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Journal articles on the topic 'Dimethyl phosphate anion'

Author: Grafiati

Published: 3 June 2025

Last updated: 31 July 2025

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1

Schwegler, Eric, Giulia Galli, and François Gygi. "Conformational dynamics of the dimethyl phosphate anion in solution." Chemical Physics Letters 342, no. 3-4 (2001): 434–40. http://dx.doi.org/10.1016/s0009-2614(01)00604-2.

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2

S., Brica, Freimane L., Kulikovska L., and Zicmanis A. "N,N'-Dialkylimidazolium Dimethyl Phosphates – Promising Media and Catalysts at the Same Time for Condensation Reactions." Chemical Science International Journal 19, no. 4 (2017): 1–9. https://doi.org/10.9734/CSJI/2017/34482.

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The objective of the current work is the elaboration of an alternative method for synthesis of <em>N,N’</em>-dialkylimidazolium dimethyl phosphates – ionic liquids useful both as media and catalysts for condensation reactions in organic synthesis. The proposed method consists of alkylation of 1-substituted imidazoles with 1-alkyl chlorides in a closed steel cylinder followed by treating of obtained imidazolium chlorides with trimethyl phosphate. Data of qualitative analyses made by <sup>1</sup>H NMR, quantitative analysis made by potentiometric titration, and thermal stability measured by ther

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3

Kamitakahara, Atsushi, Chih-Li Hsu, and Julianto Pranata. "Reexamination of the conformations of dimethyl phosphate anion in water." Journal of Molecular Structure: THEOCHEM 334, no. 1 (1995): 29–35. http://dx.doi.org/10.1016/0166-1280(94)03966-o.

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4

Tarasova, N. P., Y. O. Mezhuev, A. A. Zanin, and E. G. Krivoborodov. "Interaction of ionic liquids with sulfur." Доклады Академии наук 484, no. 2 (2019): 167–71. http://dx.doi.org/10.31857/s0869-56524842167-171.

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The interaction of tri-n-butylmethylphosphonium dimethylphosphate and 1,3-dimethylimidazolium dimethylphosphate with elemental sulfur in a benzene medium has been described. According to13C and17O NMR and high resolution mass spectrometry, the chemical reaction involves only the dimethyl phosphate anion. The reaction mechanism and the reaction product composition have been proposed.

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5

Alagona, Giuliano, Caterina Ghio, and Peter Kollman. "Monte Carlo simulations of the solvation of the dimethyl phosphate anion." Journal of the American Chemical Society 107, no. 8 (1985): 2229–39. http://dx.doi.org/10.1021/ja00294a004.

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6

TERLAND, Ole, and Torgeir FLATMARK. "Anion- and pH-dependent activation of the soluble form of dopamine beta-hydroxylase." Biochemical Journal 369, no. 3 (2003): 675–79. http://dx.doi.org/10.1042/bj20020783.

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The present study presents evidence for the conclusion that the catalytic activity of dopamine β-hydroxylase (DBH; dopamine β-mono-oxygenase, EC 1.14.17.1) is regulated independently by pH and by anions. In the absence of activating anions (i.e. in 50mM Mes buffer) the activity was essentially zero at low pH (5.1—5.3) when assayed with the artificial electron donors ferrocyanide (0.25mM), N,N,N′,N′-tetramethyl-p-phenylenediamine (TMPD, 2mM) or N,N-dimethyl-p-phenylenediamine (1mM) and tyramine (8mM) as the substrate to be hydroxylated. However, in the presence of activating anions (e.g. 0.05—0

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7

Florián, Jan, Vladimír Baumruk, Marek Štrajbl, Lucie Bednárová, and Josef Štěpánek. "IR and Raman Spectra, Conformational Flexibility, and Scaled Quantum Mechanical Force Fields of Sodium Dimethyl Phosphate and Dimethyl Phosphate Anion†." Journal of Physical Chemistry 100, no. 5 (1996): 1559–68. http://dx.doi.org/10.1021/jp9520299.

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8

Palmer, S., P. T. Hawkins, R. H. Michell, and C. J. Kirk. "The labelling of polyphosphoinositides with [32P]Pi and the accumulation of inositol phosphates in vasopressin-stimulated hepatocytes." Biochemical Journal 238, no. 2 (1986): 491–99. http://dx.doi.org/10.1042/bj2380491.

