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Dissertations / Theses on the topic 'Diimides'

Author: Grafiati

Published: 4 June 2021

Last updated: 27 July 2025

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1

Quinn, Samuel. "Colouring naphthalene diimides." Thesis, University of Nottingham, 2018. http://eprints.nottingham.ac.uk/50038/.

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Naphthalene diimides have been explored in a wide variety of ways; They are a promising candidate for organic electronics, boasting the ability to form n-type semiconductor materials, the stability of their anions further aiding in this regard. Their electron poor aromatic core can be used in host guest chemistry to generate interlocked species. The ability to tune their electronic properties and how this could be manipulated to create photovoltaic devices is primarily focus of this thesis. A series of naphthalene diimides substituted at the core with morpholine moieties have been synthesized

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2

Kim, Michelle B. "The Hydrolysis of Naphthalene Diimides." Digital Archive @ GSU, 2007. http://digitalarchive.gsu.edu/chemistry_theses/7.

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The hydrolyses of naphthalene diimides (NDIs) bearing aliphatic side chains with N-methylpyrrolidinium groups placed two (1) and three (5) atoms from the central core were studied. The Ka values for the first and second hydrolyses for 1 were 2.5 ± 0.2 x 105 M-1 and 2.0 ± 0.1 x 102 M-1, respectively; for 5 they were 1.4 ± 0.1 x 105 M-1 and 44 ± 2 M-1, respectively. NDI 1 hydrolyzed 6.8 times faster than did 5. The rates for the first and second hydrolyses of 1 at 100 mM hydroxide measured by stopped-flow were 17.0 ± 0.2 s-1 and 53.0 ± 0.1 x 10-2 s-1, respectively. NMR showed both the syn and an

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3

Pearce, Nicholas. "Thionation of asymmetric rylene diimides." Thesis, University of Nottingham, 2016. http://eprints.nottingham.ac.uk/36228/.

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Rylene diimides have attracted much attention for use in optoelectronic devices, with excellent absorption and emission profiles, as well as a tendency to form n-type semiconductors. The absorption and emission properties of rylene diimides can be varied through functionalisation at the imide nitrogens and by substitution to the aromatic core but the effects of alterations to the imide oxygen atoms are less well understood. A series of thionated naphthalene diimides (NDIs), in which the imide oxygen atoms have been replaced with sulfur has been synthesised in a single reaction using Lawesson’s

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4

Llewellyn, Ben. "Synthesis and characterisation of functionalised perylene diimides." Thesis, University of Nottingham, 2016. http://eprints.nottingham.ac.uk/35539/.

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This thesis describes the synthesis of three series of perylene diimides (PDIs) by functionalisation at all four possible regions of the molecule. The synthesised compounds were then probed by optical, electrochemical and photophysical methods in order to fully elucidate their properties. Chapter 1 gives an overview of the structure, synthesis, properties and applications of PDIs and introduces the main topics investigated in this thesis. Chapter 2 describes the synthesis of two of the first examples of PDIs with an absorption maximum in the near infrared. This was achieved by functionalisatio

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5

Weitzel, Corey R. "Investigation into water-soluble perylene diimides for thin film formation." Thesis, Manhattan, Kan. : Kansas State University, 2008. http://hdl.handle.net/2097/778.

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6

Leoni, Julien Tissien. "The multifaceted roles of Perylene Diimides in Organic Solar Cells." Thesis, The University of Sydney, 2022. https://hdl.handle.net/2123/29373.

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Owing to their good photophysical properties, perylene diimides (PDI) have been shown to possess great potential in many scientific fields. Here, we demonstrate the multifaceted roles of PDIs in optoelectronic devices, such as when used in solar cells, optical cavities and even both. We use a range of perylene analogues as cathode interlayers in PTQ10:IDIC solar cells and demonstrate > 0.1V increase in Voc. With the help of time-resolved absorbance on devices and numerical drift-diffusion simulations, we show these perylene interlayers promote improved charge extraction, thereby resulting in

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7

Silva, Francisco de Araújo. "Estudo das propriedades eletrônicas e espectroscópicas de uma série de diimidas naftálicas com substituintes aromáticos com potencial aplicação em dispositivos de armazenamento e conversão de energia." Universidade de São Paulo, 2018. http://www.teses.usp.br/teses/disponiveis/59/59138/tde-22062018-212611/.

