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1

Marshall, Nicholas, Andres Rodriguez, and Scott Crittenden. "Diazonium-functionalized thin films from the spontaneous reaction of p-phenylenebis(diazonium) salts." RSC Advances 8, no. 12 (2018): 6690–98. http://dx.doi.org/10.1039/c8ra00792f.

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2

Hetemi, Dardan, Vincent Noël, and Jean Pinson. "Grafting of Diazonium Salts on Surfaces: Application to Biosensors." Biosensors 10, no. 1 (2020): 4. http://dx.doi.org/10.3390/bios10010004.

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This review is divided into two parts; the first one summarizes the main features of surface modification by diazonium salts with a focus on most recent advances, while the second part deals with diazonium-based biosensors including small molecules of biological interest, proteins, and nucleic acids.
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3

Jane, R. T., and R. Lomoth. "Redox hysteresis on carbon electrodes covalently modified with a bistable ruthenium complex." Journal of Materials Chemistry C 3, no. 24 (2015): 6260–65. http://dx.doi.org/10.1039/c5tc00789e.

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4

Busson, Mathilde, Avni Berisha, Catherine Combellas, Frédéric Kanoufi, and Jean Pinson. "Photochemical grafting of diazonium salts on metals." Chemical Communications 47, no. 47 (2011): 12631. http://dx.doi.org/10.1039/c1cc16241a.

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5

Le Comte, A., D. Chhin, A. Gagnon, R. Retoux, T. Brousse, and D. Bélanger. "Spontaneous grafting of 9,10-phenanthrenequinone on porous carbon as an active electrode material in an electrochemical capacitor in an alkaline electrolyte." Journal of Materials Chemistry A 3, no. 11 (2015): 6146–56. http://dx.doi.org/10.1039/c4ta05536e.

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6

Zeb, Gul, Pascal Viel, Serge Palacin, and Xuan Tuan Le. "On the chemical grafting of titanium nitride by diazonium chemistry." RSC Advances 5, no. 62 (2015): 50298–305. http://dx.doi.org/10.1039/c5ra07875j.

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Grafting of aminophenylene layer onto titanium nitride at different thicknesses can be achieved through the diazonium chemistry. The functionalized titanium nitride can find applications in areas: microelectronics, electrocatalysis, biosensors.
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7

Troian-Gautier, Ludovic, Hennie Valkenier, Alice Mattiuzzi, et al. "Extremely robust and post-functionalizable gold nanoparticles coated with calix[4]arenes via metal–carbon bonds." Chemical Communications 52, no. 69 (2016): 10493–96. http://dx.doi.org/10.1039/c6cc04534k.

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8

Overton, Atiya T., and Ahmed A. Mohamed. "Gold(III) Diazonium Complexes for Electrochemical Reductive Grafting." Inorganic Chemistry 51, no. 10 (2012): 5500–5502. http://dx.doi.org/10.1021/ic300307z.

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9

Vo Thi Thuy, Hang, Dien Nguyen Duy, Thi Tran The, Trung Huynh Thi Mien, and Hai Phan Thanh. "Diazonium based surface functionalization of graphite by electrochemical grafting." Vietnam Journal of Catalysis and Adsorption 9, no. 2 (2020): 125–29. http://dx.doi.org/10.51316/jca.2020.040.

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In this respect, a combination of cyclic voltammetry (CV), Raman spectroscopy, and Atomic Force Microscopy (AFM) is employed to characterize the structural, electrochemical and electronic properties of diazonium thin layers covalently functionalized highly oriented pyrolytic graphite (HOPG) surface. As a consequence, a grafted layer thin film of 4-nitro-benzene-diazonium tetrafluoroborate (4-NBD) is formed on HOPG surface with an average thickness of about 3.5 ± 0.2 nm. A D-band peak appearrance at the wave length of 1336 cm-1 on the Raman spectrum indicates an enhancing of defects caused by c
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10

Taleghan Ghafari, Mahsa, Fahimeh Varmaghani, Babak Karimi, and Vahid Khakyzadeh. "Robust non-covalent and covalent anchored N,N,N′,N’-tetramethyl-p-phenylenediamine derivative on electrode surface via spontaneous physical immobilization and in situ generated aryldiazonium ion electro-grafting: implication for on-surface chemistry and electro-catalytic determinations." Analyst 145, no. 2 (2020): 596–606. http://dx.doi.org/10.1039/c9an01628g.

