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Dissertations / Theses on the topic 'Desorption'

Author: Grafiati

Published: 4 June 2021

Last updated: 26 July 2025

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1

Wang, Yan. "Laser Desorption Solid Phase Microextraction." Thesis, University of Waterloo, 2006. http://hdl.handle.net/10012/1283.

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The use of laser desorption as a sample introduction method for solid phase microextraction (SPME) has been investigated in this research project. Three different types of analytical instruments, mass spectrometry (MS), ion mobility spectrometry (IMS) and gas chromatography (GC) were employed as detectors. The coupling of laser desorption SPME to these three instruments was constructed and described in here. <br /><br /> Solid phase microextraction/surface enhanced laser desorption ionization fibers (SPME/SELDI) were developed and have been coupled to two IMS devices. SPME/SELDI combin

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2

Salas, Anthony Rene 1969. "Thermal desorption of neutral molecules." Thesis, Massachusetts Institute of Technology, 1998. http://hdl.handle.net/1721.1/10147.

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3

Sonnenberg, Lars. "AFM-basierte Desorption einzelner oberflächenadsorbierter Polyelektrolyte." Diss., lmu, 2007. http://nbn-resolving.de/urn:nbn:de:bvb:19-76109.

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4

Golden, James Hollis. "Ammonia - water desorption in flooded columns." Thesis, Georgia Institute of Technology, 2012. http://hdl.handle.net/1853/44884.

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Refrigeration systems employing the NH3-H2O absorption cycle provide cooling using a thermal energy input. This cycle relies on the zeotropic nature of the refrigerant - absorbent pair: because of the difference in boiling temperatures between NH3 and H2O, they can be separated through selective boiling in the desorber. Desorbers with counter-current flow of the solution and generated vapor enable efficient heat and mass transfer between the two phases, reducing the absorbent content in the generated vapor. Flow visualization experiments at temperatures, concentrations and pressures represen

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5

Rogers, Kevin Shaun. "Laser desorption/laser ionization mass spectroscopy." Thesis, University of Salford, 1993. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.357037.

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6

Whitten, James E. "Electron-stimulated desorption from aluminum surfaces /." The Ohio State University, 1991. http://rave.ohiolink.edu/etdc/view?acc_num=osu14876939231976.

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7

Schneider, Abby Ruth. "PCB desorption from resuspended Hudson River sediment." College Park, Md. : University of Maryland, 2005. http://hdl.handle.net/1903/2933.

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Thesis (Ph. D.) -- University of Maryland, College Park, 2005.<br>Thesis research directed by: Marine-Estuarine-Environmental Sciences. Title from t.p. of PDF. Includes bibliographical references. Published by UMI Dissertation Services, Ann Arbor, Mich. Also available in paper.

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8

Ghalambor, Dezfuli Abdol Mohammad. "Characteristics of a laser desorption ion source." Thesis, McGill University, 1990. http://digitool.Library.McGill.CA:80/R/?func=dbin-jump-full&object_id=60065.

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The characteristics of a pulsed laser ion source have been studied. A pulse from a heating laser (Nd: YAG laser) desorbs the neutral atoms from the surface of a metal target and then a second pulse or pulses from excimer or dye lasers selectively ionize the desorbed neutrals using the Resonance Ionization Spectroscopy technique. Time-of-flight and electrostatic energy analyzer measurements have been used to study different characteristics of this ion source such as spatial, velocity, and energy distributions. These measurements reveal that although the energy spread of the basic source is rela

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9

Takami, Akinori. "Laser induced desorption of molecules from surfaces." Thesis, University of Oxford, 1993. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.334926.

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10

McKean, S. J. "Phosphate desorption characteristics of some tropical soils." Thesis, University of Reading, 1989. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.234447.

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11

Sutherland, Graham Stuart. "Photon desorption processes in large research machines." Thesis, University of Liverpool, 1992. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.386844.

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12

Baird, M. J. "Quantum desorption of '4He and '3He atoms." Thesis, University of Exeter, 1987. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.377309.

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13

Costello, Kevin Francis. "Laser desorption time-of-flight mass spectrometry." Thesis, University of Edinburgh, 1991. http://hdl.handle.net/1842/13475.