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As diimidas naftálicas simétricas têm sido vastamente estudadas devido suas propriedades químicas, ópticas, e eletrônicas. A possibilidade de modular suas propriedades com a substituição de grupos diversos na formação da imida, viabiliza aplicações em dispositivos eletrônicos, conversão de energia e produção de redes de coordenação metalo-orgânicas. Neste trabalho sintetizou-se uma série de 5 diimidas naftálicas (NDIs) simétricas com substituintes aromáticos. Foram analisadas as características espectroscópicas e eletrônicas com obtenção dos valores de band-gap óptico através de ensaios de vol

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8

Echue, Geraldine. "Novel functional materials based on perylene diimides using ionic self-assembly." Thesis, University of Bristol, 2012. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.627982.

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A library of materials based on the ionic self-assembly (ISA) of a chiral perylene diimide (POI) with oppositely charged surfactants were prepared and characterised. Three classes of structurally related surfactants were used, so as to establish a set of design rules for the preparation of materials. The self-assembly behaviour of the materials in solution and the solid state was investigated; results and obtained structures were evaluated in terms of the influence of surfactant structure, solvent, concentration and non-covalent interactions. A general methodology was developed to synthesise a

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9

Miller, Chandra Tier. "The design, synthesis and screening of naphthalene diimides with antibacterial activity /." Digital version accessible at:, 1999. http://wwwlib.umi.com/cr/utexas/main.

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10

Ji, Yuyang. "GIANT MOLECULES BASED ON PERYLENE DIIMIDES: SYNTHESIS, CHARACTERIZATION AND SELF-ASSEMBLY BEHAVIORS." University of Akron / OhioLINK, 2017. http://rave.ohiolink.edu/etdc/view?acc_num=akron1491238979529549.

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11

Carrizales, Clarisa Michelle. "Unconventional adsorption of alkane substituted naphthalene diimides on highly ordered pyrolytic graphite." Pullman, Wash. : Washington State University, 2009. http://www.dissertations.wsu.edu/Thesis/Summer2009/c_carrizales_072309.pdf.

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12

Micco, Marialuisa <1980&gt. "Design, synthesis and biological evaluation of substituted naphthalene diimides as anticancer agents." Doctoral thesis, Alma Mater Studiorum - Università di Bologna, 2012. http://amsdottorato.unibo.it/4616/1/micco_marialuisa_tesi.pdf.

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It has been proved that naphthalene diimide (NDI) derivatives display anticancer properties as intercalators and G-quadruplex-binding ligands, leading to DNA damage, senescence and down-regulation of oncogene expression. This thesis deals with the design and synthesis of disubstituted and tetrasubstituted NDI derivatives endowed with anticancer activity, interacting with DNA together with other targets implicated in cancer development. Disubstituted NDI compounds have been designed with the aim to provide potential multitarget directed ligands (MTDLs), in order to create molecules able to si

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13

Micco, Marialuisa <1980&gt. "Design, synthesis and biological evaluation of substituted naphthalene diimides as anticancer agents." Doctoral thesis, Alma Mater Studiorum - Università di Bologna, 2012. http://amsdottorato.unibo.it/4616/.

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It has been proved that naphthalene diimide (NDI) derivatives display anticancer properties as intercalators and G-quadruplex-binding ligands, leading to DNA damage, senescence and down-regulation of oncogene expression. This thesis deals with the design and synthesis of disubstituted and tetrasubstituted NDI derivatives endowed with anticancer activity, interacting with DNA together with other targets implicated in cancer development. Disubstituted NDI compounds have been designed with the aim to provide potential multitarget directed ligands (MTDLs), in order to create molecules able to si

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14

Shokouhi, Mehr Hamideh. "Design and Synthesis of Metallosupramolecular Polymers Containing Core-Substituted Naphthalene Diimides and Bisterpyridines." University of Akron / OhioLINK, 2014. http://rave.ohiolink.edu/etdc/view?acc_num=akron1416480349.

