Relevant bibliographies by topics / Diblock polymers

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  1. Journal articles
  2. Dissertations / Theses
  3. Books
  4. Book chapters
  5. Conference papers

Academic literature on the topic 'Diblock polymers'

Author: Grafiati
Published: 4 June 2021
Last updated: 4 May 2024

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Journal articles on the topic "Diblock polymers"

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Nir, Moira Marx, and Robert E. Cohen. "Mechanical Properties of Blends of Crystallizable Polybutadienes Containing Amorphous Polybutadiene Diblock Copolymers." Rubber Chemistry and Technology 67, no. 2 (1994): 342–47. http://dx.doi.org/10.5254/1.3538679.

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Abstract Tensile failure properties of syndiotactic 1,2 polybutadiene/trans 1,4 polybutadiene crystalline blends are improved by addition of 5–10% amorphous 1,2 polybutadiene/1,4 polybutadiene diblock copolymer. The effect of block molecular weight and microphase behavior of the diblock copolymer was investigated. Heterogeneous diblocks enhance blend properties to a greater extent than homogeneous diblocks. In blends with enhanced properties, percent coverage of interfacial surface area by diblock is on the order of 10%.
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Dai, Michèle, Evangelos Georgilis, Guillaume Goudounet, et al. "Refining the Design of Diblock Elastin-Like Polypeptides for Self-Assembly into Nanoparticles." Polymers 13, no. 9 (2021): 1470. http://dx.doi.org/10.3390/polym13091470.

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Diblock copolymers based-on elastin-like polypeptide (ELP) have the potential to undergo specific phase transitions when thermally stimulated. This ability is especially suitable to form carriers, micellar structures for instance, for delivering active cargo molecules. Here, we report the design and study of an ELP diblock library based on ELP-[M1V3-i]-[I-j]. First, ELP-[M1V3-i]-[I-j] (i = 20, 40, 60; j = 20, 90) that showed a similar self-assembly propensity (unimer-to-aggregate transition) as their related monoblocks ELP-[M1V3-i] and ELP-[I-j]. By selectively oxidizing methionines of ELP-[M1
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Lipik, Vitali T., Leonardus K. Widjaja, Sing S. Liow, Subramanian S. Venkatraman, and Marc J. M. Abadie. "Synthesis of Diblocks Copolymers PCL-b-PLLA and Optimization of its Mechanical Characteristics." Eurasian Chemico-Technological Journal 12, no. 2 (2010): 117. http://dx.doi.org/10.18321/ectj33.

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<p>Biodegradable polymeric materials have a wide application in medicine, ecology and a number of other branches of industry. Overwhelming majority of such polymers is well exposed to the biodegradation, but they have mechanical properties which don’t correspond to the requirements of application areas. As a rule, these materials possess low elasticity. In this work, optimization of mechanical properties of biodegradable polymers and the search of structure of block polymer on the basis of ε-caprolactone and L-lactide with the maximal elasticity are considered. The purpose of the work is
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Lipik, Vitali T., Leonardus K. Widjaja, Sing S. Liow, Subramanian S. Venkatraman, and Marc J. M. Abadie. "Synthesis of Diblocks Copolymers PCL-b-PLLA and Optimization of its Mechanical Characteristics." Eurasian Chemico-Technological Journal 11, no. 3 (2009): 239. http://dx.doi.org/10.18321/ectj340.

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<p align="LEFT">Biodegradable polymeric materials have a wide application in medicine, ecology and a number of other branches of industry. Overwhelming majority of such polymers is well exposed to the biodegradation, but they have mechanical properties which don’t correspond to the requirements of application areas. As a rule, these materials possess low elasticity. In this work, optimization of mechanical properties of biodegradable polymers and the search of structure of block polymer on the basis of ε-caprolactone and L-lactide with the maximal elasticity are considered. The purpose o
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Da Silva, C. A., M. Weydert, H. Budde, et al. "INTERRELATIONS BETWEEN MORPHOLOGY AND SOFTENING BEHAVIOR IN SELF-ASSEMBLED POLY (BUTADIENE-BLOCK-(STYRENE-STAT-BUTADIENE)) COPOLYMERS." Rubber Chemistry and Technology 89, no. 3 (2016): 392–405. http://dx.doi.org/10.5254/rct.16.84842.

