Academic literature on the topic 'Cyclodehydration'

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Journal articles on the topic "Cyclodehydration"

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Sun, Yufeng, Yatao Huang, Minmin Li, Jia Lu, Nuo Jin, and Bei Fan. "Synthesis of cyclic ethers by cyclodehydration of 1, n -diols using heteropoly acids as catalysts." Royal Society Open Science 5, no. 9 (September 2018): 180740. http://dx.doi.org/10.1098/rsos.180740.

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Heteropoly acids were used as catalysts for cyclodehydration of various 1, n -diols. Cyclodehydration of butane-1,4-diol, pentane-1,5-diol and hexane-1,6-diol catalysed by H 3 PW 12 O 40 gave tetrahydrofuran, tetrahydropyran and oxepane, respectively. Cyclodehydration of diethylene glycol, triethylene glycol, diethylene glycol monomethyl ether and polyethylene glycol 200 catalysed by H 3 PW 12 O 40 gave 1,4-dioxane. In particular, cyclodehydration of hexane-1,6-diol gave an excellent yield of oxepane (80%). The selectivity exhibited by the H 3 PW 12 O 40 catalyst was even better than that exhibited by other reported catalyst systems for similar cyclodehydration reactions.
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Ausekle, E., A. Priksane, and A. Zicmanis. "Cyclodehydration of Diols in Acidic Ionic Liquids." Latvian Journal of Chemistry 50, no. 1-2 (January 1, 2011): 139–44. http://dx.doi.org/10.2478/v10161-011-0059-3.

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Cyclodehydration of Diols in Acidic Ionic Liquids In the presence of sulfonic acid group functionalized Bronsted-acidic ionic liquids, cyclodehydration of 1,2-ethanediol and 1,4-butanediol is investigated. The role of structure and catalytic activity of ionic liquids on the formation of cyclic ethers: 1,4-dioxane and tetrahydrofuran - is determined.
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Costa, A., and J. M. Riego. "AlPO4-Al2O3Promoted Cyclodehydration of Diols." Synthetic Communications 17, no. 11 (August 1987): 1373–76. http://dx.doi.org/10.1080/00397918708057759.

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Kelly, Brendan D., and Tristan H. Lambert. "Cyclopropenium-Activated Cyclodehydration of Diols." Organic Letters 13, no. 4 (February 18, 2011): 740–43. http://dx.doi.org/10.1021/ol102980t.

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Wali, Anil, and S. Muthukumaru Pillai. "Cyclodehydration of Some 1,n-Diols Catalysed by Sulfated Zirconia." Journal of Chemical Research 23, no. 5 (May 1999): 326–27. http://dx.doi.org/10.1177/174751989902300515.

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Gruber, Nadia, Jimena E. Díaz, and Liliana R. Orelli. "Synthesis of dihydroquinazolines from 2-aminobenzylamine: N 3 -aryl derivatives with electron-withdrawing groups." Beilstein Journal of Organic Chemistry 14 (September 26, 2018): 2510–19. http://dx.doi.org/10.3762/bjoc.14.227.

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The sequential N-functionalization of 2-aminobenzylamine (2-ABA) followed by cyclodehydration allowed for a straightforward and efficient synthesis of 3,4-dihydroquinazolines with N-aryl substituents bearing electron-withdrawing groups. The sequence involves an initial SNAr displacement, N-acylation and MW-assisted ring closure. Remarkably, the uncatalyzed N-arylation of 2-ABA led to the monosubstitution product using equimolar amounts of both reagents. The individual steps were optimized achieving good to excellent overall yields of the desired heterocycles, avoiding additional protection and deprotection steps. A mechanistic interpretation for the cyclodehydration reaction promoted by trimethylsilyl polyphosphate (PPSE) is also proposed on the basis of literature data and our experimental observations.
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Morris, Joel, Donn G. Wishka, and Yue Fang. "A Cyclodehydration Route to 2-Aminochromones." Synthetic Communications 24, no. 6 (March 1994): 849–58. http://dx.doi.org/10.1080/00397919408011307.

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Chan, Hardy Sze On, and J. R. Lusty. "Acid-Catalyzed Cyclodehydration of Quinazolone Prepolymers." Journal of Macromolecular Science, Part A 23, no. 9 (September 1, 1986): 1057–78. http://dx.doi.org/10.1080/00222338608081112.

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Ivanov, Daniela, and Mircea Constantinescu. "Computational study of maleamic acid cyclodehydration." Journal of Physical Organic Chemistry 16, no. 6 (2003): 348–54. http://dx.doi.org/10.1002/poc.639.

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Bagley, Mark C., Christian Glover, and Duncan Chevis. "Iodine-Catalysed Bohlmann-Rahtz Cyclodehydration Reactions." Synlett, no. 4 (2005): 649–51. http://dx.doi.org/10.1055/s-2005-863712.