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When hepatocytes were incubated with [32P]Pi, the kinetics for the labelling of the monoester phosphate groups of phosphatidylinositol 4-phosphate and phosphatidylinositol 4,5-bisphosphate were similar to each other and slightly slower than that for the labelling of the gamma-phosphate of ATP. Analysis of the water-soluble 3H-labelled materials derived from [3H]inositol-labelled hepatocytes revealed that, in addition to inositol and its mono-, bis- and tris-phosphates (Ins, InsP, InsP2 and InsP3), these cells contained two unidentified radioactive compounds which co-eluted with InsP on anion-e

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9

Jayaram, B., M. Mezei, and David L. Beveridge. "Conformational stability of dimethyl phosphate anion in water: liquid-state free energy simulations." Journal of the American Chemical Society 110, no. 6 (1988): 1691–94. http://dx.doi.org/10.1021/ja00214a005.

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10

Petrov, Anton S., Joni Funseth-Smotzer, and George R. Pack. "Computational study of dimethyl phosphate anion and its complexes with water, magnesium, and calcium." International Journal of Quantum Chemistry 102, no. 5 (2005): 645–55. http://dx.doi.org/10.1002/qua.20442.

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11

Zicmanis, Andris, and S. Zeltkalne. "Ionic liquids with Dimethyl Phosphate Anion as Highly Efficient Materials for Technological Processes: A Review." International Journal of Petrochemistry and Research 2, no. 1 (2018): 116–25. http://dx.doi.org/10.18689/ijpr-1000121.

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12

Kuo, I−Feng, and Douglas J. Tobias. "Electronic Polarization and Hydration of the Dimethyl phosphate Anion: An ab Initio Molecular Dynamics Study." Journal of Physical Chemistry B 105, no. 24 (2001): 5827–32. http://dx.doi.org/10.1021/jp003900a.

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13

Javed, Fatima, Faheem Ullah, and Hazizan Md Akil. "Synthesis, characterization and cellulose dissolution capabilities of ammonium-based room temperature ionic liquids (RTILs)." Pure and Applied Chemistry 90, no. 6 (2018): 1019–34. http://dx.doi.org/10.1515/pac-2017-0315.

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Abstract Green synthesis of room temperature ionic liquids (RTILs), are presented as friendly and challenging solvents for the effective dissolution of oil palm-lignocellulosic biomass. A series of Bronsted acidic-ionic liquids were prepared by the direct neutralization of diethyl dimethyl ammonium hydroxide with several (economical and environmental friendly) Bronsted acids as RTILs. The structural and physicochemical characterization was performed by applying various techniques as Fourier transform infrared (FT-IR), nuclear magnetic resonance (NMR), thermo gravimetric analysis (TGA), differe

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14

Wang, Fang-Fang, Dong-Xia Zhao, and Li-Dong Gong. "Ab initio and ABEEM/MM fluctuating charge model studies of dimethyl phosphate anion in a microhydrated environment." Theoretical Chemistry Accounts 124, no. 1-2 (2009): 139–50. http://dx.doi.org/10.1007/s00214-009-0592-2.

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15

Trigub, A. G., M. V. Medyankina, T. V. Drozdenko, and T. P. Khayrulina. "THE EFFECT OF CERTAIN POLLUTANTS ON NECTOBENTHIC CRUSTACEANS." Водные биоресурсы и среда обитания 7, no. 1 (2024): 18–26. http://dx.doi.org/10.47921/2619-1024_2024_7_1_18.

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Background. Ingress of pollutants in water bodies, both direct and from the catchment area, is constantly increasing. It creates an escalating threat to aquatic ecosystems and humans as consumers of water and aquatic biological resources, which contributes to the relevance of the monitoring and regulation of water pollution. This work is aimed at the evaluation of the effect of various toxic substances and pollutants on the survival of the amphipod Hyalella azteca in a chronic experiment. Methods. This study has been carried out according to the standard toxicological methods. Results. This pa

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16

Pichierri, Fabio, and Akinori Sarai. "Properties of phosphorothioate DNA analogs. An ab initio study of prototype model linkages derived from dimethyl-phosphate anion." Journal of Molecular Structure: THEOCHEM 460, no. 1-3 (1999): 103–16. http://dx.doi.org/10.1016/s0166-1280(98)00309-1.

