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Journal articles on the topic 'Cyclodehydration'

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1

Sun, Yufeng, Yatao Huang, Minmin Li, Jia Lu, Nuo Jin, and Bei Fan. "Synthesis of cyclic ethers by cyclodehydration of 1, n -diols using heteropoly acids as catalysts." Royal Society Open Science 5, no. 9 (September 2018): 180740. http://dx.doi.org/10.1098/rsos.180740.

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Heteropoly acids were used as catalysts for cyclodehydration of various 1, n -diols. Cyclodehydration of butane-1,4-diol, pentane-1,5-diol and hexane-1,6-diol catalysed by H 3 PW 12 O 40 gave tetrahydrofuran, tetrahydropyran and oxepane, respectively. Cyclodehydration of diethylene glycol, triethylene glycol, diethylene glycol monomethyl ether and polyethylene glycol 200 catalysed by H 3 PW 12 O 40 gave 1,4-dioxane. In particular, cyclodehydration of hexane-1,6-diol gave an excellent yield of oxepane (80%). The selectivity exhibited by the H 3 PW 12 O 40 catalyst was even better than that exhibited by other reported catalyst systems for similar cyclodehydration reactions.
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2

Ausekle, E., A. Priksane, and A. Zicmanis. "Cyclodehydration of Diols in Acidic Ionic Liquids." Latvian Journal of Chemistry 50, no. 1-2 (January 1, 2011): 139–44. http://dx.doi.org/10.2478/v10161-011-0059-3.

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Cyclodehydration of Diols in Acidic Ionic Liquids In the presence of sulfonic acid group functionalized Bronsted-acidic ionic liquids, cyclodehydration of 1,2-ethanediol and 1,4-butanediol is investigated. The role of structure and catalytic activity of ionic liquids on the formation of cyclic ethers: 1,4-dioxane and tetrahydrofuran - is determined.
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3

Costa, A., and J. M. Riego. "AlPO4-Al2O3Promoted Cyclodehydration of Diols." Synthetic Communications 17, no. 11 (August 1987): 1373–76. http://dx.doi.org/10.1080/00397918708057759.

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4

Kelly, Brendan D., and Tristan H. Lambert. "Cyclopropenium-Activated Cyclodehydration of Diols." Organic Letters 13, no. 4 (February 18, 2011): 740–43. http://dx.doi.org/10.1021/ol102980t.

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5

Wali, Anil, and S. Muthukumaru Pillai. "Cyclodehydration of Some 1,n-Diols Catalysed by Sulfated Zirconia." Journal of Chemical Research 23, no. 5 (May 1999): 326–27. http://dx.doi.org/10.1177/174751989902300515.

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6

Gruber, Nadia, Jimena E. Díaz, and Liliana R. Orelli. "Synthesis of dihydroquinazolines from 2-aminobenzylamine: N 3 -aryl derivatives with electron-withdrawing groups." Beilstein Journal of Organic Chemistry 14 (September 26, 2018): 2510–19. http://dx.doi.org/10.3762/bjoc.14.227.

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The sequential N-functionalization of 2-aminobenzylamine (2-ABA) followed by cyclodehydration allowed for a straightforward and efficient synthesis of 3,4-dihydroquinazolines with N-aryl substituents bearing electron-withdrawing groups. The sequence involves an initial SNAr displacement, N-acylation and MW-assisted ring closure. Remarkably, the uncatalyzed N-arylation of 2-ABA led to the monosubstitution product using equimolar amounts of both reagents. The individual steps were optimized achieving good to excellent overall yields of the desired heterocycles, avoiding additional protection and deprotection steps. A mechanistic interpretation for the cyclodehydration reaction promoted by trimethylsilyl polyphosphate (PPSE) is also proposed on the basis of literature data and our experimental observations.
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7

Morris, Joel, Donn G. Wishka, and Yue Fang. "A Cyclodehydration Route to 2-Aminochromones." Synthetic Communications 24, no. 6 (March 1994): 849–58. http://dx.doi.org/10.1080/00397919408011307.

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8

Chan, Hardy Sze On, and J. R. Lusty. "Acid-Catalyzed Cyclodehydration of Quinazolone Prepolymers." Journal of Macromolecular Science, Part A 23, no. 9 (September 1, 1986): 1057–78. http://dx.doi.org/10.1080/00222338608081112.

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9

Ivanov, Daniela, and Mircea Constantinescu. "Computational study of maleamic acid cyclodehydration." Journal of Physical Organic Chemistry 16, no. 6 (2003): 348–54. http://dx.doi.org/10.1002/poc.639.