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15

Wonneberger, Henrike [Verfasser]. "Light harvesting and orbital tuning : perylene monoimides and diimides for photovoltaic purposes / Henrike Wonneberger." Mainz : Universitätsbibliothek Mainz, 2014. http://d-nb.info/1060134519/34.

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16

Castaldelli, Evandro. "Polímeros de coordenação à base de cobalto(II) e N,N'-bis(4-piridil)-1,4,5,8-naftaleno diimida como ligante e suas propriedade estruturais, espectroscópicas e fotoelétricas." Universidade de São Paulo, 2016. http://www.teses.usp.br/teses/disponiveis/59/59138/tde-25042016-110820/.

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Polímeros de coordenação têm atraído a atenção de pesquisadores na última década por conta de sua incrível versatilidade e virtualmente infinito número de possibilidades de combinação de ligantes orgânicos e centros metálicos. Estes compostos normalmente herdam as características magnéticas, eletrônicas e espectroscópicas de seus componentes base. Entretanto, apesar do crescente número de trabalhos na área, ainda são raros os polímeros de coordenação que apresentem condutividade elétrica. Para este fim, utilizou-se a N,N\'-bis(4-piridil)-1,4,5,8-naftaleno diimida, ou NDI-py, que pertence a uma

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17

Brandão, Ferreira de Moraes Thaísa. "Photophysical and electrochemical study of organic semiconductor gels." Electronic Thesis or Diss., Lyon, École normale supérieure, 2024. http://www.theses.fr/2024ENSL0060.

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L'objectif de cette thèse était de développer des matériaux stimulables basés sur des molécules électro- et/ou photoactives. Au cours de ce projet, nous avons synthétisé et caractérisé trois molécules π-conjuguées différentes : un silsesquioxane ponté par une unité naphtalène-diimide (NDI-PS), un silsesquioxane ponté par une unité 4,4’-bipyridinium(VG-PS) et un naphtalène-diimide cationique (DaO). Des matériaux hybrides organiques/inorganiques ont été obtenus par polycondensation de trialkoxysilanes pontés avec des groupes organiques incorporant des ponts de type naphtalène-diimide(NDI-PS) et

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18

Marchetti, Chiara <1987&gt. "Design and Synthesis of Naphthalene Diimides Based Small Molecules as Anticancer Agents: Targeting the Polyamine Transporter, G-quadruplex Structures and HDAC." Doctoral thesis, Alma Mater Studiorum - Università di Bologna, 2015. http://amsdottorato.unibo.it/6804/1/Chiara_Marchetti_Tesi.pdf.

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Cancer is a multifactorial disease characterized by a very complex etiology. Basing on its complex nature, a promising therapeutic strategy could be based by the “Multi-Target-Directed Ligand” (MTDL) approach, based on the assumption that a single molecule could hit several targets responsible for the pathology. Several agents acting on DNA are clinically used, but the severe deriving side effects limit their therapeutic application. G-quadruplex structures are DNA secondary structures located in key zones of human genome; targeting quadruplex structures could allow obtaining an anticancer th

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19

Marchetti, Chiara <1987&gt. "Design and Synthesis of Naphthalene Diimides Based Small Molecules as Anticancer Agents: Targeting the Polyamine Transporter, G-quadruplex Structures and HDAC." Doctoral thesis, Alma Mater Studiorum - Università di Bologna, 2015. http://amsdottorato.unibo.it/6804/.

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Cancer is a multifactorial disease characterized by a very complex etiology. Basing on its complex nature, a promising therapeutic strategy could be based by the “Multi-Target-Directed Ligand” (MTDL) approach, based on the assumption that a single molecule could hit several targets responsible for the pathology. Several agents acting on DNA are clinically used, but the severe deriving side effects limit their therapeutic application. G-quadruplex structures are DNA secondary structures located in key zones of human genome; targeting quadruplex structures could allow obtaining an anticancer th

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20

Kolhe, N. B. "Design and synthesis of novel π-conjugated molecules and polymers based on naphthalene and perylene diimides and their application in organic electronics". Thesis(Ph.D.), CSIR-National Chemical Laboratory, Pune, 2015. http://dspace.ncl.res.in:8080/xmlui/handle/20.500.12252/2026.