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ABSTRACT Two series of poly(butadiene-block-(styrene-stat-butadiene) (PB-SBR) diblock copolymers were synthesized to study interrelations between microphase-separated state and relaxation dynamics. Series I consists of six symmetric PB-SBR samples (ΦSBR ∼ 0.50) with different styrene contents in the random SBR block (21 mol% ≤ xS,SBR ≤ 52 mol%). Series II contains six asymmetric PB-SBR diblock copolymers with almost constant styrene content in the SBR block (xS,SBR = 32 ± 4 mol%) and SBR volume fractions in the range of 0.20 ≤ ΦSBR ≤ 0.69. All PB-SBR diblock copolymers have a total molecular w
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Rajagopal, Karthikan, David A. Christian, Takamasa Harada, Aiwei Tian, and Dennis E. Discher. "Polymersomes and Wormlike Micelles Made Fluorescent by Direct Modifications of Block Copolymer Amphiphiles." International Journal of Polymer Science 2010 (2010): 1–10. http://dx.doi.org/10.1155/2010/379286.

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Wormlike micelles and vesicles prepared from diblock copolymers are attracting great interest for a number of technological applications. Although transmission electron microscopy has remained as the method of choice for assessing the morphologies, fluorescence microscopy has a number of advantages. We show here that when commercially available fluorophores are covalently attached to diblock copolymers, a number of their physicochemical characteristics can be investigated. This method becomes particularly useful for visualizing phase separation within polymer assemblies and assessing the dynam
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Braunová, Alena, Michal Pechar, and Karel Ulbrich. "Degradation Behavior of Poly(ethylene glycol) Diblock and Multiblock Polymers with Hydrolytically Degradable Ester Linkages." Collection of Czechoslovak Chemical Communications 69, no. 8 (2004): 1643–56. http://dx.doi.org/10.1135/cccc20041643.

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Diblock and multiblock polymers of poly(ethylene glycol) containing degradable ester bonds between the blocks were synthesized and characterized. Monofunctional poly(ethylene glycol) (PEG 2000) was modified by aliphatic dicarboxylic acids (malonic, succinic, glutaric, maleic) to obtain monocarboxylic polymers PEG-COOH containing ester bonds. Diblock polymers (4000) were prepared by polycondensation of a diamine (ethane-1,2-diamine, L-lysine) and the semitelechelic PEG-COOH. The relationship between the structure of the linkage connecting two PEG blocks and the rate of its hydrolytic degradatio
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Alzahrani, Fatimah M., Stephen G. Yeates, Michelle Webb, and Hind Ali Alghamdi. "Antibacterial Activity of Tannic Acid and Tannic Acid/Amphiphilic Cationic Polymer Mixtures." Asian Journal of Chemistry 32, no. 6 (2020): 1491–96. http://dx.doi.org/10.14233/ajchem.2020.21776.

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In this study, the antibacterial activity of tannic acid/amphiphilic cationic polymer (poly{2-[(methacryloyloxy)ethyl]trimethyl-ammonium chloride}, PMADQUAT) and tannic acid mixtures was examined on the strains of Gram-positive (S. aureus) and Gram-negative (E. coli CI2, E. coli K12, Klebsiella pneumonia and P. aeruginosa) bacteria. Tannic acid exhibited the antibacterial activity against all the studied bacterial strains. The ester linkage between glucose and gallic acid is vital for the antimicrobial activity of tannic acid. Tannic acid inhibited the growth of S. aureus and E. coli K12 (1 wt
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Jee, Jun-Pil, Maria C. Parlato, Mark G. Perkins, Sandro Mecozzi, and Robert A. Pearce. "Exceptionally Stable Fluorous Emulsions for the Intravenous Delivery of Volatile General Anesthetics." Anesthesiology 116, no. 3 (2012): 580–85. http://dx.doi.org/10.1097/aln.0b013e3182475d4d.

