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Journal articles on the topic 'Derivative of an alcohol'

Author: Grafiati

Published: 5 June 2025

Last updated: 1 August 2025

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1

Arshad, M., and K. Masud. "THE PROSPECTS OF SENSIBLE SOURCES AS HIGH POWER FUEL AND HIGH FIBER PROTEIN." Nucleus 48, no. 4 (2011): 301–13. https://doi.org/10.71330/thenucleus.2011.824.

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The sensible sources (namely; corn, wheat, barley, oat and rye) and molasses (procured from the local market of Rawalpindi), following enzymatic hydrolysis were subjected to fermentation to produce high fiber protein (HFP) and liquid protein as a by-product. The former can be used for human consumption and the later was considered fit for animal feed. Carbon dioxide gas produced during fermentation can be used as gas in beverages or converted into dry ice. Malt husk (spent grain) left behind as a result of waste has utilization for poultry and dairy farm. Ethanol produced was converted into hi

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2

Nazir, Aqsa, Naveed Ahmed, Umar Khan, and Syed Tauseef Mohyud-Din. "A conformable mathematical model for alcohol consumption in Spain." International Journal of Biomathematics 12, no. 05 (2019): 1950057. http://dx.doi.org/10.1142/s1793524519500578.

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A study on the conformable model of alcohol consumption in Spain has been presented. For the proposed model, the existence as well as the uniqueness of the solution has been discussed with the help of fixed-point theory. An analytical technique, Variational Iteration Method (VIM), has been used to obtain the solution to the governing system of differential equations. With the help of suitable plots, the role of fractional order derivative has been highlighted. For decreasing values of fractional order derivative, decrease in the number of non-consumers and non-risk consumers has been observed.

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3

Nubbemeyer, Udo, Jonas Donges, Sandra Hofmann, et al. "Synthesis of Optically Active N-(4-Hydroxynon-2-enyl)pyrrolidines: Key Building Blocks in the Total Synthesis of Streptomyces coelicolor Butanolide 5 (SCB-5) and Virginiae Butanolide A (VB-A)." Synthesis 53, no. 15 (2021): 2632–42. http://dx.doi.org/10.1055/s-0037-1610770.

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AbstractStarting from 5-methylhexanal and (S)-configured N-propargylprolinol ethers, coupling delivered N-(4-hydroxynon-2-ynyl)prolinol derivatives as mixtures of C4 diastereomers. Resolution of the epimers succeeded after introduction of an (R)-mandelic ester derivative and subsequent HPLC separation. Alternatively, suitable oxidation gave the corresponding alkynyl ketone. Midland reagent controlled diastereoselective reduction afforded a defined configured propargyl alcohol with high selectivity. LiAlH4 reduction and Mosher analyses of the allyl alcohols enabled structure elucidation. The su

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4

Julianto, T. S., F. J. Rachmawaty, H. A. Tamhid, and B. S. Putri. "THE POTENTIAL ANTIMALARIAL DRUG OF ARYL AMINO ALCOHOL DERIVATIVES FROM EUGENOL: SYNTHESIS, in-vitro AND in-silico ANALYSIS OF BIOACTIVITY." RASAYAN Journal of Chemistry 16, no. 03 (2023): 1425–34. http://dx.doi.org/10.31788/rjc.2023.1636940.

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Malaria is a significant cause of death in numerous countries, and the discovery of effective drugs is crucial. In this research, a new method was employed to synthesize a derivative of aryl amino alcohol using eugenol. Initially, an epoxide compound called 2-methoxy-4-(oxiran-2-ylmethyl) phenol was synthesized from eugenol by reacting it with peroxyacetic acid in dichloromethane. Subsequently, the epoxide compound was subjected to a reaction with various amine compounds, including aniline, naphthylamine, and diphenylamine for 10 minutes under 100 W microwave conditions, resulting in the produ

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5

Journal, Baghdad Science. "Synthesis and Characterization of New Heterocyclic Compounds from 2, 5- dimercapto -1, 3, 4-Thiadiazole and Their Resins." Baghdad Science Journal 13, no. 2 (2016): 275–88. http://dx.doi.org/10.21123/bsj.13.2.275-288.

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In this research, a new 1, 3, 4-Thiadiazole derivatives have been synthesized by many heterocyclic reactions. Starting from (2, 5 – dimercapto -1, 3, 4-Thiadiazole) a variety of derivatives have been synthesis. Compound (1) was synthesized by the reaction of hydrazine hydrate with carbon disulphide in absolute ethanol. The compound (1) was reacted with 1, 2-dibromoethane in presence of alkali ethanol to give the compound (2). The compound (3) was formed from the reaction of compound (2) with hydrazine hydrate. Schiff base (4) was obtained by reacting of compound (3) with the compound (p-hydrox

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6

Nishimura, Takahiro, Ryota Yabe, and Yusuke Ebe. "Iridium-Catalyzed Direct C–H Allylation of Ketimines." Synthesis 53, no. 17 (2021): 3051–56. http://dx.doi.org/10.1055/a-1477-7059.