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Redox active electrodes were fabricated via robust adsorption and electro-grafting of an electroactive diazonium ion. The electrodes have implications in post-functionalization as well as electro-catalytic activity.
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11

Servinis, L., L. C. Henderson, L. M. Andrighetto, M. G. Huson, T. R. Gengenbach, and Bronwyn L. Fox. "A novel approach to functionalise pristine unsized carbon fibre using in situ generated diazonium species to enhance interfacial shear strength." Journal of Materials Chemistry A 3, no. 7 (2015): 3360–71. http://dx.doi.org/10.1039/c4ta04798b.

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12

Phal, Sereilakhena, Kenichi Shimizu, Daniel Mwanza, Philani Mashazi, Andrey Shchukarev, and Solomon Tesfalidet. "Electrografting of 4-Carboxybenzenediazonium on Glassy Carbon Electrode: The Effect of Concentration on the Formation of Mono and Multilayers." Molecules 25, no. 19 (2020): 4575. http://dx.doi.org/10.3390/molecules25194575.

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Grafting of electrodes with diazonium salts using cyclic voltammetry (CV) is a well-established procedure for surface modification. However, little is known about the effect of the concentration of the diazonium salt on the number of layers grafted on the electrode surface. In this work, the impact of concentration on the grafting of 4-carboxybenzenediazonium (4-CBD) onto a glassy carbon electrode (GCE) is elucidated. The number of layers grafted on the GCE was linearly dependent on the concentration of 4-CBD and varied between 0.9 and 4.3 when the concentration was varied between 0.050 and 0.
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13

Neal, Sabine, Samuel Orefuwa, Atiya Overton, Richard Staples, and Ahmed Mohamed. "Synthesis of Diazonium Tetrachloroaurate(III) Precursors for Surface Grafting." Inorganics 1, no. 1 (2013): 70–84. http://dx.doi.org/10.3390/inorganics1010070.

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14

Le Floch, Fabien, Muriel Matheron, and Françoise Vinet. "Electrochemical grafting on SOI substrates using aryl diazonium salts." Journal of Electroanalytical Chemistry 660, no. 1 (2011): 127–32. http://dx.doi.org/10.1016/j.jelechem.2011.06.018.

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15

Bell, K. J., P. A. Brooksby, M. I. J. Polson, and A. J. Downard. "Evidence for covalent bonding of aryl groups to MnO2 nanorods from diazonium-based grafting." Chem. Commun. 50, no. 89 (2014): 13687–90. http://dx.doi.org/10.1039/c4cc05606j.

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16

Surgutskaya, N. S., P. S. Postnikov, Alexandra G. Pershina, A. I. Galanov, Marina E. Trusova, and Alexey E. Sazonov. "The Fe-Core/Carbon-Shell Ultrafine Nanopowders as Platform for Biomolecules Grafting." Advanced Materials Research 1040 (September 2014): 194–98. http://dx.doi.org/10.4028/www.scientific.net/amr.1040.194.

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The Fe-core/carbon-shell nanopowders are excellent platform for covalent grafting of biomolecules. The large-scale synthesis of Fe-core/carbon-shell nanoparticles via electropulse erosion of metal precursors in hydrocarbons was developed. The green fluorescent protein was covalently attached to the powder surface via diazonium functionalization and further carbodiimide activation.
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17

Qiu, Zhipeng, Jun Yu, Peng Yan, Zhijie Wang, Qijin Wan, and Nianjun Yang. "Electrochemical Grafting of Graphene Nano Platelets with Aryl Diazonium Salts." ACS Applied Materials & Interfaces 8, no. 42 (2016): 28291–98. http://dx.doi.org/10.1021/acsami.5b11593.

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18

Mesnage, Alice, Xavier Lefèvre, Pascale Jégou, Guy Deniau, and Serge Palacin. "Spontaneous Grafting of Diazonium Salts: Chemical Mechanism on Metallic Surfaces." Langmuir 28, no. 32 (2012): 11767–78. http://dx.doi.org/10.1021/la3011103.

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19

Simionescu, Cristofor I., and Severian Dumitriu. "Grafting of cellulose and derivatives by means of diazonium salts." Journal of Polymer Science Part C: Polymer Symposia 37, no. 1 (2007): 187–203. http://dx.doi.org/10.1002/polc.5070370111.

