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Relevant bibliographies by topics / Diazocane

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Academic literature on the topic 'Diazocane'

Author: Grafiati

Published: 4 June 2021

Last updated: 17 February 2022

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Journal articles on the topic "Diazocane"

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James, Thomas, Paul MacLellan, George M. Burslem, Iain Simpson, J. Andrew Grant, Stuart Warriner, Visuvanathar Sridharan, and Adam Nelson. "A modular lead-oriented synthesis of diverse piperazine, 1,4-diazepane and 1,5-diazocane scaffolds." Org. Biomol. Chem. 12, no. 16 (2014): 2584–91. http://dx.doi.org/10.1039/c3ob42512f.

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A modular synthetic approach is described in which combinations of cyclic sulfamidate and hydroxy sulfonamide building blocks may be converted into piperazine, 1,4-diazepine and 1,5-diazocane scaffolds.

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Rapelli, Chandrashekhar, Balasubramanian Sridhar, and B. V. Subba Reddy. "Correction: Tandem Prins cyclization for the synthesis of indole fused spiro-1,4-diazocane scaffolds." Organic & Biomolecular Chemistry 18, no. 36 (2020): 7224. http://dx.doi.org/10.1039/d0ob90122a.

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Correction for ‘Tandem Prins cyclization for the synthesis of indole fused spiro-1,4-diazocane scaffolds’ by Chandrashekhar Rapelli et al., Org. Biomol. Chem., 2020, 18, 6710–6715, DOI: 10.1039/D0OB01384F.

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Rapelli, Chandrashekhar, Balasubramanian Sridhar, and B. V. Subba Reddy. "Tandem Prins cyclization for the synthesis of indole fused spiro-1,4-diazocane scaffolds." Organic & Biomolecular Chemistry 18, no. 34 (2020): 6710–15. http://dx.doi.org/10.1039/d0ob01384f.

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A tandem Prins strategy has been developed for the first time to produce a novel class of spiro-1,4-diazocane derivatives by the condensation of indole tethered γ-hydroxyolefin with aldehydes using BF₃·OEt₂ at −40 °C in dichloromethane.

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Van Meervelt, L., and P. Kong Thoo Lin. "5,8-Bis(4-methoxy-2,3,6-trimethylbenzenesulfonyl)-1,4-dioxa-5,8-diazocane." Acta Crystallographica Section C Crystal Structure Communications 53, no. 8 (August 15, 1997): 1131–33. http://dx.doi.org/10.1107/s0108270197003806.

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Heintze, Linda, Dorian Schmidt, Theo Rodat, Lydia Witt, Julia Ewert, Malte Kriegs, Rainer Herges, and Christian Peifer. "Photoswitchable Azo- and Diazocine-Functionalized Derivatives of the VEGFR-2 Inhibitor Axitinib." International Journal of Molecular Sciences 21, no. 23 (November 25, 2020): 8961. http://dx.doi.org/10.3390/ijms21238961.

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In this study, we aimed at the application of the concept of photopharmacology to the approved vascular endothelial growth factor receptor (VEGFR)-2 kinase inhibitor axitinib. In a previous study, we found out that the photoisomerization of axitinib’s stilbene-like double bond is unidirectional in aqueous solution due to a competing irreversible [2+2]-cycloaddition. Therefore, we next set out to azologize axitinib by means of incorporating azobenzenes as well as diazocine moieties as photoresponsive elements. Conceptually, diazocines (bridged azobenzenes) show favorable photoswitching properties compared to standard azobenzenes because the thermodynamically stable Z-isomer usually is bioinactive, and back isomerization from the bioactive E-isomer occurs thermally. Here, we report on the development of different sulfur–diazocines and carbon–diazocines attached to the axitinib pharmacophore that allow switching the VEGFR-2 activity reversibly. For the best sulfur–diazocine, we could verify in a VEGFR-2 kinase assay that the Z-isomer is biologically inactive (IC50 >> 10,000 nM), while significant VEGFR-2 inhibition can be observed after irradiation with blue light (405 nm), resulting in an IC50 value of 214 nM. In summary, we could successfully develop reversibly photoswitchable kinase inhibitors that exhibit more than 40-fold differences in biological activities upon irradiation. Moreover, we demonstrate the potential advantage of diazocine photoswitches over standard azobenzenes.