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10

Bagley, Mark C., Christian Glover, and Duncan Chevis. "Iodine-Catalysed Bohlmann-Rahtz Cyclodehydration Reactions." Synlett, no. 4 (2005): 649–51. http://dx.doi.org/10.1055/s-2005-863712.

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11

ONO, MACHIKO, REIKO TODORIKI, and SHINZO TAMURA. "Preparation and cyclodehydration of .BETA.-arylaminocrotonaldehyde." CHEMICAL & PHARMACEUTICAL BULLETIN 34, no. 2 (1986): 463–70. http://dx.doi.org/10.1248/cpb.34.463.

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12

Kwon, Yongseok, Junqi Li, Jolene P. Reid, Jennifer M. Crawford, Roxane Jacob, Matthew S. Sigman, F. Dean Toste, and Scott J. Miller. "Disparate Catalytic Scaffolds for Atroposelective Cyclodehydration." Journal of the American Chemical Society 141, no. 16 (March 28, 2019): 6698–705. http://dx.doi.org/10.1021/jacs.9b01911.

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13

Bezouhanova, C. P., and F. A. Jabur. "Selective cyclodehydration of diols on zeolites." Reaction Kinetics & Catalysis Letters 51, no. 1 (November 1993): 177–81. http://dx.doi.org/10.1007/bf02062493.

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14

Ho, Tse-Lok, Wen-Lung Yeh, John Yule, and Hsing-Jang Liu. "Diels–Alder approach to (±)-longifolene: A formal synthesis." Canadian Journal of Chemistry 70, no. 5 (May 1, 1992): 1375–84. http://dx.doi.org/10.1139/v92-176.

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A formal synthesis of longifolene in racemic form is concluded starting from the Diels–Alder reaction of 6,6-di-methylfulvene and maleic anhydride. Key steps are cyclodehydration, conjugate methylation, and ring expansion.
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15

Ji, Xiao-Ming, Shu-Juan Zhou, Chen-Liang Deng, Fan Chen, and Ri-Yuan Tang. "NH4PF6-promoted cyclodehydration of α-amino carbonyl compounds: efficient synthesis of pyrrolo[3,2,1-ij]quinoline and indole derivatives." RSC Adv. 4, no. 96 (2014): 53837–41. http://dx.doi.org/10.1039/c4ra11168k.

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16

Chen, Zitao, Xiaoyan Wang, Wanfang Lu, and Jian Yu. "Facile Cyclodehydration of α-Aryloxyketones with Zeolites." Synlett 1991, no. 02 (1991): 121–22. http://dx.doi.org/10.1055/s-1991-20651.

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17

Niyogi, Sobhan, Sukumar Maiti, and Basudam Adhikari. "Cyclodehydration of Poly (amic acid) to Polyimide." International Journal of Polymeric Materials 49, no. 3 (May 2001): 323–30. http://dx.doi.org/10.1080/00914030108039783.

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18

Kelly, Brendan D., and Tristan H. Lambert. "ChemInform Abstract: Cyclopropenium-Activated Cyclodehydration of Diols." ChemInform 42, no. 22 (May 5, 2011): no. http://dx.doi.org/10.1002/chin.201122090.

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19

Andrew Hedley, K., and Stephen P. Stanforth. "Cyclodehydration ofN-(2-nitroaryl)-1,2,3,4-tetrahydroisoquinoline derivatives." Journal of Heterocyclic Chemistry 32, no. 2 (March 1995): 529–30. http://dx.doi.org/10.1002/jhet.5570320226.

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20

Onorato, Amber, Christopher Pavlik, Michael A. Invernale, Ian D. Berghorn, Gregory A. Sotzing, Martha D. Morton, and Michael B. Smith. "Polymer-mediated cyclodehydration of alditols and ketohexoses." Carbohydrate Research 346, no. 13 (September 2011): 1662–70. http://dx.doi.org/10.1016/j.carres.2011.04.017.

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21

Likhatchev, D., L. Valle, M. Canseco, R. Salcedo, R. Gaviño, A. Martinez-Richa, L. Alexandrova, and R. Vera-Graziano. "Spontaneous cyclodehydration ofN-(o-aminophenyl) amic acids." Journal of Applied Polymer Science 67, no. 4 (January 24, 1998): 609–19. http://dx.doi.org/10.1002/(sici)1097-4628(19980124)67:4<609::aid-app3>3.0.co;2-c.

