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Journal articles on the topic 'Deoximation'

Author: Grafiati

Published: 5 June 2025

Last updated: 1 August 2025

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1

Beldar, A. G., and Mamta Sharma. "Microwave Promoted Regeneration of Carbonyl Compounds from Oximes Using N, N-Dichloro Poly(Styrene-co-divinylbenzene)Sulphonamide Resin." E-Journal of Chemistry 8, no. 1 (2011): 288–92. http://dx.doi.org/10.1155/2011/590923.

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An efficient, economically viable and operationally simple method was developed for deoximation of oximes (of ketones and aldehydes) to their corresponding carbonyl compounds using polymer beads ofN, N-dichloro poly(styrene-co-divinylbenzene)sulphonamide resin. Polymeric reagent offered speedy conversion and substantial yields of products under mild condition and is recyclable. Deoximation was monitored by the use of13C NMR.

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2

Mukai, Chisato. "Dicobaltoctacarbonyl-Mediated Deoximation." Synthesis 1999, no. 11 (1999): 1872–74. http://dx.doi.org/10.1055/s-1999-3603.

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3

Ren, Qing-Gang, Xian-Tai Zhou, and Hong-Bing Ji. "Biomimetic models of nitric oxide synthase for the oxidation of oximes to carbonyl compounds catalyzed by water-soluble manganese porphyrins in aqueous solution." Journal of Porphyrins and Phthalocyanines 15, no. 03 (2011): 211–16. http://dx.doi.org/10.1142/s1088424611003173.

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A mild green and efficient approach for hydrogen peroxide oxidative converting oximes to the corresponding carbonyl compounds with a water-soluble manganese porphyrin as catalyst in water/acetone mixture has been developed. The water-soluble manganese porphyrin showed an excellent activity for the oxidative deoximation reactions of various oximes under ambient conditions in the absence of any additive. The oxidative deoximation was through the formation of high valent oxo-manganese species, which was confirmed by in situ UV-vis spectroscopy.

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4

Terent’ev, Alexander, Igor Krylov, Vera Vil’, Zhanna Pastukhova, Sergey Fastov, and Gennady Nikishin. "Synthesis of dibromo ketones by the reaction of the environmentally benign H2O2-HBr system with oximes." Open Chemistry 10, no. 2 (2012): 360–67. http://dx.doi.org/10.2478/s11532-011-0158-8.

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AbstractIt was found that oximes undergo deoximation in the presence of the H2O2aq-HBraq system to form ketones and bromo ketones. This reaction provided the basis for the synthesis of dibromo ketones in yields varying from 40% to 94%. This method is environmentally friendly, sustainable, and easy to perform. The results of this investigation extend the potential of the use of oximes for the protection of carbonyl group, thus offering the ability to perform not only conventional deoximation but also the subsequent bromination of ketones. The reaction is easily scaled up and dibromo ketones can

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5

Bandgar, B. P., Miss Lalita B. Kunde, and J. L. Thote. "Deoximation with N-Haloamides1." Synthetic Communications 27, no. 7 (1997): 1149–52. http://dx.doi.org/10.1080/00397919708003350.

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6

Tajbaksh, M., A. Khazaei, M. Shabani Mahalli, and R. Ghorbani Vaghei. "Deoximation with N-Bromosulfonamides." Russian Journal of Organic Chemistry 39, no. 7 (2003): 1053–54. http://dx.doi.org/10.1023/b:rujo.0000003204.55086.06.

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7

Li, Hongjia, Xiaobi Jing, Yaocheng Shi, and Lei Yu. "Autocatalytic deoximation reactions driven by visible light." Reaction Chemistry & Engineering 6, no. 1 (2021): 119–24. http://dx.doi.org/10.1039/d0re00333f.

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Photocatalytic deoximation reaction was found to be an autocatalytic process that occurs via free-radical mechanism. Understanding the mechanism may help chemical engineers to develop related techniques to avoid the decomposition of oximes.

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8

Bandgar, B. P., S. I. Shaikh, and Suresh Iyer. "Oxidative Deoximation with Sodium Perborate1." Synthetic Communications 26, no. 6 (1996): 1163–68. http://dx.doi.org/10.1080/00397919608003724.

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9

Telvekar, Vikas N. "tert‐Butyl Hypoiodite for Deoximation." Synthetic Communications 35, no. 21 (2005): 2827–29. http://dx.doi.org/10.1080/00397910500290599.

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10

Khurana, Jitender Mohan, Abhijit Ray, and Prabhat Kumar Sahoo. "Oxidative Deoximation with Sodium Hypochlorite." Bulletin of the Chemical Society of Japan 67, no. 4 (1994): 1091–93. http://dx.doi.org/10.1246/bcsj.67.1091.

