Academic literature on the topic 'Deoxydehydration'

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Journal articles on the topic "Deoxydehydration":

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Hacatrjan, Schanth, Lujie Liu, Jianxing Gan, Yoshinao Nakagawa, Ji Cao, Mizuho Yabushita, Masazumi Tamura, and Keiichi Tomishige. "Titania-supported molybdenum oxide combined with Au nanoparticles as a hydrogen-driven deoxydehydration catalyst of diol compounds." Catalysis Science & Technology 12, no. 7 (2022): 2146–61. http://dx.doi.org/10.1039/d1cy02144c.

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Tshibalonza, Nelly Ntumba, and Jean-Christophe M. Monbaliu. "Revisiting the deoxydehydration of glycerol towards allyl alcohol under continuous-flow conditions." Green Chemistry 19, no. 13 (2017): 3006–13. http://dx.doi.org/10.1039/c7gc00657h.

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Xi, Yongjie, Wenqiang Yang, Salai Cheettu Ammal, Jochen Lauterbach, Yomaira Pagan-Torres, and Andreas Heyden. "Mechanistic study of the ceria supported, re-catalyzed deoxydehydration of vicinal OH groups." Catalysis Science & Technology 8, no. 22 (2018): 5750–62. http://dx.doi.org/10.1039/c8cy01782d.

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Morris, Danny S., Karlotta van Rees, Massimiliano Curcio, Mirza Cokoja, Fritz E. Kühn, Fernanda Duarte, and Jason B. Love. "Deoxydehydration of vicinal diols and polyols catalyzed by pyridinium perrhenate salts." Catalysis Science & Technology 7, no. 23 (2017): 5644–49. http://dx.doi.org/10.1039/c7cy01728f.

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Wozniak, Bartosz, Yuehui Li, Sergey Tin, and Johannes G. de Vries. "Rhenium-catalyzed deoxydehydration of renewable triols derived from sugars." Green Chemistry 20, no. 19 (2018): 4433–37. http://dx.doi.org/10.1039/c8gc02387e.

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Tshibalonza, Nelly Ntumba, and Jean-Christophe M. Monbaliu. "The deoxydehydration (DODH) reaction: a versatile technology for accessing olefins from bio-based polyols." Green Chemistry 22, no. 15 (2020): 4801–48. http://dx.doi.org/10.1039/d0gc00689k.

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Chapman, Garry, and Kenneth M. Nicholas. "Vanadium-catalyzed deoxydehydration of glycols." Chemical Communications 49, no. 74 (2013): 8199. http://dx.doi.org/10.1039/c3cc44656e.

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Canale, Valentino, Lucia Tonucci, Mario Bressan, and Nicola d'Alessandro. "Deoxydehydration of glycerol to allyl alcohol catalyzed by rhenium derivatives." Catal. Sci. Technol. 4, no. 10 (2014): 3697–704. http://dx.doi.org/10.1039/c4cy00631c.

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Li, Cui, Qi Zhang, and Yao Fu. "Transition Metal Catalyzed Deoxydehydration of Alcohols." Acta Chimica Sinica 76, no. 7 (2018): 501. http://dx.doi.org/10.6023/a18040138.

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Dethlefsen, Johannes R., Daniel Lupp, Byung-Chang Oh, and Peter Fristrup. "Molybdenum-Catalyzed Deoxydehydration of Vicinal Diols." ChemSusChem 7, no. 2 (January 7, 2014): 425–28. http://dx.doi.org/10.1002/cssc.201300945.

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Dissertations / Theses on the topic "Deoxydehydration":

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Landini, Christian [Verfasser], Regina [Akademischer Betreuer] Palkovits, and Marcel [Akademischer Betreuer] Liauw. "Structure-activity correlation for Re- and Mo-based catalysts for the deoxydehydration of polyols / Christian Landini ; Regina Palkovits, Marcel Liauw." Aachen : Universitätsbibliothek der RWTH Aachen, 2020. http://d-nb.info/1227992246/34.

