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Journal articles on the topic 'Dioxazolone'

Author: Grafiati

Published: 19 October 2024

Last updated: 31 July 2025

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1

Borah, Gongutri, Preetismita Borah, and Pitambar Patel. "Cp*Co(iii)-catalyzed ortho-amidation of azobenzenes with dioxazolones." Organic & Biomolecular Chemistry 15, no. 18 (2017): 3854–59. http://dx.doi.org/10.1039/c7ob00540g.

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2

Zhang, Lei, Xiangyun Zheng, Jinkang Chen, et al. "Ru(ii)-Catalyzed C6-selective C–H amidation of 2-pyridones." Organic Chemistry Frontiers 5, no. 20 (2018): 2969–73. http://dx.doi.org/10.1039/c8qo00795k.

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3

Pan, Deng, Gen Luo, Yang Yu, Jimin Yang, and Yi Luo. "Computational insights into Ir(iii)-catalyzed allylic C–H amination of terminal alkenes: mechanism, regioselectivity, and catalytic activity." RSC Advances 11, no. 31 (2021): 19113–20. http://dx.doi.org/10.1039/d1ra03842g.

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DFT studies on Ir(iii)-catalyzed branch-selective allylic C–H amination of terminal olefins with methyl dioxazolone have been carried out to investigate the mechanism, including the origins of regioselectivity and catalytic activity difference.

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4

Hall, David S., Toren Hynes, and J. R. Dahn. "Dioxazolone and Nitrile Sulfite Electrolyte Additives for Lithium-Ion Cells." Journal of The Electrochemical Society 165, no. 13 (2018): A2961—A2967. http://dx.doi.org/10.1149/2.0341813jes.

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5

Gauthier, Roby, David S. Hall, Katherine Lin, Jazmin Baltazar, Toren Hynes, and J. R. Dahn. "Impact of Functionalization and Co-Additives on Dioxazolone Electrolyte Additives." Journal of The Electrochemical Society 167, no. 8 (2020): 080540. http://dx.doi.org/10.1149/1945-7111/ab8ed6.

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6

Ghosh, Payel, Sadhanendu Samanta, and Alakananda Hajra. "Rhodium(iii)-catalyzed ortho-C–H amidation of 2-arylindazoles with a dioxazolone as an amidating reagent." Organic & Biomolecular Chemistry 18, no. 9 (2020): 1728–32. http://dx.doi.org/10.1039/c9ob02756d.

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A simple and efficient method for directed amidation of a wide range of 2-arylindazoles has been established for the first time through a rhodium-catalyzed C–H activation reaction with alkyl, aryl and heteroaryl dioxazolones.

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7

Hande, Akshay Ekanath, Nachimuthu Muniraj, and Kandikere Ramaiah Prabhu. "Cobalt(III)-Catalyzed C-H Amidation of Azobenzene Derivatives Using Dioxazolone as an Amidating Reagent." ChemistrySelect 2, no. 21 (2017): 5965–69. http://dx.doi.org/10.1002/slct.201701277.

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8

Hande, Akshay Ekanath, and Kandikere Ramaiah Prabhu. "Ru(II)-Catalyzed C–H Amidation of Indoline at the C7-Position Using Dioxazolone as an Amidating Agent: Synthesis of 7-Amino Indoline Scaffold." Journal of Organic Chemistry 82, no. 24 (2017): 13405–13. http://dx.doi.org/10.1021/acs.joc.7b02500.

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9

Lee, Seungmin, Minsuk Kim, Hyewon Han, and Jongwoo Son. "Dioxazolones as electrophilic amide sources in copper-catalyzed and -mediated transformations." Beilstein Journal of Organic Chemistry 21 (January 22, 2025): 200–216. https://doi.org/10.3762/bjoc.21.12.

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Over the past decade, dioxazolones have been widely used as N-acylamide sources in amidation processes of challenging substrates, typically employing precious transition metals. However, these catalytic systems often present several challenges associated with cost, toxicity, stability, and recyclability. Among the 3d transition metals, copper catalysts have been gaining increasing attention owing to their abundance, cost-effectiveness, and sustainability. Recently, these catalytic systems have been applied to the chemical transformation of dioxazolones, conferring a convenient protocol towards

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10

Liu, Chen-Fei, Man Liu, Jun-Shu Sun, Chao Li, and Lin Dong. "Synthesis of 2-aminobenzaldehydes by rhodium(iii)-catalyzed C–H amidation of aldehydes with dioxazolones." Organic Chemistry Frontiers 5, no. 13 (2018): 2115–19. http://dx.doi.org/10.1039/c8qo00413g.

