Academic literature on the topic 'Dichloropropane'
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Journal articles on the topic "Dichloropropane"
Zebarth, B. J., S. Y. Szeto, B. Hii, H. Liebscher, and G. Grove. "Groundwater Contamination by Chlorinated Hydrocarbon Impurities Present in Soil Fumigant Formulations." Water Quality Research Journal 33, no. 1 (1998): 31–50. http://dx.doi.org/10.2166/wqrj.1998.003.
Full textMerriman, John C., John Struger, and Richard S. Szawiola. "Distribution of 1,3-dichloropropene and 1,2-dichloropropane in big Creek watershed." Bulletin of Environmental Contamination and Toxicology 47, no. 4 (1991): 572–79. http://dx.doi.org/10.1007/bf01700948.
Full textCrowder, G. A. "Vibrational analysis of 2,2-dichloropropane and 2,2-dichloropropane-d6." Spectrochimica Acta Part A: Molecular Spectroscopy 42, no. 9 (1986): 1079–82. http://dx.doi.org/10.1016/0584-8539(86)80022-8.
Full textPérez, P., J. Valero, M. Gracia, and C. Gutiérrez Losa. "GmE(298.15 K) of mixtures containing 1,2-dichloropropane or 1,3-dichloropropane." Journal of Chemical Thermodynamics 21, no. 3 (1989): 259–64. http://dx.doi.org/10.1016/0021-9614(89)90015-3.
Full textBaños, I., J. Valero, P. Pérez, M. Gracia, and C. Gutiérrez Losa. "Excess molar volumes of mixtures containing 1,2-dichloropropane or 1,3-dichloropropane." Journal of Chemical Thermodynamics 22, no. 5 (1990): 431–37. http://dx.doi.org/10.1016/0021-9614(90)90133-b.
Full textGrove, Gary, Sunny Y. Szeto, Hugh Liebscher, Basil Hii, and Bernie J. Zebarth. "Occurrence of 1,2-Dichloropropane and 1,3-Dichloropropene in the Abbotsford Aquifer, British Columbia." Water Quality Research Journal 33, no. 1 (1998): 51–72. http://dx.doi.org/10.2166/wqrj.1998.004.
Full textTrevisan, Andrea, Stefano Maso, and Paola Meneghetti. "Renal Cortical Slices: An In Vitro Model for Kidney Metabolism and Toxicity." Alternatives to Laboratory Animals 20, no. 1 (1992): 71–76. http://dx.doi.org/10.1177/026119299202000110.
Full textHonma, T. "Toxicity of 1, 2-dichloropropane." SANGYO EISEIGAKU ZASSHI 40, Special (1998): 712. http://dx.doi.org/10.1539/sangyoeisei.kj00001990533.
Full textTrevisan, Andrea, Paola Meneghetti, Stefano Maso, and Ornella Troso. "In-Vitro Mechanisms of 1,2-Dichloropropane Nephrotoxicity using the Renal Cortical Slice Model." Human & Experimental Toxicology 12, no. 2 (1993): 117–21. http://dx.doi.org/10.1177/096032719301200204.
Full textTornero-Velez, Rogelio, Matthew K. Ross, Courtney Granville, et al. "METABOLISM AND MUTAGENICITY OF SOURCE WATER CONTAMINANTS 1,3-DICHLOROPROPANE AND 2,2-DICHLOROPROPANE." Drug Metabolism and Disposition 32, no. 1 (2004): 123–31. http://dx.doi.org/10.1124/dmd.32.1.123.
Full textDissertations / Theses on the topic "Dichloropropane"
Schlötelburg, Cord. "Mikrobielle Diversität und Dynamik einer 1,2-Dichlorpropan dechlorierenden Mischkultur." Doctoral thesis, Humboldt-Universität zu Berlin, Mathematisch-Naturwissenschaftliche Fakultät I, 2002. http://dx.doi.org/10.18452/14678.