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20

Berg, Kathleen E., Yann R. Leroux, Philippe Hapiot, and Charles S. Henry. "Increasing Applications of Graphite Thermoplastic Electrodes with Aryl Diazonium Grafting." ChemElectroChem 6, no. 18 (2019): 4811–16. http://dx.doi.org/10.1002/celc.201901048.

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21

Madec, L., K. A. Seid, J. C. Badot, et al. "Redirected charge transport arising from diazonium grafting of carbon coated LiFePO4." Phys. Chem. Chem. Phys. 16, no. 41 (2014): 22745–53. http://dx.doi.org/10.1039/c4cp03174a.

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22

Betelu, Stéphanie, Inga Tijunelyte, Leïla Boubekeur-Lecaque, et al. "Evidence of the Grafting Mechanisms of Diazonium Salts on Gold Nanostructures." Journal of Physical Chemistry C 120, no. 32 (2016): 18158–66. http://dx.doi.org/10.1021/acs.jpcc.6b06486.

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23

Kang, Su Jin, Suseong Kim, Kyuhong Lee, Ik-Soo Shin, and Yang-Rae Kim. "Tunable Electrochemical Grafting of Diazonium for Highly Sensitive Impedimetric DNA Sensor." Journal of The Electrochemical Society 167, no. 8 (2020): 087504. http://dx.doi.org/10.1149/1945-7111/ab8ce8.

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24

Yang, Nianjun, Jiuhong Yu, Hiroshi Uetsuka, and Christoph E. Nebel. "Characterization of diamond surface terminations using electrochemical grafting with diazonium salts." Electrochemistry Communications 11, no. 11 (2009): 2237–40. http://dx.doi.org/10.1016/j.elecom.2009.09.039.

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25

Hapiot, Philippe, Corinne Lagrost, and Yann R. Leroux. "Molecular nano-structuration of carbon surfaces through reductive diazonium salts grafting." Current Opinion in Electrochemistry 7 (January 2018): 103–8. http://dx.doi.org/10.1016/j.coelec.2017.11.003.

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26

Shkirskiy, Viacheslav, Eric Levillain, and Christelle Gautier. "Capacitive Impedance for Following In‐Situ Grafting Kinetics of Diazonium Salts." ChemPhysChem 22, no. 11 (2021): 1074–78. http://dx.doi.org/10.1002/cphc.202100154.

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27

Berisha, Avni. "The influence of the grafted aryl groups on the solvation properties of the graphyne and graphdiyne - a MD study." Open Chemistry 17, no. 1 (2019): 703–10. http://dx.doi.org/10.1515/chem-2019-0083.

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AbstractThe mechanism of the adsorption and grafting of diazonium cations onto the surface of graphyne and graphdiyne was investigated using Density Functional Theory (DFT). The adsorption energy (both in vacuum and water as solvent) of the phenyl diazonium cation was evaluated at three different positions of the graphyne and graphdiyne surface. Moreover, the lowest energy adsorption sites were used to calculate and plot Non-covalent Interactions (NCI). The Bond Dissociation Energy (BDE) results (up to 66 kcal/mol) for the scission of the phenyl group support the remarkable stability of the gr
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28

Tijunelyte, I., I. Kherbouche, S. Gam-Derouich, et al. "Multi-functionalization of lithographically designed gold nanodisks by plasmon-mediated reduction of aryl diazonium salts." Nanoscale Horizons 3, no. 1 (2018): 53–57. http://dx.doi.org/10.1039/c7nh00113d.

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29

Combellas, Catherine, Frederic Kanoufi, Jean Pinson, and Fetah I. Podvorica. "Sterically Hindered Diazonium Salts for the Grafting of a Monolayer on Metals." Journal of the American Chemical Society 130, no. 27 (2008): 8576–77. http://dx.doi.org/10.1021/ja8018912.

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30

Mesnage, Alice, Mohamed Abdel Magied, Pardis Simon, et al. "Grafting polymers to titania nanoparticles by radical polymerization initiated by diazonium salt." Journal of Materials Science 46, no. 19 (2011): 6332–38. http://dx.doi.org/10.1007/s10853-011-5709-z.

