Academic literature on the topic 'Diffused Double Layer Theory'

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Journal articles on the topic "Diffused Double Layer Theory"

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Meegoda, Jay N., Shaini Aluthgun Hewage, and Janitha H. Batagoda. "Application of the Diffused Double Layer Theory to Nanobubbles." Langmuir 35, no. 37 (2019): 12100–12112. http://dx.doi.org/10.1021/acs.langmuir.9b01443.

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Fintel, M., G. A. Langer, J. C. Rohloff, and M. E. Jung. "Contribution of myocardial diffuse double-layer calcium to contractile function." American Journal of Physiology-Heart and Circulatory Physiology 249, no. 5 (1985): H989—H994. http://dx.doi.org/10.1152/ajpheart.1985.249.5.h989.

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The role of diffuse double-layer calcium in cardiac excitation-contraction coupling was examined using rabbit interventricular septa, cultured neonatal rat myocardial cells, and gas-dissected sarcolemmal membranes. The diffuse double layer refers to the space directly adjacent to the sarcolemma where the ionic composition of the media is a direct function of the membrane surface potential. The divalent cation dimethonium was used as a specific probe for the diffuse double layer. According to Gouy-Chapman theory, replacement of sodium with sucrose should increase the amount of calcium located in this compartment. Dimethonium (10 mM) was found to decrease calcium uptake and contractility during low-sodium (33 mM) perfusion when the perfusate contained sucrose but not LiCl. Dimethonium did not decrease calcium uptake or contractility during control perfusion. The results suggest that calcium present in the myocardial diffuse double layer can be augmented or reduced in accordance with Gouy-Chapman theory. Changes in diffuse double-layer calcium are accompanied by small (7.8%) but significant changes in contractility.
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Xiong, Yan, and Yu Shu Lai. "Thermal Conductivity of SOI LDMOS Device." Advanced Materials Research 571 (September 2012): 8–12. http://dx.doi.org/10.4028/www.scientific.net/amr.571.8.

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In this paper, the thermal conductivity of lateral double diffused metal oxide semiconductor (LDMOS) was studied. In order to optimize their properties, the LDMOS device based on the lower surface of field (RESURF) theory join the second field plate technology. Power device self-heating effect will affect the carrier mobility, making its negative resistance effect in IV characteristic curve under the high-power condition. As the thermal conductivity of SiO2 is low, the self-heating effect of SOI device is more obvious. The simulation using Silvaco -TCAD software for different buried oxide (BOX) with different SOI layer thickness accordingly show that the thicker SOI layer and the thinner buried oxide layer, the smaller the self-heating effect.
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Zhao, Xiaoyu, Koichi Jeremiah Aoki, Jingyuan Chen, and Toyohiko Nishiumi. "Examination of the Gouy–Chapman theory for double layer capacitance in deionized latex suspensions." RSC Adv. 4, no. 108 (2014): 63171–81. http://dx.doi.org/10.1039/c4ra11258j.

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Fawcett, W. Ronald, and Thomas G. Smagala. "New Developments in the Theory of the Diffuse Double Layer†." Langmuir 22, no. 25 (2006): 10635–42. http://dx.doi.org/10.1021/la0610699.

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Tripathy, Snehasis, Asuri Sridharan, and Tom Schanz. "Swelling pressures of compacted bentonites from diffuse double layer theory." Canadian Geotechnical Journal 41, no. 3 (2004): 437–50. http://dx.doi.org/10.1139/t03-096.

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The swelling pressures of several compacted bentonites (MX80, Febex, and Montigel) proposed for use as barrier materials in storing high-level radioactive waste in many countries were determined from the Gouy–Chapman diffuse double layer theory. The swelling pressures thus determined were compared with the reported experimental swelling pressures. The study revealed that, in general, at low compaction dry densities of the bentonites, the experimental swelling pressures are less than their theoretical counterparts, with the reverse trend at high compaction dry densities. Based on the reported experimental results for the three bentonites, relationships between the nondimensional midplane potential function, u, and the nondimensional distance function, Kd, were established. New equations for the swelling pressure were proposed on the basis of the diffuse double layer theory and the reported experimental data to compute swelling pressures of compacted bentonites. The suitability of the new equations was also verified with additionally reported experimental swelling pressures from three other bentonites (Kunigel V1, Kunigel, and bentonite S-2) that have been also proposed for use as barrier materials. Very good agreement was found in all the cases between the experimental swelling pressures and the swelling pressures obtained using the proposed equations. The use of the proposed equations is based on the weighted average valency of the cations present in bentonites, since the valency of the cations present has a significant influence on the swelling pressure.Key words: clays, compressibility, swelling pressure, expansive soils, chemical properties, radioactive waste disposal.
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Sparnaay, M. J. "Corrections of the theory of the flat diffuse double layer." Recueil des Travaux Chimiques des Pays-Bas 77, no. 9 (2010): 872–88. http://dx.doi.org/10.1002/recl.19580770911.

