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1

Marot, L., R. Schoch, R. Steiner, V. Thommen, D. Mathys, and E. Meyer. "Rhodium and silicon system: II. Rhodium silicide formation." Nanotechnology 21, no. 36 (August 12, 2010): 365707. http://dx.doi.org/10.1088/0957-4484/21/36/365707.

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2

Brunner, Henri. "Enantioselective Rhodium(II) Catalysts." Angewandte Chemie International Edition in English 31, no. 9 (September 1992): 1183–85. http://dx.doi.org/10.1002/anie.199211831.

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3

Brunner, Henri. "Enantioselektive Rhodium(II)-Katalysatoren." Angewandte Chemie 104, no. 9 (September 1992): 1208–10. http://dx.doi.org/10.1002/ange.19921040909.

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4

Bakac, Andreja. "Aqueous rhodium(iii) hydrides and mononuclear rhodium(ii) complexes." Dalton Transactions, no. 13 (2006): 1589. http://dx.doi.org/10.1039/b518230a.

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5

Zhang, Nan, Di Zhu, David E. Herbert, Nicolaas P. van Leest, Bas de Bruin, and Peter H. M. Budzelaar. "Reactivity of Rhodium(II) amido/Rhodium(I) aminyl complexes." Inorganica Chimica Acta 482 (October 2018): 709–16. http://dx.doi.org/10.1016/j.ica.2018.06.015.

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6

Cooke, Michael W., Garry S. Hanan, Frédérique Loiseau, Sebastiano Campagna, Masashi Watanabe, and Yasutaka Tanaka. "The Structural and Functional Roles of Rhodium(II)-Rhodium(II) Dimers in Multinuclear Ruthenium(II) Complexes." Angewandte Chemie International Edition 44, no. 31 (August 5, 2005): 4881–84. http://dx.doi.org/10.1002/anie.200500392.

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7

Cooke, Michael W., Garry S. Hanan, Frédérique Loiseau, Sebastiano Campagna, Masashi Watanabe, and Yasutaka Tanaka. "The Structural and Functional Roles of Rhodium(II)-Rhodium(II) Dimers in Multinuclear Ruthenium(II) Complexes." Angewandte Chemie 117, no. 31 (August 5, 2005): 4959–62. http://dx.doi.org/10.1002/ange.200500392.

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8

Leroy, G., G. Louterman-Leloup, and P. Ruelle. "Contribution à l'étude theorique de la liaison hydrogène II. Les dimères de l'acide sulfhydrique." Bulletin des Sociétés Chimiques Belges 85, no. 4 (September 1, 2010): 219–27. http://dx.doi.org/10.1002/bscb.19760850406.

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9

Leroy, G., G. Louterman-Leloup, and P. Ruelle. "Contribution à l'étude theorique de la liaison hydrogène II. Les dimères de l'acide sulfhydrique." Bulletin des Sociétés Chimiques Belges 85, no. 4 (September 1, 2010): 229–41. http://dx.doi.org/10.1002/bscb.19760850407.

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10

Bakac, Andreja, and Leonard M. Thomas. "Macrocyclic Rhodium(III) Hydrides and a Monomeric Rhodium(II) Complex." Inorganic Chemistry 35, no. 20 (January 1996): 5880–84. http://dx.doi.org/10.1021/ic960300a.

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11

Choi, Kwong Shing, Tsz Ho Lai, Siu Yin Lee, and Kin Shing Chan. "Reduction of Rhodium(III) Porphyrin Hydroxide to Rhodium(II) Porphyrin." Organometallics 30, no. 10 (May 23, 2011): 2633–35. http://dx.doi.org/10.1021/om200075f.

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12

Sharp, Paul R., David W. Hoard, and Charles L. Barnes. "Rhodium(II) complex with a highly reactive rhodium-rhodium bond: insertion of dioxygen and nitrosobenzene." Journal of the American Chemical Society 112, no. 5 (February 1990): 2024–26. http://dx.doi.org/10.1021/ja00161a071.

