Academic literature on the topic 'Dinuclear metal'

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Journal articles on the topic "Dinuclear metal"

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van der Eide, Edwin F., Ping Yang, Eric D. Walter, Tianbiao Liu, and R. Morris Bullock. "Dinuclear Metalloradicals Featuring Unsupported Metal-Metal Bonds." Angewandte Chemie 124, no. 33 (2012): 8486–89. http://dx.doi.org/10.1002/ange.201203531.

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van der Eide, Edwin F., Ping Yang, Eric D. Walter, Tianbiao Liu, and R. Morris Bullock. "Dinuclear Metalloradicals Featuring Unsupported Metal-Metal Bonds." Angewandte Chemie International Edition 51, no. 33 (2012): 8361–64. http://dx.doi.org/10.1002/anie.201203531.

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Chahen, Ludovic, Bruno Therrien та Georg Süss-Fink. "(±)-Di-μ-chlorido-(μ-N,N′-{[3,3′-methylenebis(2,4,6-trimethyl-3,1-phenylene)]dimethylene}bis(2-methylpropan-2-amine))bis[chloridopalladium(II)]". Acta Crystallographica Section E Structure Reports Online 63, № 11 (2007): m2687. http://dx.doi.org/10.1107/s1600536807047745.

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In the title dinuclear palladium complex, [Pd2Cl4(C29H46N2)], the terminal ligands adopt an anti configuration, with an intramolecular metal–metal distance of 3.3625 (5) Å. The dinuclear palladium complex adopts a V-shaped conformation, with a dihedral angle of 152.67 (3)° between the two chloride-bridged PdNCl3 square-planar systems. The benzene rings in the chelating amine ligand are at an angle of 74.9 (1)° with respect to each other. The complex is the first example of chloride-bridged dinuclear palladium complex with a bidentate secondary amine ligand.
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Chandrasekhar, Vadapalli, Palani Sasikumar, Tapas Senapati, and Atanu Dey. "Dinuclear metal phosphonates and -phosphates." Inorganica Chimica Acta 363, no. 12 (2010): 2920–28. http://dx.doi.org/10.1016/j.ica.2010.03.038.

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Behlen, Michael J., You-Yun Zhou, Talia J. Steiman, et al. "Dinuclear oxidative addition reactions using an isostructural series of Ni2, Co2, and Fe2 complexes." Dalton Transactions 46, no. 17 (2017): 5493–97. http://dx.doi.org/10.1039/c6dt04465d.

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Rösch, Andreas, Christoph M. Herzog, Simon H. F. Schreiner, Helmar Görls, and Robert Kretschmer. "Ditopic bis(N,N′,N′-substituted 1,2-ethanediamine) ligands: synthesis and coordination chemistry." Dalton Transactions 49, no. 39 (2020): 13818–28. http://dx.doi.org/10.1039/d0dt03124k.

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During the bis(amidoamine) battle, several metal tribes formed troops of mono- and dinuclear complexes. Whereas the mononuclear troops can only act passive, the dinuclear troops may act side by side and make advantage of their reactive parts.
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Yan, Tengfei, and Qingyun Wan. "Vibrational Coherence in the Metal–Metal-Bonded Excited State of Pt(II) Complexes." Inorganics 11, no. 11 (2023): 441. http://dx.doi.org/10.3390/inorganics11110441.

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In the past decade, there have been significant advancements in the investigation of coherence-related phenomena in organic systems such as biological photosynthetic reaction centers. The d8 Pt(II) dinuclear complex or molecular aggregate with a metal–metal-to-ligand charge transfer (MMLCT) or metal-centered (MC) excited state was reported to show the vibrational coherence phenomenon in the intersystem crossing (ISC) process, due to the Metal–metal (M-M) interaction at excited state. In this study, we review the coherence effect in the Pt(II)-Pt(II) complexes which are speculated to be a coher
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Lin, Ying-Chih. "A Metal-Metal Bonded Dinuclear Ruthenium Ketene Complex." Journal of the Chinese Chemical Society 32, no. 3 (1985): 295–99. http://dx.doi.org/10.1002/jccs.198500045.

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Setsune, Jun-ichiro, Aki Tsukajima, and Naho Okazaki. "Synthesis and structure of isocorrole metal complexes." Journal of Porphyrins and Phthalocyanines 13, no. 02 (2009): 256–65. http://dx.doi.org/10.1142/s1088424609000334.