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AL-Bazali, Talal. "Insight into Debye Hückel length (κ−1): smart gravimetric and swelling techniques reveals discrepancy of diffuse double layer theory at high ionic concentrations". Journal of Petroleum Exploration and Production Technology 12, № 2 (2021): 461–71. http://dx.doi.org/10.1007/s13202-021-01380-2.

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AbstractSmart gravimetric and swelling techniques were utilized in this work to examine the validity of the Debye Hückel length (κ−1) equation when shale interacts with highly concentrated salt solutions. The swelling and shrinkage behavior of two different shales, when exposed to monovalent and divalent ionic solutions (NaCl, KCl and CaCl2) at concentrations ranging from 2 to 22%w/w was observed and measured. Shale swelling and shrinkage results show that Debye Hückel length (κ−1) equation seems to work adequately at low ionic concentrations where osmotic water flow out of shale plays a major role in decreasing the diffuse double layer thickness by withdrawing water out and thereby shrinking κ−1. At high ionic concentration levels, the flow of associated water into the diffuse double layer negates the withdrawal of osmotic water out of the diffuse double layer which could maintain κ−1 or possibly increase it. Data on measured ionic uptake into shale suggests that excessive ionic diffusion into shale, especially at high concentrations, leads to higher electrical repulsion between alike ions in the diffuse layer which could lead to the expansion of the diffuse double layer thickness. Furthermore, swelling and shrinkage data analysis for shale suggests the existence of a ‘critical concentration’ below which the Debye Hückel length equation works. Above the critical concentration, the validity of the Debye Hückel length equation might be in question. The critical concentration is different for all ions and depends on ionic valence, hydrated ion diameter, and clay type.
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Sridharan, Asuri, and Deepankar Choudhury. "Computation of hydraulic conductivity of montmorillonitic clays by diffuse double layer theory." International Journal of Geotechnical Engineering 2, no. 1 (2008): 1–10. http://dx.doi.org/10.3328/ijge.2007.02.01.1-10.

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Bharat, Tadikonda Venkata, and Asuri Sridharan. "Prediction of Compressibility Data for Highly Plastic Clays Using Diffuse Double-Layer Theory." Clays and Clay Minerals 63, no. 1 (2015): 30–42. http://dx.doi.org/10.1346/ccmn.2015.0630103.

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Dissertations / Theses on the topic "Diffused Double Layer Theory"

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Yang, Guomin. "Interfacial properties of calcium montmorillonite in aqueous solutions : Density functional theory and classical molecular dynamics studies on the electric double layer." Doctoral thesis, KTH, Kemisk apparatteknik, 2017. http://urn.kb.se/resolve?urn=urn:nbn:se:kth:diva-204648.