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11

Tang, Shi-Biao, Xiao-Pan Fu, Gao-Rong Wu, et al. "Rhodium(iii)-catalyzed C4-amidation of indole-oximes with dioxazolones via C–H activation." Organic & Biomolecular Chemistry 18, no. 39 (2020): 7922–31. http://dx.doi.org/10.1039/d0ob01655a.

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12

Saxena, Paridhi, Neha Maida, and Manmohan Kapur. "Dioxazolones as masked ester surrogates in the Pd(ii)-catalyzed direct C–H arylation of 6,5-fused heterocycles." Chemical Communications 55, no. 75 (2019): 11187–90. http://dx.doi.org/10.1039/c9cc05563k.

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13

Wang, Jinlei, Guangfan Zheng, and Xingwei Li. "Rhodium(iii)-catalyzed diamidation of olefins via amidorhodation and further amidation." Chemical Communications 56, no. 56 (2020): 7809–12. http://dx.doi.org/10.1039/d0cc00952k.

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14

Liu, Yuan, Fang Xie, Ai-Qun Jia, and Xingwei Li. "Cp*Co(iii)-catalyzed amidation of olefinic and aryl C–H bonds: highly selective synthesis of enamides and pyrimidones." Chemical Communications 54, no. 34 (2018): 4345–48. http://dx.doi.org/10.1039/c8cc01447g.

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15

Song, Dan, Changfeng Huang, Peishi Liang, Baofu Zhu, Xiang Liu, and Hua Cao. "Lewis acid-catalyzed regioselective C–H carboxamidation of indolizines with dioxazolones via an acyl nitrene type rearrangement." Organic Chemistry Frontiers 8, no. 11 (2021): 2583–88. http://dx.doi.org/10.1039/d1qo00224d.

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An efficient, direct, and novel Lewis acid-catalyzed regioselective C–H carboxamidation of indolizines with dioxazolones via an acyl nitrene type rearrangement under metal-free conditions has been documented.

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16

Tobisch, Sven. "Copper hydride-mediated electrophilic amidation of vinylarenes with dioxazolones – a computational mechanistic study." Dalton Transactions 48, no. 38 (2019): 14337–46. http://dx.doi.org/10.1039/c9dt02540e.

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An in-depth computational mechanistic probe of the CuH-mediated formal hydroamidation of vinylarenes with dioxazolones allowed the substitution of mechanistic hypothesis advanced previously by a computationally verified mechanistic view.

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17

Ding, Jun, Wei Jiang, He-Yuan Bai, et al. "Experimental and computational studies on H2O-promoted, Rh-catalyzed transient-ligand-free ortho-C(sp2)–H amidation of benzaldehydes with dioxazolones." Chemical Communications 54, no. 64 (2018): 8889–92. http://dx.doi.org/10.1039/c8cc04904a.

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18

Bae, Hyeonwoong, Jinhwan Park, Rahyun Yoon, Seunghoon Lee, and Jongwoo Son. "Copper-catalyzed synthesis of primary amides through reductive N–O cleavage of dioxazolones." RSC Advances 14, no. 14 (2024): 9440–44. http://dx.doi.org/10.1039/d4ra00320a.

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Reaction of dioxazolones in the presence of a copper catalyst and a silane is represented. Mild reductive reaction conditions for the N–O bond cleavage and large-scale protocols are also highlighted with excellent tolerance in the presence of water.

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19

Yetra, Santhivardhana Reddy, Zhigao Shen, Hui Wang, and Lutz Ackermann. "Thiocarbonyl-enabled ferrocene C–H nitrogenation by cobalt(III) catalysis: thermal and mechanochemical." Beilstein Journal of Organic Chemistry 14 (June 25, 2018): 1546–53. http://dx.doi.org/10.3762/bjoc.14.131.