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21

Jodocy, Cathy [Verfasser], Matthias [Akademischer Betreuer] Wuttig, and Thomas Günter [Akademischer Betreuer] Taubner. "Perylene and its diimides : investigation of the influence of molecular diffusion on the thin film growth / Cathy Jodocy ; Matthias Wuttig, Thomas Günter Taubner." Aachen : Universitätsbibliothek der RWTH Aachen, 2017. http://d-nb.info/1130872238/34.

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22

Phillips, Sarah F. "A Photophysical Characterization on the Unique Properties of Perylene-3,4:9,10-bis((3,4,5(tris(oxtyloxy)benzohydrazide)-dicarboximide." University of Akron / OhioLINK, 2009. http://rave.ohiolink.edu/etdc/view?acc_num=akron1249081748.

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23

Perrin, Lara. "Synthèse et caractérisation de matériaux organiques dérivés du pérylène pour la conversion photovoltai͏̈que." Angers, 2003. http://www.theses.fr/2003ANGE0016.

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La demande croissante d'utilisation des énergies renouvelables suscite une recherche permanente de cellules solaires moins chères et plus efficaces. En raison de leur mise en forme facile et de leur faible coût de production, l'utilisation de matériaux organiques pour la préparation de dispositifs photovoltai͏̈ques dits " plastiques " semble être une alternative à la filière inorganique à base de silicium. La priorité doit concerner la mise au point de semi-conducteurs organiques thermiquement et photochimiquement stables. L'objectif de cette thèse a consisté à développer des nouveaux semi-con

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24

Feist, Florian. "Reading information from sequence-defined macromolecules." Thesis, Queensland University of Technology, 2021. https://eprints.qut.edu.au/208424/1/Florian_Feist_Thesis.pdf.

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Coding and decoding information into and from (bio)macromolecules is of pivotal importance for most processes in nature. A simple readout methodology constitutes a key challenge for data-storage in artificial molecules. The determination of the comonomer-order in synthetic sequence-defined macromolecules, however, requires elaborate analytical techniques. The herein presented work focuses on the synthesis of sequence-defined macromolecules via photochemical ligation reactions, and ultimately the development of a novel fluorescence-based readout of the comonomer-order. The synthesis of rigid mu

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25

Chagas-Silva, Fatima Aparecida das. "Novos materiais funcionais organo-híbridos baseados em óxidos metálicos e diimidas aromáticas." Universidade de São Paulo, 2012. http://www.teses.usp.br/teses/disponiveis/46/46136/tde-10092012-094158/.

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O uso e estudo de materiais híbridos para desenvolver novos materiais com qualidades superiores para aplicações em fotônica, sensores e áreas afins é um desafio para o químico. Neste contexto deve-se especular sobre as propriedades de associação de materiais orgânicos e inorgânicos para alcançar novas e melhores propriedades. Neste estudo, os óxidos metálicos (óxidos de cério em particular), uma classe especial entre nanopartículas inorgânicas, foram selecionados para explorar as suas aplicações com uma classe, também especial de compostos orgânicos, sendo no nosso estudo as Naftaleno Diimidas

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26

Bonasera, Aurelio. "Design and Synthesis of Perylene-Based Supramolecular Hybrids for Novel Technological Applications." Doctoral thesis, Università degli studi di Trieste, 2015. http://hdl.handle.net/10077/11109.