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The swelling properties of Bentonite are highly affected by clay content and the clay-water interactions that arise from the ion distribution in the diffuse double layer formed near the charged montmorillonite (or smectite) surfaces. Existing continuum models describing the electric double layers, such as classical Poisson-Boltzmann and DLVO theory, ignore the ion-ion correlations, which are especially important for multivalent ions at high surface charge and ionic strength. To better understand the clay-water interactions, atomistic models were developed using both density functional theory of fluids (DFT) as well as classical molecular dynamics (MD) methods. In order to increase our understanding of water-saturated, swelling smectite clays, a DFT, technique was initially developed that allowed more accurate predictions of important thermodynamic properties of the diffuse double layers. This DFT approach was then extended to handle systems with mixtures of different sizes and charges. The extended DFT model was verified against experiments and Monte-Carlo simulations. One practical application was to predict the ion exchange equilibria in Bentonite clays, which have wide practical usage in different areas. Nevertheless, in the DFT work it was realized that DFT demands that the particles, ions in this case, which are described as hard spheres, realistically cannot be described as such at low water loadings, when ion specific hydration forces govern the electric double layer properties. To study how the deformation of the hydration shells of Ca2+ influences the properties of compacted smectite clays, MD simulations using the CLAYFF forcefield were employed in order to account for the deformation of the hydration shells. Comparisons of DFT and MD modeling then allowed to demonstrate under which conditions DFT modeling becomes increasingly inaccurate and when it still can give accurate results.<br>Under senare år har mycket forskning ägnats åt att förstå egenskaperna hos svällande leror som används för att skydda mot läckage av föroreningar från kontaminerade områden och från framtida slutförvar av radionuklider. Den fria svällningen förorsakas av de starka osmotiska krafter som uppstår när vatten tränger in mellan de tunna elektriskt negativt laddade lermineralskikten och löser de laddningskompenserande jonerna i det diffusa dubbelskiktet. I flera arbeten användandes av sk. kontinuum-teori har vattenmolekylens form, specifika orientering och bindning till katjonerna i de nanometerstora utrymmen mellan lerpartiklarna ej beaktats samt ej heller hur de hydratiserade jonerna orienteras på de atomärt ojämna ytorna. Detta möjliggörs dock genom modellering av de enskilda atomernas och jonernas interaktioner med molekyldynamik simuleringar, MD. I detta arbete har programmet Gromacs använts tillsammans med kraftfältet CLAYFF för att studera dessa fenomen i montmorillonitleror med natrium- och kalciumjoner. Simuleringarna visar att natrium bildar transienta innersfärkomplex vilka orienterar sig i bi-triangulära fördjupningar på ytan, ungefär 3.8 Å från mitt-planet mellan lerytorna. Denna orientering observeras ända upp till att avståndet mellan ytorna ökat till större än motsvarande fem lager vattenmolekyler mellan lerpartiklarnas ytor. Detta sker inte med kalcium, oberoende av avståndet mellan ytorna. Natriumjoner koordineras med fyra vattenmolekyler och en syreatom på leran vid ett lager vatten mellan ytorna och med fem till sex vattenmolekyler, ortogonalt orienterade med ökande mängd vatten mellan ytorna, och med en hydratiserad jon-radie av 3.1 Å. Kalcium koordinerar till sju vattenmolekyler vid ett vattenlager mellan ytorna, men ökar till åtta ortogonalt orienterade vattenmolekyler med en jonradie på 3.3 Å vid större avstånd. Generellt visas att när avståndet mellan lerytorna är mindre än ca 10 Å, deformeras de annars symmetriskt hydratiserade jonerna. En jämförelse mellan MD simuleringar och med klassisk täthetsfunktionalteori, DFT, visar att den senare inte kan beskriva hur yttersfärkomplexen samverkar med laddningarna bundna närmast ytan, dvs i Stern-lagret.<br><p>QC 20170403</p>
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Moreira, André Guérin. "Charged systems in bulk and at interfaces." Phd thesis, Universität Potsdam, 2001. http://opus.kobv.de/ubp/volltexte/2005/69/.

