Academic literature on the topic 'Deoximation'

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Journal articles on the topic "Deoximation"

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Beldar, A. G., and Mamta Sharma. "Microwave Promoted Regeneration of Carbonyl Compounds from Oximes Using N, N-Dichloro Poly(Styrene-co-divinylbenzene)Sulphonamide Resin." E-Journal of Chemistry 8, no. 1 (2011): 288–92. http://dx.doi.org/10.1155/2011/590923.

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An efficient, economically viable and operationally simple method was developed for deoximation of oximes (of ketones and aldehydes) to their corresponding carbonyl compounds using polymer beads ofN, N-dichloro poly(styrene-co-divinylbenzene)sulphonamide resin. Polymeric reagent offered speedy conversion and substantial yields of products under mild condition and is recyclable. Deoximation was monitored by the use of13C NMR.
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Mukai, Chisato. "Dicobaltoctacarbonyl-Mediated Deoximation." Synthesis 1999, no. 11 (1999): 1872–74. http://dx.doi.org/10.1055/s-1999-3603.

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3

Ren, Qing-Gang, Xian-Tai Zhou, and Hong-Bing Ji. "Biomimetic models of nitric oxide synthase for the oxidation of oximes to carbonyl compounds catalyzed by water-soluble manganese porphyrins in aqueous solution." Journal of Porphyrins and Phthalocyanines 15, no. 03 (2011): 211–16. http://dx.doi.org/10.1142/s1088424611003173.

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A mild green and efficient approach for hydrogen peroxide oxidative converting oximes to the corresponding carbonyl compounds with a water-soluble manganese porphyrin as catalyst in water/acetone mixture has been developed. The water-soluble manganese porphyrin showed an excellent activity for the oxidative deoximation reactions of various oximes under ambient conditions in the absence of any additive. The oxidative deoximation was through the formation of high valent oxo-manganese species, which was confirmed by in situ UV-vis spectroscopy.
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Terent’ev, Alexander, Igor Krylov, Vera Vil’, Zhanna Pastukhova, Sergey Fastov, and Gennady Nikishin. "Synthesis of dibromo ketones by the reaction of the environmentally benign H2O2-HBr system with oximes." Open Chemistry 10, no. 2 (2012): 360–67. http://dx.doi.org/10.2478/s11532-011-0158-8.

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AbstractIt was found that oximes undergo deoximation in the presence of the H2O2aq-HBraq system to form ketones and bromo ketones. This reaction provided the basis for the synthesis of dibromo ketones in yields varying from 40% to 94%. This method is environmentally friendly, sustainable, and easy to perform. The results of this investigation extend the potential of the use of oximes for the protection of carbonyl group, thus offering the ability to perform not only conventional deoximation but also the subsequent bromination of ketones. The reaction is easily scaled up and dibromo ketones can
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Bandgar, B. P., Miss Lalita B. Kunde, and J. L. Thote. "Deoximation with N-Haloamides1." Synthetic Communications 27, no. 7 (1997): 1149–52. http://dx.doi.org/10.1080/00397919708003350.

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Tajbaksh, M., A. Khazaei, M. Shabani Mahalli, and R. Ghorbani Vaghei. "Deoximation with N-Bromosulfonamides." Russian Journal of Organic Chemistry 39, no. 7 (2003): 1053–54. http://dx.doi.org/10.1023/b:rujo.0000003204.55086.06.

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Li, Hongjia, Xiaobi Jing, Yaocheng Shi, and Lei Yu. "Autocatalytic deoximation reactions driven by visible light." Reaction Chemistry & Engineering 6, no. 1 (2021): 119–24. http://dx.doi.org/10.1039/d0re00333f.

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Photocatalytic deoximation reaction was found to be an autocatalytic process that occurs via free-radical mechanism. Understanding the mechanism may help chemical engineers to develop related techniques to avoid the decomposition of oximes.
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Bandgar, B. P., S. I. Shaikh, and Suresh Iyer. "Oxidative Deoximation with Sodium Perborate1." Synthetic Communications 26, no. 6 (1996): 1163–68. http://dx.doi.org/10.1080/00397919608003724.

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Telvekar, Vikas N. "tert‐Butyl Hypoiodite for Deoximation." Synthetic Communications 35, no. 21 (2005): 2827–29. http://dx.doi.org/10.1080/00397910500290599.

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Khurana, Jitender Mohan, Abhijit Ray, and Prabhat Kumar Sahoo. "Oxidative Deoximation with Sodium Hypochlorite." Bulletin of the Chemical Society of Japan 67, no. 4 (1994): 1091–93. http://dx.doi.org/10.1246/bcsj.67.1091.

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Conference papers on the topic "Deoximation"

1

Ryu, Ilhyong, Sunggak Kim, Hiroki Kuriyama, Hironari Miyazato, Mitsuo Komatsu, and Joo-Yong Yoon. "Novel Synthesis of a,b-Diketoesters from a,a-Dioxo-type Oximes or Oxime Ethers via Zinc-Induced Deoximation." In The 4th International Electronic Conference on Synthetic Organic Chemistry. MDPI, 2000. http://dx.doi.org/10.3390/ecsoc-4-01829.

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