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AbstractAromatic C–H allylation of N-sulfonyl ketimines with allyl alcohol or allyl phenyl ether as an allyl source is catalyzed by a cationic iridium complex. The presence of a catalytic amount of a pyridine derivative was found to be essential for the reaction. In contrast, direct C–H allylation of ketimines derived from benzophenone derivatives and p-methoxyaniline with allyl phenyl ether proceeded in the absence of pyridine derivatives.

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7

Leemans, Laura, Marc D. Walter, Frank Hollmann, Anett Schallmey, and Luuk M. van Langen. "Multi-Catalytic Route for the Synthesis of (S)-Tembamide." Catalysts 9, no. 10 (2019): 822. http://dx.doi.org/10.3390/catal9100822.

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Enantiopure β-amino alcohols constitute one of the most significant building blocks for the synthesis of active pharmaceutical ingredients. Despite the availability of a range of chiral β-amino alcohols from a chiral pool, there is a growing demand for new enantioselective synthetic routes to vicinal amino alcohols and their derivatives. In the present study, an asymmetric 2-step catalytic route that converts 4-anisaldehyde into a β-amino alcohol derivative, (S)-tembamide, with excellent enantiopurity (98% enantiomeric excess) has been developed. The recently published initial step consists in

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8

Černý, Ivan, Tereza Slavíková та Vladimír Pouzar. "Synthesis of (15E)-17β-hydroxy-5α-androstane-3,15-dione 15-[O-(Carboxymethyl)]oxime, New Hapten for Dihydrotestosterone (17β-hydroxy-5α-androstan-3-one)". Collection of Czechoslovak Chemical Communications 62, № 10 (1997): 1642–49. http://dx.doi.org/10.1135/cccc19971642.

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Addition of 4-methoxybenzyl alcohol to 3β-hydroxy-5α-androst-15-en-17-one gave the mixture of isomeric 15-(4-methoxyphenyl)methoxy derivatives from which, after acetylation and chromatography, the major 15β isomer was separated. Borohydride reduction gave 17β-hydroxy derivative which was protected as methoxymethyl ether. Oxidative cleavage of protecting group at position 15 and the subsequent Jones oxidation afforded corresponding 15-ketone. Its oximation with O-(carboxymethyl)hydroxylamine, deacetylation and methylation with diazomethane gave protected O-(carboxymethyl)oxime derivative with f

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9

Journal, Baghdad Science. "Preparation and Evaluation of PolyVinyl Alcohol Derivative as Antimicrobial and Antifungal Agents." Baghdad Science Journal 4, no. 4 (2007): 603–11. http://dx.doi.org/10.21123/bsj.4.4.603-611.

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Polyvinal alcohol was Cynoethylated , complex compound with Iodin in presence of Cu++ ions were preparated and their ultra violet (U.V) and infra red( IR) spectra were investigated. The prepared derivative and complexes were evaluated as antibacterial and antifungal agents following the standard dilution method. MIC(minimum inhibitory concentration) for each polymer using ten types of gram + ve and gram _ ve bacteria were determinated in addition to three types of fungi. The results obtainded showed that MIC, s were around 0.0011 × 103 molar for different polymetric derivatives tried.

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10

Abed, Ali N., Jawad K. Al-Kafaji, Ithar K. Al-Mayaly, and M. A. El-Azmirly. "Preparation and Evaluation of PolyVinyl Alcohol Derivative as Antimicrobial and Antifungal Agents." Baghdad Science Journal 4, no. 4 (2021): 603–11. http://dx.doi.org/10.21123/bsj.2007.4.4.603-611.

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Polyvinal alcohol was Cynoethylated , complex compound with Iodin in presence of Cu++ ions were preparated and their ultra violet (U.V) and infra red( IR) spectra were investigated. The prepared derivative and complexes were evaluated as antibacterial and antifungal agents following the standard dilution method. MIC(minimum inhibitory concentration) for each polymer using ten types of gram + ve and gram _ ve bacteria were determinated in addition to three types of fungi. The results obtainded showed that MIC, s were around 0.0011 × 103 molar for different polymetric derivatives tried.

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11

Kim, Taehoon, Gayeong Han, and Yeonsu Jung. "Facile Fabrication of Polyvinyl Alcohol/Edge-Selectively Oxidized Graphene Composite Fibers." Materials 12, no. 21 (2019): 3525. http://dx.doi.org/10.3390/ma12213525.

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Graphene derivatives are effective nanofillers for the enhancement of the matrix mechanical properties; nonetheless, graphene oxide (GO), reduced GO, and exfoliated graphene all present distinct advantages and disadvantages. In this study, polyvinyl alcohol (PVA) composite fibers have been prepared using a recently reported graphene derivative, i.e., edge-selectively oxidized graphene (EOG). The PVA/EOG composite fibers were simply fabricated via conventional wet-spinning methods; thus, they can be produced at the commercial level. X-ray diffractometry, scanning electron microscopy, and two-di

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12

Sokhraneva, V. A., D. A. Yusupova, V. S. Boriskin, and N. V. Groza. "Obtaining substituted phenol derivatives with potential antimicrobial activity." Fine Chemical Technologies 17, no. 3 (2022): 210–30. http://dx.doi.org/10.32362/2410-6593-2022-17-3-210-230.