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13

Zuber, Marek. "New rhodium(II)-rhodium(III) dinuclear complexes with 2-aminopyridine bridges." Transition Metal Chemistry 11, no. 1 (January 1986): 5–8. http://dx.doi.org/10.1007/bf01064491.

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14

DeWit, David G. "Reactivity of mononuclear rhodium(II) compounds." Coordination Chemistry Reviews 147 (January 1996): 209–46. http://dx.doi.org/10.1016/0010-8545(94)01127-3.

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15

Münz, Xaver, and Michael Hanack. "(Phthalocyaninato)rhodium(II)-Addukte mit Stickstoffbasen." Chemische Berichte 121, no. 2 (February 1988): 235–38. http://dx.doi.org/10.1002/cber.19881210207.

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16

BRUNNER, H. "ChemInform Abstract: Enantioselective Rhodium(II) Catalysts." ChemInform 23, no. 51 (December 22, 1992): no. http://dx.doi.org/10.1002/chin.199251340.

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17

Fussell, Eric D., and Ampofo Darko. "Adducts of Rhodium(II) Acetate and Rhodium(II) Pivalate with 1,8-Diazabicyclo[5.4.0]undec-7-ene." Crystals 11, no. 5 (May 7, 2021): 517. http://dx.doi.org/10.3390/cryst11050517.

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In this article, we describe the synthesis of 1,8-diazabicyclo[5.4.0]undec-7-ene (DBU) adducts of rhodium(II) carboxylate complexes, [Rh2(μ-O2CCR3)4(DBU)2] (R = H (1), Me (2)). The DBU ligand is coordinated to the axial site in both adducts via the imido-nitrogen atom, and single-crystal X-ray diffraction analysis of 1 and 2 revealed structurally similar attributes between the compounds. The Rh–Rh bond distance is 2.4108(3) Å for 1 and 2.4143(2) Å for 2. The Rh–N distance is 2.2681(3) Å for compound 1 and 2.2587(10) Å for compound 2. Compound 1, however, crystallized with solvent molecules in its unit cell, and Hirshfeld surface analysis showed intermolecular C–H···O interactions between oxygen atoms of [Rh2(μ-O2CCH3)4] and the hydrogen of the chloroform solvent among other intermolecular close-contact interactions. The crystal structure of compound 2 was found to be devoid of solvent and showed weak intramolecular C–H···O interactions from the DBU axial ligand to the oxygens of the bridging acetates. Otherwise, Hirshfeld analysis showed that 2 was dominated by H···H interactions. UV-vis spectroscopy of both adducts was also conducted in different solvents to examine shifts attributed to the π*(Rh2) to σ*(Rh2) band.
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18

Aullon, Gabriel, and Santiago Alvarez. "Pyramidality effect on rhodium(II)-Rh(II) single bonds." Inorganic Chemistry 32, no. 17 (August 1993): 3712–19. http://dx.doi.org/10.1021/ic00069a028.

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19

Gerisch, Michael, Jennifer R. Krumper, Robert G. Bergman, and T. Don Tilley. "Rhodium(III) and Rhodium(II) Complexes of Novel Bis(oxazoline) Pincer Ligands." Organometallics 22, no. 1 (January 2003): 47–58. http://dx.doi.org/10.1021/om0207562.

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20

Moszner, Monika, Michal Wilgocki, and Jozef J. Ziolkowski. "Polarographic Studies of Dimeric and Monomeric Rhodium(II) and Rhodium(III) Complexes." Journal of Coordination Chemistry 20, no. 3 (September 1989): 219–27. http://dx.doi.org/10.1080/00958978909408163.

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21

Lee, Sin, Mario Mediati, and Bradford Wayland. "Octaethylporphyrinato rhodium cation dimer, [(OEP)Rh]2+2: strong dimer bonding resulting from both rhodium(II)–rhodium(II) and interporphyrin cation radical interactions." J. Chem. Soc., Chem. Commun., no. 19 (1994): 2299–300. http://dx.doi.org/10.1039/c39940002299.