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2013/2014<br>Negli ultimi 50 anni, l’uomo ha attribuito un valore crescente alla ricerca scientifica in quanto strumento di innovazione e di evoluzione tecnologica. La Scienza è diventata uno strumento in grado di migliorare la qualità di vita dell’uomo portando svariate migliorie, ma anche di cambiare radicalmente il suo stile di vita a seguito di scoperte e di strumenti sconosciuti prima di allora. Il progresso tecnologico, la crescita della popolazione mondiale e delle sue esigenze ha causato degli squilibri nel nostro pianeta, dovuti soprattutto and una non omogenea distribuzione delle ris

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27

Boone, Harold Wesley 1969. "Polyaromatic quinone diimines: A novel family of polymers." Diss., The University of Arizona, 1996. http://hdl.handle.net/10150/290592.

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Polyaniline has attracted much interest due to its unusual physical properties. A polycondensation route to polyanilines is a desirable alternative to the currently used non-discriminating oxidative polymerization. The oxidative synthesis does not allow structural diversity in the monomer and the polymer's structure is not well defined. A synthetic route to polyanthraquinone diimines was recently developed in this laboratory. These pernigraniline analogs are similar in structure to the fully oxidized polyaniline and may display electrical conductivity and optoelectronic properties. The aim of

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28

Oram, Stuart John. "Synthetic approaches to improving perylene diimide-based organic electronics." Thesis, Imperial College London, 2013. http://hdl.handle.net/10044/1/33656.

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This thesis deals with the family of small molecules known as perylene diimides, their synthesis, properties, and use in organic electronics. In particular it is focussed on the use of perylene diimides as small molecular organic semiconductors in organic photovoltaics and organic field-effect transistors. Here is reported the synthesis, characterisation, properties and device testing of a range of new perylene diimide materials, designed to have properties amenable to use as acceptors in organic photovoltaics. Also reported is a method for the kinetic resolution of dicyano substituted perylen

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29

Tian, Ding. "Synthesis, Characterization and Thermal Analysis of Tetrahedral and Cyano-substituted Perylene-based Derivatives." University of Akron / OhioLINK, 2014. http://rave.ohiolink.edu/etdc/view?acc_num=akron1407868184.

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30

Everett, Thomas A. "Preparation and characterization of electrostatically selfassembled perylene-diimide/polyelectrolyte composites." Diss., Manhattan, Kan. : Kansas State University, 2010. http://hdl.handle.net/2097/3912.

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31

Slater, Anna Grace. "The synthesis of perylene diimide derivatives for self-assembled structures." Thesis, University of Nottingham, 2011. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.546287.

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32

Swartz, Leoni Destine. "Synthesis and characterization of pyridyl/quinolyl imine ruthenium(II) and palladium (II) complexes in catalysis." Thesis, University of the Western Cape, 2015. http://hdl.handle.net/11394/4932.

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>Magister Scientiae - MSc<br>We report the successful syntheses of a family of tetradentate N-donor pyridyl and quinolyl-imine ligands N1,N2-bis((pyridin-2-yl)methylene)ethane-1,2-diamine (L1), N1,N3- bis(pyridin-2-ylmethylene)propane-1,3-diamine (L2), N1,N4-bis(pyridin-2-ylmethylene) butane-1,4-diamine (L3), N1,N2-bis((quinolin-2-yl)methylene)ethane-1,2-diamine (L4), N1,N3-bis(quinolin-2-ylmethylene)propane-1,3-diamine (L5) and N1,N5-bis(pyridin-2- ylmethylene)pentane-1,5-diamine (L6). All the ligands were fully characterized by FT-IR, 1H and 13C NMR, GC-MS, Elemental analysis, UV-Vis and TGA

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33

羅錦榮 and Kam-wing Kenneth Lo. "Luminescent copper (I) and rhenium (I) diimines, and coinage metal chalcogenides." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 1996. http://hub.hku.hk/bib/B42128468.

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34

Lo, Kam-wing Kenneth. "Luminescent copper (I) and rhenium (I) diimines, and coinage metal chalcogenides." Click to view the E-thesis via HKUTO, 1996. http://sunzi.lib.hku.hk/hkuto/record/B42128468.

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35

Huang, Chun. "Perylene diimide-based materials for organic electronics and optical limiting applications." Diss., Georgia Institute of Technology, 2010. http://hdl.handle.net/1853/42755.

