Academic literature on the topic 'Cyclopentane'

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Journal articles on the topic "Cyclopentane"

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Kubozono, Yoshihiro, Makoto Okada, Makoto Aoyagi, et al. "Structure and Reactions of Radicals Derived from Cyclopentane, Cyclopentenes, and Cyclohexenes in Low-Temperature Matrices. An ESR Study." Zeitschrift für Naturforschung A 46, no. 11 (1991): 993–1000. http://dx.doi.org/10.1515/zna-1991-1111.

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AbstractThe radical species derived from cyclopentane, cyclopentenes and cyclohexenes by 60Co γ-ray irradiation at 77 K in halocarbon matrices have been studied by ESR spectroscopy. The electronic and geometrical structures of the radical species are discussed on the basis of the experimental hyperfine coupling constants and semiempirical MO calculations. Exposure of the tetramethylsilane frozen solution containing cyclopentene to 60Co γ-rays produced specifically 3-cyclopenten-l-yl.
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Xu, Li Xin, Chuan Feng Sun, Jie Li, and Guang Yuan Chen. "Gold Catalysts on TiO2-Modified Silica Gel for the Selective Cyclopentane Oxidation to Cyclopentanone." Advanced Materials Research 1094 (March 2015): 76–81. http://dx.doi.org/10.4028/www.scientific.net/amr.1094.76.

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Amorphous silica gel was modified by titania via an impregnation-surface hydrolysis approach and used as the support for preparing gold catalysts through an direct anion exchange method. These supported gold catalysts were characterized by XRD and TEM, and applied for the catalytic cyclopentane oxidation to cyclopentanone using oxygen in the absence of any solvent and initiator. The catalyst with a loading of 0.1wt.% gold and 10wt.% TiO2 exhibited 7.2% cyclopentane conversion and 77.4% selectivities (including cyclopentanone and cyclopentanol) under the reaction conditions of 145°C, 2.0 MPa an
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Guo, Hua Mei, Qian Wu, and Yu Feng Li. "Synthesis and Crystal Structure Studies on 6-Amino-5,5,7-Tricyano-3,3a,4,5-Tetrahydro-2H-Indene-4-Spirocyclopentane." Advanced Materials Research 1025-1026 (September 2014): 717–22. http://dx.doi.org/10.4028/www.scientific.net/amr.1025-1026.717.

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A malononitrile derivative, 6-Amino-5,5,7-tricyano-3,3a,4,5-tetrahydro-2H-indene-4- Spirocyclopentane was synthesized in ethanol with malononitrile and cyclopentanone as raw materials. It was characterized by X-ray single crystal diffraction analysis.The crystal of the title complex belongs to Triclinic, P21/c space group with a=6.4687(13)Å, b=8.9901(18)Å, c=12.004(2)Å, α=93.55(3) deg, β=91.86(3) deg, γ=92.25(3) deg. V=695.8(2)Å3, Z=2, F(000)=278 and final R1=0.0524,WR2=0.1497. X-ray analysis reveals that The cyclohexene ring has a distorted half-chair conformation and the cyclopentene and
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Kotha, Sambasivarao, and Yellaiah Tangella. "Modular Approaches to Cyclopentanoids and their Heteroanalogs." Synlett 31, no. 20 (2020): 1976–2012. http://dx.doi.org/10.1055/a-1288-8240.

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AbstractCyclopentanoids and their derivatives are interesting targets in synthetic organic chemistry due to their extensive applications in various branches of chemical sciences like pharmaceuticals, natural and non-natural products. In view of these applications, several synthetic strategies have been developed in the past three to four decades. In this article, we describe our work towards the synthesis of cyclopentanoids and their heteroanalogs involving diverse synthetic strategies during the past two decades. Among these, photo-thermal olefin metathesis, ring-closing metathesis, ring-rear
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Li, Lin-Qiang, Jian-Qiang Zhao, Yan-Ping Zhang, et al. "Diastereoselective Formal 1,3-Dipolar Cycloaddition of Trifluoroethyl Amine-Derived Ketimines Enables the Desymmetrization of Cyclopentenediones." Molecules 28, no. 14 (2023): 5372. http://dx.doi.org/10.3390/molecules28145372.