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22

Carneiro, Marcella LB, Eloiza S. Nunes, Raphael CA Peixoto, Ricardo GS Oliveira, Luiza HM Lourenço, Izabel CR da Silva, Andreza R. Simioni, et al. "Free Rhodium (II) citrate and rhodium (II) citrate magnetic carriers as potential strategies for breast cancer therapy." Journal of Nanobiotechnology 9, no. 1 (2011): 11. http://dx.doi.org/10.1186/1477-3155-9-11.

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23

Zhu, Di, Arzoo Z. Sharma, Christopher R. Wiebe, and Peter H. M. Budzelaar. "Rhodium(ii) dimers without metal–metal bonds." Dalton Transactions 44, no. 30 (2015): 13460–63. http://dx.doi.org/10.1039/c5dt02218e.

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Oxidation of (MeBDI)Rh(cyclooctene) (MeBDI = [2,6-Me2C6H3NCMe]2CH) with Br2 or I2 produces paramagnetic halide-bridged RhII dimers [(MeBDI)Rh]2(μ-X)2 without a direct Rh–Rh bond.
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24

Murarka, Sandip, Zhi-Jun Jia, Christian Merten, Constantin-G. Daniliuc, Andrey P. Antonchick, and Herbert Waldmann. "Rhodium(II)-Catalyzed Enantioselective Synthesis of Troponoids." Angewandte Chemie 127, no. 26 (May 8, 2015): 7763–66. http://dx.doi.org/10.1002/ange.201502233.

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25

Gainer, Morgan J., Nitasha R. Bennett, Yu Takahashi, and Ryan E. Looper. "Regioselective Rhodium(II)-Catalyzed Hydroaminations of Propargylguanidines." Angewandte Chemie 123, no. 3 (December 9, 2010): 710–13. http://dx.doi.org/10.1002/ange.201006087.

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26

Gainer, Morgan J., Nitasha R. Bennett, Yu Takahashi, and Ryan E. Looper. "Regioselective Rhodium(II)-Catalyzed Hydroaminations of Propargylguanidines." Angewandte Chemie International Edition 50, no. 3 (December 9, 2010): 684–87. http://dx.doi.org/10.1002/anie.201006087.

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27

Murarka, Sandip, Zhi-Jun Jia, Christian Merten, Constantin-G. Daniliuc, Andrey P. Antonchick, and Herbert Waldmann. "Rhodium(II)-Catalyzed Enantioselective Synthesis of Troponoids." Angewandte Chemie International Edition 54, no. 26 (May 8, 2015): 7653–56. http://dx.doi.org/10.1002/anie.201502233.

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28

Pruchnik, F. P. "Structure and reactivity of rhodium(II) complexes." Pure and Applied Chemistry 61, no. 5 (January 1, 1989): 795–804. http://dx.doi.org/10.1351/pac198961050795.

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29

Lacour, J., W. Zeghida, and C. Besnard. "Rhodium(II)-Catalyzed Synthesis of Polyether Macrocyles." Synfacts 2010, no. 12 (November 22, 2010): 1355. http://dx.doi.org/10.1055/s-0030-1258962.

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30

Guptill, David M., Carolyn M. Cohen, and Huw M. L. Davies. "Rhodium(II)-Catalyzed Stereoselective Synthesis of Allylsilanes." Organic Letters 15, no. 24 (November 27, 2013): 6120–23. http://dx.doi.org/10.1021/ol4028978.

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31

Anderson, J. E., C. L. Yao, and K. M. Kadish. "Rhodium-carbon bond formation by an electrochemically generated monomeric rhodium(II) porphyrin species." Inorganic Chemistry 25, no. 6 (March 1986): 718–19. http://dx.doi.org/10.1021/ic00226a003.