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Objectives. With the growing resistance of pathogenic microorganisms to antibiotics, the development of new antimicrobial drugs offering specific mechanisms of action becomes an urgent task. Only few antimicrobials offer a broad spectrum of activity against gram-positive and gram-negative bacteria, molds, and yeasts. In this regard, the purpose of the work was to develop methods for synthesizing biologically active derivatives of alkyl-substituted phenols (reactions at the hydroxy group) to study their biological effect.Methods. The synthesis of imidazole acetates of substituted phenols was ca

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13

Morita, Masao, Shuhei Tanabe, Tomoya Arai, and Yuichi Kobayashi. "Synthesis of Resolvin D6 and the Silyl Ether of the Resolvin E2 Methyl Ester via trans-Enynyl Alcohols." Synlett 30, no. 11 (2019): 1351–55. http://dx.doi.org/10.1055/s-0037-1611826.

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Two trans-enynyl alcohol intermediates corresponding to the C1–C8 and C13–C22 parts of resolvin D6 (RvD6) were prepared through the Hudrlik–Peterson reaction of the TMS-substituted trans-epoxy alcohols with TMS-acetylide and subsequent TMS-desilylation. These intermediates were coupled with a 1,4-dihalo-2-butyne derivative under copper catalysis, and the resulting acetylene was reduced with Zn(Cu/Ag) to afford the TBS ether of RvD6 methyl ester. Desilylation with TBAF yielded the γ-lactone of RvD6, which was hydrolyzed to RvD6. The total yield of RvD6 was 1.9% in 19 steps from (3-trimethylsily

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14

Bruno, Laura Maria, José Luiz de Lima Filho, and Heizir Ferreira de Castro. "Comparative performance of microbial lipases immobilized on magnetic polysiloxane polyvinyl alcohol particles." Brazilian Archives of Biology and Technology 51, no. 5 (2008): 889–96. http://dx.doi.org/10.1590/s1516-89132008000500003.

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Microbial lipase from Mucor miehei and Candida rugosa were immobilized by covalent binding onto magnetized polysiloxane polyvinyl alcohol particles (POS-PVA). The resulting immobilized derivatives were evaluated in aqueous solution (olive oil hydrolysis) and organic solvent (butyl butyrate synthesis). Higher catalytic activities were found when the coupling procedure was made with M. miehei lipase. Immobilized M. miehei lipase also showed a better operational stability and a higher half-life than C. rugosa lipase after the successive batches of esterification. The performance of C. rugosa immo

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15

Schaefer, Ted, Rudy Sebastian, Glenn H. Penner, and S. R. Salman. "The proximate spin–spin coupling, 5J(F,CH3), as a quantitative conformational indicator in alkylfluorobenzenes and related compounds." Canadian Journal of Chemistry 64, no. 8 (1986): 1602–6. http://dx.doi.org/10.1139/v86-266.

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The through-space or proximate nuclear spin–spin coupling constant, 5J(F,CH3) = 5J, between methyl protons and ring fluorine nuclei in alkylfluorobenzenes is postulated as [Formula: see text] θ being the torsional angle for the [Formula: see text] bond. A and B are obtained from the known internal rotational behaviour in 2,6-difluoroethylbenzene and the corresponding cumene derivative. The parameterization is tested on the observed 5J in derivatives of 2,4,6-tri-tert-butyl- and 2,4,6-tri-isopropyl-fluorobenzene, in 2-chloro-6-fluoroisopropylbenzene, 2,6-difluoro-α-methylstyrene, and N-methyl-8

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16

Skrotska, O., K. Tsvietkov, and Yu Penchuk. "Biotechnological features of receiving organic compounds for production of plasticizers." Scientific Works of National University of Food Technologies 29, no. 1 (2023): 25–43. http://dx.doi.org/10.24263/2225-2924-2023-29-1-4.

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Plasticizers are used in the production of various polymers. They give these materials flexibility, strength and elasticity. Different groups of compounds are used for obtaining plasticizers in particular acids, phenols and alcohols. They can be obtained both by chemical synthesis and by using microorganisms. Information in this article is focused on the microbial synthesis of various compounds that are the basis for the production of plasticizers. Organic acids such as oleic, linolenic, linoleic, adipic, etc. are used in the production of plasticizers. Among the producers of these acids are b

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17

Hagiwara, Hisahiro, Shohei Fujiwara, Chikako Iibachi, Toshio Suzuki, and Takashi Hoshi. "A Synthetic Approach Toward a Brominated Oxocane Labdane Diterpenoid Isolated From Laurencia obtusa." Natural Product Communications 15, no. 3 (2020): 1934578X2091286. http://dx.doi.org/10.1177/1934578x20912866.

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The synthesis of a labdane oxocane epoxy-alcohol is described starting from the Wieland–Miescher ketone derivative via ring closing olefin metathesis of a diene derivative, targeting the total synthesis of a brominated oxocane labdane diterpenoid isolated from Laurencia obtusa.