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Eine der Faustregeln der Kolloid- und Oberflächenphysik ist, dass die meisten Oberflächen geladen sind, wenn sie mit einem Lösungsmittel, normalerweise Wasser, in Kontakt treten. Dies ist zum Beispiel bei ladungsstabilisierten Kolloidalen Suspensionen der Fall, bei denen die Oberfläche der Kolloidteilchen geladen ist (gewöhnlich mit einer Ladung von mehreren Hunderttausend Elementarladungen), oder bei Monoschichten ionischer Tenside, die auf einer Luft-Wasser Grenzfläche sitzen (wobei die wasserliebenden Kopfgruppen durch die Freisetzung von Gegenionen geladen werden), sowie bei Doppelschichten, die geladene phospholipide enthalten (wie Zellmembranen). In dieser Arbeit betrachten wir einige Modellsysteme, die zwar eine vereinfachte Fassung der Realität darstellen, von denen wir aber dennoch erwarten koennen, dass wir mit ihrer Hilfe einige physikalische Eigenschaften realer geladener Systeme (Kolloide und Elektrolyte) einfangen können.<br>One of the rules-of-thumb of colloid and surface physics is that most surfaces are charged when in contact with a solvent, usually water. This is the case, for instance, in charge-stabilized colloidal suspensions, where the surface of the colloidal particles are charged (usually with a charge of hundreds to thousands of e, the elementary charge), monolayers of ionic surfactants sitting at an air-water interface (where the water-loving head groups become charged by releasing counterions), or bilayers containing charged phospholipids (as cell membranes). In this work, we look at some model-systems that, although being a simplified version of reality, are expected to capture some of the physical properties of real charged systems (colloids and electrolytes).<br /> <br /> We initially study the simple double layer, composed by a charged wall in the presence of its counterions. The charges at the wall are smeared out and the dielectric constant is the same everywhere. The Poisson-Boltzmann (PB) approach gives asymptotically exact counterion density profiles around charged objects in the weak-coupling limit of systems with low-valent counterions, surfaces with low charge density and high temperature (or small Bjerrum length). Using Monte Carlo simulations, we obtain the profiles around the charged wall and compare it with both Poisson-Boltzmann (in the low coupling limit) and the novel strong coupling (SC) theory in the opposite limit of high couplings. In the latter limit, the simulations show that the SC leads in fact to asymptotically correct density profiles. We also compare the Monte Carlo data with previously calculated corrections to the Poisson-Boltzmann theory. We also discuss in detail the methods used to perform the computer simulations.<br /> <br /> After studying the simple double layer in detail, we introduce a dielectric jump at the charged wall and investigate its effect on the counterion density distribution. As we will show, the Poisson-Boltzmann description of the double layer remains a good approximation at low coupling values, while the strong coupling theory is shown to lead to the correct density profiles close to the wall (and at all couplings). For very large couplings, only systems where the difference between the dielectric constants of the wall and of the solvent is small are shown to be well described by SC.<br /> <br /> Another experimentally relevant modification to the simple double layer is to make the charges at the plane discrete.<br /> The counterions are still assumed to be point-like, but we constraint the distance of approach between ions in the plane and counterions to a minimum distance D. The ratio between D and the distance between neighboring ions in the plane is, as we will see, one of the important quantities in determining the influence of the discrete nature of the charges at the wall over the density profiles. Another parameter that plays an important role, as in the previous case, is the coupling as we will demonstrate, systems with higher coupling are more subject to discretization effects than systems with low coupling parameter.<br /> <br /> After studying the isolated double layer, we look at the interaction between two double layers. The system is composed by two equally charged walls at distance d, with the counterions confined between them. The charge at the walls is smeared out and the dielectric constant is the same everywhere. Using Monte-Carlo simulations we obtain the inter-plate pressure in the global parameter space, and the pressure is shown to be negative (attraction) at certain conditions. The simulations also show that the equilibrium plate separation (where the pressure changes from attractive to repulsive) exhibits a novel unbinding transition. We compare the Monte Carlo results with the strong-coupling theory, which is shown to describe well the bound states of systems with moderate and high couplings. The regime where the two walls are very close to each other is also shown to be well described by the SC theory.<br /> <br /> Finally, Using a field-theoretic approach, we derive the exact low-density ("virial") expansion of a binary mixture of positively and negatively charged hard spheres (two-component hard-core plasma, TCPHC). The free energy obtained is valid for systems where the diameters d_+ and d_- and the charge valences q_+ and q_- of positive and negative ions are unconstrained, i.e., the same expression can be used to treat dilute salt solutions (where typically d_+ ~ d_- and q_+ ~ q_-) as well as colloidal suspensions (where the difference in size and valence between macroions and counterions can be very large). We also discuss some applications of our results.
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Axelsson, Andreas, and kax74@yahoo se. "Transmission problems for Dirac's and Maxwell's equations with Lipschitz interfaces." The Australian National University. School of Mathematical Sciences, 2002. http://thesis.anu.edu.au./public/adt-ANU20050106.093019.