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32

Goodman, Dawn C., Joseph H. Reibenspies, Niranjan Goswami, Silvia Jurisson, and Marcetta Y. Darensbourg. "A New Macrocyclic N3S2Ligand and Its Nickel(II), Cobalt(II), Rhodium(III)-103, and Rhodium(III)-105 Complexes." Journal of the American Chemical Society 119, no. 21 (May 1997): 4955–63. http://dx.doi.org/10.1021/ja964187z.

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33

Salem, Hiyam, Linda J. W. Shimon, Gregory Leitus, Lev Weiner, and David Milstein. "B−C Bond Cleavage of BArFAnion Upon Oxidation of Rhodium(I) with AgBArF. Phosphinite Rhodium(I), Rhodium(II), and Rhodium(III) Pincer Complexes." Organometallics 27, no. 10 (May 2008): 2293–99. http://dx.doi.org/10.1021/om800034t.

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34

Matsuzaka, Hiroyuki, Teruo Kamura, Ko Ariga, Yuko Watanabe, Takashi Okubo, Tomohiko Ishii, Masahiro Yamashita, Mitsuru Kondo, and Susumu Kitagawa. "Preparation, Structure, and Reactivities of Amido-Bridged Dinuclear Rhodium(III) and Rhodium(II) Complexes." Organometallics 19, no. 3 (February 2000): 216–18. http://dx.doi.org/10.1021/om990844v.

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35

Drommi, Dario, Carmela Grazia Arena, Francesco Nicoló, Guiseppe Bruno, and Felice Faraone. "Mononuclear(η6-arene)ruthenium(II) and (η5-pentamethllcyclopentadienyl)rhodium(III) and binuclear ruthenium(II)-platimum(II) and ruthenium(II)-rhodium(I) complexes containing 2-(diphenylphosphino)pyridine." Journal of Organometallic Chemistry 485, no. 1-2 (January 1995): 115–21. http://dx.doi.org/10.1016/0022-328x(94)24773-c.

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36

Doyle, Michael P., Surendra N. Mahapatro, Alada C. Caughey, Mitchell S. Chinn, Mark R. Colsman, Nancy K. Harn, and Ann E. Redwine. "Olefin coordination with rhodium(II) perfluoroalkanoates in solution." Inorganic Chemistry 26, no. 18 (September 1987): 3070–72. http://dx.doi.org/10.1021/ic00265a030.

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37

Zyngier, S., L. S. Sudo, M. Cabral, R. M. Colla, and A. F. J. Andrade. "Rhodium(II) citrate: an inflammatory and imunogenic substance." European Journal of Pharmacology 183, no. 3 (July 1990): 882. http://dx.doi.org/10.1016/0014-2999(90)92707-p.

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38

Adams, Julian, and Denice M. Spero. "Rhodium (II) catalyzed reactions of diazo-carbonyl compounds." Tetrahedron 47, no. 10-11 (March 1991): 1765–808. http://dx.doi.org/10.1016/s0040-4020(01)96094-6.

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39

de Souza, A. R., R. Najjar, and J. R. Matos. "Thermal behaviour of some rhodium(II) cycloalkanocarboxylate complexes." Thermochimica Acta 343, no. 1-2 (January 2000): 119–25. http://dx.doi.org/10.1016/s0040-6031(99)00316-0.

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40

Dunbar, Kim R., John H. Matonic, and Vijay P. Saharan. "Polynuclear rhodium(II) compounds with phosphino-phenoxide ligands." Inorganic Chemistry 33, no. 1 (January 1994): 25–31. http://dx.doi.org/10.1021/ic00079a007.

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41

Padwa, Albert. "Rhodium(II) mediated cyclizations of diazo alkynyl ketones." Journal of Organometallic Chemistry 610, no. 1-2 (September 2000): 88–101. http://dx.doi.org/10.1016/s0022-328x(00)00505-2.

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42

Padwa, Albert. "Rhodium(II) mediated cyclizations of diazo alkynyl ketones." Journal of Organometallic Chemistry 617-618 (January 2001): 3–16. http://dx.doi.org/10.1016/s0022-328x(00)00764-6.