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18

Phutdhawong, Weerachai, Siwaporn Inpang, Thongchai Taechowisan, and Waya S. Phutdhawong. "Synthesis and Biological Activity Studies of Methyl-5-(Hydroxymethyl)-2-Furan Carboxylate and Derivatives." Oriental Journal of Chemistry 35, no. 3 (2019): 080–1085. http://dx.doi.org/10.13005/ojc/350322.

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Methyl-5-(hydroxymethyl)-2-furan carboxylate and derivatives were prepared from furfuryl alcohol and their biological activities were studied for cytotoxicity against cancer cell lines HeLa, HepG2 and Vero, and Gram (+) and Gram (-) bacteria. The amine derivative, (5-(((2-(1H-indol-3-yl)ethyl)amino)methyl) furan-2-yl)methyl acetate, was found to have the most potent biological activity with IC50 62.37 µg/mL against the HeLa cell line and MIC 250 µg/mL against the photogenic bacteria.

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19

Kohout, Ladislav. "The synthesis of 5,6-cyclopropanocholestanes with oxygen functions in positions 3 and 7." Collection of Czechoslovak Chemical Communications 51, no. 2 (1986): 429–35. http://dx.doi.org/10.1135/cccc19860429.

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The Simmons-Smith methylenation of the double bond in 3β-acetoxycholest-5-en-7-ols takes place selectively under formation of an adduct the configuration of which is determined by the configuration of the 7-hydroxyl group: 7β-alcohol IV gave 5β,6β-cyclopropane derivative VI, 7α-alcohol V gave 5α,6α-cyclopropane derivative VIII. On photochemically initiated cyclization of 3β-acetoxy-B-homo-5-en-7a-one (XIII) we obtained the product with an α-cyclopropane ring exclusively, i.e. 3β-acetoxy-5,6α-cyclopropano-5α-cholestan-7-one (XII).

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20

Valencia, Jhesua, Oriel A. Sánchez-Velasco, Jorge Saavedra-Olavarría, Patricio Hermosilla-Ibáñez, Edwin G. Pérez, and Daniel Insuasty. "N-Arylation of 3-Formylquinolin-2(1H)-ones Using Copper(II)-Catalyzed Chan–Lam Coupling." Molecules 27, no. 23 (2022): 8345. http://dx.doi.org/10.3390/molecules27238345.

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3-formyl-2-quinolones have attracted the scientific community’s attention because they are used as versatile building blocks in the synthesis of more complex compounds showing different and attractive biological activities. Using copper-catalyzed Chan–Lam coupling, we synthesized 32 new N-aryl-3-formyl-2-quinolone derivatives at 80 °C, in air and using inexpensive phenylboronic acids as arylating agents. 3-formyl-2-quinolones and substituted 3-formyl-2-quinolones can act as substrates, and among the products, the p-methyl derivative 9a was used as a substrate to obtain different derivatives su

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21

Yacoub, Y., R. Bata, and M. Gautam. "The performance and emission characteristics of C1-C5 alcohol-gasoline blends with matched oxygen content in a single-cylinder spark ignition engine." Proceedings of the Institution of Mechanical Engineers, Part A: Journal of Power and Energy 212, no. 5 (1998): 363–79. http://dx.doi.org/10.1243/0957650981536934.

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Alcohols with carbon numbers ranging from C1 to C5 were individually blended with unleaded test gasoline. All the alcohol-gasoline blends had the same oxygen mass content. The performance characteristics of the blends were quantified using a single-cylinder spark ignition engine. The knock-limiting spark timing was determined by analysis of the third derivative of the measured in-cylinder gas pressure versus crank angle. The engine operating conditions were optimized for each (C1-C5) blend with two different values of matched oxygen mass content (2.5 and 5.0 per cent). Emission mass rates of c

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22

Umar, Zainab Garba, Moses E. Abalaka, Safiya Yahaya Daniyan, Hausatu Babayi, and Kamoru Abdulazeez Adeniyi. "Physicochemical and bio-metabolite characterizations of chitosan isolated from American cockroach (Periplaneta americana) and cricket (Acheta domesticus)." BIOMED natural and applied science 02, no. 01 (2022): 25–36. http://dx.doi.org/10.53858/bnas02012536.

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Background: Chitosan is gaining increased research interest due to its wide range of potential applications in the field of biotechnology, medicine and pharmacology, agriculture, textiles, cosmetics and wastewater treatments. This study was designed specifically to explore locally available chitosan from American cockroaches (Periplaneta americana) and cricket (Acheta domesticus) as an alternative source of chitosan for industrial application. Methods: Chitosan was extracted by alkaline deacetylation of chitin and were physicochemically characterized using Fourier Transformed Infrared Spectros

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23

Klinot, Jiří, Jarmil Světlý, Eva Klinotová, Miloš Buděšínský та Alois Vystrčil. "Preparation of isomeric 2-methyl-1-oxotriterpenoids of the 18α-oleanane series; Conformation of ring A". Collection of Czechoslovak Chemical Communications 51, № 12 (1986): 2869–78. http://dx.doi.org/10.1135/cccc19862869.