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Background IV delivery of volatile fluorinated anesthetics has a number of potential advantages when compared with the current inhalation method of administration. We reported previously that the IV delivery of sevoflurane can be achieved through an emulsion composed of a linear fluorinated diblock copolymer, a stabilizer, and the anesthetic. However, this original emulsion was subject to particle size growth that would limit its potential clinical utility. We hypothesized that the use of bulkier fluorous groups and smaller polyethylene glycol moieties in the polymer design would result in imp
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Sivokhin, Alexey, Dmitry Orekhov, Oleg Kazantsev, et al. "Random and Diblock Thermoresponsive Oligo(ethylene glycol)-Based Copolymers Synthesized via Photo-Induced RAFT Polymerization." Polymers 14, no. 1 (2021): 137. http://dx.doi.org/10.3390/polym14010137.

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Amphiphilic random and diblock thermoresponsive oligo(ethylene glycol)-based (co)polymers were synthesized via photoiniferter polymerization under visible light using trithiocarbonate as a chain transfer agent. The effect of solvent, light intensity and wavelength on the rate of the process was investigated. It was shown that blue and green LED light could initiate RAFT polymerization of macromonomers without an exogenous initiator at room temperature, giving bottlebrush polymers with low dispersity at sufficiently high conversions achieved in 1–2 h. The pseudo-living mechanism of polymerizati
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Dissertations / Theses on the topic "Diblock polymers"

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Stewart-Sloan, Charlotte (Charlotte Roberta). "Morphologies of PDMS-containing diblock polymers." Thesis, Massachusetts Institute of Technology, 2012. http://hdl.handle.net/1721.1/76132.

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Thesis (S.M.)--Massachusetts Institute of Technology, Dept. of Materials Science and Engineering, 2012.<br>Cataloged from PDF version of thesis.<br>Includes bibliographical references (p. 117-123).<br>The morphologies of polydimethylsiloxane (PDMS)-containing diblock polymers are investigated as a function of volume fraction, segregation, processing procedure, and temperature. Strongly segregated polyisoprene-PDMS and polystyrene-PDMS diblocks are prepared according to standard procedures in the literature by anionic synthesis in the laboratory of Professor Apostolos Avgeropoulos at the Univer
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Feng, Lei. "Synthesis and Characterization of Ionically Bonded Diblock Copolymers." University of Akron / OhioLINK, 2013. http://rave.ohiolink.edu/etdc/view?acc_num=akron1385331107.

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Khattari, Ziad Yousef. "Behavior of diblock-copolymers and semi-flexible polymers at interfaces." [S.l. : s.n.], 1999. http://deposit.ddb.de/cgi-bin/dokserv?idn=961385057.

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Sizovs, Antons. "Development of Carbohydrate-based Diblock Polymers for Nucleic Acid Delivery." Diss., Virginia Tech, 2012. http://hdl.handle.net/10919/77089.

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The delivery of nucleic acids remains the major obstacle for nucleic acid-based therapies such as gene therapy and gene silencing therapies based on RNA interference. In this dissertation we have developed and studied nucleic acid delivery vehicles based on cationic diblock glycopolymers that contain glucosamine and trehalosamine. Practical procedures were developed to synthesize 2-methacrylamido-2-deoxy glucose and 6-methacrylamido-6-deoxy trehalose starting with commercially available carbohydrates and utilizing trimethylsilyl protecting group chemistry. These monomers were polymerized via r
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Janert, Philipp Klaus. "Phase behavior of homopolymer/diblock blends /." Thesis, Connect to this title online; UW restricted, 1997. http://hdl.handle.net/1773/9763.

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Skey, Jared. "Synthesis of chiral nanostructures from diblock co-polymers prepared using RAFT polymerisation." Thesis, University of Cambridge, 2010. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.608727.

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Uğur, Gökce. "Interface Structure of Diblock Copolymer Brushes and Surface Dynamics of Homopolymer Brushes and Bilayers of Untethered Chains on Brushes." University of Akron / OhioLINK, 2011. http://rave.ohiolink.edu/etdc/view?acc_num=akron1311005794.

