Academic literature on the topic 'Deuterated electrolyte'

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Journal articles on the topic "Deuterated electrolyte"

1

Gauthier, Roby, Hongyi Lin, Venkat Viswanathan, and Jay F. Whitacre. "A Coupled NMR and Differential Capacity Study of the Consumption of Electrolyte and Additive Components during the Formation Cycle of Li-Ion Pouch Cells." ECS Meeting Abstracts MA2024-01, no. 2 (2024): 224. http://dx.doi.org/10.1149/ma2024-012224mtgabs.

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Understanding the side reactions occurring inside lithium-ion cells remain a significant challenge, presenting opportunities for innovation. In this context, we developed a coupled 1H NMR (nuclear magnetic resonance) and dQ/dV (differential capacity) analysis method aimed at enhancing our understanding of these reactions during the formation cycle. Using deuterated acetonitrile as an extraction solvent, we measured the relative consumption of electrolyte components inside different electrolyte, including in 1.2M LiPF6 EC:EMC 3:7 2% VC and 1.2M LiPF6 EC:EMC 3:7 2% VC + 1% DTD electrolytes at di
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2

Bin Zulkifli, Ahmad Zulazlan Shah, Muhammad Akmal Bin Kamarudin, Azizah Binti Mainal, and Suhana Binti Mohd Said. "Conductivity Studies on the Effect of a Nematic Liquid Crystal on Polyvinyl Alcohol-Based Electrolytes." Advanced Materials Research 895 (February 2014): 142–46. http://dx.doi.org/10.4028/www.scientific.net/amr.895.142.

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Recently, a few studies have shown that the introduction of liquid crystals (LCs) in polymer electrolytes would lead to an increase in the chain mobility and the ionic conductivity. It is believed that this enhancement of the polymer electrolyte performance is greatly influenced by the order parameter of the liquid crystal in this system. In this study, a deuterated 4-pentyl-4-cyano-biphenyl (5CB-d2) nematic liquid crystal-doped polyvinyl alcohol (PVA) polymer electrolyte were prepared. The orientational order of the nematic liquid crystal is then investigated via the quadrupolar splittings of
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3

Dong, Bo, Jordi Jacas Biendicho, Stephen Hull, Ronald I. Smith, and Anthony R. West. "In-Situ Neutron Studies of Electrodes for Li-Ion Batteries Using a Deuterated Electrolyte: LiCoO2as a Case Study." Journal of The Electrochemical Society 165, no. 5 (2018): A793—A801. http://dx.doi.org/10.1149/2.0291805jes.

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4

Yerdauletov, M., M. V. Avdeev, A. A. Tomchuk, F. S. Napolskiy, D. M. Djanseitov, and V. A. Krivchenko. "Nanoscale Structure of Positive Electrodes for Lithium-Ion Batteries with Graphene-Based Additives according to Small-Angle Neutron Scattering." Поверхность. Рентгеновские, синхротронные и нейтронные исследования, no. 4 (April 1, 2023): 61–66. http://dx.doi.org/10.31857/s1028096023040052.

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The adaptation of neutron scattering methods for studying the microstructure of electrode materials of lithium-ion batteries was continued in order to improve their characteristics with respect to specific energy. Using small-angle scattering of thermal neutrons, the effect of conductive carbon additives (graphene and graphene oxide) on the porous structure of electrodes made from LiFePO4, Li4Ti5O12 and LiNiMnCoO2 was studied. To separate the scattering by closed and open pores, the electrodes were wetted with a typical liquid electrolyte with a deuterated liquid carrier (dimethyl carbonate),
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5

Koizumi, Satoshi. "In-situ Observation of Polymer Electrolyte Fuel Cell Using Deuterium Gas." Acta Crystallographica Section A Foundations and Advances 70, a1 (2014): C1324. http://dx.doi.org/10.1107/s2053273314086756.