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In this research, a metal-free diastereoselective formal 1,3-dipolar cycloaddition of N-2,2,2-trifluoroethylisatin ketimines and cyclopentene-1,3-diones which can efficiently lead to the desymmetrization of cyclopentene-1,3-diones is developed. With the developed protocol, a series of tetracyclic spirooxindoles containing pyrrolidine and cyclopentane subunits can be smoothly obtained with good results (up to 99% yield and 91:9 dr). Furthermore, the methodology can be extended to trifluoromethyl-substituted iminomalonate, and the corresponding formal [3+2] cycloaddition reaction affords bicycli
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Wang, Wei, Ling An, Chi Qian, et al. "Synthesis of Renewable High-Density Fuel with Vanillin and Cyclopentanone Derived from Hemicellulose." Molecules 28, no. 13 (2023): 5029. http://dx.doi.org/10.3390/molecules28135029.

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1,3-bis(cyclohexylmethyl)cyclopentane, a renewable high-density fuel, was first produced in a high overall carbon yield (79.5%) with vanillin and cyclopentanone, which can be derived from biomass. The synthetic route used in this work contains two steps. In the first step, 2,5-bis(4-hydroxy-3-methoxybenzylidene)cyclopentanone was synthesized by aldol condensation of vanillin and cyclopentanone under the catalysis of sulphuric acid. Over the optimized condensation, a high carbon yield (82.6%) of 2,5-bis(4-hydroxy-3-methoxybenzylidene) cyclopentanone was achieved at 80 ºC. In the second step, 2,
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Manna, Madhu Sudan, and Santanu Mukherjee. "Catalytic asymmetric desymmetrization approaches to enantioenriched cyclopentanes." Organic & Biomolecular Chemistry 13, no. 1 (2015): 18–24. http://dx.doi.org/10.1039/c4ob01649a.

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Asymmetric desymmetrization represents an excellent strategy for obtaining highly functionalized chiral building blocks. However, the application of this strategy for the synthesis of cyclopentane derivatives remained limited, when compared to cyclohexanes. Here, we give an overview of asymmetric desymmetrization reactions leading to enantioenriched cyclopentanes.
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Yang, Jin-Song, Kazuhiro Kondo, and Yasuoki Murakami. "Synthesis and Resolution of a New C2-Symmetric Chiral Bis-Aniline, trans-1,2-Bis(2-aminophenyl)cyclopentane." Collection of Czechoslovak Chemical Communications 65, no. 4 (2000): 549–54. http://dx.doi.org/10.1135/cccc20000549.

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New C2-symmetric trans-1,2-bis(2-aminophenyl)cyclopentanes 2a and 2b were synthesized in optically pure forms (99% ee) from the known racemic trans-1,2-bis(2-hydroxyphenyl)cyclopentane (3) by the conversion to its bis-triflate 4 followed by the Buchwald amination and resolution.
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Zhao, Ying Xian. "Selectivity Patterns of Radical Reactions in 1-Hexene Pyrolysis." Advanced Materials Research 391-392 (December 2011): 1406–11. http://dx.doi.org/10.4028/www.scientific.net/amr.391-392.1406.

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The pyrolysis of 1-hexene at 873 K was investigated. Primary products include C1-C4 paraffins, C2-C4 olefins, butadiene, pentadiene, cyclopentane, cyclopentene, coke and hydrogen. A chain reaction mechanism was developed to interpret the distribution of products, and the quantitative analysis on the selectivity patterns of radical reactions was presented.
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Silm, Estelle, Sandra Kaabel, Ivar Järving, and Tõnis Kanger. "Asymmetric Organocatalytic Michael Addition–Cyclisation Cascade of Cyclopentane-1,2-dione with Alkylidene Malononitriles." Synthesis 51, no. 22 (2019): 4198–204. http://dx.doi.org/10.1055/s-0039-1690484.

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An asymmetric organocatalytic cascade reaction between cyclopentane-1,2-diones and alkylidene malononitriles affords highly substituted 4H-pyrans in moderate to high enantiomeric excess. The selective reduction of a bridged double bond leads to the formation of cis-substituted cyclopentanone with three contiguous stereogenic centres.
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Dissertations / Theses on the topic "Cyclopentane"

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McAdam, Catherine. "Claisen-Sakurai approaches to cyclopentane scaffolds." Thesis, Queen's University Belfast, 2015. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.679210.