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Cai, Xiao-Qing, Ai-Li Liu, Xiao-Wei Yan, Ke-Jian Zhao, Mei-Rong Li, and Xiao-Nuan Xie. "Crystal structure of N,N-ditosyldibenzo-1,5-diazocane-2,6-dione, C28H22N2O6S2." Zeitschrift für Kristallographie - New Crystal Structures 224, no. 2 (June 2009): 224–26. http://dx.doi.org/10.1524/ncrs.2009.0100.

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Cai, Xiao-Qing, Ai-Li Liu, Xiao-Wei Yan, Ke-Jian Zhao, Mei-Rong Li, and Xiao-Nuan Xie. "Crystal structure of N,N-ditosyldibenzo-1,5-diazocane-2,6-dione, C28H22N2O6S2." Zeitschrift für Kristallographie - New Crystal Structures 224, no. 1-4 (April 2009): 224. http://dx.doi.org/10.1524/ncrs.2009.224.14.224.

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Cai, Xiao-Qing, Ai-Li Liu, Xiao-Wei Yan, Ke-Jian Zhao, Mei-Rong Li, and Xiao-Nuan Xie. "Crystal structure of N,N-ditosyldibenzo-1,5-diazocane-2,6-dione, C28H22N2O6S2." Zeitschrift für Kristallographie - New Crystal Structures 224, no. 1-4 (April 2009): 234–36. http://dx.doi.org/10.1524/ncrs.2009.224.14.234.

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Schehr, Miriam, Daniel Hugenbusch, Tobias Moje, Christian Näther, and Rainer Herges. "Synthesis of mono-functionalized S-diazocines via intramolecular Baeyer–Mills reactions." Beilstein Journal of Organic Chemistry 14 (November 7, 2018): 2799–804. http://dx.doi.org/10.3762/bjoc.14.257.

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Herein we report a reliable method to synthesize mono-functionalized S-diazocines in reproducible yields via intramolecular Baeyer–Mills reactions. Diazocines exhibit excellent photoswitchable properties. As opposed to azobenzenes they are more stable in their cis configuration. Particularly in photopharmacology mono-functionalized diazocines should be potentially useful and superior to the frequently used azobenzenes because the sterically more demanding cis configuration should be inactive, and the slender trans configuration should fit in a tight binding pocket of a receptor. Hence, it should be possible to administer the stabile inactive compound and switch it on at the site of illness with visible light. To date only a limited number of diazocine derivatives have been published of which most are symmetrically functionalized. Using the Baeyer–Mills reaction for the synthesis of diazocines opens a novel and convenient access to unsymmetrically substituted diazocines.

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VAN MEERVELT, L., and P. KONG THOO LIN. "ChemInform Abstract: 5,8-Bis(4-methoxy-2,3,6-trimethylbenzenesulfonyl)-1,4-dioxa-5,8- diazocane (V)." ChemInform 28, no. 48 (August 2, 2010): no. http://dx.doi.org/10.1002/chin.199748206.

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More sources

Dissertations / Theses on the topic "Diazocane"

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Sandh, Gustaf. "Towards an understanding of diazocyte development and diazotrophy in the marine cyanobacterium Trichodesmium /." Stockholm : Department of Botany, Stockholm University, 2009. http://urn.kb.se/resolve?urn=urn:nbn:se:su:diva-27206.

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Nonnenmacher, Elisabeth. "Synthèse de nouvelles 5,11-dibenzyldibenzo[b,f][1,5]diazocine-6,12-diones : études des activités anti-HIV et anti-MDR." Aix-Marseille 2, 1998. http://theses.univ-amu.fr.lama.univ-amu.fr/PHA_1998_1508.pdf.

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Ohier, Philippe. "Réactions d'annelation en diazépines, oxazocines, diazocines et indolines fusionnées à un cycle thiophène ou [1] benzothiophène." Le Havre, 1995. http://www.theses.fr/1995LEHA0003.