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Versatile C–H amidations of synthetically useful ferrocenes were accomplished by weakly-coordinating thiocarbonyl-assisted cobalt catalysis. Thus, carboxylates enabled ferrocene C–H nitrogenations with dioxazolones, featuring ample substrate scope and robust functional group tolerance. Mechanistic studies provided strong support for a facile organometallic C–H activation manifold.

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20

Bondock, Samir, Ehab Abdel Latif та Johann Lex. "Solvent-free Photooxygenation of 5-methoxyoxazoles: Stereoselective Synthesis of α-amino-α-hydroxy Carboxylic Acid Derivatives". Journal of Chemical Research 2005, № 7 (2005): 422–26. http://dx.doi.org/10.3184/030823405774309168.

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A solvent-free photooxygenation of 5-methoxyoxazoles 1a–j embedded in porphrin-loaded polystyrene beads as solid support is described and applied for the synthesis of 3H-1,2,4-dioxazole derivatives 2a–j. Acid catalysed hydrolysis of 3H-1,2,4-dioxazole derivatives gave α-amino-α-hydroxy carboxylic acid derivatives 3a–j. The structural elucidation of the new compounds were carried on the basis of spectral and X-ray analyses.

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21

Pan, Jie, Haocong Li, Kai Sun, Shi Tang, and Bing Yu. "Visible-Light-Induced Decarboxylation of Dioxazolones to Phosphinimidic Amides and Ureas." Molecules 27, no. 12 (2022): 3648. http://dx.doi.org/10.3390/molecules27123648.

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A visible-light-induced external catalyst-free decarboxylation of dioxazolones was realized for the bond formation of N=P and N–C bonds to access phosphinimidic amides and ureas. Various phosphinimidic amides and ureas (47 examples) were synthesized with high yields (up to 98%) by this practical strategy in the presence of the system’s ppm Fe.

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22

Colbeaux, Aimeline, Françoise Fenouillot, Jean-François Gerard, Mohamed Taha, and Henri Wautier. "Dioxazoline coupling of maleic anhydride modified polyethylene." Journal of Applied Polymer Science 97, no. 3 (2005): 837–43. http://dx.doi.org/10.1002/app.21793.

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23

Nishii, Yuji, Masahiro Miura, Chandrababu Naidu Kona, and Rikuto Oku. "Peri-Selective Direct Acylmethylation and Amidation of Naphthalene Derivatives Using Iridium and Rhodium Catalysts." Synthesis 53, no. 17 (2021): 3126–36. http://dx.doi.org/10.1055/a-1472-1059.

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AbstractAn iridium-catalyzed acylmethylation and a rhodium-catalyzed amidation of naphthalene derivatives are reported, adopting sulfoxonium ylides and dioxazolones as carbene and nitrene transfer agents, respectively. The use of SMe group as a directing group was key to ensure the peri-selective functionalization, and it can be easily removed or diversely transformed to other synthetically useful functionalities after the catalysis.

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24

Liao, Xian-Zhang, Man Liu, and Lin Dong. "An Approach to Vinylidenequinazolines from Isoxazoles and Dioxazolones." Journal of Organic Chemistry 87, no. 5 (2022): 3741–50. http://dx.doi.org/10.1021/acs.joc.1c02746.

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25

van Vliet, Kaj M., and Bas de Bruin. "Dioxazolones: Stable Substrates for the Catalytic Transfer of Acyl Nitrenes." ACS Catalysis 10, no. 8 (2020): 4751–69. http://dx.doi.org/10.1021/acscatal.0c00961.

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26

Samanta, Sadhanendu, Susmita Mondal, Debashis Ghosh, and Alakananda Hajra. "Rhodium-Catalyzed Directed C–H Amidation of Imidazoheterocycles with Dioxazolones." Organic Letters 21, no. 12 (2019): 4905–9. http://dx.doi.org/10.1021/acs.orglett.9b01832.

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27

Mi, Xia, Weisheng Feng, Chao Pi, and Xiuling Cui. "Iridium(III)-Catalyzed C–H Amidation of Nitrones with Dioxazolones." Journal of Organic Chemistry 84, no. 9 (2019): 5305–12. http://dx.doi.org/10.1021/acs.joc.9b00300.