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A general approach to the synthesis of densely functionalised cyclopentenols was developed to circumvent selectivity and functionalization issues often encountered when attempting to access these synthetic intermediates using the methods currently in use. A range existing reactions were expanded upon, culminating in the formation of allyl silane starting materials for an intramolecular Sakurai reaction. The protocol was adapted to grant access to 'three of the four possible diastereoisomers of the cyclopentenol product. Conditions for a combined Claisen-Sakurai reaction were established. Treat
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Martinez, de Baños Maria Lourdes. "Mechanisms of formation and dissociation of cyclopentane hydrates." Thesis, Pau, 2015. http://www.theses.fr/2015PAUU3037/document.

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Les mécanismes de formation et dissociation d’hydrates de cyclopentane (CP), qui forment á pression ambiante et á des températures entre 0ºC et 7ºC, ont été observés dans/sur/proche des gouttes d’eau immergées dans du CP á des échelles qui vont du micron jusqu’au millimètre. Plusieurs techniques d’observation ont été utilisées, telles que la macrophotographie et la microscopie optique en champ clair, par contraste interférentiel différentiel (CID), par fluorescence et par réflectance confocale. Des substrats hydrophiles et hydrophobes ont été utilisés. Dans une première série d’expériences, un
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STENDER, ALBERTO SANT ANNA. "HYDRATE RHEOLOGY OF WATER-IN-OIL EMULSIONS WITH CYCLOPENTANE." PONTIFÍCIA UNIVERSIDADE CATÓLICA DO RIO DE JANEIRO, 2015. http://www.maxwell.vrac.puc-rio.br/Busca_etds.php?strSecao=resultado&nrSeq=25289@1.

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Hidratos de gás natural são sólidos cristalinos, formados pela associação de moléculas de água a certos hidrocarbonetos leves, sob condições adequadas de pressão e temperatura. No cenário de produção de petróleo offshore, sua ocorrência é motivo de preocupação constante para a indústria de petróleo, pois podem resultar em bloqueios das linhas submarinas e interrupção completa do fluxo. Os custos de prevenção, no entanto, têm se tornado proibitivos, forçando uma mudança conceitual em projetos e privilegiando métodos de gerenciamento desse risco. Dentro dessa estratégia, uma vertente promissora
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LEOPERCIO, BRUNA COSTA. "KINETICS OF CYCLOPENTANE HYDRATE FORMATION: AN INTERFACIAL RHEOLOGY STUDY." PONTIFÍCIA UNIVERSIDADE CATÓLICA DO RIO DE JANEIRO, 2016. http://www.maxwell.vrac.puc-rio.br/Busca_etds.php?strSecao=resultado&nrSeq=29255@1.

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PONTIFÍCIA UNIVERSIDADE CATÓLICA DO RIO DE JANEIRO<br>CONSELHO NACIONAL DE DESENVOLVIMENTO CIENTÍFICO E TECNOLÓGICO<br>Os processos de formação e de dissociação de hidratos são de grande interesse nas áreas ambiental e energética. Especificamente para a indústria de petróleo e gás, o hidrato aparece como um empecilho à garantia de escoamento, alavancando ainda mais a necessidade urgente de ampliar o conhecimento sobre seus fenômenos. Neste trabalho, uma nova abordagem para observar e compreender a cinética e as propriedades mecânicas de hidratos por meio da reologia interfacial é apresentada.
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Lewis, Richard Thomas. "Cyclopentane annulation studies and their application in the polyquinane area." Thesis, Imperial College London, 1987. http://hdl.handle.net/10044/1/47082.

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Aksnes, Dagfinn W., and Kjersti Førland. "Diffusion of cyclohexane and cyclopentane confined in mesoporous MCM-41." Universitätsbibliothek Leipzig, 2016. http://nbn-resolving.de/urn:nbn:de:bsz:15-qucosa-196392.

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Aksnes, Dagfinn W., and Kjersti Førland. "Diffusion of cyclohexane and cyclopentane confined in mesoporous MCM-41." Diffusion fundamentals 2 (2005) 81, S. 1-2, 2005. https://ul.qucosa.de/id/qucosa%3A14417.