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Lors de ce travail nous avons synthétisé plusieurs benzothiénoindolizidinones, indolizidinédiones et quinolizidinones par réaction de type Friedel et Crafts à partir des acides carboxyliques correspondants. La réaction de Schmidt appliquée à ces cétones conduit sélectivement aux benzothiéno |1,3| diazépines fusionnées à divers cycles azotes : pyrrolidine, pyrrolidone et pipéridine. Une transposition de Beckmann aboutit également en série pyrrolidinique à la même |1,3| diazépine. La thermolyse de carbonylazides convenablement substitues en série benzothiophenique, dans l'acide acétique glacial, nous a permis d'accéder aux benzothienopyrrolo |1,4| diazepines et diazépinones. Un mécanisme rendant compte de ce réarrangement est discuté. La cyclodésydratation intramoléculaire de Diols ainsi que l'application de la réaction de Pictet-Spengler en série thiophénique, aboutissent aux thiénopyrroloxazocines et thienopyrrolodiazocines. Par ailleurs, une voie originale permettant d'obtenir la thiénophyrrolo |1,3| diazépine est proposée. Enfin, la première synthèse d'indolizines |2(3), 3(2)-f| fusionnées au thiophène et au |1| benzothiophène est présentée. L'étude de certaines propriétés chimiques de ces structures, notamment vis-à-vis de dienophiles actifs, nous a permis d'accéder dans de bonnes conditions aux |3,2,2| cyclazines correspondantes par cycloadditions (1,3) dipolaires

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Langbehn, Daniel [Verfasser], Rainer [Akademischer Betreuer] Herges, and Ulrich [Gutachter] Lüning. "Synthese mono- und di-substituierter Diazocine und ihre Verwendung als Bausteine in responsiven Materialien und weiteren Anwendungsgebieten / Daniel Langbehn ; Gutachter: Ulrich Lüning ; Betreuer: Rainer Herges." Kiel : Universitätsbibliothek Kiel, 2020. http://d-nb.info/1226154107/34.

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Moormann, Widukind [Verfasser], Rainer [Akademischer Betreuer] Herges, and Frank [Gutachter] Sönnichsen. "Synthese von funktionalisierten Diazocinen für die Photopharmakologie, Molekularbiologie und für responsive Materialien / Widukind Moormann ; Gutachter: Frank Sönnichsen ; Betreuer: Rainer Herges." Kiel : Universitätsbibliothek Kiel, 2020. http://d-nb.info/1209947366/34.

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Moormann, Widukind Verfasser], Rainer [Akademischer Betreuer] [Herges, and Frank [Gutachter] Sönnichsen. "Synthese von funktionalisierten Diazocinen für die Photopharmakologie, Molekularbiologie und für responsive Materialien / Widukind Moormann ; Gutachter: Frank Sönnichsen ; Betreuer: Rainer Herges." Kiel : Universitätsbibliothek Kiel, 2020. http://nbn-resolving.de/urn:nbn:de:gbv:8-mods-2020-00157-3.

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Mamouni, Aïcha. "Synthèse et réactivité de pyrrolo(ou pyrido)thiéno[2]azépine diversement fonctionnalisées." Le Havre, 1996. http://www.theses.fr/1996LEHA0010.

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Lors de ce travail, nous avons synthétisé des N-thiénylméthylsuccinimides (ou tétraméthylsuccinimides) dont nous avons étudié la réactivité. Leur réduction conduit aux hydroxylactames qui donnent deux types de réaction selon que le milieu acide est ou basique. Dans le premier cas, nous assistons à la formation d'ions N-acyliminiums ou d'énamidones (formés par réarrangement de Meyer-Schuster). Dans le second cas, nous avons formation du carbonyle masqué qui donne lieu à des réactions de type Wittig. Les produits précédents ont été utilisés dans diverses réactions de cyclisation telles que : 1) - L'attaque d'un ion N-acyliminium sur un système π (aromatique ou oléfinique) ; 2) - le couplage entre un système π (aromatique ou oléfinique) et un dérivé halogéné en présence de palladium (0) ou (II) ; 3) - une réaction de type Friedel et Crafts appliquée aux acides acétiques (ou thioglycoliques) substitués. Les réarrangements de Schmidt et Beckmann, appliqués à nos azépinones et oximes fusionneées à la succinimide, conduisent sélectivement à des dérivées des pyrrolothiéno[1,3]azocines. Par ailleurs, nous avons synthétisé des pyridothiénoazépinones (ou thiénoazocinones) par traitement dans l'acide polyphosphorique à partir des acides N-alkylpipéridine-2-acétiques (ou 2-propanoïques). Nous avons ainsi formé des structures polycycliques incluant le motif pyrrolidinone ou pipéridine fusionné au thiophène par l'intermédiaire d'un cycle comportant 6 à 8 chaînons (azépine, azocine, indolizine, oxazocine, thiazocine,. . . ), avec des hétéroatomes tels que l'oxygène, le soufre et l'azote.