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gem-dimethylisocorrole gave four-coordinate Ni (II) and Cu (II) complexes, five-coordinate (chloro) Fe (III) and (chloro) Mn (III) complexes, and six-coordinate (chloro)(pyridinato) Rh (III) complex in moderate to good yields. The dinuclear complexes such as the μ-oxo-diiron(III) complex and tetracarbonyldirhodium(I) complex were also prepared. The structures of these mononuclear and dinuclear complexes were determined by X-ray crystallography. These structures are very similar to those of the corresponding metaloporphyrins but the presence of the sp3-meso carbon allows tilting of the pyrrole
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Li, Guangfu, Dongxia Zhu, Xinlong Wang, Zhongmin Su, and Martin R. Bryce. "Dinuclear metal complexes: multifunctional properties and applications." Chemical Society Reviews 49, no. 3 (2020): 765–838. http://dx.doi.org/10.1039/c8cs00660a.

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Dissertations / Theses on the topic "Dinuclear metal"

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Fine, David Andrew. "Structure and reactivity of dinuclear complexes of iridium /." Thesis, Connect to this title online; UW restricted, 1996. http://hdl.handle.net/1773/11618.

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Wilson, F. I. C. "Reactions of some dinuclear transition metal complexes." Thesis, Kingston University, 1988. http://eprints.kingston.ac.uk/20522/.

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The work in this thesis consists of three related studies. (i) Further investigations have been made into the mechanism of the photochemical reaction between (Mn[sub]2(CO)[sub]8{PBu[sub]3}[sub]2) and benzyl halides, equation 1. A previous study in these laboratories, which included an (Mn[sub]2(CO)[sub]8{PBu[sub]3}[sub]2) + PhCH[sub]2Cl -->(MnCl(CO)[sub]4PBu[sub]3) + (Mn(PhCH[sub]2)(CO)[sub]4PBu[sub]3) 1 examination of reaction kinetics, led to the suggestion that the mechanism involved CO dissociation from the manganese dimer, followed by metal-metal bond homolysis and subsequent reaction of
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Zhao, Yanyan. "Dinuclear Heterogeneous Catalysts on Metal Oxide Supports:." Thesis, Boston College, 2020. http://hdl.handle.net/2345/bc-ir:109003.

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Thesis advisor: Dunwei Wang<br>Atomically dispersed catalysts refer to substrate-supported heterogeneous catalysts featuring one or a few active metal atoms that are separated from one another. They represent an important class of materials ranging from single atom catalysts (SACs) and nanoparticles (NPs). The study of SACs has brought an attention of understanding the reaction mechanism at the molecular level. SACs is a promising field, however, there are still many challenges and opportunities in developing the next generation of catalysts. Catalysts featuring two atoms with well-defined str
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Bray, A. C. "The synthesis of metal cluster species for unsaturated dinuclear metal compounds." Thesis, University of Bristol, 1986. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.373734.

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Cheung, William M. L. (William Man Lung). "Artificial phosphodiesterases : dinuclear metal complexes with bridging hydroxides." Thesis, McGill University, 1996. http://digitool.Library.McGill.CA:80/R/?func=dbin-jump-full&object_id=23875.

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The reactivities of two dinuclear metals complexes with bridging hydroxides for hydrolyzing phosphrite diesters have been examined.<br>The second-order rate constants ($ rm k sp prime sb{hyd}/M sp{-1} s sp{-1}$) for the hydroxidecatalysed hydrolysis of bridging aryl methyl phosphates in di-$ mu$-hydroxodinuclear cobalt(III) complex ($ rm Co sb2( lbrack 9 rbrack aneN sb3) sb2(OH) sb2(OP(O)(OMe)(OAr) rbrack sp{3+}$ ( (9) aneN$ sb3$ = 1,4,7-triazacyclononane) and the corresponding free aryl methyl phosphates (25$ sp circ$C and 0.1 M ionic strength) obey the following Bronsted equations: eqalign{
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Graham, Alasdair. "Dinuclear and polynuclear metal complexes with bulky ligands." Thesis, University of Edinburgh, 2001. http://hdl.handle.net/1842/12051.

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Epton, Jeremy W. "Alkene hydroformylation catalysed by dinuclear rhodium complexes." Thesis, Kingston University, 1990. http://eprints.kingston.ac.uk/20536/.