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Deaton, Timothy Maxwell. "A Boron Alkylidene-Alkene Cycloaddition Reaction: Application to the Synthesis of Aphanamal." Thesis, Boston College, 2017. http://hdl.handle.net/2345/bc-ir:107597.

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Thesis advisor: James P. Morken<br>Described herein is the exploration of a novel methodology whereby boronate-ester bearing cyclopentanes are produced by reaction between an unactivated olefin and what is described as a boron alkylidene. The mechanism is evaluated and concluded to proceed through a boracyclic intermediate that is achieved by a closed-shell, carbanion addition to the olefin. This mechanistic conclusion is arrived upon by considering two likely alternative routes (an open-shell, radical cyclization and a [2+2] concerted process) and providing evidence to refute them. A reaction
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Саган, В. В., В. А. Константинов, В. П. Ревякин та А. В. Карачевцева. "Оценка влияния внутримолекулярных возбуждений на поведение изохорной теплопроводности в циклопентане (C[5]H[10])". Thesis, Сумский государственный университет, 2015. http://essuir.sumdu.edu.ua/handle/123456789/40657.

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Clary, Heather Margaret Foster. "Synthesis and study of some cyclopentane-1,3-diyl derivatives as potentially long-lived singlet diradicals /." Thesis, Connect to this title online; UW restricted, 2003. http://hdl.handle.net/1773/8500.

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Books on the topic "Cyclopentane"

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Stahnecker, Peter. EPC-Synthesen von Aminosäuren und Cyclopentan-Derivaten. [s.n.], 1989.

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Ziegenfuss, Hans-Peter. D-(+)-Glucopyranose als Startverbindung zur Synthese von enantiomerenreinen Cyclopentan-Derivaten. [s.n.], 1990.

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Mackert, Peter J. Synthese und Eigenschaften von 2H-Cyclopenta[e]-1,2,3,4-tetrazinen. [s.n.], 1995.

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S, Bhatt Tarlochan, ed. Cyclopenta(a)phenanthrenes: Polycyclic aromatic compounds structurally related to steroids. Cambridge University Press, 1987.

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Grebe, Helmut. Enantioselektive Routen zu konfigurativ stabilen 4-Hydroxy-2-Cyclopenten-1-ON-Derivaten. [s.n.], 1987.

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B, Little Stephen, and United States. Environmental Protection Agency., eds. Epoxide ring opening and related reactivities of cyclopenta polycyclic aromatic hydrocarbons: Quantum mechanical studies. U.S. Environmental Protection Agency, 1992.

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Hannover, Universität, ed. Flexible Cyclopentanon-Anellierungen. 1985.

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Coombs, Maurice M., and Tarlochan S. Bhatt. Cyclopenta[a]phenanthrenes. Cambridge University Press, 2008.

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Coombs, Maurice M., and Tarlochan S. Bhatt. Cyclopenta[a]-phenanthrenes (Cambridge Monographs on Cancer Research). Cambridge University Press, 1987.

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Bierwirth, Klaus Dieter. Beiträge zur Chemie des 2,5-Di-tert-butyl-7H-cyclopenta [a] pentalens. 1993.

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Book chapters on the topic "Cyclopentane"

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Gooch, Jan W. "Cyclopentane." In Encyclopedic Dictionary of Polymers. Springer New York, 2011. http://dx.doi.org/10.1007/978-1-4419-6247-8_3247.

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Lide, David R. "Cyclopentane." In Handbook of Organic Solvents. CRC Press, 2024. http://dx.doi.org/10.1201/9781003575191-111.

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Howard, Philip H., Edward M. Michalenko, William M. Meylan, et al. "Cyclopentane." In Handbook of Environmental Fate and Exposure Data for Organic Chemicals, Volume IV. CRC Press, 2023. http://dx.doi.org/10.1201/9781003418887-18.

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Bährle-Rapp, Marina. "Cyclopentane Carboxylic Acid." In Springer Lexikon Kosmetik und Körperpflege. Springer Berlin Heidelberg, 2007. http://dx.doi.org/10.1007/978-3-540-71095-0_2595.

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Wohlfarth, Christian. "Viscosity of cyclopentane." In Viscosity of Pure Organic Liquids and Binary Liquid Mixtures. Springer Berlin Heidelberg, 2017. http://dx.doi.org/10.1007/978-3-662-49218-5_146.

