Academic literature on the topic 'Diaza-bicyclo-[3.2.1]octane'

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Journal articles on the topic "Diaza-bicyclo-[3.2.1]octane"

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Boehringer, Régis, Philippe Geoffroy, and Michel Miesch. "Base catalyzed synthesis of bicyclo[3.2.1]octane scaffolds." Organic & Biomolecular Chemistry 13, no. 25 (2015): 6940–43. http://dx.doi.org/10.1039/c5ob00933b.

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A base-catalyzed and time controlled reaction of 1,3-cyclopentanediones tethered to activated olefins afforded in high yields either bicyclo[3.2.1]octane-6,8-dione or bicyclo[3.2.1]octane-6-carboxylate derivatives.
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Dastlik, KA, EL Ghisalberti, BW Skelton, and AH White. "Structural Studies of Bicyclo[3.2.1]octane and Bicyclo[2.2.2]octane Diols." Australian Journal of Chemistry 45, no. 5 (1992): 959. http://dx.doi.org/10.1071/ch9920959.

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The crystal structures of 4 α,5 α and 4 β,5 β-dihydroxyisoeremone (4) and (5), incorporating the bicyclo[2.2.2]octane skeleton, and the bicyclo[3.2.l]octane diol (6) have been determined by X-ray crystallographic methods.
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Zhou, Xiao-Han, Ying Liu, Rui-Jie Zhou, Hao Song, Xiao-Yu Liu, and Yong Qin. "Construction of the highly oxidized bicyclo[3.2.1]octane CD ring system of aconitine via a late stage enyne cycloisomerization." Chemical Communications 54, no. 86 (2018): 12258–61. http://dx.doi.org/10.1039/c8cc06819d.

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Zaytsev, Andrey V., James E. Pickles, Suzannah J. Harnor, et al. "Concise syntheses of bridged morpholines." RSC Advances 6, no. 59 (2016): 53955–57. http://dx.doi.org/10.1039/c6ra08737j.

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Practical syntheses of 8-oxa-3-aza-bicyclo[3.2.1]octane and 9-oxa-3-aza-bicyclo[3.3.1]nonane, useful intermediates for synthesising kinase inhibitors, were achieved from readily available starting materials, using a solvent-free thermolytic cyclisation for the key step.
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Bakthadoss, Manickam, and Mohammad Mushaf. "Intramolecular [3 + 2] nitrone cycloaddition reaction: highly regio and diastereoselective synthesis of bicyclo[3.2.1]octane scaffolds." Organic & Biomolecular Chemistry 18, no. 47 (2020): 9653–59. http://dx.doi.org/10.1039/d0ob01960g.

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Development of a regio- and a diastereoselective protocol for the synthesis of bicyclo[3.2.1]octane frameworks from vinylogous carbonates and N-substituted hydroxylamine hydrochlorides via intramolecular 1,3-dipolar nitrone cycloaddition reaction.
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6

Della, EW, and J. Tsanaktsidis. "Synthesis of Bridgehead-Bridgehead Substituted Bicycloalkanes." Australian Journal of Chemistry 38, no. 11 (1985): 1705. http://dx.doi.org/10.1071/ch9851705.

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A convenient synthetic route to several bicycloalkanes bearing substitution at both bridgehead positions is described. The two-step procedure, which involves alkylation of the monoenolates of readily available cyclohexane diesters with 1,2-dihaloethane followed by a base-induced cyclization of the derived haloethylated product, was successfully applied to the synthesis of dimethyl bicyclo[2.2.2]octane- 1,4-dicarboxylate, dimethyl bicyclo[2.2.1]heptane-1,4-dicarboxylate and dimethyl bicyclo[3.2.1]octane-1,5-dicarboxylate. Additionally, it was found that the two latter diesters could be obtained
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DASTLIK, K. A., E. L. GHISALBERTI, B. W. SKELTON, and A. H. WHITE. "ChemInform Abstract: Structural Studies of Bicyclo(3.2.1)octane and Bicyclo(2.2.2)octane Diols." ChemInform 23, no. 35 (2010): no. http://dx.doi.org/10.1002/chin.199235251.

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Lebe, Karen E., and Russell J. Cox. "Oxidative steps during the biosynthesis of squalestatin S1." Chemical Science 10, no. 4 (2019): 1227–31. http://dx.doi.org/10.1039/c8sc02615g.

