Academic literature on the topic 'Cyclometallates'

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Dissertations / Theses on the topic "Cyclometallates"

1

Chhetri, Satyadeep Singh. "C (Aryl) - H bond activation : isolation, characterization and reactivity of cyclometallates." Thesis, University of North Bengal, 2012. http://hdl.handle.net/123456789/1471.

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2

Tan, Guiping. "Synthesis of new iridium (iii) and platinum (ii) cyclometallates and theiir application in high-efficiency organic light-emitting devices." HKBU Institutional Repository, 2012. https://repository.hkbu.edu.hk/etd_ra/1418.

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3

Neogi, Debatra Narayan. "Cyclometallated compounds: synthesis, characterization and reactivity." Thesis, University of North Bengal, 2005. http://hdl.handle.net/123456789/746.

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4

Slater, Jonathan. "Cyclometallated nitrogen heterocycles - metallomesogens." Thesis, University of Warwick, 2002. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.269196.

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5

de, Geest Duncan J. "Synthesis and study of new cyclometallated complexes." Thesis, University of Canterbury. Chemistry, 1998. http://hdl.handle.net/10092/8523.

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Twenty-nine heteroaromatic ligands, which are potentially capable of forming cyclometallated complexes, have been reacted with palladium and rhodium salts. In addition to a number of mono-cyclometallated complexes, two doubly cyclopalladated complexes have been prepared, as have a number of coordination complexes. Specifically, a number of phenoxy- and phenylthio-substituted pyridines and diazines, four of which could potentially be doubly cyclometallated, have been synthesised, and their coordination and cyclopalladation chemistry investigated. The previously reported reactions of 2-benzoylp
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6

Singh, Shalini. "Luminescent cyclometallated Ir(III) complexes : synthesis, characterisation and applications." Thesis, University of Leicester, 2011. http://hdl.handle.net/2381/9067.

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A range of luminescent Ir(III) complexes [Ir(C^N)2(X^Y)]n+ (n = 0, 1) containing different cyclometallated (C^N) and ancillary (X^Y) ligands has been synthesised. All new compounds were fully characterised by 1H and 13C NMR spectroscopy, mass spectrometry and elemental analyses and several compounds have been structurally characterised by X-ray crystallography. The photophysical and electrochemical properties of the complexes were also studied. Chapter one provides an introduction to luminescent transition metal complexes, in particular Ru(II) and Ir(III) complexes and gives an overview of the
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7

Crosby, Sarah H. "Cyclometallated complexes of platinum : C-H activation, oxidation and reduction." Thesis, University of Warwick, 2011. http://wrap.warwick.ac.uk/55449/.

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Within this thesis, research related to the synthesis of Pt(II) and Pt(IV) cyclometallated complexes involving both aryl and alkyl C-H activation is discussed. The introduction reviews literature relevant to C-H activation, cyclometallation and reductive elimination, both historic and current. Four pyridine based pro-ligands, all with a 4-fluorophenyl substituent and a varying alkyl substituent, were synthesised in order to study both aryl and alkyl C-H activation. Initial reactions with K2PtCl4 led to the cyclometallation of the phenyl ring via a reversible aryl C-H activation, which then res
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8

Al-Duaij, Omar Khalid. "Synthesis and reactivity of cyclometallated complexes containing nitrogen donor ligands." Thesis, University of Leicester, 2005. http://hdl.handle.net/2381/30095.

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This thesis describes the synthesis and reactivity of cyclometallated complexes containing nitrogen donor ligands.;Chapter One introduces the general chemistry of cyclometallated complexes containing C,N-bidentate ligands, then describes the mechanism of cyclometallated complexes. This is followed by an overview of the applications of cyclometallated complexes.;Chapter Two provides an introduction to hemilability and reviews the synthesis of cyclopalladated complexes containing C,N,X tridentate ligands (X= N, S, O). The synthesis of new cyclopalladated imines containing oxygen-functionalised t
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9

Zaarour, Moussa. "Luminescent and NLO active tris- and bis-cyclometallated iridium complexes." Rennes 1, 2012. http://www.theses.fr/2012REN1S110.

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New series of substituted Ir(ppy)3 derivatives incorporating various vinyl-aryl systems with electron-donating groups on their pyridyl rings or donor/acceptor groups on their phenyl rings were synthesized using the so-called technique “chemistry on the complex”. These complexes are luminescent with emission wavelength that is tuned by introducing stronger donating groups or extending the π-system. These complexes present strong NLO properties controlled by the charge transfer transitions (ILCT and MLCT) induced by donor-acceptor interaction within the complex. We have developed the first examp
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10

Contaldi, Simone <1982&gt. "Synthesis and Structures of palladium(II) and platinum(II) complexes containing cyclometallated 2-thienylpyridines." Doctoral thesis, Alma Mater Studiorum - Università di Bologna, 2010. http://amsdottorato.unibo.it/2727/1/contaldi_simone_tesi.pdf.

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