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Wohlfarth, Ch. "Viscosity of cyclopentane." In Supplement to IV/18. Springer Berlin Heidelberg, 2008. http://dx.doi.org/10.1007/978-3-540-75486-2_149.

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Bährle-Rapp, Marina. "Sodium Cyclopentane Carboxylate." In Springer Lexikon Kosmetik und Körperpflege. Springer Berlin Heidelberg, 2007. http://dx.doi.org/10.1007/978-3-540-71095-0_9519.

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Wohlfarth, Ch. "Surface tension of cyclopentane." In Supplement to IV/16. Springer Berlin Heidelberg, 2008. http://dx.doi.org/10.1007/978-3-540-75508-1_95.

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Wohlfarth, Christian. "Refractive index of cyclopentane." In Optical Constants. Springer Berlin Heidelberg, 2017. http://dx.doi.org/10.1007/978-3-662-49236-9_178.

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Englund, Ethan A., Ning Zhang, and Daniel H. Appella. "Cyclopentane Peptide Nucleic Acids." In Peptide Nucleic Acids. Humana Press, 2013. http://dx.doi.org/10.1007/978-1-62703-553-8_2.

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Conference papers on the topic "Cyclopentane"

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Ramkumar, Sowmya, and D. Nalini. "Corrosion Abatement in Acid Pickling Industries by Effective N-Heterocyclic Compounds: Dry and Wet Lab Studies." In CORROSION 2016. NACE International, 2016. https://doi.org/10.5006/c2016-07431.

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Abstract During the chemical cleaning process using acids, in many electroplating and other descaling industries, there exists the problem of heavy metal loss. Hence there is always a need for abatement of this metal loss. A critical (steady state) value of the resistivity to corrosion of two organic compounds, 5-[2-(4-methoxyphenyl)-vinyl]-3-phenyl isoxazole (MVI) and 5-[2-(4-methoxyphenyl)-vinyl]-1,3,8-triaza-cyclopenta[a]indene (MCI) were determined by a combination of non-electrochemical and electrochemical monitoring techniques. The behavior of organic compound, on a metallic alloy, i.e.,
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Bandeira, Marina, Gustavo Alonso Barrientos Sandoval, Monica Naccache, Paulo Roberto de Souza Mendes, Adriana Teixeira, and Leandro Valim. "Interfacial rheology of cyclopentane hydrates." In 26th International Congress of Mechanical Engineering. ABCM, 2021. http://dx.doi.org/10.26678/abcm.cobem2021.cob2021-0281.

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Miyoshi, Akira. "SI Combustion Characteristics of Cyclopentane - Detailed Kinetic Mechanism." In 2019 JSAE/SAE Powertrains, Fuels and Lubricants. SAE International, 2019. http://dx.doi.org/10.4271/2019-01-2305.

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Pillers, Roy A., Timothy B. Morgan, Theodore J. Heindel, and Douglas Estanga. "X-Ray Flow Visualization of Cyclopentane Hydrate Formation." In ASME-JSME-KSME 2019 8th Joint Fluids Engineering Conference. American Society of Mechanical Engineers, 2019. http://dx.doi.org/10.1115/ajkfluids2019-5091.

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Abstract Natural gas hydrates form under high pressure and low-temperature environments common in deepwater off-shore petroleum production operations. Once hydrates form, they can agglomerate and deposit resulting in solid plugs within the piping system, which could require extensive downtime for remediation and recommission of the systems. Hydrate plug formation is difficult to characterize because of the challenging environments in which they form, the lack of instrumentation for such environments, and the fast reaction time compared to other blocking mechanisms. This study explores the use
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Aman, Zachary M., Luis E. Zerpa, Giovanny Grasso, et al. "Interfacial Tension and Mineral Adhesion Properties of Cyclopentane Hydrate." In Unconventional Resources Technology Conference. Society of Exploration Geophysicists, American Association of Petroleum Geologists, Society of Petroleum Engineers, 2013. http://dx.doi.org/10.1190/urtec2013-235.

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Alberto Sant Anna Stender, Mônica Feijó Naccache, and Paulo R. de Souza Mendes. "Hydrate rheology of water-in-oil emulsions with cyclopentane." In 23rd ABCM International Congress of Mechanical Engineering. ABCM Brazilian Society of Mechanical Sciences and Engineering, 2015. http://dx.doi.org/10.20906/cps/cob-2015-1087.

