Academic literature on the topic 'Diazo compounds'

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Journal articles on the topic "Diazo compounds"

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Osipov, Sergey, and Daria Vorobyeva. "Selective Synthesis of 2- and 7-Substituted Indole Derivatives via Chelation-Assisted Metallocarbenoid C–H Bond Functionalization." Synthesis 50, no. 02 (2017): 227–40. http://dx.doi.org/10.1055/s-0036-1591498.

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Functionally substituted indole derivatives are important intermediates for the synthesis of new potential drug candidates exhibiting strong bioactivities. Over the past few years, significant progress has been made in the direct C–H functionalization of the indole ring through the usage of metal-catalyzed intermolecular cross-coupling with diazo compounds. Directing group strategy provides a unique possibility for selective insertion of carbenes catalytically generated from diazo compounds into challenging indole C2–H and C7–H bonds. This short review summarizes recent advances in carbenoid f
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Valdés, Carlos, Miguel Paraja, and Manuel Plaza. "Transition-Metal-Free Reactions Between Boronic Acids and N-Sulfonylhydrazones or Diazo Compounds: Reductive Coupling Processes and Beyond." Synlett 28, no. 18 (2017): 2373–89. http://dx.doi.org/10.1055/s-0036-1590868.

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The metal-free reaction between diazo compounds and boronic acids has been established in recent years as a powerful C(sp3)–C bond-forming reaction. This account covers the recent advances in this area. First, the various synthetic applications of reactions with N-sulfonylhydrazones as a convenient source of diazo compounds is discussed. These transformations can be regarded as reductive couplings of carbonyl compounds. Also covered is the incorporation of other mild sources of diazo compounds in these reactions: diazotization of amines and oxidation of hydrazones. Finally, the development of
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Zhukovsky, Daniil, Dmitry Dar’in, Olga Bakulina та Mikhail Krasavin. "Preparation and Synthetic Applications of Five-to-Seven-Membered Cyclic α-Diazo Monocarbonyl Compounds". Molecules 27, № 6 (2022): 2030. http://dx.doi.org/10.3390/molecules27062030.

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The reactivity of cyclic α-diazo monocarbonyl compounds differs from that of their acyclic counterparts. In this review, we summarize the current literature available on the synthesis and synthetic applications of three major classes of cyclic α-diazo monocarbonyl compounds: α-diazo ketones, α-diazo lactones and α-diazo lactams.
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Wang, Jianbo. "When diazo compounds meet with organoboron compounds." Pure and Applied Chemistry 90, no. 4 (2018): 617–23. http://dx.doi.org/10.1515/pac-2017-0713.

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AbstractTransition-metal free reactions of diazo compounds with organoboron compounds provide some unique approaches for the formation of C–C, C–B and C–Si bonds. WithN-tosylhydrazones as the precursors for non-stabilized diazo compound, this type of reaction becomes practically useful in organic synthesis. Transition-metal-free synthetic methodologies for borylation,gem-diborylation,gem-silylborylation arylation, 2,2,2-trifluoroethylation andgem-difluorovinylation have been successfully developed.
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Ciszewski, Łukasz W., Katarzyna Rybicka-Jasińska, and Dorota Gryko. "Recent developments in photochemical reactions of diazo compounds." Organic & Biomolecular Chemistry 17, no. 3 (2019): 432–48. http://dx.doi.org/10.1039/c8ob02703j.

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Chemistry of diazo compounds is dominated by transition metal catalysis but recently, photoinitiated reactions of diazo compounds have attracted a lot of attention. This mini-review describes recent discoveries on the reactivity of diazo compounds under light irradiation.
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Durka, Jakub, Joanna Turkowska, and Dorota Gryko. "Lightening Diazo Compounds?" ACS Sustainable Chemistry & Engineering 9, no. 27 (2021): 8895–918. http://dx.doi.org/10.1021/acssuschemeng.1c01976.

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Sutton, Derek. "Organometallic diazo compounds." Chemical Reviews 93, no. 3 (1993): 995–1022. http://dx.doi.org/10.1021/cr00019a008.

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Yates, Peter, and J. A. Eenkhorn. "Aliphatic diazo compounds." Tetrahedron 44, no. 11 (1988): 3159–70. http://dx.doi.org/10.1016/s0040-4020(01)85947-0.

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Böhshar, Manfred, Heinrich Heydt, and Manfred Regitz. "Diazo compounds-66." Tetrahedron 42, no. 6 (1986): 1815–22. http://dx.doi.org/10.1016/s0040-4020(01)87600-6.

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Zhu, Shou-Fei, and Qi-Lin Zhou. "Iron-catalyzed transformations of diazo compounds." National Science Review 1, no. 4 (2014): 580–603. http://dx.doi.org/10.1093/nsr/nwu019.

