investigated. The nitrile oxides were generated <i>in situ</i> by two principal routes: (i) by the base catalysed dehydration of nitromethyl compounds using tolylene-2,4-diisocyanate (the Mukaiyama method), and (ii) by thermolysis of nitro-acetate and -malonate esters (the Shimizu method). In order to faciliate the identification of modified jojoba products and establish optimum conditions for reaction with the unsaturation present in jojoba oil, the cycloaddition reactions of nitrile oxides with selected model alkenes wer
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8

Shengxian, Zhao. "Cycloaddition reactions of meso-tetraarylporphyrins." Doctoral thesis, Universidade de Aveiro, 2005. http://hdl.handle.net/10773/4871.

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Doutoramento em Química<br>O trabalho apresentado nesta dissertação descreve o comportamento de meso-tetra-arilporfirinas em reacções de ciclo-adição e suas possíveis aplicações na síntese de novas porfirinas com grupos policíclicos aromáticos (“π-extended porphyrins”). No capítulo 1 apresenta-se uma revisão das aplicações de porfirinas e compostos afins e também das reacções de ciclo-adição que envolvem ligações duplas (periféricas) do macrociclo. O capítulo 2 descreve o trabalho feito em reacções de cicloadição 1,3-dipolar de meso-tetra-arilporfirinas com iletos de azometino. Considerou-s
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9

Braunton, Alan James. "Tethered cycloaddition reactions for heterocycle synthesis." Thesis, Imperial College London, 2004. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.407915.

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10

Heaney, Mary Frances Teresa. "Cycloaddition reactions of oximes and imines." Thesis, Queen's University Belfast, 1990. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.335415.

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11

Davies, Mark William. "Application of alkynylboronates in cycloaddition reactions." Thesis, University of Sheffield, 2001. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.247171.

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12

Martin, Jason Neil. "Chiral imidazoline nitrones for cycloaddition reactions." Thesis, Open University, 2000. http://oro.open.ac.uk/58065/.

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Previous work in this group has demonstrated that azomethine ylide 1,3-dipoles based on the 2-imidazoline chiral template show high regio- and enantioselectivity in their 1,3-dipolar cycloaddition reactions with a range of dipolarophiles. We proposed to synthesise nitrone 1,3-dipoles based on this 2-imidazoline template in order to investigate their utility in 1,3-dipolar cycloaddition chemistry. We have developed the synthesis of chiral 4-phenyl-2-imidazoline nitrones 126a-c via a key hydroxylamino amine dihydrochloride intermediate 140a, available in four steps (61% overall yield) from comme
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13

Dunn, Peter James. "The cycloaddition reactions of sulphur nitrides." Thesis, Imperial College London, 1987. http://hdl.handle.net/10044/1/38294.

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14

Henderson, Deirdre. "Cyclisations and cycloaddition reactions of azomethine ylides." Thesis, Queen's University Belfast, 1992. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.482775.

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15

Henderson, A. J. "Studies towards solid-phase nitrone cycloaddition reactions." Thesis, University of Cambridge, 1999. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.603957.

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The work outlined in this thesis is directed towards the use of resin-bound nitrones in 1,3-dipolar cycloaddition reactions towards the synthesis of heterocyclic compounds. Chapter one provides a brief introduction of a solid-phase synthesis, highlighting some key elements within the technique. A detailed review of solid-phase 1,3-dipolar cycloaddition reactions follows this. Chapter two describes the solution-phase model studies carried out towards an intramolecular 1,3-dipolar cycloaddition on a solid support. Interesting developments such as the effect of the nitrone substituent R on the cy
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16

Grainger, Richard Sheridan. "Cycloaddition reactions of C2-symmetric vinyl sulfoxides." Thesis, University of Sheffield, 1996. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.387754.

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17

Twin, Heather Clare. "Multi component and cycloaddition reactions of methyleneaziridines." Thesis, University of Exeter, 2002. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.246381.

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18

Williams, Anthony. "The crisscross cycloaddition reactions of aryl azines." Thesis, Open University, 1992. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.259488.

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19

Shipman, Michael. "Novel intramolecular transition metal catalysed cycloaddition reactions." Thesis, Imperial College London, 1990. http://hdl.handle.net/10044/1/46551.

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20

Fox, Martin Edward. "Intramolecular cycloaddition reactions of nitrones and hydroxylamines." Thesis, University of Cambridge, 1992. https://www.repository.cam.ac.uk/handle/1810/272243.

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21

Wan, Honghe. "Allenes and (2+2+1) cycloaddition reactions." Morgantown, W. Va. : [West Virginia University Libraries], 1998. http://etd.wvu.edu/templates/showETD.cfm?recnum=195.

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Thesis (M.S.)--West Virginia University, 1998.<br>Title from document title page. Document formatted into pages; contains xii, 99 p. : ill. Includes abstract. Includes bibliographical references (p. 93-99).
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22

Lu, Yafan. "(4+3) cycloadditions and tandem (4+3) cycloaddition/nucleophilic trapping reactions of propargylic diether dicobalt complexes via sequential Nicholas reactions." Thesis, National Library of Canada = Bibliothèque nationale du Canada, 2001. http://www.collectionscanada.ca/obj/s4/f2/dsk3/ftp04/MQ62246.pdf.