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Mbyas, Saroukou Mariame Scarlett. "Synthèse et étude de nouvelles molécules potentiellement polymérisables pour la fabrication de matériaux électroluminescents : analogues du 1,3,5 benzènetripyrrole, méthyle 3,5-bipyrrolebenzoate et 6,12-diméthyle-1,5-dipyrrolediazocane." Thèse, 2014. http://hdl.handle.net/1866/13695.

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Pyrroles are found in various natural products and in the chemical composition of certain drugs because of their interesting biological properties. Lipitor, Tolmetin and Amtolmetin are examples of drugs with 1,2,5-substituted pyrroles in their composition, in which biological activities have been certified. Moreover, pyrroles are used as precursors of semiconductor polymers, oligomers and dendrimers useful for the synthesis of electroluminescent materials used in devices, such as organic light-emitting diodes, field-effect transistors, solar and organic photovoltaic cells. We are interested in conjugated polymers based on pyrrole due to their optical properties, electrochemical and the conductivity produced by electron delocalization along their carbon chains. The overall objective of the work presented in this thesis is the synthesis of new molecules based on pyrrole for studying their electronic and electrochemical properties as well for the synthesis of conjugated polymers. Initially, we performed the synthesis of 1,3,5-tri-(1-alkyl-5-methylpyrrol-2-yl)benzenes, which may serve as precursors for the synthesis of conjugated dendrimers. Their synthesis was made in three steps starting from trimethyl 1,3,5-benzene-tricarboxylate which was converted to 1,3,5-tri-(pent-4-enoyl)benzene using vinylmagnesium bromide in a Grignard reaction catalyzed by copper cyanide. The olefins of 1,3,5-tri-(pent-4-enoyl)benzene were oxidized to produce 1,3,5-tri-(4-oxopentanoyl)benzene using a modified protocol of the Tsuji-Wacker reaction. Subsequent, Paal-Knorr condensation reactions on 1,3,5-tri-(4-oxopentanoyl)benzene with different amines were used to synthesize 1,3,5-tri-(1-alkyl-5-methylpyrrol-2-yl)benzenes with different N-substituents in yields between 44 and 60%. Incomplete reaction of vinylmagnesium bromide with trimethyl 1,3,5-benzenetricarboxylate gave the methyl-3,5-di(pent-4-enoyl)benzoate, which was converted to methyl-3,5-dipyrrolylbenzoate following the reaction of Tsuji- Wacker and Paal-Knorr with yields between 30 and 60%. The photochemical and electrochemical properties of the 1,3,5-tri-(1-alkyl-5-methylpyrrol-2-yl)benzenes and methyl-3,5-dipyrrolylbenzoates were studied in collaboration with the research group of professor William Skene. The results have shown that both types of pyrrole have potential for the synthesis of conjugated polymers and dendrimers used in the manufacture of electroluminescent materials. Following these encouraging results, we performed the synthesis of 6,12-dimethyl-1,5-dipyrrolediazocane. Methyl N-(Boc)-β-alaninate was converted to its corresponding homoallylic ketone, which was oxidized to N-(Boc)aminoheptan-3,6-dione. The Paal-Knorr condensation between N-(Boc)aminoheptan-3,6-dione and aminoheptan-3,6-dione hydrochloride gave 6,12-dimethyl-1,5-dipyrrolediazocane in 17% yield. In sum, we have synthesized and characterized seven new molecules, six of them having photochemical and electrochemical properties interesting for the synthesis of conjugated polymers and dendrimers. The latter offering potential as precursor for the conception of compounds of therapeutic interest.
Les pyrroles sont une classe de molécules que l'on trouve dans divers produits naturels ainsi que dans la composition chimique de certains médicaments en raison de leurs propriétés biologiques intéressantes. Le Lipitor, la Tolmetin et l'Amtolmetin sont des exemples de médicaments à base de pyrroles 1,2,5 substitués dont les activités biologiques ont été certifiées. Les pyrroles sont aussi utilisés comme précurseurs de polymères, oligomères et dendrimères semi-conducteurs nécessaires à la synthèse de certains matériaux électroluminescents, tels que les diodes organiques électroluminescentes, les transistors à effets de champ et les cellules organiques photovoltaïques. Nous nous sommes intéressés à ces polymères conjugués à base de pyrroles en raison de leurs qualités de bons conducteurs, de leurs propriétés optiques et électrochimiques que leur confère la délocalisation des électrons le long de leurs chaines carbonées. L'objectif général des travaux présentés dans ce mémoire est de synthétiser de nouvelles molécules à base de pyrroles pouvant éventuellement servir de précurseurs à la synthèse de dendrimères conjugués ainsi qu'à la synthèse de molécules thérapeutiques. Une étude de leurs propriétés électroniques et électrochimiques sera effectuée afin de déterminer leur potentiel pour la fabrication de matériaux électroluminescents. Dans un premier temps, la synthèse des analogues du 1,3,5-benzènetripyrrole a été faite en trois étapes à partir du 1,3,5-benzènetricarboxylate de triméthyle. Celui-ci a été converti en premier lieu en 1,3,5-benzènetricétone-γ,δ-insaturée lors d'une réaction de Grignard catalysée par le cyanure de cuivre. Ce dernier composé fut oxydé lors de la seconde étape en 1,3,5-tri-(4-oxopentanoyl)benzène selon un protocole modifié de la réaction de Tsuji-Wacker. Enfin, la réaction de condensation de Paal-Knorr du 1,3,5-tri-(4-oxopentanoyl)benzène de l'étape précédente mène au 1,3,5-benzènetripyrrole N-substitué selon l'amine utilisée pour la condensation, avec des rendements entre 44 et 60%. La réaction incomplète du bromure de vinylmagnésium avec le 1,3,5-benzènetricarboxylate de triméthyle mène au méthyl-3,5-di-(pent-4-énoyl)benzoate, qui a été converti en méthyl-3,5-dipyrrolylbenzoate suite à la réaction de Tsuji-Wacker et de Paal-Knorr avec des rendements entre 30 et 60%. L'étude des propriétés photochimiques et électrochimiques des tripyrroles et des bipyrroles a été faite en collaboration avec le groupe de recherche du professeur William Skene. Les résultats obtenus démontrèrent que ces pyrroles auraient un potentiel pour la synthèse de dendrimères conjugués servant à la fabrication de matériaux électroluminescents. Suite à ces résultats encourageants, la synthèse du 6,12-diméthyle-1,5-dipyrrolediazocane a aussi été réalisée. Celui-ci a été synthétisé à partir de l’ester méthylique de l’acide 3-tert-butoxycarbonylaminopropionique qui a été converti en sa cétone homoallylique correspondante, puis oxydée en N-Boc-3,6-dioxoheptylcarbamate. La condensation de Paal-Knorr de ce dernier composé avec le sel d'hydrochlorure 7-aminoheptane-2,5-dione mène au 6,12-diméthyle-1,5-dipyrrolediazocane avec un rendement de 17%. En somme, la recherche effectuée a permis la synthèse et la caractérisation de six nouvelles molécules ayant des propriétés photochimiques et électrochimiques intéressantes pour la synthèse de polymères et dendrimères conjugués. Ainsi que la synthèse d'un diazacycle, qui de part sa structure pourrait servir de précurseur à la synthèse de molécules thérapeutiques.