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2β-Methyl-1α-hydroxy (XV) and two isomeric 2-methyl-1-oxo derivatives (XVI and XVII) of 19β,28-epoxy-18α-oleanane were prepared from 19β,28-epoxy-2-methyl-18α-olean-1-en-3-one (XI) via 3β-chloro derivative XIII and unsaturated 1α-hydroxy derivative XIV. Allylic oxidation of 2-methyl-2-ene VI was studied as an alternative approach to compound XIV. Oxidation with selenium dioxide led to diol VII, aldehyde VIII and alcohol IV, oxidation with tert-butyl chromate gave epoxy ketone X. According to 1H NMR and CD data, ring A in the 2β-methyl derivatives XV and XVI exists in a boat conformation. The 2

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24

Rosario Cayetano, Omar, Alberto Fleitas Imbert, José Francisco Gómez-Aguilar, and Antonio Fernando Sarmiento Galán. "Modeling Alcohol Concentration in Blood via a Fractional Context." Symmetry 12, no. 3 (2020): 459. http://dx.doi.org/10.3390/sym12030459.

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We use a conformable fractional derivative G T α through two kernels T ( t , α ) = e ( α − 1 ) t and T ( t , α ) = t 1 − α in order to model the alcohol concentration in blood; we also work with the conformable Gaussian differential equation (CGDE) of this model, to evaluate how the curve associated with such a system adjusts to the data corresponding to the blood alcohol concentration. As a practical application, using the symmetry of the solution associated with the CGDE, we show the advantage of our conformable approaches with respect to the usual ordinary derivative.

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25

Su, Ming-Der. "A mechanistic study of the addition of alcohol to a five-membered ring silene via a photochemical reaction." Physical Chemistry Chemical Physics 18, no. 11 (2016): 8228–34. http://dx.doi.org/10.1039/c5cp06857f.

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The mechanisms for the alcohol addition reactions for a cyclic divinyldisilane (1-Si) are theoretically studied using the CASSCF and CAS-MP2 methods. However, it is theoretically predicted that the carbon derivative (1-C) does not undergo alcohol addition reactions when it absorbs light.

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26

Meier, C., L. Habel, F. Haller-Meier, et al. "Chemistry and Anti-Herpes Simplex virus Type 1 Evaluation of CycloSal-Nucleotides of Acyclic Nucleoside Analogues." Antiviral Chemistry and Chemotherapy 9, no. 5 (1998): 389–402. http://dx.doi.org/10.1177/095632029800900503.

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The synthesis of different cycloSal-phosphotriesters of the acyclic nucleoside analogues acyclovir (ACV), penciclovir (PCV) and T-penciclovir (T-PCV) as potential new lipophilic, membrane-soluble pronucleotides is described. The introduction of the cycloSal moiety was achieved by using reactive cyclic chlorophosphane reagents. In addition to the cycloSal-PCV monophosphate (MP) phosphotri-esters, a second derivative bearing an acetyl group at the second primary alcohol function was prepared. In hydrolysis studies the cycloSal-ACVMPs showed the expected range of hydrolytic stability dependent on

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27

Zhu, Hong-yan, Di Zhang, Qi Zhang, et al. "4-Hydroxybenzyl alcohol derivatives and their sedative–hypnotic activities." RSC Advances 8, no. 35 (2018): 19539–50. http://dx.doi.org/10.1039/c8ra01972j.

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28

Corder, Ria D., Prajesh Adhikari, Michael C. Burroughs, Orlando J. Rojas, and Saad A. Khan. "Cellulose nanocrystals for gelation and percolation-induced reinforcement of a photocurable poly(vinyl alcohol) derivative." Soft Matter 16, no. 37 (2020): 8602–11. http://dx.doi.org/10.1039/d0sm01376e.

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29

Katsumoto, Yukiteru, Daisuke Adachi, Harumi Sato, and Yukihiro Ozaki. "Usefulness of a Curve Fitting Method in the Analysis of Overlapping Overtones and Combinations of CH Stretching Modes." Journal of Near Infrared Spectroscopy 10, no. 1 (2002): 85–91. http://dx.doi.org/10.1255/jnirs.325.

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This paper reports the usefulness of a curve fitting method in the analysis of NIR spectra. NIR spectra in the 7500–5500 cm−1 (1333–1818 nm) region were measured for water–methanol, water–ethanol and water–1-propanol mixtures with alcohol concentrations of 0–100 wt% at 25°C. The 6000–5600 cm−1 (1667–1786 nm) region, where the overtones and combinations of CH3 and CH2 stretching modes are expected to appear, shows significant band shifts with the increase in the alcohol content. To analyse the concentration-dependent spectral changes, a curve fitting method was utilised, and the results were co

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30

Begunov, Roman, Luisa Savina, and Alexander Khlopotinin. "Main and by-processes at 1-(2-nitroaryl)-1H-benzotriazole reduction." From Chemistry Towards Technology Step-By-Step 5, no. 1 (2024): 107–13. http://dx.doi.org/10.52957/2782-1900-2024-5-1-107-113.