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Kaur, Gurpreet. "Structure and reactivity of dinuclear and polynuclear metal complexes." Thesis, University of Canterbury. Chemistry, 2014. http://hdl.handle.net/10092/9945.

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This thesis documents the successful syntheses of six novel 2,2':6',2"-terpyridine-amine based polydentate ligands and a range of mono-, di-, and polynuclear complexes derived from them. The ability of some dinuclear complexes to affect the rate of hydrolysis of the phosphate diester group in the DNA model compound, bis-p-nitrophenyl phosphate (BNPP) has also been explored. Owing to the presence of two potential ligating groups in each polydentate ligand, a number of dinuclear, tetranuclear and serendipitous supramolecular architectures have been produced and characterised during this research
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Saini, Prabhjot Kaur. "Dinuclear metal catalysts for the synthesis of oxygenated polymers." Thesis, Imperial College London, 2014. http://hdl.handle.net/10044/1/44836.

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This thesis describes the synthesis of heterodinuclear and homodinuclear catalysts and the in depth investigations carried out when using these catalysts for the ring opening copolymerisation of epoxide/CO2 or epoxide/anhydride to generate polycarbonates or polyesters, respectively. Chapter 2 reports the kinetic and mechanistic studies carried out for cyclohexene oxide/CO2 copolymerisation reactions. Several di-magnesium catalysts bearing a symmetrical N4O2 macrocyclic ligand and different co-ligands (acetate, trifluoroacetate, benzoate, aryl oxide and bromide) were explored. These investigati
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Mitchell, Ellen Margaret. "Photochemical Studies of Dinuclear Methylene-Bridged Transition- Metal Complexes /." The Ohio State University, 1995. http://rave.ohiolink.edu/etdc/view?acc_num=osu1487930304688889.

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Book chapters on the topic "Dinuclear metal"

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Busetto, L., S. Bordoni, V. Zanotti, V. G. Albano, and D. Braga. "Cyanocarbene Dinuclear Derivatives of Iron." In Advances in Metal Carbene Chemistry. Springer Netherlands, 1989. http://dx.doi.org/10.1007/978-94-009-2317-1_15.

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Busetto, L., V. Zanotti, S. Bordoni, L. Carlucci, and A. Palazzi. "Carbyne to Carbene Ligand Conversion in Dinuclear Complexes." In Transition Metal Carbyne Complexes. Springer Netherlands, 1993. http://dx.doi.org/10.1007/978-94-011-1666-4_17.

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Bursten, Bruce E., and William F. Schneider. "Theoretical Studies of Dinuclear Compounds with Multiple Metal-Metal Bonds." In Metal-Metal Bonds and Clusters in Chemistry and Catalysis. Springer US, 1990. http://dx.doi.org/10.1007/978-1-4899-2492-6_3.

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Chisholm, Malcolm H. "Reactivity of Dinuclear and Tetranuclear Clusters of Molybdenum and Tungsten." In Metal-Metal Bonds and Clusters in Chemistry and Catalysis. Springer US, 1990. http://dx.doi.org/10.1007/978-1-4899-2492-6_5.

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Tsuchida, Eishun, Kimihisa Yamamoto, and Kenichi Oyaizu. "Multi-Electron Transfer Process of a Vanadium Dinuclear Complex for Molecular Conversions." In Metal-Containing Polymeric Materials. Springer US, 1996. http://dx.doi.org/10.1007/978-1-4613-0365-7_10.

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Romain, Charles, Arnaud Thevenon, Prabhjot K. Saini, and Charlotte K. Williams. "Dinuclear Metal Complex-Mediated Formation of CO2-Based Polycarbonates." In Topics in Organometallic Chemistry. Springer International Publishing, 2015. http://dx.doi.org/10.1007/3418_2015_95.

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Daumann, Lena Josefine. "Understanding the Overall Structure of GpdQ and Metal Binding." In Spectroscopic and Mechanistic Studies of Dinuclear Metallohydrolases and Their Biomimetic Complexes. Springer International Publishing, 2014. http://dx.doi.org/10.1007/978-3-319-06629-5_3.

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Feringa, Ben L., Onko-Jan Gelling, Minze T. Rispens, and Marcel Lubben. "Self-Assembly of Mono- and Dinuclear Metal Complexes; Oxidation Catalysis and Metalloenzyme Models." In Transition Metals in Supramolecular Chemistry. Springer Netherlands, 1994. http://dx.doi.org/10.1007/978-94-015-8380-0_9.