Full textThe toxic and carcinogenic compound 1,2-dichloropropane (DCP) is widely used in industry and agriculture. DCP shows a low chemical reactivity. It is only moderately soluble in aqueous systems and almost recalcitrant to microbial degradation under aerobic conditions. As a consequence DCP accumulates in groundwater, sediments and soil, thus endangering humans and animals via the food chain. To efficiently transform DCP to harmless organic compounds microbial mixed cultures have been enriched from sediments and were subsequently transferred into a fluidized bed bioreactor. This process allowed a continuous anaerobic dechlorination of DCP to propene. Bioreactor processes using complex microbiota represent a promising technology for transformation of chlorinated compounds. However, the composition of the used population is usually unknown, hence hindering both optimization and control of the degradation process. Subject of this work was the analysis of the microbial diversity of the DCP-dechlorinating bioreactor population. Conventional culture-dependent microbiological methods are often limited if used for the analysis of complex communities. Therefore, a combination of different molecular methods based on comparative 16S rRNA analysis was applied. It was found that the bioreactor population was highly diverse and consisted mainly of as yet-uncultured bacteria. Members of the green nonsulfur bacteria and the gram-positive bacteria with low G+C content dominated the consortium. In contrast the archaea were represented by only two species, Methanosaeta concilii and Methanomethylovorans hollandica. The comparison of the rDNA data with those of other biotopes revealed that reductively dechlorinating freshwater habitats show a specific community structure. 16S rDNA-clusters were defined, which could still be detected after a longer operation time of the bioreactor. Furthermore, Dehalobacter restrictus- and Dehalococcoides ethenogenes-like bacteria were found in the DCP-dechlorinating bioreactor population. Both species are capable of reductive dechlorination using hydrogen as the sole electron source. Therefore, it could be assumed that these bacteria were also involved in the dechlorination of DCP. The investigation of the bioreactor population for a longer period of time revealed that Dehalobacter-like bacteria were significantly enriched and subsequently became the most frequently found bacterium within the bioreactor. This indicates a major role of Dehalobacter spp. within the transformation process of DCP to propene. Consequently, the addition of hydrogen to the bioreactor led to an increase of the DCP transformation rate. Dehalobacter und Dehalococcoides spp. as well as the bacteria represented by the specific SHA-clusters are possibly suitable as indicator organisms for the transformation of DCP within the bioreactor. A continuous monitoring of these bacteria would lead to a more efficient control and hence, to an optimization of the transformation process.
Minnis, Stephen T. "Distribution of potato cyst nematodes in England and Wales and the use of 1,3-dichloropropene for their control." Thesis, Open University, 2000. http://oro.open.ac.uk/58068/.
Full textLAMASTRA, LUCREZIA. "Le caratteristiche ambientali di selezionate alternative chimiche all'uso del Metil Bromuro come geodisinfestante: 1,3- Dicloropropene e Cloropicrina." Doctoral thesis, Università Cattolica del Sacro Cuore, 2011. http://hdl.handle.net/10280/976.
Full textProduction and use of methyl bromide, a soil fumigant, are being restricted because of this chemical’s deleterious effects on stratospheric ozone concentrations. This research examines the environmental fate and properties of methyl bromide replacement: 1,3-Dichloropropene (1,3-D), and Chloropicrin (CP). 1,3-D is a broad-spectrum soil fumigant used to control numerous species of soil-borne plant-parasitic nematodes. 1,3-D consists of two isomers, (Z)- and (E)-1,3-D, and has a number of low-level chlorinated compounds that could potentially be part of the manufacturing process. This study has investigated the hydrolytic stability, under biotic and abiotic conditions, of an extensive representative list of 1,3-D potentially related chlorinated compounds. Furthermore, a monitoring programme was carried out to investigate the leaching of all of this compounds. CP is a broad-spectrum fumigant chemical which is extensively used in agriculture and has an important toxicological profile. This study has assessed CP emission in the atmosphere and operator exposure during and after application in soil through injection of the test substances with routine agronomical application. Finally the environmental fate of CP and its metabolite dichloronitromethane in groundwater were investigated through the use of simulation model FOCUS PELMO and FOCUS PEARL using fully justified input parameters in five realistic scenarios.
Ahubelem, Nwakamma. "Formation of toxic compounds in the thermal decomposition of 1,3-dichloropropene." Thesis, 2016. http://hdl.handle.net/1959.13/1311967.