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43

Minus, Matthew B., Marci K. Kang, Sarah E. Knudsen, Wei Liu, Michael J. Krueger, Morgen L. Smith, Michele S. Redell, and Zachary T. Ball. "Assessing the intracellular fate of rhodium(ii) complexes." Chemical Communications 52, no. 78 (2016): 11685–88. http://dx.doi.org/10.1039/c6cc05192h.

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44

Chuprakov, Stepan, Brady T. Worrell, Nicklas Selander, Rakesh K. Sit, and Valery V. Fokin. "Stereoselective 1,3-Insertions of Rhodium(II) Azavinyl Carbenes." Journal of the American Chemical Society 136, no. 1 (December 17, 2013): 195–202. http://dx.doi.org/10.1021/ja408185c.

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45

Bień, Małgorzata, Tadeusz M. Lachowicz, Agnieszka Rybka, Florian P. Pruchnik, and Lilianna Trynda. "Binuclear Rhodium(II) Complexes With Selective Antibacterial Activity." Metal-Based Drugs 4, no. 2 (January 1, 1997): 81–88. http://dx.doi.org/10.1155/mbd.1997.81.

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Binuclear rhodium(II) complexes [Rh2Cl2(μ-OOCR)2(N-N)2] {R = H, Me; N-N = 2,2'-bipyridine (bpy), 1,10-phenanthroline (phen)} and [Rh2(μ-OOCR)2(N-N)2(H2O)2](RCOO)2 (R = Me, Et;) have been synthesized and their structure and properties have been studied by electronic, IR and H1 NMR spectroscopy. Antibacterial activity of these complexes against Escherichia coli and Staphylococcus aureus has been investigated. The most active antibacterial agents against E. coli were [Rh2Cl2(μ-OOCR)2(N-N)2] and [Rh2(μ-OOCR)2(N-N)2(H2O)2](RCOO)2 {R = H and Me} which were considerably more active than the appropriate nitrogen ligands. The complexes show low activity against S. aureus. The activity of the complexes [Rh2(OOCR)2(N-N)2(H2O)2](OOCR)2 against E. coli decreases in the series: R=H≅CH3>C2H5>C3H7≅C4H9. The reverse order was found in the case of S. aureus.
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46

Maeda, A., T. Takei, H. Hoshino, and W. Mori. "Syntheses of dinuclear rhodium(II) monocarboxylates with micropores." Transactions of the Materials Research Society of Japan 33, no. 4 (2008): 1351–54. http://dx.doi.org/10.14723/tmrsj.33.1351.

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47

Tuchscherer, André, Rico Packheiser, Tobias Rüffer, Herbert Schletter, Michael Hietschold, and Heinrich Lang. "Rhodium Nanoparticles from Dirhodium(II) Ethylene Glycol Tetracarboxylates." European Journal of Inorganic Chemistry 2012, no. 13 (March 15, 2012): 02251–2258. http://dx.doi.org/10.1002/ejic.201101424.

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48

DEWIT, D. G. "ChemInform Abstract: Reactivity of Mononuclear Rhodium(II) Compounds." ChemInform 27, no. 28 (August 5, 2010): no. http://dx.doi.org/10.1002/chin.199628303.

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49

Hansen, Jørn H., Brendan T. Parr, Philip Pelphrey, Quihui Jin, Jochen Autschbach, and Huw M. L. Davies. "Rhodium(II)-Catalyzed Cross-Coupling of Diazo Compounds." Angewandte Chemie 123, no. 11 (February 14, 2011): 2592–96. http://dx.doi.org/10.1002/ange.201004923.

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50

Hansen, Jørn H., Brendan T. Parr, Philip Pelphrey, Quihui Jin, Jochen Autschbach, and Huw M. L. Davies. "Rhodium(II)-Catalyzed Cross-Coupling of Diazo Compounds." Angewandte Chemie International Edition 50, no. 11 (February 14, 2011): 2544–48. http://dx.doi.org/10.1002/anie.201004923.

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