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Abstract Although iron-promoted diazo transformations were only discovered during the 1990s, iron can undergo facile changes in its oxidation state and possesses distinct Lewis acid character, and these properties have afforded iron a privileged position as a catalyst in the transformations of diazo compounds. In this review, we have provided an overview of the iron-catalyzed diazo transformation reactions reported in the literature by the end of 2013 with the aim of stimulating further interest in this area of research.
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Dissertations / Theses on the topic "Diazo compounds"

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Morfitt, Charles Neil. "Diazo compounds in asymmetric synthesis." Thesis, University of Exeter, 1999. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.286531.

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Mueller, Simon T. R. "Diazo compounds in continuous flow technology." Thesis, Cardiff University, 2015. http://orca.cf.ac.uk/86662/.

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Diazo compounds are highly reactive carbene precursors which can be used to generate molecular complexity rapidly. However, diazo compounds are highly energetic and dangerous compounds and therefore, their use in large-scale applications remains rare. In this work, the use of continuous flow technology for the safe, efficient and scalable use of diazo compounds is described. By using flow chemistry, diazo compounds were safely generated within small diameter devices and directly used in subsequent reactions without a hazardous isolation of the diazo reagents. This thesis describes five new pro
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Khodaei, M. M. "The reactions of diazo compounds with nucleophiles." Thesis, University of Liverpool, 1988. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.384393.

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Poh, Jian Siang. "Coupling reactions using flow-generated diazo compounds." Thesis, University of Cambridge, 2017. https://www.repository.cam.ac.uk/handle/1810/268223.

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In recent years, the exploitation of flow technologies as an enabling tool to access unique chemical reactivity has flourished. This dissertation describes the utilisation of these flow methods to access new sets of highly versatile, unstable diazo compounds and their application in coupling reactions. In the first chapter, an introduction into the structure and reactivity of diazo compounds is provided, as well as a discussion of currently available methods for their generation. The second chapter describes the coupling of flow-generated, semi-stabilised diazo compounds with terminal alkynes
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Sheldon, Chris G. "Development of new synthetic transformations using diazo compounds." Thesis, University of Bristol, 2003. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.396672.

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Hersey, Richard. "Stabilisation of diazo compounds used in lithographic systems." Thesis, Sheffield Hallam University, 1991. http://shura.shu.ac.uk/19786/.

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The research undertaken has been an investigation of the deterioration that occurs during lithographic plate manufacture and storage. The aim of the research was to identify and eliminate the causes of the deterioration. Deterioration was found to be due to the presence in the formulation of diazonium compounds that were thermally unstable. These compounds were studied in coating solutions and printing plates. Alternative analytical techniques for diazonium analysis were examined. It was found that HPLC and UV/vis spectroscopy were most useful. These techniques gave information on loss of spec
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Wilson, Paul. "Reactions of diene and triene-conjugated diazo-compounds /." Thesis, University of Edinburgh, 1999. http://hdl.handle.net/1842/14686.

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Webster, R. "Approaches to novel materials based on poly(diazo)-compounds." Thesis, University of Liverpool, 1991. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.317292.

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Nakamuro, Takayuki. "New Reactions Using Diazo Intermediates Generated from Azole Compounds." Kyoto University, 2018. http://hdl.handle.net/2433/232059.

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McGuiness, Mark J. "Synthesis of diazo compounds with azidotris(diethylamino)phosphonium bromide /." The Ohio State University, 1991. http://rave.ohiolink.edu/etdc/view?acc_num=osu1487694702785261.

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Books on the topic "Diazo compounds"

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Saunders, K. H. Aromatic diazo compounds. 3rd ed. E. Arnold, 1985.

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Zollinger, Heinrich. Diazo chemistry. VCH, 1995.

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Zollinger, Heinrich. Diazo chemistry. VCH, 1994.

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Regitz, Manfred. Diazo compounds: Properties and synthesis. Academic Press, 1986.

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Regitz, Manfred. Diazo compounds: Properties and syntheses. Academic Press, 1986.

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Zollinger, Heinrich. Diazo chemistry.: Aromatic and heteroaromatic compounds. VCH, 1994.

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Eisler, Ronald. Diazinon hazards to fish, wildlife, and invertebrates: A synoptic review. U.S. Dept. of the Interior, Fish and Wildlife Service, 1986.

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1938-, McKervey M. Anthony, and Ye Tao 1963-, eds. Modern catalytic methods for organic synthesis with diazo compounds: From cyclopropanes to ylides. Wiley, 1998.

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Diazo Compounds. Elsevier, 1986. http://dx.doi.org/10.1016/b978-0-12-585840-3.x5001-6.

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Zollinger, Heinrich. Diazo Chemistry. John Wiley & Sons Inc, 1997.

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Book chapters on the topic "Diazo compounds"

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Wrackmeyer, B. "By Reaction with Diazo Compounds." In Inorganic Reactions and Methods. John Wiley & Sons, Inc., 2007. http://dx.doi.org/10.1002/9780470145241.ch51.

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Davies, A. G. "17.9.3 Radical cations of diazo compounds." In Phosphorus-Centered Radicals, Radicals Centered on Other Heteroatoms, Organic Radical Ions. Part 2. Springer Berlin Heidelberg, 2009. http://dx.doi.org/10.1007/978-3-540-87641-0_42.