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23

Ma, Jihai. "Mono(trimethylsilyl) bisketenes, cycloaddition and electrophilic addition reactions." Thesis, National Library of Canada = Bibliothèque nationale du Canada, 1997. http://www.collectionscanada.ca/obj/s4/f2/dsk2/tape16/PQDD_0016/NQ28003.pdf.

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24

Warnock, William James. "1,3-dipolar cycloaddition reactions of imines and oximes." Thesis, Queen's University Belfast, 1988. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.356974.

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25

Conyers, Ryan C. "An Investigation of Gold(I) Catalyzed Cycloaddition Reactions." Miami University / OhioLINK, 2013. http://rave.ohiolink.edu/etdc/view?acc_num=miami1366197923.

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26

Lee, Sang Won. "Cycloaddition reactions of organic molecules on GE(100) /." free to MU campus, to others for purchase, 2001. http://wwwlib.umi.com/cr/mo/fullcit?p3012995.

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27

Wren, S. A. C. "Cycloadditions of heterocyclic sulphinylamines." Thesis, University of York, 1986. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.377290.

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28

Linaza, Sabin. "Catalytic properties of antibodies in [4+2] cycloaddition." Thesis, University of Strathclyde, 2000. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.248702.

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29

Chumachenko, Natasha. "[Beta]-acryloyloxysulfonyl tethers for intramolecular Diels-Alder cycloaddition reactions." [Kent, Ohio] : Kent State University, 2005. http://rave.ohiolink.edu/etdc/view?acc%5Fnum=kent1135392557.

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Thesis (Ph.D.)--Kent State University, 2005.<br>Title from PDF t.p. (viewed July 28, 2005). Author's first name appears on the abstract page as: Nataliya. Advisor: Paul Sampson. Keywords: b-hydroxysulfones; [beta]-hydroxysulfones; epoxide opening; intramolecular Diels-Alder reaction; vinylsulfones. Includes bibliographical references (p.194- 202).
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30

Lavers, Jodi Anne. "Synthesis of taxoid analogues via tether controlled cycloaddition reactions." Thesis, University of Ottawa (Canada), 1997. http://hdl.handle.net/10393/4109.

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The syntheses of potential Taxol$\sp\circler$ analogues 35 and 57-b are described. The route selected employed a planar group (aromatic ring or a double bond) in the tether to facilitate the key step, an intramolecular Diels-Alder reaction. This approach afforded the tricyclic core of 35 in an efficient and direct manner. The Diels-Alder precursor 33 was synthesized from 3-methylbenzyl alcohol, acrolein, and (Z)-1-iodo-2-p-methoxybenzyloxymethyl-1,3-butadiene (15). The cyclization of alcohol 33 proceeded readily under oxidative conditions at room temperature to afford the cis-fused ring system
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31

Lavers, Jodi A. "Synthesis of taxoid analogues via tether controlled cycloaddition reactions." Thesis, National Library of Canada = Bibliothèque nationale du Canada, 1997. http://www.collectionscanada.ca/obj/s4/f2/dsk3/ftp04/mq20928.pdf.

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32

Pohlhaus, Patrick Dennis Johnson Jeffrey Scott. "Lewis acid-promoted cycloaddition reactions of aziridines and cyclopropanes." Chapel Hill, N.C. : University of North Carolina at Chapel Hill, 2006. http://dc.lib.unc.edu/u?/etd,379.

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Thesis (Ph. D.)--University of North Carolina at Chapel Hill, 2006.<br>Title from electronic title page (viewed Oct. 10, 2007). "... in partial fulfillment of the requirements for the degree of Doctor of Philosophy in the Department of Chemistry." Discipline: Chemistry; Department/School: Chemistry.
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33

Stones, James Alexander. "[4+2] cycloaddition reactions of conformationally restricted tethered trienes." Thesis, Imperial College London, 1996. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.338511.

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34

Tucker, Toby Terence. "The preparation and cycloaddition reactions of chiral carbonyl ylides." Thesis, University of Oxford, 1999. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.299467.

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35

Lo, Tsz-kiu Brian, and 盧子翹. "Intermolecular [4+3] cycloaddition reactions using epoxy enol silanes." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 2011. http://hub.hku.hk/bib/B45877749.

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36

Montana, John Gary. "The synthesis of novel prostaglandin analogues via cycloaddition reactions." Thesis, University of East Anglia, 1989. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.237077.

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37

Millington, Emma Louise. "Complex pyrrolidines via metal catalysed 1,3-dipolar cycloaddition reactions." Thesis, University of Leeds, 2003. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.400169.

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38

Cosstick, Kevin. "Regio- and stereochemical aspects of arene-ethene cycloaddition reactions." Thesis, University of Reading, 1990. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.258238.

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39

Prévost, Natacha. "Radical, alkylation and cycloaddition reactions of a 2-alkylideneaziridines." Thesis, University of Exeter, 2003. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.273005.