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17

Mokrushin, Ivan G., Maxim A. Kozin, Ekaterina A. Kurunova, and Marina P. Krasnovskih. "Benzalkonium fluorophosphates: synthesis, thermal and anticorrosive properties." Вестник Пермского университета. Серия «Химия» = Bulletin of Perm University. CHEMISTRY 14, no. 4 (2024): 161–71. https://doi.org/10.17072/2223-1838-2024-4-161-171.

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The use of ionic liquids containing fluorine for corrosion protection is a promising direction for protecting metals and steel from chemical and biological corrosion. The paper studies the method for the synthesis and properties of benzalkonium fluorophosphates, the production technologies of which were developed at JSC "R&D Center "Applied Chemistry (GIPH)". The production of ionic compounds containing the alkyl dimethyl benzyl ammonium cation (BA, ABDA), and the fluorophosphorus anion is based on the metathesis reaction with the corresponding acid. It was found that the obtained hexafluo

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18

AL-Hamdani, Nasser, Paula V. Saravia, Javier Luque Di Salvo, Sergio A. Paz, and Giorgio De Luca. "Unravelling Lithium Interactions in Non-Flammable Gel Polymer Electrolytes: A Density Functional Theory and Molecular Dynamics Study." Batteries 11, no. 1 (2025): 27. https://doi.org/10.3390/batteries11010027.

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Lithium metal batteries (LiMBs) have emerged as extremely viable options for next-generation energy storage owing to their elevated energy density and improved theoretical specific capacity relative to traditional lithium batteries. However, safety concerns, such as the flammability of organic liquid electrolytes, have limited their extensive application. In the present study, we utilize molecular dynamics and Density Functional Theory based simulations to investigate the Li interactions in gel polymer electrolytes (GPEs), composed of a 3D cross-linked polymer matrix combined with two differen

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19

Langlet, J., P. Claverie, B. Pullman, and D. Piazzola. "Studies of solvent effects. IV. Study of hydration of the dimethyl phosphate anion (DMP−) and of the solvent effect upon its conformation." International Journal of Quantum Chemistry 16, S6 (2009): 409–37. http://dx.doi.org/10.1002/qua.560160728.

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20

Jayaram, B., G. Ravishanker, and D. L. Beveridge. "Conformational preferences of phosphodiester torsion angles in dimethyl phosphate anion in free space and water: quasi-harmonic Monte Carlo and hydration shell calculations." Journal of Physical Chemistry 92, no. 5 (1988): 1032–34. http://dx.doi.org/10.1021/j100316a009.

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21

Enrique, Sánchez-León, Amils Ricardo, and Abrusci Concepción. "Antioxidant and Emulsifying Activity of the Exopolymer Produced by Bacillus licheniformis." International Journal of Molecular Sciences 25, no. 15 (2024): 8249. http://dx.doi.org/10.3390/ijms25158249.

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The exopolymer (ESPp) was obtained from Bacillus licheniformis IDN-EC, composed of a polyglutamic acid and polyglycerol phosphate chain O-substituted with αGal moieties (αGal/αGlcNH2 3:1 molar ratio) and with a 5000 Da molecular weight. The cytotoxicity activity of EPSp was determined by reducing the MTT (3-[4,5-dimethyl-thiazol-2-yl]-2,5-diphenyltetrazolium bromide) to formazan on HeLa cells. This EPS did not show cytotoxicity against the tested cell line. The ESPp presented great advantages as an antioxidant with free radical scavenging activities (1,1-diphenyl-2-picryl-hydrazyl radical (DPP

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22

Rafizadeh, Masoud, Hamid Reza Saadati Moshtaghin та Vahid Amani. "Tris(ethylenediamine-κ2N,N′)nickel(II) bis(dimethyl phosphate)". Acta Crystallographica Section E Structure Reports Online 68, № 8 (2012): m1032. http://dx.doi.org/10.1107/s1600536812029984.