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Two enzymes of previously unknown function encoded by the squalestatin biosynthetic gene cluster from the fungus Phoma MF5453 catalyse a remarkable series of six consecutive oxidations to form the 4,8-dioxa-bicyclo[3.2.1]octane core of the squalestatins.
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Eggimann, Thomas, Nan Ibrahim, R. Anthony Shaw, and Hal Wieser. "The vibrational spectra (100–1500 cm−1) of a series of bicyclo[3.2.1]octanes assigned by means of scaled 3-21G ab initio harmonic force fields." Canadian Journal of Chemistry 71, no. 4 (1993): 578–609. http://dx.doi.org/10.1139/v93-080.

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The infrared absorption (vapor phase and solution) and Raman (liquid phase) spectra of bicyclo[3.2.1]octane, 8-oxabicyclo[3.2.1]octane, 6-oxabicyclo[3.2.1]octane, 6,8-dioxabicyclo[3.2.1]octane, and the 7,7-dideutero-substituted derivatives of the last two compounds are reported in the region 100–1500 cm−1 for the first time. The vibrational spectra are assigned almost completely with the guidance of ab initio 3-21G geometries and scaled force fields. A total of 14 force-field scale facors are transferred from smaller molecules, predicting the frequencies with an average error of 7.6 cm−1 (1.2%
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Hanson, James R. "Skeletal Rearrangements of Rings C and D of the Kaurene and Beyerene Tetracyclic Diterpenoids." Journal of Chemical Research 42, no. 4 (2018): 175–80. http://dx.doi.org/10.3184/174751918x15233039624478.

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The skeletal rearrangement of the bicyclo[3.2.1]octane portion of rings C and D of the kaurene and beyerene tetracyclic diterpenoids are reviewed, revealing the tendency of the secondary carbocations to rearrange to tertiary carbocations with the eventual preferential formation of bicyclo[2.2.2]octanes. Under acid-catalysed conditions the variations in the products with the nucleophilicity of the counter ions suggest that the intervention of discrete rather than completely delocalised non-classical carbonium ions may be contributing to the reaction pathway.
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Dissertations / Theses on the topic "Diaza-bicyclo-[3.2.1]octane"

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Liron, Mélanie. "Synthèse totale de la quinocarcine." Phd thesis, Ecole Polytechnique X, 2006. http://pastel.archives-ouvertes.fr/pastel-00002175.

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La quinocarcine appartient à la famille des tétrahydroisoquinoléines, produits naturels qui constituent de puissants agents cytotoxiques et possèdent de nombreuses activités biologiques telles qu'antitumorales et antibiotiques. Son intérêt biologique ainsi qu'un faible rendement d'extraction du milieu naturel ont fait d'elle une cible attrayante en synthèse organique. Dans le but d'effectuer la synthèse totale de la quinocarcine, plusieurs stratégies ont été envisagées pour construire la structure tétracyclique ABCD. Ces stratégies se sont appuyées sur différentes étapes clé comme des réaction
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Couturier, Cédric. "Etudes vers la synthèse totale de la (-)-lémonomycine. Synthèse d'acides beta-aminés fonctionnalisés par ouverture nucléophile d'aziridiniums dérivés de la sérine." Phd thesis, Palaiseau, Ecole polytechnique, 2005. http://www.theses.fr/2005EPXX0029.

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Book chapters on the topic "Diaza-bicyclo-[3.2.1]octane"

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Sun, Fuxing, Guangshan Zhu, Qianrong Fang, and Shilun Qiu. "A novel Metal-Organic Framework with pcu topology constructed from cadmium and 1, 4-diaza-bicyclo [2.2.2] octane-N, N’-dioxide." In Zeolites and related materials: Trends, targets and challenges, Proceedings of the 4th International FEZA Conference. Elsevier, 2008. http://dx.doi.org/10.1016/s0167-2991(08)80235-2.

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Conference papers on the topic "Diaza-bicyclo-[3.2.1]octane"

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Šála, Michal, Milan Dejmek, Eliška Procházková, et al. "Novel conformationally locked nucleosides and oligonucleotides based on bicyclo[3.2.1]octane scaffold as a pseudosugar moiety." In XVIth Symposium on Chemistry of Nucleic Acid Components. Institute of Organic Chemistry and Biochemistry, Academy of Sciences of the Czech Republic, 2014. http://dx.doi.org/10.1135/css201414379.

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