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Thikekar, Tushar Ulhas, and 杜夏. "Design and Synthesis of Indole-Fused Diazocine, Diazepine and Triazole Fused-Benzoxazocinones of Biological Interest." Thesis, 2017. http://ndltd.ncl.edu.tw/handle/h4k3cw.

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博士
國立交通大學
應用化學系碩博士班
106
This dissertation describes the development of new synthetic organic transformations by using metal free catalyst and with metal catalyst. Transition metal free catalyst transformations such as Pictet-Spengler reaction and with transition metal-catalyst transformation such as [5+2] annulation are described in this dissertation. For sake of convenience and better understanding, the thesis is divided into four chapters. The first chapter deals with the synthesis of structurally diverse indole-fused diazocine and diazepine derivatives. A substrate-based diversification approach of methyl-3- aminoindole/ indoline benzoates coupled with the Pictet−Spengler reaction and three different reaction cascades furnished indolodiazepine and indoloquinoxalines. The formation of indolodiazocines proceeds through an initial condensation followed by intramolecular alkylation. In the second chapter describes an efficient and regioselective Pd(II)-catalyzed [5+2] annulation of unprotected o-indolo anilines with internal alkynes under microwave irradiation. The diverse imine-containing 1,2-fused indole [1,7-a] diazepines are constructed in moderate to excellent yields. The mechanistic pathway shows pivalic acid and molecular oxygen to play crucial roles for the regeneration of highly active electrophilic Pd-species in the catalytic cycle. The third chapter emphasized the efficient and regioselective synthesis of novel 1,2,3- triazole-fused-1,5-benzoxazocinones through intramolecular cyclization of substituted ethynyl triazoyl benzoic acids. A crucial precursor 5-iodo-1,2,3-triazole benzoate was obtained from substituted 2-azido benzoic acid esters in a single step through a Copper- Catalyzed Azide−Alkyne Cycloaddition (CuAAC) reaction using a CuI/NBS catalytic system. A carbon−carbon triple bond was installed through a Sonogashira coupling reaction by various terminal alkynes. Finally, the 1,4,5-substituted ethynyl triazoyl benzoic acids were cyclized by a AgOTf mediated intramolecular cyclization to afford 8-endo-dig 1,2,3-triazolefused- 1,5-benzoxazocinones exclusively. The fourth chapter deals with a facile and efficient synthesis of novel oxo, thio and selenohydantoin fused tetrahydroazepino [4, 5-b]indoles. Naturally occurring iboga class alkaloid inspired seven-member azepino[4,5-b]indole ring was synthesized as a new scaffold through Pictet-Spengler reaction followed by skeletal rearrangement of aziridine ring. To improve the efficiency of the synthetic route, the double bond of the rearranged olefinic product was reduced and privileged hydantoin moiety was constructed on the core system through urea formation using variety of isocyanates, isothiocyanates and isoselenocyanates followed by intramolecular cyclization to incorporate elements of diversity. The regeneration of the double bond afforded hydantoin-fused tetrahydroazepino [4, 5-b]indoles.