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31

Torréns, Mabel, Mayreli Ortiz, Diego Bejarano-Nosas, and Ciara K. O’Sullivan. "Electrochemiluminescent DNA sensor based on controlled Zn-mediated grafting of diazonium precursors." Analytical and Bioanalytical Chemistry 407, no. 19 (2015): 5579–86. http://dx.doi.org/10.1007/s00216-015-8765-4.

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32

Idriss, H., O. Guselnikova, P. Postnikov, et al. "Polymer icephobic surface by graphite coating and chemical grafting with diazonium salts." Surfaces and Interfaces 25 (August 2021): 101226. http://dx.doi.org/10.1016/j.surfin.2021.101226.

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33

Berisha, Avni. "Interactions between the Aryldiazonium Cations and Graphene Oxide: A DFT Study." Journal of Chemistry 2019 (February 26, 2019): 1–5. http://dx.doi.org/10.1155/2019/5126071.

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Understanding the grafting behavior of the aryldiazonium cations is of fundamental and also of practical importance for the vast number of applications that involve the use of modified graphene oxide (from simple adsorption process to electronic and photovoltaic applications). In this work, the mechanism of the adsorption and grafting of diazonium cations on the graphene oxide surface was investigated by the use of density functional theory. Two types of aryldiazonium cations, one bearing only phenyl ring and the other nitrophenyl, were selected as adsorbates/grafted moiety. By evaluating the
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34

Greenwood, John, Thanh Hai Phan, Yasuhiko Fujita, et al. "Covalent Modification of Graphene and Graphite Using Diazonium Chemistry: Tunable Grafting and Nanomanipulation." ACS Nano 9, no. 5 (2015): 5520–35. http://dx.doi.org/10.1021/acsnano.5b01580.

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35

Menanteau, Thibaud, Sylvie Dabos-Seignon, Eric Levillain, and Tony Breton. "Impact of the Diazonium Grafting Control on the Interfacial Reactivity: Monolayer versus Multilayer." ChemElectroChem 4, no. 2 (2016): 278–82. http://dx.doi.org/10.1002/celc.201600710.

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36

Hadj, F. Ait El, A. Amiar, M. Cherkaoui, J. N. Chazalviel, and F. Ozanam. "Study of organic grafting of the silicon surface from 4-nitrobenzene diazonium tetrafluoroborate." Electrochimica Acta 70 (May 2012): 318–24. http://dx.doi.org/10.1016/j.electacta.2012.03.072.

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37

Salmi, Zakaria, Aazdine Lamouri, Philippe Decorse, et al. "Grafting polymer–protein bioconjugate to boron-doped diamond using aryl diazonium coupling agents." Diamond and Related Materials 40 (November 2013): 60–68. http://dx.doi.org/10.1016/j.diamond.2013.10.007.

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38

Neal, Sabine N., Bizuneh Workie, Brian E. McCandless, and Ahmed A. Mohamed. "Gold-organic thin films from the reductive grafting of diazonium gold(III) salts." Journal of Electroanalytical Chemistry 757 (November 2015): 73–79. http://dx.doi.org/10.1016/j.jelechem.2015.09.017.

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39

Delaporte, Nicolas, Karim Zaghib, and Daniel Bélanger. "In situ formation of bromobenzene diazonium ions and their spontaneous reaction with carbon-coated LiFePO4 in organic media." New Journal of Chemistry 40, no. 7 (2016): 6135–40. http://dx.doi.org/10.1039/c6nj00132g.

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40

Haccoun, Julien, Christine Vautrin-Ul, Annie Chaussé, and Alain Adenier. "Electrochemical grafting of organic coating onto gold surfaces: Influence of the electrochemical conditions on the grafting of nitrobenzene diazonium salt." Progress in Organic Coatings 63, no. 1 (2008): 18–24. http://dx.doi.org/10.1016/j.porgcoat.2008.04.001.

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41

Majumder, Mainak, Karin Keis, Xin Zhan, Corey Meadows, Jeggan Cole, and Bruce J. Hinds. "Enhanced electrostatic modulation of ionic diffusion through carbon nanotube membranes by diazonium grafting chemistry." Journal of Membrane Science 316, no. 1-2 (2008): 89–96. http://dx.doi.org/10.1016/j.memsci.2007.09.068.

