Academic literature on the topic 'Diastereoselective reduction'

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Journal articles on the topic "Diastereoselective reduction"

1

Pereira, Vera L. P., Francine P. Meirelis та Bruna G. N. Vieira. "Divergent and Diastereoselective Synthesis of α-Monosubstituted and trans-α,β-Disubstituted γ-Lactams from (S)-N,N-Dibenzyl-α-amino Aldehydes via Henry and Michael Reactions". Synthesis 52, № 23 (2020): 3650–56. http://dx.doi.org/10.1055/s-0040-1706423.

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γ-Monosubstituted and trans-α,β-disubstituted γ-lactams were diastereoselectively synthesized from common intermediates (S)-N,N-dibenzylated aldehydes derived from natural l-(α)-amino acids, employing a divergent approach. The key features of the routes include diastereoselective Henry and Michael reactions that produced chiral γ-nitroester derivatives, which were subsequently submitted to a tandem reduction-lactamization sequence providing the title compounds. The versatility of routes can allow the preparation of several other mono-, di-, or tri-substituted γ-lactams.
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2

Ramaswamy, Sowmianarayanan, and Allan C. Oehlschlager. "Efficient synthesis of exo- and endo-brevicomin from a single precursor." Canadian Journal of Chemistry 67, no. 5 (1989): 794–96. http://dx.doi.org/10.1139/v89-120.

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Diastereoselective reduction of 2-propionyl-6-methyl-3,4-dihydropyran and its ring opened derivatives, followed by acidic work-up, gives mixtures rich (>9:1) of either exo- or endo-brevicomin. Keywords: exo- and endo-brevicomin, diastereoselective ketone reduction.
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3

Zielinski, Claudia, and Hans J. Schäfer. "Diastereoselective cathodic reduction of chiral phenylglyoxylamides." Tetrahedron Letters 35, no. 31 (1994): 5621–24. http://dx.doi.org/10.1016/s0040-4039(00)77263-7.

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4

Tavtorkin, A. N., L. A. Sviridova, G. A. Golubeva, Yu V. Nelyubina, K. A. Lyssenko та K. A. Kochetkov. "Diastereoselective reduction of α-pyrazolidinyl ketones". Russian Chemical Bulletin 58, № 3 (2009): 624–30. http://dx.doi.org/10.1007/s11172-009-0066-7.

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5

Lóránda, Tamás, Erzsébet Osza, Gyula Kispála, et al. "Diastereoselective reduction of cyclic bioactive Mannich ketones." Arkivoc 2004, no. 7 (2003): 34–52. http://dx.doi.org/10.3998/ark.5550190.0005.704.

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6

Malamakal, Roy M., Whitney R. Hess та Todd A. Davis. "Highly Efficient Diastereoselective Reduction of α-Fluoroimines". Organic Letters 12, № 10 (2010): 2186–89. http://dx.doi.org/10.1021/ol100647b.

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7

Mohanta, Pramod K., Todd A. Davis, Jeremy R. Gooch та Robert A. Flowers. "Chelation-Controlled Diastereoselective Reduction of α-Fluoroketones". Journal of the American Chemical Society 127, № 34 (2005): 11896–97. http://dx.doi.org/10.1021/ja052546x.

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8

Miyashita, Kazuyuki, Tomohiro Toyoda, Hideto Miyabe та Takeshi Imanishi. "Diastereoselective Reduction of α-(p-Tolylsulfinyl)ketoximes". Synlett 1995, № 12 (1995): 1229–31. http://dx.doi.org/10.1055/s-1995-5253.

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9

Salom-Roig, Xavier, and Claude Bauder. "Recent Applications in the Use of Sulfoxides as Chiral Auxiliaries for the Asymmetric Synthesis of Natural and Biologically Active Products." Synthesis 52, no. 07 (2020): 964–78. http://dx.doi.org/10.1055/s-0039-1690803.

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The contribution of chiral sulfoxides as versatile auxiliaries in the field of organic chemistry has shown a prevalent interest in the asymmetric synthesis of natural products during the last 45 years. In this short review, we report the recent applications of these chiral auxiliaries to the synthesis of natural and biological active products highlighted from 2010 to 2019. We hope to allow the reader to have an overview of the potential of sulfoxide chemistry in the field of enantio­selective synthesis.1 Introduction2 Diastereoselective Additions to Ketones2.1 Reduction of β-Keto Sulfoxides2.2
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10

Chen, Kau-Ming, Goetz E. Hardtmann, Kapa Prasad, Oljan Repič та Michael J. Shapiro. "1,3- diastereoselective reduction of β-hydroxyketones utilizing alkoxydialkylboranes". Tetrahedron Letters 28, № 2 (1987): 155–58. http://dx.doi.org/10.1016/s0040-4039(00)95673-9.

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