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This thesis described the synthesis and characterization of new perylene diimide (PDI)-based photonic and electronic materials. In the first part of this thesis, PDI-based polynorbornenes, including PDI-grafted homopolymers and block-copolymers (BCPs) were synthesized and characterized as alternative acceptors for fullerenes for organic electronics. It was found that the PDIs on the polymer side-chains affect π-π stacking with the neighboring PDIs, which has implications for the use of these materials for organic field-effect transistors (OFETs) and organic photovoltaic devices (OPVs). It shou

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36

Cohen, Terry Suzanne. "Synthesis and photophysics of 3, 4, 9, 10 perylene tetracarboxylic diimide dendrimers /." Full text (PDF) from UMI/Dissertation Abstracts International, 2000. http://wwwlib.umi.com/cr/utexas/fullcit?p3004240.

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37

Fleming, Sean Robert. "Charge Transfer Properties of the Substituted Perylene Diimide/Transparent Conducting Oxide Interface." Thesis, The University of Arizona, 2013. http://hdl.handle.net/10150/297563.

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The charge collection efficiency at organic semiconductor/transparent conducting oxide (TCO) interfaces is one of the key parameters controlling the overall efficiency of organic photovoltaics (OPVs). Using Cyclic Voltammetry (CV), the electrochemical surface coverage of an organic semiconductor molecule (a substituted perylene diimide, PDI) was evaluated in order to determine an optimal deposition procedure to obtain a monolayer of PDI on the indium-tin oxide (ITO) surface. The electron transfer rate constant of PDI molecules across the PDI/TTO interface was also evaluated using CV.

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38

Lin, Xingwang. "Hydrogenation of unsaturated polymers in latex form." Thesis, University of Waterloo, 2005. http://hdl.handle.net/10012/957.

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Diimide generated from the hydrazine/hydrogen peroxide/catalyst system can be used to hydrogenate unsaturated polymers in latex form. As an economical and environmentally benign alternative to the commercial processes based on hydrogen/transition metal catalysts, this method is of special interest to industry. This thesis provides a detailed description of the diimide hydrogenation process. Reaction kinetics, catalysts and gel formation mechanism have been investigated. <br /> <br /> Four main reactions and a mass transfer process form three parallel processes in this system: diimi

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39

Slageren, Joris van. "Sigma-bond-to-ligand charge transfer transitions and excited states of d6 metal-diimine complexes efficient radical formation and very long-lived excited states /." [S.l. : Amsterdam : s.n.] ; Universiteit van Amsterdam [Host], 2000. http://dare.uva.nl/document/57139.

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40

Lavaud, Lucien. "Des diamino-benzoquinone-diimines aux azacalixphyrines : développement de colorants émergents du proche infrarouge." Thesis, Aix-Marseille, 2018. http://www.theses.fr/2018AIXM0404/document.

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Les colorants organiques du proche infrarouge présentent un intérêt majeur dans différent secteurs technologiques. Les travaux présentés dans cette thèse portent sur le développement de ce type de chromophores à partir d’unités quinones possédant une conjugaison électronique particulière : les 2,5-diamino-1,4-benzoquinone-diimines (DABQDI). De nouvelles DABQDI ont pu être synthétisées et leur utilisation comme ligand a notamment permis d’obtenir des complexes absorbant du domaine visible jusqu’à celui du proche infrarouge. Ces unités DABQDI ont également pu être incorporées au sein de macrocyc

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Lavaud, Lucien. "Des diamino-benzoquinone-diimines aux azacalixphyrines : développement de colorants émergents du proche infrarouge." Electronic Thesis or Diss., Aix-Marseille, 2018. http://www.theses.fr/2018AIXM0404.