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40

Lu, Jun. "The total synthesis of C-glycosides by cycloaddition reactions." Scholarly Commons, 2002. https://scholarlycommons.pacific.edu/uop_etds/2709.

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C-glycosides play important roles in biological processes. Synthetic efforts to prepare carbohydrate mimetics—C-glycosides were undertaken. This thesis introduces the total syntheses of C-glycosides by starting with two cycloaddition reactions. The [4+2] reaction of 1,3-pentadiene with glyoxylic acid and subsequent reactions afforded five C-pyranosides. The [4+3] cycloaddition of furan and pentachloroacetone and subsequent reactions provided C-furanosides and C-pyranosides. A new type of C-disaccharide mimetic coupled by an amide bond was synthesized. This thesis describes how bromolactonizati
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41

Allart, Eric A. "Metal-promoted [3+2] and [4+2] cycloaddition reactions." Thesis, Loughborough University, 2008. https://dspace.lboro.ac.uk/2134/33615.

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Dicobalt complexes have been extensively used in synthetic chemistry to protect triple bonds, to form new carbon/carbon bonds using the Nicholas reaction and to form polycyclic molecules using the Pauson-Khand reaction. Using these dicobalt complexes, the formation of new carbon-heteroatom bonds was developed through [3+2] and [4+2] cycloaddition reactions via a stabilised dipole intermediate. Initial work carried out makes use of cyclopropanes substituted with a metal-alkyne complex towards the synthesis of tetrahydrofurans and pyrrolidines in good yields and with acceptable diastereoselectiv
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42

Chumachenko, Nataliya. "b-Acryloyloxysulfonyl Tethers for Intramolecular Diels-Alder Cycloaddition Reactions." Kent State University / OhioLINK, 2005. http://rave.ohiolink.edu/etdc/view?acc_num=kent1135392557.

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43

Carter, Kevin William. "Methodological and synthetic studies of [4+3] cycloaddition reactions /." free to MU campus, to others for purchase, 1997. http://wwwlib.umi.com/cr/mo/fullcit?p9842583.

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44

Sanders, Shanina Devondia Brookhart Maurice S. "Lewis acid-catalyzed cycloaddition reactions of donor-acceptor cyclopropanes." Chapel Hill, N.C. : University of North Carolina at Chapel Hill, 2009. http://dc.lib.unc.edu/u?/etd,2534.

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Thesis (Ph. D.)--University of North Carolina at Chapel Hill, 2009.<br>Title from electronic title page (viewed Oct. 5, 2009). "... in partial fulfillment of the requirements for the degree of Doctor of Philosophy in the Department of Chemistry." Discipline: Chemistry; Department/School: Chemistry.
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45

Bachollet, Sylvestre. "Regiocontrolled routes to substituted pyridines via directed cycloaddition reactions." Thesis, University of Sheffield, 2016. http://etheses.whiterose.ac.uk/15887/.

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New strategies have been investigated for the synthesis of highly substituted pyridine rings via inverse electron demand aza-Diels-Alder reactions of 1,2,4-triazines with alkynes. The synthesis of pyridines via cycloaddition/retro-cycloaddition strategies has largely focused on the use of enamine dienophiles as alkyne surrogates, as alkynes themselves only participate in [4+2] cycloadditions with triazines under very harsh conditions. Moreover, such processes usually provide the products in low yields and regioselectivities. To tackle these drawbacks, we were interested in a directed cycloaddi
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46

Markson, A. "The use of 8-oxabicyclo(3.2.1.)octenones in the synthesis of natural product analogues." Thesis, University of Reading, 1988. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.233152.

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47

Moss, William Osburn. "Novel amino acid synthons based on ketene thioacetals." Thesis, University of Bath, 1990. https://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.253997.

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48

Leftwich, Timothy Ray. "Modification of silicon-based substrates with cyclocondensation and cycloaddition reactions." Access to citation, abstract and download form provided by ProQuest Information and Learning Company; downloadable PDF file, 111 p, 2010. http://proquest.umi.com/pqdweb?did=1992491831&sid=7&Fmt=2&clientId=8331&RQT=309&VName=PQD.

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49

Katkova, Olga. "Photochemical isomerization and stereoselective thermal cycloaddition reactions of conjugated nitrones." Connect to this title online, 2005. http://rave.ohiolink.edu/etdc/view?acc%5Fnum=bgsu1123003688.

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50

Haraburda, Ewelina. "[2+2+2] cycloaddition reactions involving allenes catalysed by rhodium." Doctoral thesis, Universitat de Girona, 2015. http://hdl.handle.net/10803/328439.

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The development of new chemical processes for the formation of carbon-carbon bonds is an important topic in organic chemistry. In particular, the transition metal catalysed [2+2+2] cycloaddition reaction is a highly efficient synthetic tool that allows six-membered polysubstituted carbo- and heterocyclic derivatives to be obtained in an atom economy process. Allenes are versatile substrates for cycloaddition reactions that provide a good reactivity profile together with the ability to increase the stereochemical complexity of the cycloadducts obtained. This doctoral thesis, divided into seven
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