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11

Mukai, Chisato, Izumi Nomura, Osamu Kataoka, and Miyoji Hanaoka. "ChemInform Abstract: Dicobaltoctacarbonyl-Mediated Deoximation." ChemInform 31, no. 8 (2010): no. http://dx.doi.org/10.1002/chin.200008079.

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12

HAMAL, S., S. K. MAHTO, and C. L. GAJUREL. "ChemInform Abstract: Oxidative Deoximation of Ketoximes." ChemInform 27, no. 52 (2010): no. http://dx.doi.org/10.1002/chin.199652074.

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13

Chakraborty, Vaishali, and Manobjyoti Bordoloi. "Deoximation by Pyridinium Chlorochromate under Microwave Irradiation." Journal of Chemical Research 23, no. 2 (1999): 120–21. http://dx.doi.org/10.1177/174751989902300227.

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14

Sanabria, Rubén, René Miranda, Victor Lara, and Francisco Delgado. "“Oxidative Deoximation with Bentonite-Supported Silver Carbonate”." Synthetic Communications 24, no. 19 (1994): 2805–8. http://dx.doi.org/10.1080/00397919408010599.

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15

Chrisman, William, Michael J. Blankinship, Brady Taylor, and Clifford E. Harris. "Selective deoximation using alumina supported potassium permanganate." Tetrahedron Letters 42, no. 29 (2001): 4775–77. http://dx.doi.org/10.1016/s0040-4039(01)00850-4.

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16

Chakraborty, Vaishali, and Manobjyoti Bordoloi. "Deoximation by Pyridinium Chlorochromate under Microwave Irradiation." Journal of Chemical Research, no. 2 (1999): 120–21. http://dx.doi.org/10.1039/a803979h.

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17

Sahu, Sandhyamayee, Sabita Patel, and Bijay K. Mishra. "Deoximation by cetyltrimethylammonium dichromate: A kinetic study." International Journal of Chemical Kinetics 43, no. 9 (2011): 482–88. http://dx.doi.org/10.1002/kin.20576.

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18

Li, Yongshu, Nizhou Xu, Guangyao Mei, et al. "Fe(NO3)3·9H2O-catalyzed aerobic oxidative deoximation of ketoximes and aldoximes under mild conditions." Canadian Journal of Chemistry 96, no. 8 (2018): 810–14. http://dx.doi.org/10.1139/cjc-2017-0567.

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A mild, simple process for the effective aerobic oxidative deoximation of a wide range of ketoximes and aldoximes has been developed that utilizes Fe(NO3)3·9H2O as the single catalyst and molecular oxygen as the green oxidant. The environmentally benign protocol provides moderate to excellent yield and broad functional groups tolerance and is a valuable synthetic method for practical applications. According the relevant verification experiment, a plausible mechanism has been proposed.

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19

Asutay, Oktay, Nilüfer Hamarat, Nesimi Uludag, and Necdet Coşkun. "Selective oxidative deoximation with anhydrous Ce(IV) sulfate." Tetrahedron Letters 56, no. 25 (2015): 3902–4. http://dx.doi.org/10.1016/j.tetlet.2015.04.111.

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20

Radhakrishna, A. S., Beena Augustine, K. Sivaprakash, and B. B. Singh. "Iodobenzene Dichloride II - An Efficient Reagent for Deoximation." Synthetic Communications 21, no. 14 (1991): 1473–76. http://dx.doi.org/10.1080/00397919108016420.

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21

Balicki, Roman, and Lukasz Kaczmarek. "Mild Reductive Deoximation with TiCl4/NaI Reagent System." Synthetic Communications 21, no. 17 (1991): 1777–82. http://dx.doi.org/10.1080/00397919108021576.

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22

Kuo, Yueh-Hsiung, and Tay Lang Jang. "A Useful Method for Oxidative Deoximation with Photooxygenation." Journal of the Chinese Chemical Society 38, no. 2 (1991): 203–6. http://dx.doi.org/10.1002/jccs.199100034.

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23

Mao, Yu-Zhu, Zhong-Ii Liu, and Long-Min Wu. "A novel oxygen-dependent deoximation by nitric oxide." Chinese Journal of Chemistry 18, no. 5 (2010): 789–91. http://dx.doi.org/10.1002/cjoc.20000180526.

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24

Saravanselvi, Chockalingam, Narayanan Somasundaram, Sakthivel Vijaikumar, and Chockalingam Srinivasan. "Deoximation on irradiated TiO2: regeneration of ketones from ketoximes." Photochemical & Photobiological Sciences 1, no. 8 (2002): 607–8. http://dx.doi.org/10.1039/b203721c.