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42

Raicopol, Matei, Corina Andronescu, Ruxandra Atasiei, et al. "Synthesis of conducting azopolymers by electrochemical grafting of a diazonium salt at polypyrrole electrodes." Synthetic Metals 206 (August 2015): 84–91. http://dx.doi.org/10.1016/j.synthmet.2015.05.006.

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43

Gohier, Aurélien, Fabien Nekelson, Mickael Helezen, et al. "Tunable grafting of functional polymers onto carbon nanotubes using diazonium chemistry in aqueous media." Journal of Materials Chemistry 21, no. 12 (2011): 4615. http://dx.doi.org/10.1039/c0jm03679j.

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44

Via, Garrhett G., Chelsea L. Shugart, Sophia L. Melnyk, Stephanie R. Hupman, and Kristin K. Cline. "One-step Solvent-free Synthesis and Grafting of Diazonium Ions at Glassy Carbon Electrodes." Electroanalysis 30, no. 10 (2018): 2421–26. http://dx.doi.org/10.1002/elan.201800407.

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45

Menanteau, Thibaud, Corentin Benoît, Tony Breton, and Charles Cougnon. "Enhancing the performance of a diazonium-modified carbon supercapacitor by controlling the grafting process." Electrochemistry Communications 63 (February 2016): 70–73. http://dx.doi.org/10.1016/j.elecom.2015.12.014.

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46

Garrett, David J., Peter Jenkins, Matthew I. J. Polson, Dónal Leech, Keith H. R. Baronian, and Alison J. Downard. "Diazonium salt derivatives of osmium bipyridine complexes: Electrochemical grafting and characterisation of modified surfaces." Electrochimica Acta 56, no. 5 (2011): 2213–20. http://dx.doi.org/10.1016/j.electacta.2010.11.070.

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47

Lim, Jungmoon, Gahyun Ahn, Inho Jeong, and Hyunwook Song. "Intrinsic Tunneling Characteristics of Aryl Alkane Monolayers Sandwiched Between Single-Layer Graphene Electrodes." Science of Advanced Materials 12, no. 4 (2020): 470–73. http://dx.doi.org/10.1166/sam.2020.3639.

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In this study, we report on charge transport through aryl alkane monolayers sandwiched between single-layer graphene (SLG) electrodes. Raman spectroscopy identified the chemically grafting of aryl diazonium compounds onto bottom SLG electrodes. Current densities of three different aryl alkane monolayers were exponentially deceased with a correct decay coefficient (β) as the length of a tunneling barrier increased. Transition voltage measurements for variable lengths of alkyl chains showed that the SLG/monolayer/SLG arrangement provides the formation of a valid tunneling junction to observe int
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48

Marshall, Nicholas, and Andres Rodriguez. "Cross-coupling polymerization at iodophenyl thin films prepared by spontaneous grafting of a diazonium salt." PeerJ Materials Science 2 (April 9, 2020): e6. http://dx.doi.org/10.7717/peerj-matsci.6.

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Cross-coupling at aryl halide thin films has been well-established as a technique for the surface-initiated Kumada catalyst transfer polymerization (SI-KCTP), used to produce covalently bound conjugated polymer thin films. In this work, we report that the spontaneous grafting of 4-iodobenzenediazonium tetrafluoroborate on gold substrates creates a durable iodoarene layer which is effective as a substrate for cross-coupling reactions including SI-KCTP. Using cyclic voltammetry of a surface-coupled ferrocene terminating agent, we have measured initiator surface coverage produced by oxidative add
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49

Cincotto, Fernando H., Gonzalo Martínez-García, Paloma Yáñez-Sedeño, Thiago C. Canevari, S. A. S. Machado, and José M. Pingarrón. "Electrochemical immunosensor for ethinylestradiol using diazonium salt grafting onto silver nanoparticles-silica–graphene oxide hybrids." Talanta 147 (January 2016): 328–34. http://dx.doi.org/10.1016/j.talanta.2015.09.061.

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50

Bui-Thi-Tuyet, Van, Caroline Cannizzo, Corinne Legros, Michel Andrieux, and Annie Chaussé. "Modification of fluorine-doped tin oxide surface: Optimization of the electrochemical grafting of diazonium salt." Surfaces and Interfaces 15 (June 2019): 110–16. http://dx.doi.org/10.1016/j.surfin.2019.01.012.

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