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The aim of this thesis is to give a mathematical framework for scattering of electromagnetic waves by rough surfaces. We prove that the Maxwell transmission problem with a weakly Lipschitz interface,in finite energy norms, is well posed in Fredholm sense for real frequencies. Furthermore, we give precise conditions on the material constants ε, μ and σ and the frequency ω when this transmission problem is well posed. To solve the Maxwell transmission problem, we embed Maxwell’s equations in an elliptic Dirac equation. We develop a new boundary integral method to solve the Dirac transmission problem. This method uses a boundary integral operator, the rotation operator, which factorises the double layer potential operator. We prove spectral estimates for this rotation operator in finite energy norms using Hodge decompositions on weakly Lipschitz domains. To ensure that solutions to the Dirac transmission problem indeed solve Maxwell’s equations, we introduce an exterior/interior derivative operator acting in the trace space. By showing that this operator commutes with the two basic reflection operators, we are able to prove that the Maxwell transmission problem is well posed. We also prove well-posedness for a class of oblique Dirac transmission problems with a strongly Lipschitz interface, in the L_2 space on the interface. This is shown by employing the Rellich technique, which gives angular spectral estimates on the rotation operator.
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Bharat, T. V. "Simplified Methods Of Evaluation Of Diffused Double Layer Parameters Employed In Geotechnical Engineering." Thesis, 2004. https://etd.iisc.ac.in/handle/2005/1228.

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Bharat, T. V. "Simplified Methods Of Evaluation Of Diffused Double Layer Parameters Employed In Geotechnical Engineering." Thesis, 2004. http://etd.iisc.ernet.in/handle/2005/1228.

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Tseng, Shu-Chuan, and 曾淑娟. "Modeling and Characteristic Analysis of the Epitaxial Layer Drift Region of High Power Lateral Double Diffused Metal Oxide Semiconductor Transistor." Thesis, 2018. http://ndltd.ncl.edu.tw/handle/5br26g.

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碩士<br>國立勤益科技大學<br>電子工程系<br>106<br>Power semiconductor devices are commonly used in LED bulbs and computer transformers, and are also widely used in industrial equipment, automotive electronic ignition systems, mobile phone battery charging and communication equipment, so power semiconductors are often served as protective switches as the first goalkeeper for electrical appliances, and are also regarded as the main direction of future research in terms of miniature size. This paper mainly studies the thickness reduction of the epitaxial layer, and confirms that the component breakdown voltage range reaches 700 V or more, ensuring the safety of components. This study used the Synopsys TCAD simulation software pro Vided by the National Center for High-performance Computing (NCHC), which was paired with the National Nano Device Laboratories, Process parameters of NDL Semiconductor Manufacturing Machine, as well as machine process parameters that can be produced by academic laboratories. The power semiconductors simulated in this study reaches a static breakdown voltage of 765 V of bulk silicon, and a static breakdown voltage of 805 V of SOI with the silicon substrate of 15 μm thickness. In the discussion of the thickness reduction of the epitaxial layer, the static breakdown voltage of the structure of the SOI epitaxial layer thickness of 3 μm is 751 V, and the dynamic breakdown voltage can reach 704 V under the gate input 5 V. In the future, this power semiconductor component structure will be able to apply this structure to production.
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Sheng-TengHuang and 黃勝騰. "Analysis of Asymmetric Electric Double Layer and Water Lubrication Theory on Pure Squeeze." Thesis, 2019. http://ndltd.ncl.edu.tw/handle/5umd82.

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碩士<br>國立成功大學<br>材料科學及工程學系<br>107<br>Debye Huckel and nonlinear Poisson-Boltzmann solution is classical solution derived by semi-infinite space boundary conditiom. In this research, Our electric double layer model want to deviate from the topic of classic assumption, and developed a numerical solution for electrical double layer with asymmetric boundary condition instead of symmetric boundary condition.   In past study, the electric conductivity in classic Reynold is constant, In our new modified Reynold equation, the electric conductivity varies with temperatue and ionic coconcentration, at the same time, our new modified Reynold equation is derived with asymmetric boundary condition and ionic conservation rule.
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Axelsson, Andreas. "Transmission problems for Dirac's and Maxwell's equations with Lipschitz interfaces." Phd thesis, 2002. http://hdl.handle.net/1885/46056.