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Lejars, Marlène. "Synthèse de copolymères diblocs par le procédé RAFT : Application pour revêtements anti-salissures marines hybrides FRC/SPC." Thesis, Toulon, 2012. http://www.theses.fr/2012TOUL0011/document.

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Actuellement, il existe deux types de peintures anti-salissures marines sur le marché : - Les Self-Polishing Coatings (SPC), revêtements auto-polissants à base de liants polymères hydrolysables, efficaces par relargage de biocides dans le milieu marin mais toxiques pour l’environnement ; - Les Fouling Release Coatings (FRC), revêtements hydrophobes à base de silicone, sans biocides, qui limitent la force d’adhésion des salissures mais ne sont pas efficaces en mode statique.L’objectif de cette étude est d’élaborer des peintures anti-salissures marines hybrides FRC/SPC. Pour ce faire, des polymè
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Ibrahim, Fathima Shaida. "Fabrication and characterization of sub-micron and nanoscale structures in commercial polymers." Diss., Kansas State University, 2010. http://hdl.handle.net/2097/7019.

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Doctor of Philosophy<br>Department of Chemistry<br>Takashi Ito<br>This dissertation describes the fabrication and characterization of nanoscale structures in commercially available polymers via multiphoton ablation and bottom-up self assembly techniques. High-resolution surface imaging techniques, such as atomic force microscopy (AFM) and chemical force microscopy (CFM) were used to characterize the physical features and chemical properties, respectively, of these nanoscale structures. Fabrication using both top-down and bottom-up methods affords flexibility in that top-down allows random, use
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Montenegro-Galindo, Gladys Rocio. "Synthesis and Protein Adsorption Studies of Pegylated-Polyester Nanoparticles with Different Peg Architectures." University of Akron / OhioLINK, 2013. http://rave.ohiolink.edu/etdc/view?acc_num=akron1384629996.

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Books on the topic "Diblock polymers"

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Shakir, S. A. Studies of stabilization of non-aqueous polymer dispersions with diblock copolymers. 1987.

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Book chapters on the topic "Diblock polymers"

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Gooch, Jan W. "Diblock Polymers." In Encyclopedic Dictionary of Polymers. Springer New York, 2011. http://dx.doi.org/10.1007/978-1-4419-6247-8_3515.

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Nguyen, Chi, Prashant Deshmukh, Xiaorui Chen, Sergio Granados-Focil, and Rajeswari Kasi. "Thermoreversible Ion Gels From Side-Chain Liquid Crystalline Brushes Diblock Copolymers." In Functional Polymers. CRC Press, 2017. http://dx.doi.org/10.1201/9781315366524-9.

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Stelzer, F., W. Fischer, G. Leising, and Ch Heller. "Well Defined Polyacetylene-block-Poly(1,3-cyclopentylene Vinylene) Diblock Copolymers, Synthesis and Characterization." In Electronic Properties of Polymers. Springer Berlin Heidelberg, 1992. http://dx.doi.org/10.1007/978-3-642-84705-9_43.

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Champagne, Michel F., and Michel M. Dumoulin. "Compatibilization of HDPE/PS Blends by Tapered Diblock PE-PS Copolymers." In Interfacial Aspects of Multicomponent Polymer Materials. Springer US, 1997. http://dx.doi.org/10.1007/978-1-4757-5559-6_13.

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"Diblock polymers." In Encyclopedic Dictionary of Polymers. Springer New York, 2007. http://dx.doi.org/10.1007/978-0-387-30160-0_3462.

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Schechtman, L. A. "Emulsion polymerization with oligomeric diblock macromonomer stabilizers." In Polymer Solutions, Blends, and Interfaces. Elsevier, 1992. http://dx.doi.org/10.1016/b978-0-444-89397-0.50007-5.

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Raghavan, Srinivasa. "TiO2 Nanostructures by Sol–Gel Processing." In Sol-Gel Method - Recent Advances [Working Title]. IntechOpen, 2023. http://dx.doi.org/10.5772/intechopen.111440.