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22

Kudelko, Agnieszka, Anna Kędzia, and Karolina Jasiak. "An Efficient Synthesis of New 2-Aryl-5-phenylazenyl-1,3,4-oxadiazole Derivatives from N,N'-Diarylcarbonohydrazides." Synlett 29, no. 13 (June 19, 2018): 1745–48. http://dx.doi.org/10.1055/s-0037-1610105.

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A series of new 1,3,4-oxadiazoles conjugated to aromatic substituents by an azo linker was synthesized in a four-step reaction sequence, involving cyclodehydration of a N,N'-diacylhydrazine fragment and dehydrogenation of the neighboring hydrazine fragment of the intermediate N,N'-diarylcarbonohydrazide.
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23

Yang, Sai, Liu-lan Shen, Yoon-Jung Kim, and Jin-Hyun Jeong. "Effective and novel enantioselective preparation of pyranopyrazoles and pyranocoumarins that is catalyzed by a quinine-derived primary amine." Organic & Biomolecular Chemistry 14, no. 2 (2016): 623–30. http://dx.doi.org/10.1039/c5ob01656h.

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In this study, we executed an effective and novel enantioselective Michael/cyclodehydration sequential reaction between pyrazolin-5-one (or 4-hydroxy-2-pyrone) and chalcones that is catalyzed by a quinine-derived primary amine L7 in the presence of Boc-d-Phg-OH.
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24

Veeraraghavan Ramachandran, P., and Barnabas Otoo. "Facile synthesis of 1-trifluoromethylalkenes via the decarboxylation of α-trifluoromethyl-β-lactones." Chemical Communications 51, no. 62 (2015): 12388–90. http://dx.doi.org/10.1039/c5cc03230j.

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DCC-mediated cyclodehydration of α-trifluoromethyl-β-hydroxy acids provides α-trifluoromethylated β-lactone intermediates, without loss of stereoselectivity. These lactones undergo facile decarboxylation providing a simple route to obtain both alkyl and aryl 1-trifluoromethyl alkenes in excellent yields and stereoselectivity.
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25

Wilkerson, Phillip D., Andrew C. Bean, and Chad E. Stephens. "Synthesis of 4H-3-aryl-2-cyano-1,4-benzothiazine 1,1-dioxides for antiviral studies." Heterocyclic Communications 23, no. 2 (April 1, 2017): 101–3. http://dx.doi.org/10.1515/hc-2017-0028.

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Abstract2-Cyano-substituted 1,4-benzothiazine 1,1-dioxides, required for antiviral studies, were prepared by a reductive cyclodehydration of an ortho-nitro sulfone precursor containing a pendant aryl ketone group. The ring-forming reaction also furnishes a non-cyclized benzamide as a major byproduct via an unexpected acyl transfer reaction.
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26

Kelly, Jeffery W., and Slayton A. Evans. "Regioselective phosphoranylation and cyclodehydration of triols with diethoxytriphenylphosphorane." Journal of the American Chemical Society 108, no. 24 (November 1986): 7681–85. http://dx.doi.org/10.1021/ja00284a036.

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27

Kantin, Grigory, Evgeny Chupakhin, Dmitry Dar'in, and Mikhail Krasavin. "Efficient cyclodehydration of dicarboxylic acids with oxalyl chloride." Tetrahedron Letters 58, no. 32 (August 2017): 3160–63. http://dx.doi.org/10.1016/j.tetlet.2017.06.089.

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28

Faisal, Muhammad, Nobuaki Sato, Armando T. Quitain, Hiroyuki Daimon, and Koichi Fujie. "Hydrolysis and Cyclodehydration of Dipeptide under Hydrothermal Conditions." Industrial & Engineering Chemistry Research 44, no. 15 (July 2005): 5472–77. http://dx.doi.org/10.1021/ie0500568.

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29

Sun, Qi, Run-Tao Li, Shuo Zhao, You Wu, and Tie-Ming Cheng. "Triphenylphosphine–N-Bromosuccinimide Mediated Chemoselective Cyclodehydration of Diols." Synthesis 47, no. 08 (February 10, 2015): 1154–62. http://dx.doi.org/10.1055/s-0034-1380132.

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30

Gebben, B., M. H. V. Mulder, and C. A. Smolders. "The kinetics of the cyclodehydration reaction of polyhydrazides." Makromolekulare Chemie. Macromolecular Symposia 20-21, no. 1 (July 1988): 37–48. http://dx.doi.org/10.1002/masy.19880200109.