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The aim of this thesis is to give a mathematical framework for scattering of electromagnetic waves by rough surfaces. We prove that the Maxwell transmission problem with a weakly Lipschitz interface, in finite energy norms, is well posed in Fredholm sense for real frequencies. Furthermore, we give precise conditions on the material constants ε, μ and σ and the frequency ω when this transmission problem is well posed. To solve the Maxwell transmission problem, we embed Maxwell’s equations in an elliptic Dirac equation. We develop a new boundary integral method to solve the Dirac transmission problem. This method uses a boundary integral operator, the rotation operator, which factorises the double layer potential operator. We prove spectral estimates for this rotation operator in finite energy norms using Hodge decompositions on weakly Lipschitz domains. To ensure that solutions to the Dirac transmission problem indeed solve Maxwell’s equations, we introduce an exterior/interior derivative operator acting in the trace space. By showing that this operator commutes with the two basic reflection operators, we are able to prove that the Maxwell transmission problem is well posed. We also prove well-posedness for a class of oblique Dirac transmission problems with a strongly Lipschitz interface, in the L_2 space on the interface. This is shown by employing the Rellich technique, which gives angular spectral estimates on the rotation operator.
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Books on the topic "Diffused Double Layer Theory"

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Shing, Kuai, and Meng Ji, eds. Electrolysis: Theory, types, and applications. Nova Science Publishers, 2009.

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Masliyah, Jacob H. Electrokinetic and colloid transport phenomena. J. Wiley, 2006.

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Electrokinetic and colloid transport phenomena. Wiley-Interscience, 2006.

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Molecular Theory Electric Double Layer. Institute of Physics Publishing, 2021.

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Masliyah, Jacob H., and Subir Bhattacharjee. Electrokinetic and Colloid Transport Phenomena. Wiley & Sons, Incorporated, John, 2008.

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Masliyah, Jacob H., and Subir Bhattacharjee. Electrokinetic and Colloid Transport Phenomena. Wiley & Sons, Incorporated, John, 2006.

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Pavlovskis, Pēteris. Analysis of Two Actual Problems of Interlaminar Fracture Assessment of Layered Composite. RTU Press, 2022. http://dx.doi.org/10.7250/9789934228148.

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Two types of specimens were studied based on applying the nonlinear theory of flexible plates to obtain the interlaminar fracture toughness of layered composites. For a specimen of the thin sub-layer type, a theoretical solution was obtained in relation to the determination of the interlaminar fracture toughness for a mixed II/I mode. The fundamental possibility of using this solution in test practice was confirmed. The application of the nonlinear theory of flexible plates to the well-known standard specimen of the double-cantilever beam (DCB) was studied in more detail. A theoretical solution was obtained, an iterative algorithm for processing test results based on MATLAB code was developed, highly flexible glass fiber reinforced polymer (GFRP) specimens were tested and their comparison with the results of processing according to the ASTM D 5528-01 standard with correction of the linear solution was given.
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Book chapters on the topic "Diffused Double Layer Theory"

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Sun, Haiquan. "Prediction of Swelling Pressure of Compacted Bentonite with Respect to Void Ratio Based on Diffuse Double Layer Theory." In Sustainable Civil Infrastructures. Springer International Publishing, 2017. http://dx.doi.org/10.1007/978-3-319-61931-6_8.

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Fang, Zhou, and Xu Kuangdi. "Electron Double Layer Theory in Flotation." In The ECPH Encyclopedia of Mining and Metallurgy. Springer Nature Singapore, 2023. http://dx.doi.org/10.1007/978-981-19-0740-1_645-1.

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Mitrea, Dorina, Irina Mitrea, and Marius Mitrea. "Compactness, or Lack Thereof, for the Harmonic Double Layer." In Operator Theory: Advances and Applications. Springer International Publishing, 2021. http://dx.doi.org/10.1007/978-3-030-75425-9_17.

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Ayop, Osman, Mohamad Kamal A. Rahim, Noor Asniza Murad, and Noor Asmawati Samsuri. "Double Layer Polarization Insensitive Metamaterial Absorber with Dual Resonances." In Theory and Applications of Applied Electromagnetics. Springer International Publishing, 2015. http://dx.doi.org/10.1007/978-3-319-17269-9_25.

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Hall, D. G. "Application of Double Layer Theory to Moderately Complex Systems." In The Structure, Dynamics and Equilibrium Properties of Colloidal Systems. Springer Netherlands, 1990. http://dx.doi.org/10.1007/978-94-011-3746-1_55.