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28

Chen, Jiajia, and Yuanzhi Xia. "Visible-Light-Induced Iron Catalysis for Nitrene Transfer Reactions with Dioxazolones." Chinese Journal of Organic Chemistry 41, no. 9 (2021): 3748. http://dx.doi.org/10.6023/cjoc202100069.

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29

Jeoung, Daeun, Kunyoung Kim, Sang Hoon Han, et al. "Phthalazinone-Assisted C–H Amidation Using Dioxazolones Under Rh(III) Catalysis." Journal of Organic Chemistry 85, no. 11 (2020): 7014–23. http://dx.doi.org/10.1021/acs.joc.0c00352.

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30

Huang, Yanzhen, Chao Pi, Zhen Tang, Yangjie Wu, and Xiuling Cui. "Cp*Co(III)-catalyzed C H amidation of azines with dioxazolones." Chinese Chemical Letters 31, no. 12 (2020): 3237–40. http://dx.doi.org/10.1016/j.cclet.2020.08.046.

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31

Chalamet, Yvan, and Mohamed Taha. "Carboxyl terminated polyamide 12 chain extension using a dioxazoline coupling agent." Journal of Polymer Science Part A: Polymer Chemistry 35, no. 17 (1997): 3697–705. http://dx.doi.org/10.1002/(sici)1099-0518(199712)35:17<3697::aid-pola9>3.0.co;2-p.

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32

Mishra, Neeraj Kumar, Yongguk Oh, Mijin Jeon, et al. "Site-Selective C-H Amidation of Azobenzenes with Dioxazolones under Rhodium Catalysis." European Journal of Organic Chemistry 2016, no. 29 (2016): 4976–80. http://dx.doi.org/10.1002/ejoc.201601096.

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33

Tang, Jing‐Jing, Xiaoqiang Yu, Yi Wang, Yoshinori Yamamoto, and Ming Bao. "Interweaving Visible‐Light and Iron Catalysis for Nitrene Formation and Transformation with Dioxazolones." Angewandte Chemie 133, no. 30 (2021): 16562–71. http://dx.doi.org/10.1002/ange.202016234.

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34

Tang, Jing‐Jing, Xiaoqiang Yu, Yi Wang, Yoshinori Yamamoto, and Ming Bao. "Interweaving Visible‐Light and Iron Catalysis for Nitrene Formation and Transformation with Dioxazolones." Angewandte Chemie International Edition 60, no. 30 (2021): 16426–35. http://dx.doi.org/10.1002/anie.202016234.

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35

Han, Gi Uk, Seohyun Shin, Yonghyeon Baek, et al. "Mechanochemical Iridium(III)-Catalyzed B-Amidation of o-Carboranes with Dioxazolones." Organic Letters 23, no. 21 (2021): 8622–27. http://dx.doi.org/10.1021/acs.orglett.1c03336.

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36

Jeon, Bomi, Uiseong Yeon, Jeong-Yu Son, and Phil Ho Lee. "Selective Rhodium-Catalyzed C–H Amidation of Azobenzenes with Dioxazolones under Mild Conditions." Organic Letters 18, no. 18 (2016): 4610–13. http://dx.doi.org/10.1021/acs.orglett.6b02250.

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37

Chamni, Supakarn, Jinquan Zhang, and Hongbin Zou. "Benign synthesis of unsymmetrical arylurea derivatives using 3-substituted dioxazolones as isocyanate surrogates." Green Chemistry Letters and Reviews 13, no. 3 (2020): 246–57. http://dx.doi.org/10.1080/17518253.2020.1807616.

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38

Wang, Xiaoyang, Song Song, and Ning Jiao. "Rh-catalyzed Transient Directing Group Promoted C-H Amidation of Benzaldehydes Utilizing Dioxazolones." Chinese Journal of Chemistry 36, no. 3 (2018): 213–16. http://dx.doi.org/10.1002/cjoc.201700726.

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39

Guo, Wusheng, and Biwei Yan. "Recent Advances in Decarboxylative Conversions of Cyclic Carbonates and Beyond." Synthesis 54, no. 08 (2021): 1964–76. http://dx.doi.org/10.1055/a-1715-7413.