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25

Kamal, Ahmed, Maddamsetty V. Rao, and Harshadas M. Meshram. "Enzymatic deoximation of oximes by ultrasonically stimulated baker's yeast." Journal of the Chemical Society, Perkin Transactions 1, no. 8 (1991): 2056. http://dx.doi.org/10.1039/p19910002056.

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26

Zhang, Guofu, Xin Wen, Yong Wang, Weimin Mo, and Chengrong Ding. "Sodium Nitrite Catalyzed Aerobic Oxidative Deoximation under Mild Conditions." Journal of Organic Chemistry 76, no. 11 (2011): 4665–68. http://dx.doi.org/10.1021/jo102571e.

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27

Bencharif, L., A. Tallec, and R. Tardivel. "Anodic behaviour of aromatic oximes: an electrochemical deoximation reaction." Electrochimica Acta 42, no. 23-24 (1997): 3509–12. http://dx.doi.org/10.1016/s0013-4686(97)00047-9.

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28

SANABRIA, R., R. MIRANDA, V. LARA, and F. DELGADO. "ChemInform Abstract: “Oxidative Deoximation with Bentonite-Supported Silver Carbonate”." ChemInform 26, no. 13 (2010): no. http://dx.doi.org/10.1002/chin.199513094.

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29

Chakraborty, Vaishali, and Manobjyoti Bordoloi. "ChemInform Abstract: Deoximation by Pyridinium Chlorochromate under Microwave Irradiation." ChemInform 30, no. 31 (2010): no. http://dx.doi.org/10.1002/chin.199931087.

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30

Chrisman, William, Michael J. Blankinship, Brady Taylor, and Clifford E. Harris. "ChemInform Abstract: Selective Deoximation Using Alumina-Supported Potassium Permanganate." ChemInform 32, no. 41 (2010): no. http://dx.doi.org/10.1002/chin.200141098.

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31

Raquel, Correia Cordeiro, Ríos‐Lombardía Nicolás, Morís Francisco, Kourist Robert та González‐Sabín Javier. "One-Pot Transformation of Ketoximes into Optically Active Alcohols and Amines by Sequential Action of Laccases and Ketoreductases or ω-Transaminases". ChemCatChem 11, № 4 (2019): 1272–77. https://doi.org/10.5281/zenodo.3233867.

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Abstract An enzymatic one‐pot process for asymmetric transformation of prochiral ketoximes into alcohols or amines was developed by sequential coupling of a laccase‐catalyzed deoximation either with a ketone reduction (ketoreductase, KRED) or bioamination (ω‐transaminase, ω‐TA) in aqueous medium. An accurate selection of biocatalysts provided the corresponding products in excellent enantiomeric excesses and overall conversions ranging from 83 to >99 % for alcohols and 70 to >99 % for amines. Likewise, the employment of exclusively 1 % (w/w) of Cremophor&r

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32

Lin, Mei-Huey, Han-Jun Liu, Cheng-Yu Chang, Wei-Cheng Lin, and Tsung-Hsun Chuang. "SnCl2/TiCl3-Mediated Deoximation of Oximes in an Aqueous Solvent." Molecules 17, no. 3 (2012): 2464–73. http://dx.doi.org/10.3390/molecules17032464.

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33

Chaudhari, Sachin S., and Krishnacharya G. Akamanchi. "Deoximation using Dess-Martin periodinane: Regeneration of ketones from ketoximes." Tetrahedron Letters 39, no. 20 (1998): 3209–12. http://dx.doi.org/10.1016/s0040-4039(98)00392-x.

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34

Chidambaram, N., K. Satyanarayana, and S. Chandrasekaran. "An Efficient and Highly Selective Method for Deoximation of Ketoximes." Synthetic Communications 19, no. 9-10 (1989): 1727–34. http://dx.doi.org/10.1080/00397918908051072.

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35

Du, Liyong, Jing Gao, Shuyang Yang, et al. "An efficient approach to deoximation using hexachlorodisilane under mild conditions." Russian Journal of General Chemistry 84, no. 11 (2014): 2200–2204. http://dx.doi.org/10.1134/s1070363214110267.

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36

Tajbakhsh, Mahmood, Majid M. Heravi, Farajollah Mohanazadeh, Siavosh Sarabi, and Mitra Ghassemzadeh. "N-Methylpiperidinium Chlorochromate Adsorbed on Alumina: A New Deoximation Reagent." Monatshefte fuer Chemie/Chemical Monthly 132, no. 10 (2001): 1229–31. http://dx.doi.org/10.1007/s007060170038.