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The techniques of supersonic molecular beam cooling and laser multiphoton ionisation (MPI) spectroscopy have been combined to give a potentially powerful analytical technique. Two methods of sample introduction into the molecular beam have been employed, namely resistive heating and laser desorption. The resistive heating method allowed 2-colour MPI spectra of naphthalene, anthracene and perylene to be recorded in a simple free jet apparatus. A sensitivity for anthracene of 600 ppb is estimated. A time-of-flight (TOF) mass spectrometer has been developed, incorporating both linear and reflecti

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14

Amman, Nahom. "PROTECTION AND DESORPTION OF CLAY-BOUND DNA." Thesis, Umeå universitet, Kemiska institutionen, 2018. http://urn.kb.se/resolve?urn=urn:nbn:se:umu:diva-150535.

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15

Xiong, Fengyang. "Desorption and Adsorption of Subsurface Shale Gas." The Ohio State University, 2020. http://rave.ohiolink.edu/etdc/view?acc_num=osu1591975402482308.

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16

Soriano, Joey Kim Tumbali. "Novel plasma-based ambient desorption/ionization source." Thesis, https://doors.doshisha.ac.jp/opac/opac_link/bibid/BB13133185/?lang=0, 2020. https://doors.doshisha.ac.jp/opac/opac_link/bibid/BB13133185/?lang=0.

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周囲プラズマベースの周囲脱離/イオン化ソースにより、従来の大気圧イオン化では不可能な周囲条件下でのサンプルの直接分析が可能になります。これにより、面倒な準備と、多くの有害で複雑なサンプルの分析用質量分析計への導入が解消されます。既存のプラズマベースのアンビエント脱離/イオン化ソースは、通常、2つの電極間にキロヘルツから数メガヘルツの範囲の周波数で直流（DC）または交流（AC）電圧を印加することによって形成されます。この研究では、新しいプラズマベースの周囲脱離/イオン化は、13.56 MHz RFソースから供給される非常に低い電力密度で動作する誘導結合によって生成されたワイヤ安定化大気圧プラズマで構成されています。ワイヤ安定化大気圧プラズマの点火特性、安定性およびプラズマ特性を研究した。<br>Ambient plasma-based ambient desorption/ionization source enables direct analysis of samples under ambient conditions that traditional atmospheric pressure ionization is incapable. It overcomes the tedious preprocessing and often detrimental and com

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17

Tayal, R. K. "Hydrophilic acrylics: polymerisation kinetics, adsorption/ desorption isotherms." Thesis(Ph.D.), CSIR-National Chemical Laboratory, Pune, 2013. http://dspace.ncl.res.in:8080/xmlui/handle/20.500.12252/2178.

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18

Tungtakanpoung, Dondej. "Biosorption of heavy metals by Streptomyces subrutilus (A101) biofilm in a fluidized bed reactor." Thesis, University of Newcastle Upon Tyne, 2002. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.246725.

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19

Fuxen, Claus. "Adsorption, Struktur und Desorption von Organothiolaten auf Goldsubstraten." [S.l.] : [s.n.], 2001. http://deposit.ddb.de/cgi-bin/dokserv?idn=963053744.

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20

Liu, Li. "Thermal dissociation and desorption: A Nose equation approach." Thesis, University of Ottawa (Canada), 1996. http://hdl.handle.net/10393/9482.

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In this theoretical study, I have applied the Nose-Hoover equations of motion with and without rotational considerations to the thermal dissociation of a diatomic molecule, H$\sb2$ in an inert gas. I calculated the pseudo-unimolecular rate constants and activation energy of thermal dissociation. My calculated values of the activation energy agree with the results of other research quite well. In addition, I have shown that the inclusion of rotation in the Nose-Hoover equations of motion does not cause the Nose-Hoover dynamics to be more ergodic, but such inclusion does promote the dissociation

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21

Smith, Marline T. "Treatment of contaminated soils by batch thermal desorption." Thesis, National Library of Canada = Bibliothèque nationale du Canada, 1997. http://www.collectionscanada.ca/obj/s4/f2/dsk3/ftp05/mq24722.pdf.