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Goodwin, Zachary A. H., J. Pedro de Souza, Martin Z. Bazant, and Alexei A. Kornyshev. "Mean-Field Theory of the Electrical Double Layer in Ionic Liquids." In Encyclopedia of Ionic Liquids. Springer Singapore, 2021. http://dx.doi.org/10.1007/978-981-10-6739-6_62-1.

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Goodwin, Zachary A. H., J. Pedro de Souza, Martin Z. Bazant, and Alexei A. Kornyshev. "Mean-Field Theory of the Electrical Double Layer in Ionic Liquids." In Encyclopedia of Ionic Liquids. Springer Nature Singapore, 2022. http://dx.doi.org/10.1007/978-981-33-4221-7_62.

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Didenko, Victor D., and Anh My Vu. "Spline Galerkin Methods for the Double Layer Potential Equations on Contours with Corners." In Recent Trends in Operator Theory and Partial Differential Equations. Springer International Publishing, 2017. http://dx.doi.org/10.1007/978-3-319-47079-5_7.

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DeSimone, John A., Gerard L. Heck, and Shirley K. DeSimone. "An Empirical Relation for the Surface Potential of Phosphatidic Acid Monolayers: Its Dependence on Calcium and the Role of Double Layer Theory." In Electrical Double Layers in Biology. Springer US, 1986. http://dx.doi.org/10.1007/978-1-4684-8145-7_2.

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Schmickler, Wolfgang. "The double layer in the absence of specific adsorption." In Interfacial Electrochemistry. Oxford University Press, 1996. http://dx.doi.org/10.1093/oso/9780195089325.003.0024.

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One of the fundamental problems in electrochemistry is the distribution of the potential and of the particles at the interface. Here we will expand on the subject of Chapter 3, and consider the interface between a metal and an electrolyte solution in the absence of specific adsorption. Until about 1980 a simple model of this interface prevailed, which was based on a particular interpretation of the interfacial capacity. The metal was assumed to be a perfect conductor in the classical sense, and hence a region of constant potential right up to the metal surface. As was pointed out in Chapter 3, the inverse capacity can be split into two terms, a Gouy-Chapman and a Helmholtz term: l/C = l/CGc + 1/CH. It was argued that these two terms pertain to two different regions in the solution: the space charge or diffuse double layer, which is already familiar to us, and the Stern or outer Helmholtz layer giving rise to the Helmholtz capacity. Since the latter does not depend on the concentration of the ions, the Stern layer was supposed to consist of a monolayer of solvent molecules adsorbed on the metal surface. The plane passing through the centers of these molecules was called the outer Helmholtz plane. Rather elaborate models were developed for the dielectric properties of this layer in order to explain Helmholtz capacity curves such as those shown in Fig. 3.3. This Gouy-Chapman-Stern model, as it was named after its main contributors, is a highly simplified model of the interface, too simple for quantitative purposes. It has been superseded by more realistic models, which account for the electronic structure of the metal, and the existence of an extended boundary layer in the solution. It is, however, still used even in current publications, and therefore every electrochemist should be familiar with it. In the remainder of this chapter we will present elements of modern double-layer theory. Two phases meet at this interface: the metal and the solution. We will consider each phase in turn.
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Conference papers on the topic "Diffused Double Layer Theory"

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Wei, Shijun, and Sherif L. Abdelaziz. "Freezing Effects on the Behavior of Diffused Double Layer Using Molecular Dynamics." In Geo-Congress 2023. American Society of Civil Engineers, 2023. http://dx.doi.org/10.1061/9780784484692.024.

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Wei, Shijun, and Sherif L. Abdelaziz. "Temperature Effects on the Thickness of the Diffused Double Layer Using Molecular Dynamics." In Geo-Congress 2022. American Society of Civil Engineers, 2022. http://dx.doi.org/10.1061/9780784484036.063.

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Ribbing, Carl G., Arne Roos, and Mikael Bergkvist. "Modeling diffuse reflectance spectra from noncorrelated roughness of double layers." In OSA Annual Meeting. Optica Publishing Group, 1989. http://dx.doi.org/10.1364/oam.1989.mdd1.