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Book chapters on the topic "Diazocane"

1

Perlmutter, Howard D. "1,4-Diazocines." In Advances in Heterocyclic Chemistry Volume 45, 185–229. Elsevier, 1989. http://dx.doi.org/10.1016/s0065-2725(08)60331-1.

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Perlllmutter, Howard D. "1,2-Diazocines,1,3-Diazocines,Triazocines,and Tetrazocines." In Advances in Heterocyclic Chemistry, 1–83. Elsevier, 1990. http://dx.doi.org/10.1016/s0065-2725(08)60061-6.

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Keller, P. A. "From 1,4-Diazocines." In Six-Membered Hetarenes with One Nitrogen or Phosphorus Atom, 1. Georg Thieme Verlag KG, 2005. http://dx.doi.org/10.1055/sos-sd-015-01780.

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Spitzner, D. "From 1,2-Diazocines." In Six-Membered Hetarenes with One Nitrogen or Phosphorus Atom, 1. Georg Thieme Verlag KG, 2005. http://dx.doi.org/10.1055/sos-sd-015-00219.

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Borzilleri, R. M. "Diazocines and Diheterocines." In Six-Membered Hetarenes with Two Unlike or More than Two Heteroatoms and Fully Unsaturated Larger-Ring Heterocycles, 1. Georg Thieme Verlag KG, 2004. http://dx.doi.org/10.1055/sos-sd-017-01547.

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Borzilleri, R. M. "Bonded to 1,2-Diazocines." In Six-Membered Hetarenes with Two Unlike or More than Two Heteroatoms and Fully Unsaturated Larger-Ring Heterocycles, 1. Georg Thieme Verlag KG, 2004. http://dx.doi.org/10.1055/sos-sd-017-01579.

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Borzilleri, R. M. "Bonded to 1,5-Diazocines." In Six-Membered Hetarenes with Two Unlike or More than Two Heteroatoms and Fully Unsaturated Larger-Ring Heterocycles, 1. Georg Thieme Verlag KG, 2004. http://dx.doi.org/10.1055/sos-sd-017-01580.

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Borzilleri, R. M. "1,2-Diazocine from a Polycyclic Azoalkane." In Six-Membered Hetarenes with Two Unlike or More than Two Heteroatoms and Fully Unsaturated Larger-Ring Heterocycles, 1. Georg Thieme Verlag KG, 2004. http://dx.doi.org/10.1055/sos-sd-017-01561.

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Borzilleri, R. M. "Synthesis of Bicyclic 1,5-Diazocines." In Six-Membered Hetarenes with Two Unlike or More than Two Heteroatoms and Fully Unsaturated Larger-Ring Heterocycles, 1. Georg Thieme Verlag KG, 2004. http://dx.doi.org/10.1055/sos-sd-017-01565.

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Borzilleri, R. M. "Synthesis of Bicyclic 1,2-Diazocines." In Six-Membered Hetarenes with Two Unlike or More than Two Heteroatoms and Fully Unsaturated Larger-Ring Heterocycles, 1. Georg Thieme Verlag KG, 2004. http://dx.doi.org/10.1055/sos-sd-017-01563.

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