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The paper investigates the HCl concentration impact on the main and by-processes during the reduction of 1-(2-nitroaryl)-1H-benzotriazole by tin (II) chloride in acidic aqueous-alcoholic medium. The authors have observed the formation of azoxy compounds in addition to the target amino derivative at low HCl content in the reaction mass. The use of 36% hydrochloric acid causes the alkylation of the formed amino compound with alcohol as a solvent.

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31

Begunov, Roman, Luisa Savina, and Alexander Khlopotinin. "Main and by-processes at 1-(2-nitroaryl)-1H-benzotriazole reduction." From Chemistry Towards Technology Step-By-Step 5, no. 1 (2024): 33–39. http://dx.doi.org/10.52957/2782-1900-2024-5-1-33-39.

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The paper investigates the HCl concentration impact on the main and by-processes during the reduction  of 1-(2-nitroaryl)-1H-benzotriazole by tin (II) chloride in acidic aqueous-alcoholic medium. The authors have observed the formation of azoxy compounds in addition to the target amino derivative at low HCl content in the reaction mass. The use of 36% hydrochloric acid causes the alkylation of the formed amino compound with alcohol as a solvent.

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32

Bratychak, Michael, Taras Chervinskyy, Olena Shust, and Olena Shyshchak. "Chemical Modification of ED-24 Epoxy Resin Peroxy Derivative by C9H4F16O Fluorine-Containing Alcohol-Telomer." Chemistry and Chemical Technology 4, no. 2 (2010): 125–30. http://dx.doi.org/10.23939/chcht04.02.125.

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The possibility of chemical modification of ED-24 epoxy resin peroxy derivative (PDER) by C9H4F16O fluorine-containing alcohol-telomer (FAT-C9) has been shown using 18-Crown and ZnCl2 catalytic system. The effect of catalyst amount, temperature and process time on the reaction rate has been studied. New peroxy oligomer containing fluorine atoms (FPO) has been synthesized and characterized. The FPO structure has been confirmed by IR-spectroscopy. It has been proposed to use FPO as an active additive to the polymeric mixes based on ED-20 industrial epoxy resin and TGM-3 oligoesteracrylate.

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Popsavin, Velimir, Ostoja Beric, Ljubica Radic, Mirjana Popsavin, Vera Cirin-Novta, and Dušan Miljković. "Stereospecific Synthesis of (+)-Muscarine from D-Glucose, Suitable for Preparation of 5-Substituted Analogues." Collection of Czechoslovak Chemical Communications 63, no. 10 (1998): 1522–27. http://dx.doi.org/10.1135/cccc19981522.

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A stereospecific synthesis of (+)-muscarine iodide (1) has been achieved starting from D-glucose as a chiral precursor. The key steps of the synthesis involved a stereospecific cyclization of 3,5-di-O-mesyl derivative 3 into the 2,5-anhydride 4, the stereospecific catalytic hydrogenation of unsaturated derivative 6, and the C-4 epimerization of alcohol 12 by Mitsunobu reaction.

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34

Zappaterra, Federico, Francesco Presini, Domenico Meola, et al. "Green Biocatalysis of Xylitol Monoferulate: Candida antarctica Lipase B-Mediated Synthesis and Characterization of Novel Bifunctional Prodrug." BioTech 14, no. 2 (2025): 25. https://doi.org/10.3390/biotech14020025.

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Natural compounds with significant bioactive properties can be found in abundance within biomasses. Especially prominent for their anti-inflammatory, neuroprotective, antibacterial, and antioxidant activities are cinnamic acid derivatives (CAs). Ferulic acid (FA), a widely studied phenylpropanoid, exhibits a broad range of therapeutic and nutraceutical applications, demonstrating antidiabetic, anticancer, antimicrobial, and hepato- and neuroprotective activities. This research investigates the green enzymatic synthesis of innovative and potentially bifunctional prodrug derivatives of FA, desig

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35

Miki, Ryotaro, Tsutomu Yamaki, Masaki Uchida, and Hideshi Natsume. "Diol responsive viscosity increase in a cetyltrimethylammonium bromide/sodium salicylate/3-fluorophenylboronic acid micelle system." RSC Advances 12, no. 11 (2022): 6668–75. http://dx.doi.org/10.1039/d1ra08831a.

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36

BANI, TALAPAlRA, CHAKRABORTY SYAMAL, BISWAS KALLOLMAY, MONDAL SUDIPTA та KUMAR TALAPATRA SUNIL. "Friedel-Crafts Reaction with Arylcarbinols : One-Pot Synthesis of 10-Methylbenzo[ α ]fluoranthene". Journal of Indian Chemical Society Vol. 75, Oct-Dec 1998 (1998): 788–94. https://doi.org/10.5281/zenodo.5923195.

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Centre of Advanced Studies on Natural Products, Department of Chemistry, University College of Science, 92 Acharya Prafulla Chandra Road, Calcutta-700 <em>009</em> <em>Manuscript received 14 September 1998</em> Friedel-Crafts reaction with some monoaryl and diaryl carbinols have been studied. The products suggest a rational mode of formation of trityl alcohol and anthracene derivatives modifying the earlier reported conjecture of their formation from carbon monoxide, generated from benzhydrol and solvent benzene. It now appears that during Friedel-Crafts reaction the benzyl carbocation generat

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37

Nesterova, A. A., I. I. Prokofiev, V. N. Perfilova, O. Yu Evsyukov, M. V. Kustova, and I. N. Tyurenkov. "Morphological changes in the myocardium of rats with chronic alcohol intoxication after treatment with new GABAand glutamic acid derivatives." Bulletin of Siberian Medicine 22, no. 1 (2023): 73–80. http://dx.doi.org/10.20538/1682-0363-2023-1-73-80.