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In the title compound, [Ni(C2H8N2)3][O2P(OCH3)2]2, the NiIIatom is six-coordinated in a distorted octahedral geometry by six N atoms from three ethylenediamine ligands. The P atoms of the anions adopt a distorted tetrahedral geometry. In the crystal, intermolecular N—H...O and C—H...O hydrogen bonds link the cations and anions into a three-dimensional network.

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23

Moroz, Olesia V., Viktor A. Trush, Tatiana Yu Sliva, Kateryna O. Znovjyak та Vladimir M. Amirkhanov. "{Dimethyl [(phenylsulfonyl)amido]phosphato-κ2O,O′}bis(triphenylphosphane-κP)copper(I)". Acta Crystallographica Section E Structure Reports Online 70, № 6 (2014): m209—m210. http://dx.doi.org/10.1107/s1600536814010095.

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In the title complex, [Cu(C8H11NO5PS)(C18H15P)2], the CuIion is coordinated by two triphenylphosphane molecules and two O atoms of the chelating dimethyl(phenylsulfonyl)amidophosphate anion, generating a squashed CuO2P2tetrahedron. In the six-membered chelate ring, the Cu, P and O atoms are almost coplanar (r.m.s. deviation = 0.024 Å), with the N and S atoms displaced in the same direction, by 0.708 (5) and 0.429 (2) Å, respectively.

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24

Liang, Congxin, Carl S. Ewig, Terry R. Stouch, and Arnold T. Hagler. "Ab initio studies of lipid model species. 1. Dimethyl phosphate and methyl propyl phosphate anions." Journal of the American Chemical Society 115, no. 4 (1993): 1537–45. http://dx.doi.org/10.1021/ja00057a046.

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25

Russell, Glen A., Jong Uk Rhee, and Woonphil Baik. "Reactions ofp-nitrobenzyl halides with dialkyl phosphite anions in dimethyl sulfoxide." Heteroatom Chemistry 9, no. 2 (1998): 201–8. http://dx.doi.org/10.1002/(sici)1098-1071(1998)9:2<201::aid-hc16>3.0.co;2-v.

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26

Marin, P., M. Maus, J. Bockaert, J. Glowinski, and J. Prémont. "Oxygen free radicals enhance the nitric oxide-induced covalent NAD+-linkage to neuronal glyceraldehyde-3-phosphate dehydrogenase." Biochemical Journal 309, no. 3 (1995): 891–98. http://dx.doi.org/10.1042/bj3090891.

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Nitric oxide (NO) induces a covalent modification of glyceraldehyde-3-phosphate dehydrogenase (GAPDH) from various tissues. This phenomenon, which has previously been interpreted as an auto-ADP-ribosylation, is in fact a covalent binding of NAD+ to the enzyme. In the present study, we show that 3-morpholino-sydnonimine (SIN-1) is much more efficient than sodium nitroprusside (SNP) in stimulating the covalent labelling of GAPDH from cultured striatal neurones in the presence of [adenylate-32P]NAD+ (877 +/- 110 and 266 +/- 33% increase in NAD(+)-labelling induced by maximally effective concentra

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27

Urban, Jiří, David Havlíček, and Josef Krajbich. "Preparation of quaternary pyridinium salts as possible proton conductors." Chemical Papers 69, no. 3 (2015). http://dx.doi.org/10.1515/chempap-2015-0037.

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AbstractOn basis of earlier experimental experience, the transfer of protons in salts of the organic cation-inorganic anion type occurs primarily through directional arrangement of the anion-anion type short hydrogen bonds. The submitted work presents the preparation of quaternary pyridinium salts of inorganic hydrogen anions in the absence of solvent molecules in their crystal structure. These substances can form only the above-described anion-anion type hydrogen bonds; in addition, the absence of solvate anions increases the stability of the prepared compounds. A total of six substituted pyr

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28

Struhatska, Mariia B., Vladimir A. Ovchynnikov, Nataliia S. Kariaka, Paula Gawryszewska, and Volodymyr M. Amirkhanov. "Crystal structure of tetraphenyl phosphate tetrakis[dimethyl (2,2,2-trichloroacetyl)phosphoramidato]lutetium(III), PPh₄[LuL ₄]." Acta Crystallographica Section E Crystallographic Communications 80, no. 4 (2024). http://dx.doi.org/10.1107/s205698902400210x.