Full textThe formation of chlorobenzenes from oxidative thermal decomposition of 1,3-dichloropropene have been investigated using a combined combustion experiments and quantum chemical calculations. Experimental and computational results elucidate the chemistry of formation of toxic compounds from combustion chlorinated pesticides as could occur in bush fires or accidental fires of such chemicals in their storage facilities. Mono- to hexa-chlorobenzenes were observed between 800 – 1150 K, and the extent of chlorination was proportional to the combustion temperature. Higher chlorinated congeners of chlorobenzene (tetra-, penta-, hexa-chlorobenzene) were only observed in trace amounts between 950 – 1050 K. DFT calculations indicated that cyclisation of chlorinated hexatrienes proceeds via open-shell, radical pathways. Oxidation of phenylvinyl radical intermediates and subsequent ring closure were the key mechanistic pathways in the formation of benzofuran and chlorobenzofuran. Quantum chemical molecular dynamics (QM/MD) at 1,500 and 3,000 K revealed that the thermal oxidation of 1,3-dichloropropene was initiated by (1) abstraction of allylic H/Cl by O₂ and (2) intra-annular C-Cl bond scission and elimination of allylic Cl. A kinetic analysis showed that (2) is the more dominant initiation pathway, in agreement with QM/MD results. These QM/MD simulations revealed new routes to the formation of major products (H₂O, CO, HCl, CO₂), which were propagated primarily by the chloroperoxy (ClO₂), OH and 1,3-dichloropropene derived radicals. In particular, intra-annular C-C/C-H bond dissociation reactions of intermediate aldehydes/ketones were shown to play a dominant role in the formation of CO and CO₂. QM/MD simulations demonstrated that both combustion temperature and radical concentration can influence the product yield, however not the combustion mechanism. In order to elucidate the dehydrochlorination kinetics of 1,3-dichloropropene and related compounds, the unimolecular HCl elimination reactions of 1,3-dichloropropene and other chloroaliphatic hydrocarbons were investigated using high level computational chemistry methods. Two generic pathways for the elimination of HCl was found. The first involves a C-Cl fission at an allylic site and a C-H cleavage at a vinylic site, whereas the second entails scissions of allylic Cl and methylenic H. The latter pathway appears more favourable from thermodynamic and kinetic standpoints. The effect of the length of carbon chain on reaction and activation enthalpies was also investigated by considering analogous dehydrochlorination pathways for short chlorinated aliphatics (i.e., C₃, C₄), discovering the reaction and activation enthalpies required for HCl elimination to be independent of the length of the carbon chain. Dehydrochlorination reactions investigated exhibited a pressure-independent behaviour even under ambient pressure and results suggest that electronic factors rather than anchimeric assistance influence dehydrochlorination reactions of substituted ethyl halides.
Books on the topic "Dichloropropane"
Kagaku Busshitsu Hyōka Kenkyū Kikō and Shin Enerugī Sangyō Gijutsu Sōgō Kaihatsu Kikō (Japan), eds. 1,2-jikuroropuropan: 1,2-Dichloropropane. Seihin Hyōka Gijutsu Kiban Kikō Kagaku Busshitsu Hyōka Kenkyū Kikō, 2007.
B, Terrill James, and United States. Environmental Protection Agency., eds. The Subacute and subchronic oral toxicity of 1,3-dichloropropane in the rat. U.S. Environmental Protection Agency, 1992.
United, States Environmental Protection Agency Prevention Pesticides and Toxic Substances. Reregistration eligibility decision: 1,3-dichloropropene, list A, case 0328. U.S. Environmental Protection Agency, Prevention, Pesticides, and Toxic Substances, 1998.
Dichloropropane (1,3), Dichloropropane (1,2) (Health & Safety Guide). World Health Organization, 1992.
International Program on Chemical Safety., International Labour Organisation, World Health Organization, and United Nations Environment Programme, eds. 1,3-dichloropropene, 1,2-dichloropropane and mixtures health and safety guide. World Health Organization, 1992.
1, 3-Dichloropropene, 1,2-Dichloropropane and Mixtures (Environmental Health Criteria Series No. 146). World Health Organization, 1993.
Annette, Ashizawa, United States. Agency for Toxic Substances and Disease Registry., Syracuse Research Corporation, and United States. Environmental Protection Agency., eds. Draft toxicological profile for dichloropropenes. U.S. Dept. of Health and Human Services, Public Health Service, Agency for Toxic Substances and Disease Registry, 2006.
Reregistration eligibility decision: 1,3-dichloropropene, list A, case 0328. U.S. Environmental Protection Agency, Prevention, Pesticides, and Toxic Substances, 1998.
Reregistration eligibility decision: 1,3-dichloropropene, list A, case 0328. U.S. Environmental Protection Agency, Prevention, Pesticides, and Toxic Substances, 1998.
Book chapters on the topic "Dichloropropane"
Ware, George W. "1,2-Dichloropropane." In Reviews of Environmental Contamination and Toxicology. Springer New York, 1988. http://dx.doi.org/10.1007/978-1-4613-8785-5_8.
Full textWohlfarth, Christian. "Refractive index of 1,2-dichloropropane." In Optical Constants. Springer Berlin Heidelberg, 2017. http://dx.doi.org/10.1007/978-3-662-49236-9_92.
Full textWohlfarth, Christian. "Refractive index of 1,3-dichloropropane." In Optical Constants. Springer Berlin Heidelberg, 2017. http://dx.doi.org/10.1007/978-3-662-49236-9_93.