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31

Patel, Jagdish M., and Shubhangi S. Soman. "Regioselective cyclodehydration ofortho-hydroxy acetyl aryloxyketones to benzofuran." Journal of Heterocyclic Chemistry 44, no. 4 (July 2007): 945–49. http://dx.doi.org/10.1002/jhet.5570440434.

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32

MORRIS, J., D. G. WISHKA, and Y. FANG. "ChemInform Abstract: A Cyclodehydration Route to 2-Aminochromones." ChemInform 25, no. 47 (August 18, 2010): no. http://dx.doi.org/10.1002/chin.199447159.

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33

Quek, Xian-Yang, Yejun Guan, Rutger A. van Santen, and Emiel J. M. Hensen. "Ionic-Liquid-Stabilized Rhodium Nanoparticles for Citral Cyclodehydration." ChemSusChem 3, no. 11 (August 30, 2010): 1264–67. http://dx.doi.org/10.1002/cssc.201000188.

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34

Kelly, Jeffery W., and Slayton A. Evans. "Bis(neopentyloxy)triphenylphosphorane: a versatile, nonalkylating cyclodehydration reagent." Journal of Organic Chemistry 51, no. 26 (December 1986): 5490–92. http://dx.doi.org/10.1021/jo00376a103.

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35

Nayak, Maloy, Youngeun Jung, and Ikyon Kim. "Syntheses of pterocarpenes and coumestans via regioselective cyclodehydration." Organic & Biomolecular Chemistry 14, no. 34 (2016): 8074–87. http://dx.doi.org/10.1039/c6ob01451h.

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36

Likhatchev, D., L. Valle, M. Canseco, R. Salcedo, R. Gaviño, A. Martinez-Richa, L. Alexandrova, and R. Vera-Graziano. "Spontaneous cyclodehydration of N-(o-aminophenyl) amic acids." Journal of Applied Polymer Science 67, no. 4 (January 24, 1998): 609–19. http://dx.doi.org/10.1002/(sici)1097-4628(19980124)67:4<609::aid-app3>3.0.co;2-u.

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37

Kurzer, Frederick, and Jayantilal N. Patel. "Diisophorone and Related Compounds, Part 29. 3-Aminodiisophorane Derivatives." Zeitschrift für Naturforschung B 46, no. 4 (April 1, 1991): 530–40. http://dx.doi.org/10.1515/znb-1991-0416.

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3-Aminodiisophor-2(7)-en-1-ol and homologues are obtained from the readily accessible 3-ketones by reduction of their respective ketoximes, and are characterized as suitable derivatives. The 3-(ω-phenylthioureido) compound undergoes cyclodehydration to a substituted 8,11a-methanocycloocta[d,e][3.1]benzthiazine. The structures of the individual compounds are correlated with their assigned 13C NMR spectra.
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38

Francis, Raju, Pallepogu Raghavaiah, and Kuruvilla Pius. "Unusual crystal structure ofN-substituted maleamic acid – very strong effect of intramolecular hydrogen bonds." Acta Crystallographica Section B Structural Science, Crystal Engineering and Materials 70, no. 6 (December 1, 2014): 942–47. http://dx.doi.org/10.1107/s2052520614018952.

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N-Carbamylmaleamic acid (malur) undergoes cyclodehydration under favourable conditions, as expected, to giveN-carbamyl maleimide.N-(Carboxymethyl) maleamic acid (malgly), however, does not undergo a similar cyclization reaction. Strong π bonding between the C and N of the amide group as well as two intramolecular hydrogen bonds makesmalglya planar molecule, as revealed by single-crystal X-ray studies.
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39

Jacobsen, NW, and AE Philippides. "Heterocyclic Variants of the Purine System. III. Derivatives of Oxazolo[5,4-e]-1,2,4-Triazine and Oxazolo[4,5-e]-1,2,4-Triazine, Two New Heterocyclic Ring Systems." Australian Journal of Chemistry 40, no. 5 (1987): 977. http://dx.doi.org/10.1071/ch9870977.

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Representative derivatives of the [5,4-e] and [4,5-e] oxazolo-1,2,4-triazine ring systems were prepared by cyclodehydration of the respective 5-acylaminotriazin-6-ones and 6-acylaminotriazin-5-ones. 5-Methylthio-3-phenyltriazin-6-amine also gave a 6-anilino derivative of the [5,4-e] series when treated with phenyl isocyanate, but the method was not a successful route to the [4,5-e] series.
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40

Loughlin, Wendy A., I. Wayan Muderawan, Michelle A. McCleary, Katie E. Volter, and Malcolm D. King. "Studies Towards the Synthesis of Phorbazoles A - D: Formation of the Pyrrole Oxazole Skeleton." Australian Journal of Chemistry 52, no. 3 (1999): 231. http://dx.doi.org/10.1071/c98169.