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REGITZ, MANFRED, and GERHARD MAAS. "Isotope-Labeled Diazo Compounds." In Diazo Compounds. Elsevier, 1986. http://dx.doi.org/10.1016/b978-0-12-585840-3.50021-0.

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"Front Matter." In Diazo Compounds. Elsevier, 1986. http://dx.doi.org/10.1016/b978-0-12-585840-3.50001-5.

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"Copyright." In Diazo Compounds. Elsevier, 1986. http://dx.doi.org/10.1016/b978-0-12-585840-3.50002-7.

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"Dedication." In Diazo Compounds. Elsevier, 1986. http://dx.doi.org/10.1016/b978-0-12-585840-3.50003-9.

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"Preface." In Diazo Compounds. Elsevier, 1986. http://dx.doi.org/10.1016/b978-0-12-585840-3.50004-0.

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REGITZ, MANFRED, and GERHARD MAAS. "Structure and Spectroscopic Properties." In Diazo Compounds. Elsevier, 1986. http://dx.doi.org/10.1016/b978-0-12-585840-3.50005-2.

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REGITZ, MANFRED, and GERHARD MAAS. "Thermal Properties." In Diazo Compounds. Elsevier, 1986. http://dx.doi.org/10.1016/b978-0-12-585840-3.50006-4.

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REGITZ, MANFRED, and GERHARD MAAS. "Reactivity toward Acids." In Diazo Compounds. Elsevier, 1986. http://dx.doi.org/10.1016/b978-0-12-585840-3.50007-6.

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Conference papers on the topic "Diazo compounds"

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Khuzina, Liliya L., Airat R. Tuktarov, and Usein M. Dzhemilev. "Catalytic Cycloaddition of Diazo Compounds Based on Pharmacologically Significant and Natural Compounds to C60-Fullerene." In International Electronic Conference on Synthetic Organic Chemistry. MDPI, 2022. http://dx.doi.org/10.3390/ecsoc-26-13534.

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Bruno, Ferdinando, Lauren Elizabeth Belton, and Diane Michelle Steeves. "Novel Enzymatic Polymerization of Diazo Compounds: A New group of Dyes." In 2008 MRS Fall Meetin. Materials Research Society, 2008. http://dx.doi.org/10.1557/proc-1134-bb05-02.

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Dubenskaia, N. A., E. M. Sokolova, B. L. Psikha, and N. I. Neshev. "KITETICS AND MECHANISMS OF OXIDATIVE HEMOLYSIS OF ERYTHROCYTES UNDER THE INFLUENCE OF RADICAL INITIATORS OF LIPID PEROXIDATION." In XI МЕЖДУНАРОДНАЯ КОНФЕРЕНЦИЯ МОЛОДЫХ УЧЕНЫХ: БИОИНФОРМАТИКОВ, БИОТЕХНОЛОГОВ, БИОФИЗИКОВ, ВИРУСОЛОГОВ, МОЛЕКУЛЯРНЫХ БИОЛОГОВ И СПЕЦИАЛИСТОВ ФУНДАМЕНТАЛЬНОЙ МЕДИЦИНЫ. IPC NSU, 2024. https://doi.org/10.25205/978-5-4437-1691-6-139.

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The kinetics of oxidative hemolysis of a 0.2 % suspension of mouse erythrocytes under the influence of radical-forming initiators of a peroxide nature: cumene hydroperoxide (Cumyl-OOH), hydrogen peroxide (HP), tert-butyl hydroperoxide (t-BuOOH) and 2,2’-azobis (2-amidinopropane) dihydrochloride (AAPH), belonging to the diazo compounds family.
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Al-Douh, Mohammed Hadi, Elham Abdalrahem Bin Selim, Haydar A. Mohammad Salim, and Hassan Hadi Abdullah. "Molecular Structure and Spectroscopic Studies of Some Diazo Dyes Compounds using DFT Method." In 2019 First International Conference of Intelligent Computing and Engineering (ICOICE). IEEE, 2019. http://dx.doi.org/10.1109/icoice48418.2019.9035176.

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Mašulović, Aleksandra, Anita Lazić, Ivana Đorđević, et al. "Assessing the pharmacological potential of synthetic colorants with pyridone core." In 37th International Congress on Process Industry. SMEITS, 2024. http://dx.doi.org/10.24094/ptk.024.299.

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Azo dyes are known as structurally diverse class of organic compounds bearing one or more azo groups (–N=N–) as a bridge between organic residues of which at least one is an aromatic moiety. This group of synthetic dyes is obtained easily by the reaction of diazo coupling with high yield. The importance of azo dyes is reflected in the fact that they account for 60 % of the total number of the dye structures known to be manufactured and used in the coloration of textiles, leather, plastics and cosmetics. Aside from their traditional usage, azo dyes are known for their therapeutic properties and
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