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Ferrari, Wesley, Edson Soares, Roney Thompson, et al. "Rheological characterization and formation protocol of cyclopentane hydrate slurries." In 20th Brazilian Congress of Thermal Sciences and Engineering. ABCM, 2024. https://doi.org/10.26678/abcm.encit2024.cit24-0566.

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Dor. "First and second O2 addition in low-temperature cyclopentane oxidation." In Proposed for presentation at the 38th International Symposium on Combustion held January 24-29, 2021 in Adelaide, Australia. US DOE, 2020. http://dx.doi.org/10.2172/1837617.

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Ozorio, Marcio, Gustavo Alonso Barrientos Sandoval, Monica Naccache, Paulo Roberto de Souza Mendes, Adriana Teixeira, and Leandro Valim. "Rheology of Cyclopentane Hydrates formed in Water-in-model Oil Emulsions." In 18th Brazilian Congress of Thermal Sciences and Engineering. ABCM, 2020. http://dx.doi.org/10.26678/abcm.encit2020.cit20-0027.

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Demireva, Maria, James Oreluk, Amanda Dewyer, Judit Zador, and Leonid Sheps. "Genetic Algorithm Optimization of A Theory-Based Low-Temperature Cyclopentane Oxidation Model." In Proposed for presentation at the 26th International Symposium on Gas Kinetics and Related Phenomena held August 28-September 1, 2022 in Rennes, France. US DOE, 2022. http://dx.doi.org/10.2172/2004466.

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Reports on the topic "Cyclopentane"

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Wernett, P. C., J. Maioriello, and J. W. Larsen. Thermodynamics and surface structure of coals. [BET surface area with cyclopentane]. Office of Scientific and Technical Information (OSTI), 1990. http://dx.doi.org/10.2172/7181409.

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Forster, Nelson H., Jeffrey R. Brown, and David T. Gerardi. Carbon-Phenolic Cages for High-Speed Bearings. Part II - Bearing Evaluation with a Multiply-Alkylated Cyclopentane (MAC) Lubricant. Defense Technical Information Center, 2003. http://dx.doi.org/10.21236/ada416136.

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Forster, Nelson H. Carbon-Phenolic Cages for High-Speed Bearings. Part 1 - Friction and Wear Response of Phenolic Composite Impregnated with a Multiply-Alkylated Cyclopentane (MAC) Lubricant and MoS2 Solid Lubricant. Defense Technical Information Center, 2003. http://dx.doi.org/10.21236/ada416130.

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ชัยเจริญพงศ์, จรรยา. สารยับยั้งไลเพสจากพืชสมุนไพร : รายงานการวิจัย (ปี 2559). จุฬาลงกรณ์มหาวิทยาลัย, 2016. https://doi.org/10.58837/chula.res.2016.56.

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พืชสมุนไพรที่มีฤทธิ์ยับยั้งไลเพส ได้แก่ ส่วนสกัดหยาบเอทานอลของตะไคร้ เหง้าขมิ้น เมล็ดพริกไทยดำ และผลมะเขือพวงมีฤทธิ์การยับยั้งที่สูง มีค่าเท่ากับ 71±2, 75±1, 76±2 และ 87±9% ตามลำดับ และส่วนสกัดหยาบน้ำของเหง้ากระชาย ใบทองพันชั่ง ผลพุทราจีน ผลส้มแขก เหง้าข่า ฐานรองดอกกระเจี๊ยบแดง และใบสะระแหน่ ด้วยเปอร์เซ็นต์การยับยั้ง 71±5, 76±1, 77±10, 77±7, 88±1, 91±1, 92±2% ตามลำดับ ผลมะเขือพวงถูกคัดเลือกเพื่อการทดลองในขั้นต่อไป สารสกัดหยาบเอทิลแอซิเทตของผลมะเขือพวงมีฤทธิ์ยับยั้งไลเพสดีที่สุด มีค่าการยับยั้งเท่ากับ 67.2±3.6% และรองลงมาคือสารสกัดหยาบเฮกเซนมีค่าการยับยั้งเท่ากับ 46.0±6.7% ดังนั้นส่วนสกัดหยาบเฮ
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