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Ishii, T., M. Kenmotsu, K. Tsuge, et al. "Luminescence Wavelengths and Energy Level Structure of Dinuclear Copper Complexes and Related Metal Complexes." In Quantum Systems in Chemistry and Physics. Springer Netherlands, 2012. http://dx.doi.org/10.1007/978-94-007-5297-9_20.

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Amendola, Valeria, and Luigi Fabbrizzi. "Molecular Motions Driven by Transition Metal Redox Couples: Ion Translocation and Assembling-Disassembling of Dinuclear Double-Strand Helicates." In Electrochemistry of Functional Supramolecular Systems. John Wiley & Sons, Inc., 2010. http://dx.doi.org/10.1002/9780470583463.ch2.

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Conference papers on the topic "Dinuclear metal"

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PHILLIPS, D. L., K. H. LEUNG, C. M. CHE, M. C. TSE, and V. M. MISKOWSKI. "RESONANCE RAMAN INVESTIGATION OF METAL-METAL BONDING INTERACTIONS IN METAL-METAL CHARGE TRANSFER TRANSITIONS OF DINUCLEAR INORGANIC COMPLEXES." In Proceedings of the Third Joint Meeting of Chinese Physicists Worldwide. WORLD SCIENTIFIC, 2002. http://dx.doi.org/10.1142/9789812776785_0071.

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Linjalahti, Heidi, Guoqiang Feng, Juan C. Mareque-Rivas, Satu Mikkola, and Nicholas H. Williams. "Cleavage and isomerisation of UpU promoted by dinuclear metal ion complexes." In XIVth Symposium on Chemistry of Nucleic Acid Components. Institute of Organic Chemistry and Biochemistry, Academy of Sciences of the Czech Republic, 2008. http://dx.doi.org/10.1135/css200810404.

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Šmit, Biljana, Asija Halilagić, Enisa Selimović, Jelena Katanić Stanković, Nikola Srećković, and Tanja Soldatović. "STUDIES OF SUBSTITUTION REACTIONS WITH IMPORTANT BIOMOLECULES AND ANTIMICROBIAL ACTIVITY OF NOVEL ZN(II)-L-CU(II) COMPLEXES." In 1st INTERNATIONAL Conference on Chemo and BioInformatics. Institute for Information Technologies, University of Kragujevac, 2021. http://dx.doi.org/10.46793/iccbi21.328s.

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New dinuclear Zn(II)-L-Cu(II) complexes with different bridging ligands were synthesized. Interactions of these complexes with biologically important nucleophiles, 5′-GMP, 5′-IMP and GSH, were investigated by Uv-Vis spectrofotometric method. The distances between the metal ions lead to less reactivity of both centers due to reduced electronic communication between them and an increasing of electron density on the metal centers itself. Both complexes showed moderate antimicrobial activity against most of the tested bacterial and fungal strains.
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Sanmartín-Matalobos, Jesús, Cristina Portela-García, Matilde Fondo, and Ana García-Deibe. "A simple route to dinuclear metal complexes of a sulfonamide ligand with a potential interest in the catalysis field." In The 19th International Electronic Conference on Synthetic Organic Chemistry. MDPI, 2015. http://dx.doi.org/10.3390/ecsoc-19-a030.

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Reports on the topic "Dinuclear metal"

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Norton, J. R. Catalytic applications of mono- and dinuclear complexes containing metal-carbon sigma bonds. Final report, November 1, 1993--October 31, 1996. Office of Scientific and Technical Information (OSTI), 1996. http://dx.doi.org/10.2172/541813.

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Leeladee, Pannee. Cooperative small-molecule activation toward sustainable catalysis. Faculty of Science, Chulalongkorn University, 2018. https://doi.org/10.58837/chula.res.2018.47.

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In this research, a series of copper complexes containing polypyridyl ligands were designed to study the influence from ligands, nuclearity, solvents and secondary coordination on reactivity toward small-molecule activation. This structure-reactivity relationship was used in investigation for oxygen reduction reactions (ORR), and applied in detection of ascorbic acid (AsH₂). Firstly, copper (II) complexes containing polypyridyl derivatives ligands (i.e., Cu(dpa), Cu(adpa) and Cu₂ (addpa)) were synthesized and fully characterized by elemental analysis, mass spectrometry and X-ray crystallograph
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