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In order to visualize water distribution in an operating fuel cell, we combined two different methods using neutron as a probe, i.e., a combined method of small-angle & ultra-small-angle scattering (SANS) and radiography imaging. SANS observes water distribution in a membrane electrolyte assembly (MEA), whereas radiography observes bulk water appeared in a gas flow channel (so called "flooding"). The polymer electrolyte fuel cell (PEFC) was specially designed suitable for small-angle neutron scattering by replacing materials with aluminum in order to decrease background scattering. We empl
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Campillo-Robles, Jose Miguel, Damian Goonetilleke, Mallol Daniel Soler, et al. "Monitoring lead-acid battery function using operando neutron radiography." Journal of Power Sources 438 (August 10, 2019): 226976. https://doi.org/10.1016/j.jpowsour.2019.226976.

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Investigating batteries while they operate allows researchers to track the inner electrochemical processes involved in working conditions. This study describes the first neutron radiography investigation of a lead-acid battery. A custom-designed neutron friendly lead-acid cell and casing is developed and studied operando during electrochemical cycling, in order to observe the activity within the electrolyte and at the electrodes. This experimental work is coupled with Monte Carlo simulations of neutron transmittance. Details of cell construction, data collection and data analysis are pres
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Niemann, Valerie Anne, Mathieu Doucet, Hanyu Wang, et al. "Determining the Composition and Structure of a High-Performing SEI Layer for Lithium-Mediated Nitrogen Reduction to Ammonia." ECS Meeting Abstracts MA2023-02, no. 60 (2023): 2902. http://dx.doi.org/10.1149/ma2023-02602902mtgabs.

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The industrial synthesis of ammonia (NH3) via the Haber-Bosch process has enabled mass production of fertilizer and the human population growth to 8 billion.1 NH3 also shows promise as a long-term, energy-dense fuel amenable to widespread distribution.2 However, the Haber-Bosch process operates at high temperatures and pressures in centralized facilities and accounts for 1.3% of global carbon emissions.1,2 To ensure a food-secure future and realize NH3 as a truly carbon-free fuel, we must develop an NH3 synthesis alternative that operates at ambient conditions and can be driven by renewables.
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8

Yu, Sunmoon, Hiroki Yamauchi, and Yang Shao-Horn. "Effect of Cations on Electrocatalytic CO2-to-Methanol Conversion by Heterogenized Molecular Catalyst." ECS Meeting Abstracts MA2023-01, no. 26 (2023): 1696. http://dx.doi.org/10.1149/ma2023-01261696mtgabs.

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Catalytic benefit and role of electrolyte cations for electrochemical CO2 reduction reaction have recently received significant research attention. It has been experimentally and theoretically demonstrated that cations can stabilize the key intermediate species, for example, *CO2 –, through mid- or short-range electrostatic interactions, facilitating the CO2 activation step.1-2 However, to date, these discussions are mostly limited to CO2-to-CO conversion (a two electron/proton transfer reaction) and electrostatic stabilization of reaction intermediate species. In present work, we show that ca
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9

Petibon, R., Jing Li, Neeraj Sharma, Wei Kong Pang, Vanessa K. Peterson, and J. R. Dahn. "The use of deuterated ethyl acetate in highly concentrated electrolyte as a low-cost solvent for in situ neutron diffraction measurements of Li-ion battery electrodes." Electrochimica Acta 174 (August 2015): 417–23. http://dx.doi.org/10.1016/j.electacta.2015.05.169.

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10

Lee, Jongmin, Alexander Bychkov, Inbal Gavish Segev Gavish, Yair Ein-Eli, and Markus Strobl. "Neutron Imaging of Proton-Irradiated Batteries for Space Applications." ECS Meeting Abstracts MA2025-01, no. 5 (2025): 611. https://doi.org/10.1149/ma2025-015611mtgabs.

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A Li-ion battery (LIB) is the core component of energy stroage systems for space applications. To ensure performance stability and durability, it is crucial to understand the impact of cosmic radiations on LIB components and identify the underlying degradation mechanisms. Protons (H+), predominant species in cosmic rays, introduce defects in a crystalline structure, such as Frenkel pairs [1]. Graphite-based anodes are critically affected by these defects, influencing the formation of the solid-electrolyte interphase (SEI) and dead Li. Therefore, analyzing Li distribution in operating batteries
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