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22

Naghash, Mahmood. "Steady turbulent gas desorption in a horizontal pipeline." Diss., Georgia Institute of Technology, 1989. http://hdl.handle.net/1853/19006.

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23

Scott, Colin Thomas Joseph. "A characterisation of matrix-assisted laser desorption ionisation." Thesis, University of Glasgow, 1997. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.388567.

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24

Jassim, K. N. "The desorption of anionic dyes from textile fibres." Thesis, University of Leeds, 1989. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.235397.

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25

Prendergast, James W. "Hydrogen desorption and absorption for activated magnesium hydride." Thesis, University of Birmingham, 2010. http://etheses.bham.ac.uk//id/eprint/1143/.

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The interaction between MgH2 and LiBH4 was studied to determine the resultant effects on hydrogen desorption and absorption kinetics for potential use as a hydrogen storage material. It is found that the addition of LiBH4 in small molar ratios results in improved kinetics of the same order as those observed for mechanically milled magnesium. The mixture of MgH2 + LiBH4 in ratios at and below 4:1, once reacted, is a highly reversible material at 300°C and it is observed that the kinetics improve upon the process of hydrogen cycling. This improvement is partially attributed to a refinement in mi

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26

Gunasingam, Pathma V. "Adsorption and desorption of gases in porous silicon." Thesis, Middlesex University, 2001. http://eprints.mdx.ac.uk/13588/.

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This research was undertaken to provide an understanding of the nature, origin and desorption mechanism of species found on the porous silicon (PS) surface and the changes that occur when PS is stored under varying conditions. The PS used in this work was produced from p-, high-resistivity FZ c-Si substrates. Three types of commonly used HF-based electrolytes were chosen for anodisation, under the same process conditions. With the resulting samples, temperature programmed desorption (TPD) coupled with mass spectrometry were used to identify species liberated at different temperatures. FTIR was

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27

Coover, James Brigham. "Phosphorus sorption and desorption in ephemeral gully erosion." Thesis, Kansas State University, 2014. http://hdl.handle.net/2097/17865.

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Master of Science<br>Department of Agronomy<br>Nathan O. Nelson<br>Phosphorus (P) is an essential nutrient in crop production, but P inputs to surface waters have resulted in impairments such as eutrophication and algae blooms. Non-point sources such as agricultural fields are a main contributor of P. Kansas, being a high agricultural dependent state, has frequent fresh water body impairments. Multiple erosion and transport processes contribute to P loss. While P loss from sheet and rill erosion has been studied extensively, P loss from ephemeral gully erosion is largely unknown. The obje

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28

Reed, Stewart T. "Copper adsorption/desorption characteristics on copper amended soils." Diss., This resource online, 1993. http://scholar.lib.vt.edu/theses/available/etd-06062008-171512/.

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29

Wang, Lin-Lin. "A computational study of surface adsorption and desorption." [Gainesville, Fla.] : University of Florida, 2004. http://purl.fcla.edu/fcla/etd/UFE0004383.

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30

Harris, Peter Ronald. "Laser desorption from a room temperature ionic liquid." W&M ScholarWorks, 2009. https://scholarworks.wm.edu/etd/1539623542.

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We report laser desorption from a Room Temperature Ionic Liquid (RTIL) as a novel source for time of flight mass spectrometry. We use the 2nd harmonic of an Nd:YAG laser to deposit intensities of 1-50 MW/cm2 via backside illumination onto our RTIL desorption sample. A microstructured metal grid situated on top of a glass microscope slide coated with RTIL serves as our desorption sample. The RTIL we use, 1-Butyl, 3-Methylimidazolium Hexafluorophosphate, remains liquid at pressures below 10-8 torr. The use of liquid desorption sample allows for improved surface conditions, homogeneity and sample

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31

Gladh, Jörgen. "Bonding and Desorption Mechanismsof CO on Metal Surfaces." Licentiate thesis, Stockholms universitet, Fysikum, 2012. http://urn.kb.se/resolve?urn=urn:nbn:se:su:diva-77218.