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AbstractIn recent years, functionalized cyclic organic carbonates have emerged as valuable building blocks for the construction of interesting and useful molecules upon decarboxylation under transition-metal catalysis. By employing suitable catalytic systems, the development of chemo-, regio-, stereo- and enantioselective methods for the synthesis of useful and interesting compounds has advanced greatly. On the basis of previous research on this topic, this short review highlights the synthetic potential of cyclic carbonates under transition-metal catalysis over the last two years.1 Introducti

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40

Sheng, Yaoguang, Jianmin Zhou, Yi Gao, et al. "Ruthenium(II)-Catalyzed Direct C7-Selective Amidation of Indoles with Dioxazolones at Room Temperature." Journal of Organic Chemistry 86, no. 3 (2021): 2827–39. http://dx.doi.org/10.1021/acs.joc.0c02779.

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41

Tang, Jing-Jing, Xiaoqiang Yu, Yoshinori Yamamoto, and Ming Bao. "Visible-Light-Promoted Iron-Catalyzed N-Arylation of Dioxazolones with Arylboronic Acids." ACS Catalysis 11, no. 22 (2021): 13955–61. http://dx.doi.org/10.1021/acscatal.1c04538.

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42

Lee, Sumin, and Tomislav Rovis. "Rh(III)-Catalyzed Three-Component Syn-Carboamination of Alkenes Using Arylboronic Acids and Dioxazolones." ACS Catalysis 11, no. 14 (2021): 8585–90. http://dx.doi.org/10.1021/acscatal.1c02406.

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43

Wang, Jie, Shanke Zha, Kehao Chen, Feifei Zhang, Chao Song, and Jin Zhu. "Quinazoline Synthesis via Rh(III)-Catalyzed Intermolecular C–H Functionalization of Benzimidates with Dioxazolones." Organic Letters 18, no. 9 (2016): 2062–65. http://dx.doi.org/10.1021/acs.orglett.6b00691.

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44

Schroth, Werner, and Olaf Peters. "2-Acylmethyl-1, 3, 4-dioxazole durch Ketovinylierung von Hydroxamsäuren." Zeitschrift für Chemie 18, no. 2 (2010): 57–58. http://dx.doi.org/10.1002/zfch.19780180204.

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45

Yu, Yongqi, Jinjin Bai, Mengdan You та ін. "Cp∗Co(III)-catalyzed C–H amidation of 2-arylimidazo[1,2-α]pyridines with dioxazolones". Tetrahedron 171 (лютий 2025): 134420. https://doi.org/10.1016/j.tet.2024.134420.

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46

Huang, Jie, Jun Ding, Tong-Mei Ding, et al. "Cobalt-Catalyzed Ortho-C(sp2)–H Amidation of Benzaldehydes with Dioxazolones Using Transient Directing Groups." Organic Letters 21, no. 18 (2019): 7342–45. http://dx.doi.org/10.1021/acs.orglett.9b02632.

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47

Dhiman, Ankit Kumar, Ankita Thakur, Inder Kumar, Rakesh Kumar, and Upendra Sharma. "Co(III)-Catalyzed C–H Amidation of Nitrogen-Containing Heterocycles with Dioxazolones under Mild Conditions." Journal of Organic Chemistry 85, no. 14 (2020): 9244–54. http://dx.doi.org/10.1021/acs.joc.0c01237.

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48

Khan, Bhuttu, Vikas Dwivedi, and Basker Sundararaju. "Cp*Co(III)‐Catalyzed o ‐Amidation of Benzaldehydes with Dioxazolones Using Transient Directing Group Strategy." Advanced Synthesis & Catalysis 362, no. 5 (2020): 1195–200. http://dx.doi.org/10.1002/adsc.201901267.

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49

Chalamet, Yvan, and Mohamed Taha. "In-line residence time distribution of dicarboxylic acid oligomers/dioxazoline chain extension by reactive extrusion." Polymer Engineering & Science 39, no. 2 (1999): 347–55. http://dx.doi.org/10.1002/pen.11421.

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50

Chalamet, Yvan, and Mohamed Taha. "Kinetic and rheokinetic study of dicarboxylic fatty acid chain extension using a dioxazoline coupling agent." Journal of Applied Polymer Science 74, no. 4 (1999): 1017–24. http://dx.doi.org/10.1002/(sici)1097-4628(19991024)74:4<1017::aid-app29>3.0.co;2-y.

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