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37

Nath, Utpal, Satya Sandhy Das, Dibakar Deb, and Pranab Jyoti Das. "Tetra-n-alkylammonium bromates—new and efficient reagents for deoximation." New J. Chem. 28, no. 12 (2004): 1423–25. http://dx.doi.org/10.1039/b409319d.

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38

Zheng, Yinghao, Aiqiong Wu, Yangyang Ke, Hongen Cao, and Lei Yu. "Recent advances on deoximation: From stoichiometric reaction to catalytic reaction." Chinese Chemical Letters 30, no. 5 (2019): 937–41. http://dx.doi.org/10.1016/j.cclet.2019.01.012.

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39

Asutay, Oktay, Niluefer Hamarat, Nesimi Uludag, and Necdet Coskun. "ChemInform Abstract: Selective Oxidative Deoximation with Anhydrous Ce(IV) Sulfate." ChemInform 46, no. 40 (2015): no. http://dx.doi.org/10.1002/chin.201540088.

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40

BALICKI, R., and L. KACZMAREK. "ChemInform Abstract: Mild Reductive Deoximation with TiCl4/NaI Reagent System." ChemInform 23, no. 14 (2010): no. http://dx.doi.org/10.1002/chin.199214146.

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41

BANDGAR, B. P., L. B. KUNDE, and J. L. THOTE. "ChemInform Abstract: Synthetic Methods. Part 6. Deoximation with N-Haloamides." ChemInform 28, no. 28 (2010): no. http://dx.doi.org/10.1002/chin.199728065.

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42

Zhang, Xiaoxia, Bin Lu, Xiaoguang Wang, Jingxiang Zhao, and Qinghai Cai. "Deoximation Reaction in Room Temperature Ionic Liquids under Mild Conditions." Chinese Journal of Chemistry 29, no. 9 (2011): 1846–50. http://dx.doi.org/10.1002/cjoc.201100041.

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43

Beheshtiha, Yahya Sh, Majid M. Heravi, Nooshin Sarmad, and Rahim Hekmat Shoar. "Deoximation with hexamethylenetetramine-bromine supported on alumina in non-aqueous condition." Journal of Chemical Research 2001, no. 2 (2001): 76–77. http://dx.doi.org/10.3184/030823401103169018.

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44

Heravi, Majid M., Mahmood Tajbakhsh, Setareh Habibzadeh, and Mitra Ghassemzadeh. "Solid State Deoximation with Clay Supported Potassium Ferrate Under Microwave Irradiation." Phosphorus, Sulfur, and Silicon and the Related Elements 176, no. 1 (2001): 195–99. http://dx.doi.org/10.1080/10426500108055118.

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45

Chaudhari, Sachin S., and Krishnacharya G. Akamanchi. "A Mild, Chemoselective, Oxidative Method for Deoximation Using Dess-Martin Periodinane." Synthesis 1999, no. 05 (1999): 760–64. http://dx.doi.org/10.1055/s-1999-3476.

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46

Heravi, Majid M., Dariush Ajami, Mahmood Tajbakhsh, and Mitra Ghassemzadeh. "Clay Supported Bis-(trimethylsilyl)-chromate: An Efficient Reagent for Oxidative Deoximation." Monatshefte für Chemie/Chemical Monthly 131, no. 10 (2000): 1109–13. http://dx.doi.org/10.1007/s007060070045.

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47

Tamami, B., and A. R. Kiasat. "Microwave Promoted Rapid Oxidative Deoximation of Oximes under Solvent-Free Conditions." Synthetic Communications 30, no. 22 (2000): 4129–35. http://dx.doi.org/10.1080/00397910008087029.

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48

Dewan, Sharwan K., and Ravinder Singh. "A Rapid Deoximation of Carbonyl Compounds With Febric Chlordie Part -4." Material Science Research India 1, no. 2 (2004): 109–10. http://dx.doi.org/10.13005/msri/010207.

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49

Zhang, Guofu, Xin Wen, Yong Wang, Weimin Mo, and Chengrong Ding. "ChemInform Abstract: Sodium Nitrite Catalyzed Aerobic Oxidative Deoximation under Mild Conditions." ChemInform 42, no. 38 (2011): no. http://dx.doi.org/10.1002/chin.201138077.

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50

BANDGAR, B. P., S. I. SHAIKH, and S. IYER. "ChemInform Abstract: Synthetic Methods. Part 1. Oxidative Deoximation with Sodium Perborate." ChemInform 27, no. 27 (2010): no. http://dx.doi.org/10.1002/chin.199627117.

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