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This book chapter discusses the versatile sol–gel processing technique that has been used to synthesize the nanostructures of titanium dioxide (TiO2) and their different morphologies. The sol–gel syntheses of different nanostructures of TiO2, namely TiO2 nanoparticles, nanocrystalline thin film, nanorods, nanofibers, nanowires, nanotubes, aerogels, and opals are described. These nanostructures have been characterized by Scanning Electron Microscopy (SEM) and Transmission Electron Microscopy (TEM) whose images clearly depict the formation of the nanostructures. Some of the morphologies of nano-TiO2 such as nanorods, nanotubes, nanofibers, nanowires, have been synthesized by sol–gel process in combination with spin-coating, dip-coating, template, surfactant, diblock polymer, micelles, polystyrene. In comparison to the bulk TiO2, presence of porous and nanocrystalline morphologies has played a role in enhancing the performance in applications such as photovoltaics, photocatalysis, photocatalytic water-splitting, H2 storage, gas sensors, photochromic, opto-electronic, and electrochromic devices. The chapter concludes with challenges and practical concerns in using the sol–gel process to produce thin films of complex oxides, porous nanostructures, solid nanorods, nanotubes, which need to be addressed in future research efforts.
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Han, Chang Dae. "Rheology of Block Copolymers." In Rheology and Processing of Polymeric Materials: Volume 1: Polymer Rheology. Oxford University Press, 2007. http://dx.doi.org/10.1093/oso/9780195187823.003.0014.

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Block copolymer consists of two or more long blocks with dissimilar chemical structures which are chemically connected. There are different architectures of block copolymers, namely, AB-type diblock, ABA-type triblock, ABC-type triblock, and AmBn radial or star-shaped block copolymers, as shown schematically in Figure 8.1. The majority of block copolymers has long been synthesized by sequential anionic polymerization, which gives rise to narrow molecular weight distribution, although other synthesis methods (e.g., cationic polymerization, atom transfer radical polymerization) have also been developed in the more recent past. Owing to immiscibility between the constituent blocks, block copolymers above a certain threshold molecular weight form microdomains (10–50 nm in size), the structure of which depends primarily on block composition (or block length ratio). The presence of microdomains confers unique mechanical properties to block copolymers. There are many papers that have dealt with the synthesis and physical/mechanical properties of block copolymers, too many to cite them all here. There are monographs describing the synthesis and physical properties of block copolymers (Aggarwal 1970; Burke and Weiss 1973; Hamley 1998; Holden et al. 1996; Hsieh and Quirk 1996; Noshay and McGrath 1977). Figure 8.2 shows schematically four types of equilibrium microdomain structures observed in block copolymers. Referring to Figure 8.2, it is well established (Helfand and Wasserman 1982; Leibler 1980) that in microphase-separated block copolymers, spherical microdomains are observed when the volume fraction f of one of the blocks is less than approximately 0.15, hexagonally packed cylindrical microdomains are observed when the value of f is between approximately 0.15 and 0.44, and lamellar microdomains are observed when the value of f is between approximately 0.44 and 0.50. Some investigators have observed ordered bicontinuous double-diamonds (OBDD) (Thomas et al. 1986; Hasegawa et al. 1987) or bicontinuous gyroids (Hajduk et al. 1994) at a very narrow range of f (say, between approximately 0.35 and 0.40) for certain block copolymers. Figure 8.2 shows only one half of the symmetricity about f = 0.5. Transmission electron microscopy (TEM), small-angle X-ray scattering (SAXS), and small-angle neutron scattering (SANS) have long been used to investigate the types of microdomain structures in block copolymers.
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"diblock copolymer 1991SA2 Characterization: M /g.mol = 3438, 24.8 mol% ethylene oxide Polysciences, Inc., Warrington, PA, USA Solvent (A): water H O 7732-18-5." In CRC Handbook of Thermodynamic Data of Aqueous Polymer Solutions. CRC Press, 2004. http://dx.doi.org/10.1201/9780203998205-78.

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Conference papers on the topic "Diblock polymers"

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Karnik, Rohit, Frank X. Gu, Suman Bose, et al. "Microfluidic Synthesis of Polymeric Nanoparticles." In ASME 2008 6th International Conference on Nanochannels, Microchannels, and Minichannels. ASMEDC, 2008. http://dx.doi.org/10.1115/icnmm2008-62218.