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Synthetic approaches towards the synthesis of the pyrrole oxazole skeleton of phorbazoles A–D are described. An efficient synthesis of the pyrrole oxazole skeleton (19) from pyrrole and 4- methoxyacetophenone was developed. In the key step, cyclodehydration of the amide (16) resulted in formation of the diprotected pyrrole oxazole (17). Subsequent deprotection of the diprotected pyrrole oxazole (17) gave the target phorbazole skeleton (19).
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41

Tka, Najeh, Mohamed Adnene Hadj Ayed, Mourad Ben Braiek, Mahjoub Jabli, and Peter Langer. "Synthesis and investigation on optical and electrochemical properties of 2,4-diaryl-9-chloro-5,6,7,8-tetrahydroacridines." Beilstein Journal of Organic Chemistry 17 (September 20, 2021): 2450–61. http://dx.doi.org/10.3762/bjoc.17.162.

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A facile synthesis of 2,4-diaryl-9-chloro-5,6,7,8-tetrahydroacridine derivatives is reported which is based on POCl3-mediated cyclodehydration followed by double Suzuki–Miyaura cross-coupling. The absorption and fluorescence properties of the obtained products were investigated and their HOMO/LUMO energy levels were estimated by cyclic voltammetry measurements. Besides, density functional theory calculations were carried out for further exploration of their electronic properties.
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42

Weissman, Steven A., Kai Rossen, and Paul J. Reider. "Stereoselective Synthesis of Styrene Oxides via a Mitsunobu Cyclodehydration." Organic Letters 7, no. 13 (June 2005): 2803. http://dx.doi.org/10.1021/ol051014i.

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43

Gamedze, Makhosazana P., and Comfort M. Nkambule. "Dibutyltin oxide mediated diastereoselective cyclodehydration/sulfonylation of 1,2,4-triols." Tetrahedron Letters 56, no. 14 (April 2015): 1825–29. http://dx.doi.org/10.1016/j.tetlet.2015.02.083.

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44

Filippi, Jean-Jacques, Elisabet Duñach, Xavier Fernandez, and Uwe J. Meierhenrich. "Stereospecific cyclodehydration of 1,4-sulfanylalcohols to thiolanes: mechanistic insights." Tetrahedron 64, no. 42 (October 2008): 9999–10003. http://dx.doi.org/10.1016/j.tet.2008.07.088.

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45

Klimenkovs, Igors, Eduards Bakis, and Anda Priksane. "Propanephosphonic Acid Anhydride–Mediated Cyclodehydration of Maleic Acid Monoamides." Synthetic Communications 43, no. 19 (June 26, 2013): 2634–40. http://dx.doi.org/10.1080/00397911.2012.727060.

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46

Constantinescu, Mircea, and Daniela Ivanov. "Computational study of maleamic acid cyclodehydration with acetic anhydride." International Journal of Quantum Chemistry 106, no. 6 (2006): 1330–37. http://dx.doi.org/10.1002/qua.20889.

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47

ONO, MACHIKO, REIKO TODORIKI, and SHINZO TAMURA. "A kinetic study of cyclodehydration of .BETA.-arylaminocrotonaldehyde derivatives." CHEMICAL & PHARMACEUTICAL BULLETIN 34, no. 4 (1986): 1468–72. http://dx.doi.org/10.1248/cpb.34.1468.

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48

Weissman, Steven A., Kai Rossen, and Paul J. Reider. "Stereoselective Synthesis of Styrene Oxides via a Mitsunobu Cyclodehydration." Organic Letters 3, no. 16 (August 2001): 2513–15. http://dx.doi.org/10.1021/ol016167u.

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49

Hwang, Soonho, Heemin Park, Yongseok Kwon, and Sanghee Kim. "Acid promoted cyclodehydration of amino alcohols with amide acetal." RSC Adv. 4, no. 104 (2014): 60017–24. http://dx.doi.org/10.1039/c4ra10625c.

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50

Sun, Daolai, Junjie Wang, Yasuhiro Yamada, and Satoshi Sato. "Cyclodehydration of diethylene glycol over Ag-modified Al2O3 catalyst." Applied Catalysis A: General 505 (September 2015): 422–30. http://dx.doi.org/10.1016/j.apcata.2015.03.047.

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