Full textWohlfarth, Ch. "Refractive index of 1,3-dichloropropane." In Refractive Indices of Pure Liquids and Binary Liquid Mixtures (Supplement to III/38). Springer Berlin Heidelberg, 2008. http://dx.doi.org/10.1007/978-3-540-75291-2_59.
Full textGorzka, Zbigniew, Marek Kaźmierczak, and Andrzej Żarczyński. "Catalytic Oxidation of 1,2-Dichloropropane on Copper-Zinc Catalyst." In Chemistry for the Protection of the Environment 3. Springer US, 1998. http://dx.doi.org/10.1007/978-1-4757-9664-3_17.
Full textWohlfarth, Christian. "Refractive index of binary liquid mixture of nitromethane and 1,3-dichloropropane." In Optical Constants. Springer Berlin Heidelberg, 2017. http://dx.doi.org/10.1007/978-3-662-49236-9_468.
Full textWohlfarth, Christian. "Refractive index of binary liquid mixture of nitroethane and 1,3-dichloropropane." In Optical Constants. Springer Berlin Heidelberg, 2017. http://dx.doi.org/10.1007/978-3-662-49236-9_534.
Full textCibulka, I., L. Hnědkovský, J. C. Fontaine, K. Sosnkowska-Kehiaian, and H. V. Kehiaian. "Volumetric Properties of the Mixture 1,2-Dichloropropane C3H6Cl2 + C6H6 Benzene (LB2263, VMSD1211)." In Binary Liquid Systems of Nonelectrolytes. Springer Berlin Heidelberg, 2009. http://dx.doi.org/10.1007/978-3-540-73584-7_681.
Full textCibulka, I., L. Hnědkovský, J. C. Fontaine, K. Sosnkowska-Kehiaian, and H. V. Kehiaian. "Volumetric Properties of the Mixture 1,3-Dichloropropane C3H6Cl2 + C6H6 Benzene (LB2262, VMSD1211)." In Binary Liquid Systems of Nonelectrolytes. Springer Berlin Heidelberg, 2009. http://dx.doi.org/10.1007/978-3-540-73584-7_682.
Full textCibulka, I., L. Hnědkovský, J. C. Fontaine, K. Sosnkowska-Kehiaian, and H. V. Kehiaian. "Volumetric Properties of the Mixture 1,2-Dichloropropane C3H6Cl2 + C6H12 Cyclohexane (LB2259, VMSD1211)." In Binary Liquid Systems of Nonelectrolytes. Springer Berlin Heidelberg, 2009. http://dx.doi.org/10.1007/978-3-540-73584-7_701.
Full textConference papers on the topic "Dichloropropane"
Xie, Fei, Wenhua Song, Lingyue Lv, and Zhen Chen. "FDS Simulation of the Pool Fire in the Dichloropropane Tank." In 2012 4th International Conference on Multimedia Information Networking and Security (MINES). IEEE, 2012. http://dx.doi.org/10.1109/mines.2012.111.
Full textLueong, S., S. Villar, V. Cahais, et al. "PO-319 Mutational signatures of 1,2-dichloropropane and dichloromethane identified in mouse carcinogenicity assays." In Abstracts of the 25th Biennial Congress of the European Association for Cancer Research, Amsterdam, The Netherlands, 30 June – 3 July 2018. BMJ Publishing Group Ltd, 2018. http://dx.doi.org/10.1136/esmoopen-2018-eacr25.349.
Full textXie, Fei, Wenhua Song, Zhen Chen, and Lingyue Lv. "The Applied Research of Thomas Model in the Pool Fire Risk Assessment in Fire Embankment of Dichloropropane Storage Tank Area." In 2012 4th International Conference on Multimedia Information Networking and Security (MINES). IEEE, 2012. http://dx.doi.org/10.1109/mines.2012.218.
Full textReports on the topic "Dichloropropane"
NIOSH skin notation (SK) profile: 1,3-dichloropropene (1,3-D) [CAS No. 542-75-6]. U.S. Department of Health and Human Services, Public Health Service, Centers for Disease Control and Prevention, National Institute for Occupational Safety and Health, 2011. http://dx.doi.org/10.26616/nioshpub2011155.
Full textSoil analyses for 1,3-dichloropropene (1,3-DCP), sodium n-methyldithiocarbamate (metam-sodium), and their degradation products near Fort Hall Idaho, September 1999 through March 2000. US Geological Survey, 2001. http://dx.doi.org/10.3133/wri014052.
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