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A central challenge in the development of drug-encapsulated polymeric nanoparticles is the inability to control the nanoparticle physicochemical properties that affect their biodistribution, drug release, and efficacy. Nanoparticles may be developed by mixing and nanoprecipitation of polymers and drugs dissolved in organic solvents with non-solvents. Inadequate control over this mixing process is a source of variability in the synthesis of these nanoparticles by nanoprecipitation. We demonstrate that rapid and tunable mixing through hydrodynamic flow focusing in a microfluidic device can be us
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Barandiaran, Irati, and Galder Kortaberria. "Morphological and magnetic properties of PS-b-PMMA diblock copolymer based nanocomposites." In 9TH INTERNATIONAL CONFERENCE ON “TIMES OF POLYMERS AND COMPOSITES”: From Aerospace to Nanotechnology. Author(s), 2018. http://dx.doi.org/10.1063/1.5045923.

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GORZOLNIK, B., J. PENELLE, D. GRANDE, et al. "MESOPOROUS POLYMERS WITH CONTROLLED POROSITY AND FUNCTIONALITY DERIVED FROM SEMI-DEGRADABLE DIBLOCK COPOLYMERS." In Proceedings of the 5th International Symposium. WORLD SCIENTIFIC, 2008. http://dx.doi.org/10.1142/9789812779168_0025.

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Tsai, Jing-Cherng, Ya-Chun Yang, Cheng-Hung Chiang, Shih-Hung Huang, and Yeo-Wan Chiang. "Palladium-catalyst-mediated coupling reactions for the preparation of stereoregular flurescent polymers and diblock copolymers." In 2017 International Conference on Applied System Innovation (ICASI). IEEE, 2017. http://dx.doi.org/10.1109/icasi.2017.7988246.

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Ling-Hai Xie and Wei Huang. "Bandgaps enigeering in light-emitting polymers via from p-n diblock compolymerization to inorganic/organic hybridization." In 2009 14th OptoElectronics and Communications Conference (OECC). IEEE, 2009. http://dx.doi.org/10.1109/oecc.2009.5221629.

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Giri, R. P., and M. K. Mukhopadhyay. "Self-assembly of diblock co-polymers at air-water interface: A microscopy and x-ray scattering study." In DAE SOLID STATE PHYSICS SYMPOSIUM 2015. Author(s), 2016. http://dx.doi.org/10.1063/1.4947894.

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Jayaraman, Ashish, Diana Zhang, Beth Dewing, and Mahesh K. Mahanthappa. "Approximants of dodecagonal quasicrystals in aqueous diblock polymer dispersions." In Aperiodic 2018 ("9th Conference on Aperiodic Crystals"). Iowa State University, Digital Press, 2018. http://dx.doi.org/10.31274/aperiodic2018-180810-28.

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Handge, Ulrich A., Taida Gil Haenelt, Prokopios Georgopanos, et al. "Analysis of stability and viscoelastic properties of melts of polystyrene-block-polyisoprene diblock copolymers in oscillatory shear and creep-recovery experiments." In PROCEEDINGS OF PPS-30: The 30th International Conference of the Polymer Processing Society – Conference Papers. AIP Publishing LLC, 2015. http://dx.doi.org/10.1063/1.4918519.

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Carpenter, Corinne L., Kris T. Delaney, Nabil Laachi, and Glenn H. Fredrickson. "Directed self-assembly of diblock copolymers in cylindrical confinement: effect of underfilling and air-polymer interactions on configurations." In SPIE Advanced Lithography, edited by Douglas J. Resnick and Christopher Bencher. SPIE, 2015. http://dx.doi.org/10.1117/12.2085639.

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Luo, Zhonglin, and Jianwen Jiang. "Drug Loading and Release by a pH-Sensitive Amphiphilic Diblock Polymer: From Fully Atomistic to Coarse-grained Simulations." In 14th Asia Pacific Confederation of Chemical Engineering Congress. Research Publishing Services, 2012. http://dx.doi.org/10.3850/978-981-07-1445-1_271.

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