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A lutetium(III) complex based on the anion of the ligand dimethyl (2,2,2-trichloroacetyl)phosphoramidate (HL) and tetraphenylphosphonium, of composition PPh4[LuL 4] (L = CAPh = carbacylamidophosphate), or (C24H20)[Lu(C4H6Cl3NO4P)4], has been synthesized and structurally characterized. The X-ray diffraction study of the compound revealed that the lutetium ion is surrounded by four bis-chelating CAPh ligands, forming the complex anion [LuL 4]− with a coordination number of 8[O] for LuIII, while PPh4 + serves as a counter-ion. The coordination geometry around the Lu3+ ion was determined to be a n

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29

ALAGONA, G., C. GHIO, and P. A. KOLLMAN. "ChemInform Abstract: MONTE CARLO SIMULATIONS OF THE SOLVATION OF THE DIMETHYL PHOSPHATE ANION." Chemischer Informationsdienst 16, no. 34 (1985). http://dx.doi.org/10.1002/chin.198534085.

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30

Gao, Yuanhang, Gang Wu, Wenqiang Fang, et al. "Transesterification Induced Multifunctional Additives Enable High‐Performance Lithium Metal Batteries." Angewandte Chemie, March 10, 2024. http://dx.doi.org/10.1002/ange.202403668.

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The electrolyte chemistry is crucially important for promoting the practical application of lithium metal batteries (LMBs). Here, we demonstrate for the first time that 1,3‐dimethylimidazolium dimethyl phosphate (DIDP) and trimethylsilyl trifluoroacetate (TMSF) can undergo in situ transesterification in carbonate electrolyte to generate dimethyl trimethylsilyl phosphate (DTMSP) and 1,3‐dimethylimidazolium trifluoroacetate (DITFA) as multifunctional additives for LMBs. H2O and HF can be removed by the Si−O group in DTMSP to improve the moisture resistance of electrolyte and the stability of cat

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31

Gao, Yuanhang, Gang Wu, Wenqiang Fang, et al. "Transesterification Induced Multifunctional Additives Enable High‐Performance Lithium Metal Batteries." Angewandte Chemie International Edition, March 10, 2024. http://dx.doi.org/10.1002/anie.202403668.

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The electrolyte chemistry is crucially important for promoting the practical application of lithium metal batteries (LMBs). Here, we demonstrate for the first time that 1,3‐dimethylimidazolium dimethyl phosphate (DIDP) and trimethylsilyl trifluoroacetate (TMSF) can undergo in situ transesterification in carbonate electrolyte to generate dimethyl trimethylsilyl phosphate (DTMSP) and 1,3‐dimethylimidazolium trifluoroacetate (DITFA) as multifunctional additives for LMBs. H2O and HF can be removed by the Si−O group in DTMSP to improve the moisture resistance of electrolyte and the stability of cat

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32

Singh, Surajit, Ananda Shit, Milan Gumtya, and Debasish Haldar. "A Synthetic Tetra‐Amide Macrocycle for Anion Recognition at Molecular Level." ChemistrySelect 9, no. 33 (2024). http://dx.doi.org/10.1002/slct.202401969.

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AbstractAn engineered tetra‐amide macrocycle is presented, and its conformation and anion recognition properties are investigated. The tetra‐amide macrocycle 1, containing the m‐amino benzoic acid, 1,3‐benzenedicarboxylic acid and m‐xylenedinediamine adopts an envelope‐like conformation in solid‐state, where the m‐xylenedinediamine ring is perpendicular with the molecular plain. The tetra‐amide macrocycle 1 is able to bind anions such as halides, sulphate and phosphate in DMSO (dimethyl sulphoxide) solution. The stabilities of the fluoride (2.6×103 M−1) and chloride (5.6×102 M−1) complexes of

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33

JAYARAM, B., M. MEZEI, and D. L. BEVERIDGE. "ChemInform Abstract: Conformational Stability of Dimethyl Phosphate Anion in Water: Liquid-State Free Energy Simulations." ChemInform 19, no. 28 (1988). http://dx.doi.org/10.1002/chin.198828046.