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Dissertations / Theses on the topic "Cyclodehydration"

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Haelters, Jean-Pierre. "Synthèse de dérivés phosphono-indoliques-benzofuranniques et -pyrroliques à partir d'hydrazones phosphonates." Brest, 1987. http://www.theses.fr/1987BRES2002.

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Des derives phosphonoindoliques sont prepares par cyclisation d'arylhydrazones d'oxoalkylphosphonates selon fisher et par cyclodeshydratation d'arylamino-1 et arylamino-3 oxo-2 propylphosphonates selon bischler. Des indolyl-2 et indolyl-3 phosphonates, des indolylmethyl-2 et des indolylmethyl-3 phosphonates diversement substitues et leurs acides phosphoniques correspondants sont decrits. Toutes structures sont analysees par rmn **(1)h, **(31)p et 1**(3)c. L'analogue phosphore de l'intermediaire a aussi ete prepare. L'extention de la reaction de bischler aux aryloxycetones permet d'atteindre des benzofuryl-2 phosphonate et de benzofurylmethyl-3 phosphonates. Deux nouveaux reactifs sont utilises pour acceder aux arylaminocetones et aux aryloxycetones : les chloro-1 et chloro-3 methoxycarbonylhydrazono-2 propyl-phosphonates de diethyle, composes qui, traites en milieu basique, donnent des azoenes qui additionnent les anilines et les phenols. Ces azoenes additionnent aussi les carbanions, notamment les carbanions derives de cetones pour conduire, apres hydrolyse soit a des derives du pyrrole, soit a des dioxy-2, -5-alkylphosphonates precurseurs de cyclopentenones selon wittig-horner
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Book chapters on the topic "Cyclodehydration"

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Rasmussen, Jerald K., Larry R. Krepski, Steven M. Heilmann, Kumars Sakizadeh, Dean M. Moren, Howell K. Smith, and Alan R. Katritzky. "Polyimidazolinones via Thermal Cyclodehydration of Polyamides Containing α-Amino Acid Units." In ACS Symposium Series, 119–26. Washington, DC: American Chemical Society, 1988. http://dx.doi.org/10.1021/bk-1988-0364.ch009.

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Toyota, S., and T. Iwanaga. "Thermal Cyclodehydration." In Monocyclic Arenes, Quasiarenes, and Annulenes, 1. Georg Thieme Verlag KG, 2010. http://dx.doi.org/10.1055/sos-sd-045-00850.

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Meigh, J. P. K. "By Bischler–Napieralski Cyclodehydration." In Six-Membered Hetarenes with Two Unlike or More than Two Heteroatoms and Fully Unsaturated Larger-Ring Heterocycles, 1. Georg Thieme Verlag KG, 2004. http://dx.doi.org/10.1055/sos-sd-017-01360.

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Murphy, P. J. "By Cyclodehydration of Ketones." In Fused Five-Membered Hetarenes with One Heteroatom, 1. Georg Thieme Verlag KG, 2001. http://dx.doi.org/10.1055/sos-sd-010-00369.

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Meigh, J. P. K. "Reduction–Cyclodehydration of 2-(2-Nitrophenyl)benzophenones." In Six-Membered Hetarenes with Two Unlike or More than Two Heteroatoms and Fully Unsaturated Larger-Ring Heterocycles, 1. Georg Thieme Verlag KG, 2004. http://dx.doi.org/10.1055/sos-sd-017-01358.

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Camp, J. E. "By Bischler–Napieralski Cyclodehydration of -(2-Benzylphenyl)-2-chloroacetamide." In Six-Membered Hetarenes with Two Unlike or More than Two Heteroatoms and Fully Unsaturated Larger-Ring Heterocycles, 1. Georg Thieme Verlag KG, 2012. http://dx.doi.org/10.1055/sos-sd-117-00098.

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Khartulyari, A., and M. E. Maier. "Method 1: Cyclodehydration of α-Acylamino Aldehydes or Ketones." In Science of Synthesis Knowledge Updates KU 2011/1, 1. Georg Thieme Verlag KG, 2010. http://dx.doi.org/10.1055/sos-sd-111-00504.

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Koutentis, P. A., and H. A. Ioannidou. "Cyclodehydration of -(2-Oxoalkyl) Thioesters in the Presence of Ammonium Acetate." In Science of Synthesis Knowledge Updates KU 2010/4, 1. Georg Thieme Verlag KG, 2010. http://dx.doi.org/10.1055/sos-sd-111-00173.

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Conference papers on the topic "Cyclodehydration"

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Popovici, Dumitru. "COMPUTATIONAL STUDY OF CYCLODEHYDRATION OF BICYCLO[2.2.2]OCT-7-ENE-2,3,5,6-TETRACARBOXYLIC DIANHYDRIDE BASE AMIDIC ACID." In 15th International Multidisciplinary Scientific GeoConference SGEM2015. Stef92 Technology, 2015. http://dx.doi.org/10.5593/sgem2015/b61/s24.005.

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