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I have investigated two different systems CO/Fe(100) and CO/Ru(0001), toobtain new information on the binding and desorption processes. The twodifferent systems have served as a model system, one for a static examination,CO on iron, and for the dynamic case, CO on ruthenium. To perform theseinvestigations, several types of techniques have been used such as, X-rayabsorption spectroscopy, X-ray emission spectroscopy, and femtosecond laserinduced desorption techniques such as two-pulse correlation. For the CO/Fe(100) system, we found that the on-top CO “<img src="http://www.diva-portal.org/cgi-bi

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32

Ochoa, Mariela L. "Forensic and Proteomic Applications of Thermal Desorption Ion Mobility Spectrometry and Matrix-Assisted Laser Desorption/Ionization Time-of-Flight Mass Spectrometry." Ohio University / OhioLINK, 2005. http://www.ohiolink.edu/etd/view.cgi?ohiou1113585811.

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33

Olgun, Asim. "The kinetics and dynamics of the liquid surface from molecular beam scattering." Thesis, University of Sussex, 1997. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.388968.

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34

Thiel, Stephan. "Theoretische Untersuchungen zur laserinduzierten Desorption kleiner Moleküle von Oberflächen." [S.l. : s.n.], 2000. http://www.diss.fu-berlin.de/2001/36/index.html.

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35

Huisinga, Marten. "Ultraviolet photoelectron spectroscopy and electron stimulated desorption from CaF2." [S.l. : s.n.], 1998. http://www.diss.fu-berlin.de/1999/24/index.html.

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36

Niedermayer, Thomas Philipp. "Nichtthermische und thermische Desorption von Helium auf Pt(111)." [S.l. : s.n.], 2002. http://deposit.ddb.de/cgi-bin/dokserv?idn=965396592.

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37

Zacharia, Renju. "Desorption of gases from graphitic and porous carbon surfaces." [S.l. : s.n.], 2004. http://www.diss.fu-berlin.de/2004/162/index.html.

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38

Lafferty, Brandon James. "Methyl arsenic adsorption and desorption behavior on iron oxides." Thesis, Texas A&M University, 2003. http://hdl.handle.net/1969.1/2264.

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Arsenic is a toxic element that is widely distributed throughout the earth??s crust as a result of both natural geologic processes and anthropogenic activities. In virtually all environments, methylated forms of arsenic can be found. Because of the widespread distribution and toxicity of arsenic and methyl-arsenic, their adsorption behavior on soil minerals is of great interest. Although considerable attention has been given to the behavior of inorganic arsenic on mineral surfaces, little research has been conducted regarding interactions of the methyl-arsenic forms. The objective of this stu

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39

Bennett, Kathryn C. (Kathryn Condreay). "Desorption/Diffusion of Benzene After Simulated Ground Water Remediation." Thesis, University of North Texas, 1989. https://digital.library.unt.edu/ark:/67531/metadc500458/.

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A study was undertaken to examine the desorption/ iffusion of benzene after simulated ground water remediation in aquifer material of differing carbon content using column experiments and comparing the results to batch experiments and adsorption empirical relationships. It was hypothesized that the organic carbon of the aquifer material will affect desorption/diffusion. Results from the column experiment indicated no significant difference in the increase benzene concentrations after remediation between aquifer materials of differing carbon content, however, a significant increase in benzene c

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40

Wyplosz, Nicolas. "Laser desorption mass spectrometric studies of artists' organic pigments." [S.l. : Amsterdam : s.n.] ; Universiteit van Amsterdam [Host], 2003. http://dare.uva.nl/document/69401.

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41

Millitzer, Marcus. "Zur Ad- und Desorption von Proteinen an hydrophoben Adsorbentien /." Berlin : Logos, 2007. http://d-nb.info/986953156/04.

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42

Kukowski, Hermann. "Untersuchungen zur Ad- und Desorption ausgewählter Chemikalien in Böden /." Kiel, 1989. http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&doc_number=003832767&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA.

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43

Acharya, Ananta R. "Indium Nitride Surface Structure, Desorption Kinetics and Thermal Stability." Digital Archive @ GSU, 2013. http://digitalarchive.gsu.edu/phy_astr_diss/62.