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34

Xu, Yanqi, Andrei Filippov, Manishkumar Shimpi, Faiz Ullah Shah, and Patrik Johansson. "Fluorine‐Free Bis(glycolato)borate Anion‐Based Salts and Electrolytes: Structures, Properties, and Lithium Compatibility." Batteries & Supercaps, November 19, 2024. http://dx.doi.org/10.1002/batt.202400672.

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A number of bis(glycolato)borate (BGB) anion‐based salts, comprising Li+, Na+, K+, Mg2+ and Ca2+ cations, has been synthesized and characterized. Fluorine‐free electrolytes based on LiBGB and organic solvents, such as dimethyl sulfoxide (DMSO), triethyl phosphate (TEP), and trimethyl phosphate (TMP) have been created and their transport properties, thermal and electrochemical stabilities, and lithium compatibility examined. The ionic conductivities of the 1 M LiBGB‐TEP and 1 M LiBGB‐TMP electrolytes are ca. 2‐3 times lower than for the 1 M LiBGB‐DMSO electrolytes (2.05, 2.65 vs. 5.70 mS cm‐1 a

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35

Meyer, Marco, Lorenzo Mardegan, Daniel Tordera, et al. "A counterion study of a series of [Cu(P^P)(N^N)][A] compounds with bis(phosphane) and 6-methyl and 6,6'-dimethyl-substituted 2,2'-bipyridine ligands for light-emitting electrochemical cells." November 2, 2021. https://doi.org/10.1039/d1dt03239a.

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The syntheses and characterisations of a series of heteroleptic copper(I) compounds [Cu(POP)(Mebpy)][A], [Cu(POP)(Me2bpy)][A], [Cu(xantphos)(Mebpy)][A] and [Cu(xantphos)(Me2bpy)][A] in which [A]− is [BF4]−, [PF6]−, [BPh4]− and [BArF 4]− (Mebpy = 6-methyl-2,2’-bipyridine, Me2bpy = 6,6’-dimethyl-2,2’-bipyridine, POP = oxydi(2,1-phenylene)bis(diphenylphosphane), xantphos = (9,9-dimethyl-9H-xanthene-4,5-diyl)bis (diphenylphosphane), [BArF 4]− = tetrakis(3,5-bis(trifluoromethyl)phenyl)borate) are reported. Nine of the compounds have been charact

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36

DANIKIEWICZ, W., and M. MAKOSZA. "ChemInform Abstract: Reactions of Organic Anions. Part 141. An Unusual Reaction of 4-Methoxy-1-nitronaphthalene and 4-Amino-1-nitronaphthalene with Dimethyl Phosphite Under Basic Conditions." ChemInform 18, no. 39 (1987). http://dx.doi.org/10.1002/chin.198739208.

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37

Upmann, Daniel, and Peter G. Jones. "Crystal structures of six complexes of phosphane chalcogenides R ¹ R ² R ³PE (R = tert-butyl or isopropyl, E = S or Se) with the metal halides MX ₂ (M = Pd or Pt, X = Cl or Br), two halochalcogenylphosphonium derivatives (^tBu₂ ⁱPrPEBr)₂[Pd₂Br₆] and one hydrolysis product." Acta Crystallographica Section E Crystallographic Communications 81, no. 3 (2025). https://doi.org/10.1107/s2056989025000805.

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The L 2 MX 2 complexes 1–5 (1: L = t BuiPr2PSe, M = Pd, X = Cl; 2: L = t Bu2 iPrPSe, M = Pd, X = Cl; 3: L = t Bu2 iPrPSe, M = Pd, X = Br; 4: L = t Bu2 iPrPS, M = Pd, X = Br; 5: L = t Bu2 iPrPS, M = Pt, X = Cl) {systematic names: (tert-butyldiisopropylphosphine selenide-κSe)dichloridopalladium(II), [PdCl2(C10H23PSe)2] (1), (di-tert-butylisopropylphosphine selenide-κSe)dichloridopalladium(II), [PdCl2(C11H25PSe)2] (2), dibromido(di-tert-butylisopropylphosphine selenide-κSe)palladium(II), [PdBr2(C11H25PSe)2] (3), dibromido(di-tert-butylisopropylphosphine sulfide-κS)palladium(II), [PdBr2(C11H25PS)2

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