Academic literature on the topic 'Decarboxylative Radical Coupling'

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Journal articles on the topic "Decarboxylative Radical Coupling"

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Niu, Pengfei, Jingya Yang, Yong Yuan, et al. "Photocatalyzed redox-neutral decarboxylative alkylation of heteroaryl methanamines." Green Chemistry 23, no. 2 (2021): 774–79. http://dx.doi.org/10.1039/d0gc04094k.

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A redox-neutral decarboxylative radical–radical coupling reaction of heteroaryl methylamines with NHPI esters has been developed by employing a copper complex as a photocatalyst with blue LED irradiation.
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Wu, Guibing, Jingwen Wang, Chengyu Liu та ін. "Transition metal-free, visible-light-mediated construction of α,β-diamino esters via decarboxylative radical addition at room temperature". Organic Chemistry Frontiers 6, № 13 (2019): 2245–49. http://dx.doi.org/10.1039/c9qo00407f.

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Guo, Li-Na, Hua Wang, and Xin-Hua Duan. "Recent advances in catalytic decarboxylative acylation reactions via a radical process." Organic & Biomolecular Chemistry 14, no. 31 (2016): 7380–91. http://dx.doi.org/10.1039/c6ob01113f.

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Hong, Guangfeng, Jinwei Yuan, Junhao Fu та ін. "Transition-metal-free decarboxylative C3-difluoroarylmethylation of quinoxalin-2(1H)-ones with α,α-difluoroarylacetic acids". Organic Chemistry Frontiers 6, № 8 (2019): 1173–82. http://dx.doi.org/10.1039/c9qo00105k.

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Zhang, Yifang, Qian Wang, Yi Peng, et al. "Metal-free, oxidative decarboxylation of aryldifluoroacetic acid with the formation of the ArS–CF2 bond." Organic & Biomolecular Chemistry 19, no. 32 (2021): 7024–30. http://dx.doi.org/10.1039/d1ob01165k.

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A metal-free, oxidative decarboxylative reaction of aryldifluoroacetic acids with disulfides or thiols under mild reaction conditions has been developed. It is an efficient radical cross-coupling method for synthesis of difluoromethylthio ethers.
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Pan, Shulei, Min Jiang, Jinjin Hu, Ruigang Xu, Xiaofei Zeng та Guofu Zhong. "Synthesis of 1,2-amino alcohols by decarboxylative coupling of amino acid derived α-amino radicals to carbonyl compounds via visible-light photocatalyst in water". Green Chemistry 22, № 2 (2020): 336–41. http://dx.doi.org/10.1039/c9gc03470f.

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A general and efficient visible-light photoredox-catalyzed decarboxylative radical coupling reaction of N-aryl amino acids with aldehydes or ketones for the synthesis of 1,2-amino alcohols in water at room temperature is described.
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Fang, Zhongxue, Chenlong Wei, Jing Lin, et al. "Silver-catalyzed decarboxylative C(sp2)–C(sp3) coupling reactions via a radical mechanism." Organic & Biomolecular Chemistry 15, no. 47 (2017): 9974–78. http://dx.doi.org/10.1039/c7ob02455j.

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A silver catalyzed decarboxylative C(sp<sup>2</sup>)–C(sp<sup>3</sup>) coupling of vinylic carboxylic acids with alcohols, alkylbenzenes, cycloalkanes and cyclic ethers was developed by using DTBP as an oxidant.
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Zhao, Jiancan, Hong Fang, Jianlin Han, and Yi Pan. "Iron-catalyzed decarboxylative alkenylation of cycloalkanes with arylvinyl carboxylic acids via a radical process." Beilstein Journal of Organic Chemistry 9 (August 21, 2013): 1718–23. http://dx.doi.org/10.3762/bjoc.9.197.

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A Fe(acac)3-catalyzed decarboxylative coupling of 2-(aryl)vinyl carboxylic acids with cycloalkanes was developed by using DTBP as an oxidant through a radical process. This reaction tolerates a wide range of substrates, and products are obtained in good to excellent yields (71–95%). The reaction also shows excellent stereoselectivity, and only trans-isomers are obtained.
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Yang, Hailong, Peng Sun, Yan Zhu, et al. "Copper-catalyzed decarboxylative C(sp2)–C(sp3) coupling reactions via radical mechanism." Chemical Communications 48, no. 63 (2012): 7847. http://dx.doi.org/10.1039/c2cc33203e.