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Unique physical properties such as small effective mass, high electron drift velocities, high electron mobility and small band gap energy make InN a candidate for applications in high-speed microelectronic and optoelectronic devices. The aim of this research is to understand the surface properties, desorption kinetics and thermal stability of InN epilayers that affect the growth processes and determine film quality as well as device performance and life time. We have investigated the structural properties, the surface desorption kinetics, and the thermal stability using Auger electron spectros

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44

Uygur, Veli. "Zn sorption/desorption chemistry in calcareous soils from Turkey." Thesis, University of Newcastle Upon Tyne, 1998. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.388131.

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45

Clipston, Nigel L. "Laser desorption/laser ionization Time-of-Flight Mass Spectrometry." Thesis, University of Salford, 1997. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.360476.

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46

Arab, F. K. "A study of desorption of ammonia from landfill leachate." Thesis, University of Strathclyde, 1985. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.304813.

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47

PORTES, VANIA LUCIA DE OLIVEIRA. "THE USE OF THERMAL DESORPTION FOR CLEANING OILED DEBRIS." PONTIFÍCIA UNIVERSIDADE CATÓLICA DO RIO DE JANEIRO, 2002. http://www.maxwell.vrac.puc-rio.br/Busca_etds.php?strSecao=resultado&nrSeq=2899@1.

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CONSELHO NACIONAL DE DESENVOLVIMENTO CIENTÍFICO E TECNOLÓGICO<br>Notícias ambientais no Brasil foram dominadas através de derramamentos de óleo nos últimos anos. Esta dissertação apresenta os resultados de um programa experimental para estudar a capacidade de desorção térmica em limpar as costas afetadas.A temperatura ambiente, os resíduos oleosos emitem metano e amônia e estas emissões tendem a aumentar com a elevação das temperaturas. Por outro lado, o teor de óleo e graxa dos resíduos oleosos cai com o aumento da temperatura e exposição prolongada.Um cobertor térmico foi construído

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48

LIMA, FRANCISCO ALBERTO FERNANDEZ. "LASER INDUCED DESORPTION IN INSULIN, CARBON AND ALKALI HALIDES." PONTIFÍCIA UNIVERSIDADE CATÓLICA DO RIO DE JANEIRO, 2006. http://www.maxwell.vrac.puc-rio.br/Busca_etds.php?strSecao=resultado&nrSeq=8666@1.

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CENTRO LATINO-AMERICANO DE FÍSICA<br>O fenômeno de dessorção iônica a partir da incidência de pulsos de radiação laser ultravioleta sobre superfícies em vácuo foi estudada. A dessorção de três tipos diferentes de sólidos foi analisada: insulina, carbono (amorfo e grafite) e policristais de haletos alcalinos. Os processos fundamentais da interação da radiação laser com sólido e o vapor formado, assim como a evolução do plasma gerado, foram descritos satisfatoriamente através de um modelo térmico e da simulação de espectros de têmpo-de-vôo para os primeiros instante da expansão ao vácuo.

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49

VIANA, ALVARO DE FREITAS. "DEVELOPMENT OF THERMAL DESORPTION IN SITU PIECES OF EQUIPMENT." PONTIFÍCIA UNIVERSIDADE CATÓLICA DO RIO DE JANEIRO, 2006. http://www.maxwell.vrac.puc-rio.br/Busca_etds.php?strSecao=resultado&nrSeq=9816@1.

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PONTIFÍCIA UNIVERSIDADE CATÓLICA DO RIO DE JANEIRO<br>COORDENAÇÃO DE APERFEIÇOAMENTO DO PESSOAL DE ENSINO SUPERIOR<br>O uso do calor como meio alternativo para a remediação de áreas contaminadas por compostos orgânicos - hidrocarbonetos derivados de petróleo e policíclicos aromáticos, organoclorados, pesticidas, dentre outros - tem se mostrado competitivo quando comparado a outras soluções, principalmente levando-se em consideração questões práticas como a eficiência dos seus resultados e o seu tempo de execução. Seguindo uma linha de pesquisa do Núcleo de Geotecnia Ambiental da PUC-Rio,

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50

Haas, Ole-Erich, Jean-Marc Simon, and Signe Kjelstrup. "Adsorption-desorption kinetics of H 2 molecules on graphite." Universitätsbibliothek Leipzig, 2015. http://nbn-resolving.de/urn:nbn:de:bsz:15-qucosa-189614.

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