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A model for light scattering spectra from double layers with uncorrelated roughness is discussed. The model is based on Fresnel multilayer calculations with amplitude reflection coefficients reduced according to the scalar scattering theory and uses the normalized electric field intensity to scale the resulting interface scattering.1 It is demonstrated that the effect of uncorrelated roughness at the two interfaces is to change the electric field pattern in a way which enhances the scattering at wavelengths where the specular interference pattern has a minimum and vice versa. The rms roughness values are considered as parameters and have been used to fit the calculated results to experimental spectra. For the particular case of oxidized copper, which exhibits high scattering levels, the parameters thus obtained show good agreement with roughness values obtained by other techniques.2 In particular we emphasize the importance of using spectral variation to extract information from scattering measurements on this kind of system.
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Tong Zhang, Guo-hui Yang, Wan-lu Li, and Qun Wu. "A novel double-layer semi-circle fractal multi-band frequency selective surface." In EM Theory (ISAPE - 2010). IEEE, 2010. http://dx.doi.org/10.1109/isape.2010.5696675.

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Li, Yongqian, Liding Wang, and Zheng Xu. "Deviations of Electroosmotic Fluidic Profile from Electric Double Layer Theory." In 2006 1st IEEE International Conference on Nano/Micro Engineered and Molecular Systems. IEEE, 2006. http://dx.doi.org/10.1109/nems.2006.334653.

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Feng, Deng, Zheng Shenquan, Wang Dongdong, and Dingfan. "A double-layer miniaturized dual band frequency selective surface." In 2016 11th International Symposium on Antennas, Propagation and EM Theory (ISAPE). IEEE, 2016. http://dx.doi.org/10.1109/isape.2016.7834070.

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Gongadze, Ekaterina, Ales Iglic, Sabine Petersen, and Ursula van Rienen. "An electrical double layer model with spatial variation of the permittivity." In 2010 URSI International Symposium on Electromagnetic Theory (EMTS 2010). IEEE, 2010. http://dx.doi.org/10.1109/ursi-emts.2010.5637185.

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Zhao, Liwei, Fujun Liu, Shuai Kong, Zhangwei Ling, and Liqin Wang. "Study on Leakage Diffusion and Force Analysis of Double-Layer Structure of Oil Storage Tank." In ASME 2013 Pressure Vessels and Piping Conference. American Society of Mechanical Engineers, 2013. http://dx.doi.org/10.1115/pvp2013-97842.

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Given the limitation of existing inspection technology and the severity of corrosion in tank floor, a double-layer structure of oil storage tank was proposed in this paper. It was verified that the reliability of the calculated values based on the comparison between stress test values and calculated ones. Then, the numerical simulation method was put forward to research the stress distribution and deformation of tank floor under six different support schemes. Generally considering the strength and the stiffness of tank floor, the weight of the support structure and the ease of manufacture, an optimizing design of the support structure was adopted. Furtherly, the influencing rule of leak positions and volume of leak (Q) on the leakage diffusion was studied by using 93# gasoline. The results show that for the same amount of leakage, the leakage on the center of tank floor diffused quickly, was the most easily detected part, and the edge of the tank floor was the most difficult to be detected. For leakage occurred in same position, the volume fraction (φ) in pipeline increased with the increase of leakage.
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Yu, Da-peng, Hang Song, and Ying-gang Liu. "Estimate of shielding efficiency for double layer enclosure with apertures array." In 2008 8th International Symposium on Antennas, Propagation and EM Theory. IEEE, 2008. http://dx.doi.org/10.1109/isape.2008.4735244.

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Tian, Dou, Ran Xu, Zhuo Xu, Anxue Zhang, and Hongyu Shi. "Multiband plasmonic filter based on double layer spoof surface plasmon polaritons." In 2016 11th International Symposium on Antennas, Propagation and EM Theory (ISAPE). IEEE, 2016. http://dx.doi.org/10.1109/isape.2016.7834115.

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Reports on the topic "Diffused Double Layer Theory"

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Bhuiyan, L. B., and C. W. Outhwaite. Modified Poisson-Boltzmann Equation in the Electric Double Layer Theory for an Electrolyte with Size Asymmetric Ions. Defense Technical Information Center, 1988. http://dx.doi.org/10.21236/ada201410.

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