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Les colorants organiques du proche infrarouge présentent un intérêt majeur dans différent secteurs technologiques. Les travaux présentés dans cette thèse portent sur le développement de ce type de chromophores à partir d’unités quinones possédant une conjugaison électronique particulière : les 2,5-diamino-1,4-benzoquinone-diimines (DABQDI). De nouvelles DABQDI ont pu être synthétisées et leur utilisation comme ligand a notamment permis d’obtenir des complexes absorbant du domaine visible jusqu’à celui du proche infrarouge. Ces unités DABQDI ont également pu être incorporées au sein de macrocyc

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42

Krebs, Ina [Verfasser], and Carsten [Akademischer Betreuer] Schmuck. "Zwitterion-Perylene diimide-Modules for switchable supramolecular systems / Ina Krebs. Betreuer: Carsten Schmuck." Duisburg, 2016. http://d-nb.info/1081899565/34.

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43

Solak, Sevinç Selen [Verfasser]. "Charge transport in bulk heterojunctions with perylene diimide based acceptors / Selen Solak Sevinç." Mainz : Universitätsbibliothek Mainz, 2017. http://d-nb.info/1126759317/34.

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44

Cuenca, Alonso Francisco. "Synthesis and evaluation of acridone and naphthalene diimide G-quadruplex DNA targeting agents." Thesis, University College London (University of London), 2008. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.497611.

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Yang, Y. "Synthesis of perylene diimide-based nanoparticles as NIR probes for in vivo imaging." Thesis, University of Liverpool, 2017. http://livrepository.liverpool.ac.uk/3019228/.

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Al, Kaabi Khalid (Khalid Abdulaziz). "Transparent-to-dark electrochromic behavior in naphthalene-diimide-based mesoporous MOF-74 analogs." Thesis, Massachusetts Institute of Technology, 2016. http://hdl.handle.net/1721.1/107566.

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Thesis: S.M., Massachusetts Institute of Technology, Department of Chemistry, 2016.<br>Cataloged from PDF version of thesis. Vita.<br>Includes bibliographical references (pages 40-41).<br>The deliberate insertion of redox-active naphthalene diimide ligands in the versatile family of metal-organic frameworks known as MOF-74 (CPO-27) gives rise to a mesoporous electrochromic MOF that can be switched from transparent to dark, a desirable feature in electrochromic devices such as smart windows. Specifically, we report two new materials with the MOF-74 topology that display redox activity stemming

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Perticarari, Sofia. "Low cost aqueous batteries with organic electrode materials for renewable energy storage." Thesis, Nantes, 2018. http://www.theses.fr/2018NANT4025/document.

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La gestion des sources renouvelables est probablement l'un des enjeux majeurs du 21ème siècle. La part croissante de ces ressources intermittentes et fluctuantes telles que les énergies solaires, éoliennes et marines connectées au réseau électrique requiert des systèmes de stockage efficaces pour sécuriser et réguler l'approvisionnement électrique. L'objectif principal de cette thèse est donc la création de batteries aqueuses écologiques et durables à base de matériaux organiques à faible coût. En particulier, ce projet avait pour but d’identifier des stratégies pour synthétiser, comprendre et

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Mazel, Antoine. "Conception de solides hybrides poreux pour la photosynthèse artificielle." Thesis, Nantes, 2018. http://www.theses.fr/2018NANT4079/document.

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Les travaux décris dans cette thèse rapportent la conception de Metal-Organic Frameworks (MOFs) photoactifs et leur immobilisation sur surface dans le but d’obtenir et d’étudier des SurMOFs (Surface anchored Metal-Organic Frameworks) propices aux processus photoinduits dans le cadre de la photosynthèse artificielle. Pour accomplir cela, nous avons synthétisé différents ligands photoactifs et réalisé leur immobilisation sur surface à l’aide de la croissance épitaxiale en phase liquide. Ainsi, différents SurMOFs à base de zinc(II), présentant tous une structure de type SurMOF-2, ont été préparés

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Redmond, Simon Paul. "Linking metal centres with #pi#-conjugated diimido bridges." Thesis, University College London (University of London), 1998. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.393627.

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Hoogervorst, Wilhelmus Johannes. "Isophthalaldimine compounds of palladium, platinum and rhodium." [S.l. : Amsterdam : s.n.] ; Universiteit van Amsterdam [Host], 2003. http://dare.uva.nl/document/69284.

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