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Aim. To study pathohistological changes in the myocardium of rats with chronic alcohol intoxication (CAI) after treatment with a new glutamic acid derivative glufimet (compound RSPU-238) and a new gamma-aminobutyric acid (GABA) derivative (compound RSPU-260).Materials and methods. Experiments were performed on female Wistar rats aged 10 months. The rats were divided into the following groups: group 1 – intact females; group 2 – a control group which included animals after CAI simulated by replacing drinking water with 10% ethanol solution for 24 weeks; groups 3 and 4 – experimental groups, in

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Vatmurge, Namdev S., Braja G. Hazra, and Vandana S. Pore. "Syntheses of 1,2-Amino Alcohols and Their Applications for Oxazaborolidine Catalyzed Enantioselective Reduction of Aromatic Ketones." Australian Journal of Chemistry 60, no. 3 (2007): 196. http://dx.doi.org/10.1071/ch06412.

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Six new chiral 1,2-amino alcohol derivatives have been synthesized starting from (1R,2R)-2-amino-1-phenylpropane-1,3-diol. Asymmetric reduction of aryl ketones with in-situ generated oxazaborolidine from these amino alcohol derivatives and BH3·Me2S afforded secondary alcohols with good yield and moderate to high enantiomeric excess.

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39

Şahin, Zeynel. "Oxidation of Benzyl Alcohols by Monomeric Iron Phthalocyanine Complexes: Substituents’ Effect on Their Catalytic Performance." Celal Bayar Üniversitesi Fen Bilimleri Dergisi 21, no. 2 (2025): 100–104. https://doi.org/10.18466/cbayarfbe.1570991.

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Iron phthalocyanines tetra substituted with either electron-donating n-hexyloxy or electron-withdrawing n-hexylsulfonyl substituents were prepared and tested as oxidation catalysts for benzyl alcohol, 4-bromobenzyl alcohol, 4-methylbenzyl alcohol and 4-tert-butylbenzyl alcohol. Oxidation reactions were performed at room temperature in acetonitrile, acetone, ethanol, toluene, and the best result was obtained in acetonitrile. Oxidation of alcohols using tert-butyl hydroperoxide as an oxidant in the presence of these iron(II) phthalocyanines resulted in the production of corresponding benzaldehyd

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Huang, Yi Chiang, Hsu Feng Lee, Po Hsun Wang, et al. "Water/Alcohol Soluble Poly(3-Alkylthiophene) Derivative Self-Assembly with Fullerene Derivative via Hydrogen Bonding." Advanced Materials Research 1051 (October 2014): 303–7. http://dx.doi.org/10.4028/www.scientific.net/amr.1051.303.

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In this research, a regioregular poly (3-alkylthiophene) derivative had been synthesized via the post-polymerization functionalization, poly (3-hexylamine thiophene), which are soluble in water and water miscible solvents such as methanol, DMSO. The suitable energy level, good thermal stability and water/alcohol solubility of polymers which promising applied in polymer solar cells and processed by water or environmental-friendly solvents. In blend of functionalization polymers and fullerene derivative potassium [6,6]-phenyl-C61-butyrate shows significant UV absorption decay phenomenon and occu

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41

Breen, C., J. J. Flynn, and G. M. B. Parkes. "Thermogravimetric, infrared and mass-spectroscopic analysis of the desorption of methanol, propan-1-ol, propan-2-ol and 2-methylpropan-2-ol from montmorillonite." Clay Minerals 28, no. 1 (1993): 123–37. http://dx.doi.org/10.1180/claymin.1993.028.1.11.

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AbstractThe desorption of methanol (MeOH), propan-1-ol (n-PrOH), propan-2-ol (i-PrOH) and 2-methylpropan-2-ol (t-BuOH) from Na+-, Ca2+-, Al3+-, Cr3+- and Fe3+-exchanged montmorillonite has been studied using variable temperature infrared (IR) spectroscopy and thermogravimetric analysis (TGA). Alcohol-saturated trivalent cation (M3+) exchanged samples exhibit maxima in the derivative thermograms at 20 and 110°C (MeOH), 30 and 160°C (n-PrOH), 20 and 110°C (i-PrOH) and 20, 55 and 80°C (t-BuOH). Alcohol-saturated Na+ and Ca2+-exchanged montmorillonite samples exhibit maxima at higher temperatures

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Davis, Noelle, Daniel Liu, Ashok K. Jain, et al. "MODIFIED POLYVINYL ALCOHOL-BENZOPORPHYRIN DERIVATIVE CONJUGATES AS PHOTOTOXIC AGENTS." Photochemistry and Photobiology 57, no. 4 (1993): 641–47. http://dx.doi.org/10.1111/j.1751-1097.1993.tb02930.x.