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Wan, Zi-juan, Jin-yuan Wang, and Jun Luo. "NiCl2-catalyzed radical cross decarboxylative coupling between arylpropiolic acids and cyclic ethers." Tetrahedron Letters 60, no. 8 (2019): 613–16. http://dx.doi.org/10.1016/j.tetlet.2019.01.039.

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Dissertations / Theses on the topic "Decarboxylative Radical Coupling"

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Rokade, Balaji Vasantrao. "Copper-Catalyzed Novel Oxidative Transformations : Construction of Carbon-Hetero Bonds." Thesis, 2014. http://etd.iisc.ernet.in/2005/3479.

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The thesis entitled “Copper-Catalyzed Novel Oxidative Transformations: Construction of Carbon-Hetero Bonds” is divided into two main sections. Section A deals with the utility of azide as a nitrogen source for C-N bond formation, which is further divided into 4 chapters, and section B presents decarboxylative radical coupling reaction for C-heteroatom bond formation which is further divided in to two chapters. Section A Chapter 1 describes an approach for the direct synthesis of nitrile from the corresponding alcohols using azide as a nitrogen source. Nitrile functionality is a versatile an
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Book chapters on the topic "Decarboxylative Radical Coupling"

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Taber, Douglass F. "C–C Bond Construction: The Kingsbury Synthesis of (−)-Dihydrocuscohygrine." In Organic Synthesis. Oxford University Press, 2017. http://dx.doi.org/10.1093/oso/9780190646165.003.0024.

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Akio Baba of Osaka University combined (Chem. Lett. 2013, 42, 1551) reduction of the acid 1 with subsequent condensation with the ketene silyl acetal 2 to directly give the coupled product 3. Song-Lin Zhang of Soochow University showed (Chem. Commun. 2013, 49, 10635) that the allyl Sm reagent 5 could be added to an aldehyde 4 under reducing conditions, leading to the alkene 6. In a related development, Patrick Perlmutter of Monash University reduced (Org. Lett. 2013, 15, 4327) the interme­diate lactol from addition of the alkyl lithium reagent 8 to the lactone 7, to give the alcohol 9. Yoshihiro Miyake, now at Nagoya University, and Yoshiaki Nishibayashi of the University of Tokyo added (Chem. Commun. 2013, 49, 7854) the benzyl radical from the decarboxylation of 10 to the acceptor 11 to give 12. Yasuharu Yoshimi of the University of Fukui (Tetrahedron Lett. 2013, 54, 4324) and Larry E. Overman of the University of California, Irvine (J. Am. Chem. Soc. 2013, 135, 15342) reported related results. David Milstein of the Weizmann Institute of Science developed (Angew. Chem. Int. Ed. 2013, 52, 14131) an Fe catalyst for the hydrogenation of an alkyne 13 to the E-alkene 14. Zhi-Xiang Yu of Peking University showed (Org. Lett. 2013, 15, 4634) that kinetic isomerization of the alkene 15 led selectively to the Z-alkene 16. Umasish Jama of Jadavpur University prepared (Eur. J. Org. Chem. 2013, 4823) the nitroalkene 18 by condensing nitromethane with the aldehyde 17. Vladimir A. D’yakonov of the Russian Academy of Sciences, Ufa described (Chem. Commun. 2013, 49, 8401; Tetrahedron 2013, 69, 8516) the remarkably selective coupling of the allene 19 with the allene 20 to give the Z,Z-diene 21. Sang-Hyeup Lee of the Catholic University of Daegu assembled (Synlett 2013, 24, 1953) the ketone 24 by coupling the alkynyl aluminum 23 with the nitrile 22. Jean-Marc Weibel and Patrick Pale of the Université de Strasbourg showed (Chem. Eur. J. 2013, 19, 8765) that the alkenyl nosylate (p-nitrobenzenesulfonate) 25 coupled smoothly with 26, leading to the enyne 27. Reinhold Zimmer and Hans-Ulrich Reissig of the Freie Universität Berlin described (Synthesis 2013, 45, 2752) similar results with alkenyl nonaflates.
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