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Silva, Vargas Karen Zulay. "Mise à l'échelle de la synthèse d'alcool allylique à partir de Glycérol." Thesis, Centrale Lille Institut, 2020. http://www.theses.fr/2020CLIL0024.

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Abstract:
L'alcool allylique est une molécule plate-forme intéressante en raison de sa large gamme d’applications. La Désoxydehydratation (DODH) du glycérol semble actuellement la méthode la plus compétitive pour synthétiser l'alcool allylique à partir de ressources renouvelables. Cependant, jusqu'à présent, cette réaction n'a été que peu étudiée en littérature. Le but de cette thèse était de développer un procédé de production intégré d'alcool allylique via DODH de glycérol en utilisant un alcool secondaire comme solvant-réducteur. Le développement du catalyseur a été réalisé en utilisant un catalyseur d'oxyde de rhénium supporté sur cérine. Ce dernier a été synthétisé via un processus de nanocasting en utilisant de la silice et du charbon actif comme agents structurants, donnant d'excellents rendements allant jusqu'à 86%, en utilisant un 2-hexanol ou MIBC comme donneur d'hydrogène et solvant. En ce qui concerne le développement du procédé, les données d'équilibre liquide vapeur isobare ont été déterminées pour les principaux systèmes binaires afin de modéliser la colonne de distillation. Les données expérimentales de VLE ont été ajustées avec succès en utilisant les modèles thermodynamique NRTL, UNIQUAC et Wilson. Enfin, la modélisation intégrée du procédé a été réalisée à partir des résultats expérimentaux et proposant différents scénarios en fonction du solvant utilisé. Toutes les stratégies proposées ont permis une purification d'alcool allylique de 99,99%. Dans tous les scénarios, le procédé MIBC s'est révélé être une faisable stratégie d’un point de vue technique, qui pourrait potentiellement servir de point de départ pour le développement d'un procédé DODH à grande échelle
Allyl Alcohol is an interesting platform molecule due to its broad range of applications. The Deoxydehydration (DODH) of glycerol seems currently the most competitive method to synthesize allyl alcohol from renewable sources. However, so far, this reaction has been only marginally investigated. The aim of this thesis was to develop an integrated production process of allyl alcohol via DODH of glycerol using a secondary alcohol as solvent-reductant. The catalyst development was carried out using ceria-supported rhenium oxide catalyst. Mesoporous ceria materials were synthetized via a nanocasting process using SiO2 and activated carbon as hard templates, giving excellent yields of up to 86%, using a 2-Hexanol or MIBC as a hydrogen donor and solvent. With respect to the process development, isobaric vapor liquid equilibrium data were determined for main binary systems in order to model the distillation column. The experimental VLE data was successfully fitted using NRTL, UNIQUAC and Wilson thermodynamic model. Finally, the integrated process modelling was carried out based on the experimental results and proposing different scenarios depending on the used solvent. All the proposed strategies allowed to obtain an allyl alcohol purity of 99.99%. In any scenario, the MIBC process proved to be a feasible strategy from a technical point of view, which could potentially be used as starting point for the development of a large scale DODH process

Book chapters on the topic "Deoxydehydration":

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Boucher-Jacobs, Camille, and Kenneth M. Nicholas. "Deoxydehydration of Polyols." In Topics in Current Chemistry, 163–84. Cham: Springer International Publishing, 2014. http://dx.doi.org/10.1007/128_2014_537.

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Liu, Shuo, Jing Yi, and Mahdi M. Abu-Omar. "Deoxydehydration (DODH) of Biomass-Derived Molecules." In Green Chemistry and Sustainable Technology, 1–11. Singapore: Springer Singapore, 2016. http://dx.doi.org/10.1007/978-981-287-769-7_1.

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Reports on the topic "Deoxydehydration":

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Nicholas, Kenneth M. Catalytic Deoxydehydration of Carbohydrates and Polyols to Chemicals and Fuels. Office of Scientific and Technical Information (OSTI), January 2016. http://dx.doi.org/10.2172/1234909.

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