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Ohtsuka, Minoru, Shigeru Sakai, Takahiro Kusunoki, et al. "Cardiovascular activity of FR46171, a new pyridine alcohol derivative." Japanese Journal of Pharmacology 39 (1985): 138. http://dx.doi.org/10.1016/s0021-5198(19)63444-x.

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Ruiz, J., A. Mantecón, and V. Cádiz. "States of water in poly(vinyl alcohol) derivative hydrogels." Journal of Polymer Science Part B: Polymer Physics 41, no. 13 (2003): 1462–67. http://dx.doi.org/10.1002/polb.10503.

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Journal, Baghdad Science. "Synthesis of New Heterocyclic Derivatives from 4-(3, 5-Dimethyl-1-phenyl-1H-pyrazol-4-ylazo)- benzoic acid." Baghdad Science Journal 7, no. 1 (2010): 727–36. http://dx.doi.org/10.21123/bsj.7.1.727-736.

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In this work pyrazolin derivatives were prepared from the diazonium chloride salt of 4-aminobenzoic acid. Azo compounds were prepared from the reaction of an ethanolic solution of sodium acetate and calculated amount of active methylene compound namely, acetyl acetone to obtain the corresponding hydrazono derivative (1). Cyclocondensation reaction of compounds (1) with hydrazine hydrate and phenyl hydrazine in boiling ethanol affording the corresponding pyrazoline-5-one derivatives of 4-aminobenzoic acid (2,3). Then compound (3) was reacted with thionyl chloride to give the corresponding acid

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Schmidt, Bernd, and Sylvia Hauke. "Olefin cross metathesis based de novo synthesis of a partially protected L-amicetose and a fully protected L-cinerulose derivative." Beilstein Journal of Organic Chemistry 10 (May 6, 2014): 1023–31. http://dx.doi.org/10.3762/bjoc.10.102.

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Shaw, Mukta, Yogesh Kumar, Rima Thakur, and Amit Kumar. "Electron-deficient pyridinium salts/thiourea cooperative catalyzed O-glycosylation via activation of O-glycosyl trichloroacetimidate donors." Beilstein Journal of Organic Chemistry 13 (November 9, 2017): 2385–95. http://dx.doi.org/10.3762/bjoc.13.236.

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The glycosylation of O-glycosyl trichloroacetimidate donors using a synergistic catalytic system of electron-deficient pyridinium salts/aryl thiourea derivatives at room temperature is demonstrated. The acidity of the adduct formed by the 1,2-addition of alcohol to the electron-deficient pyridinium salt is increased in the presence of an aryl thiourea derivative as an hydrogen-bonding cocatalyst. This transformation occurs under mild reaction conditions with a wide range of O-glycosyl trichloroacetimidate donors and glycosyl acceptors to afford the corresponding O-glycosides in moderate to goo

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48

Yan, Yong-Ming, Xiao-Hui Meng, Hong-Fu Bai, and Yong-Xian Cheng. "Nonpeptide small molecules with a ten-membered macrolactam or a morpholine motif from the insect American cockroach and their antiangiogenic activity." Organic Chemistry Frontiers 8, no. 7 (2021): 1401–8. http://dx.doi.org/10.1039/d0qo01653e.

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(±)-Periplactam A (1), a rare ten-membered macrolactam composed of lignan and putrescine, (±)-periplanol E (2), a dimeric phenethyl alcohol derivative formed via morpholine, and periplactams B (3) and C (4) were isolated from American cockroach.

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Klemenov, A. V. "Alcoholic cardiomyopathy: aspects of pathogenesis and clinic." Clinician 18, no. 1 (2024): 31–36. http://dx.doi.org/10.17650/1818-8338-2024-18-1-k706.

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Alcoholic cardiomyopathy is the most common form of myocardial damage caused by ethanol. Ethanol and its main active metabolite acetaldehyde have a direct toxic effect on the myocardium. The mechanisms of the cardiotoxic effect of ethanol are diverse and include membranotropic action, damage to cellular organelles, activation of lipid peroxidation, and a number of others. Dissolving in the lipids of biological membranes, ethanol changes their physico-chemical properties, disrupts the activity of membrane receptors, eventually disconnecting the connection of excitation with the contraction of c

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Popova, Tamara A., Margarita V. Kustova, Gulnara Kh. Khusainova, et al. "Changes in the respiratory function of the heart and brain mitochondria of animals after chronic alcohol intoxication affected by a new GABA derivative." Research Results in Pharmacology 7, no. (1) (2021): 33–40. https://doi.org/10.3897/rrpharmacology.7.60469.

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Introduction: Chronic ethanol consumption leads to significant functional and structural changes in the mitochondria of the heart and brain, increasing generation of reactive oxygen species. Therefore, the search for substances, which improve the functional state of the mitochondria and, meantime, reduce the oxidative stress, is relevant. Materials and methods: 10-months-old Wistar female rats were used in the experiments. Chronic alcohol intoxication (CAI) was modelled by replacing drinking water with a 10% ethanol solution containing sucrose (50 g/L) for 24 weeks. Four groups were formed: 1

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