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Dissertations / Theses on the topic 'Diphosphines synthesis'

Author: Grafiati

Published: 21 December 2024

Last updated: 31 July 2025

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1

Taylor, Peter Neil. "Synthesis and study of medium-ring diphosphines." Thesis, University of Bristol, 1996. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.319096.

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2

Long, James Maurice. "Synthesis of new axially chiral diphosphines and phosphinamines for asymmetric catalysis." Thesis, University of Oxford, 1996. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.337600.

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3

Woodworth, Patrick. "Synthesis and Analysis of Gold Nanoclusters." VCU Scholars Compass, 2018. https://scholarscompass.vcu.edu/etd/5569.

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Gold Nanoclusters are of particular interest due to their many possible applications across a wide range of scientific fields. More specifically, nano-sized gold particles have potential to be used in drug delivery systems, cancer therapy and catalysis. This dissertation focuses on improving our understanding of ligated gold nanoclusters by examining the role of a variety of phosphine based ligands, novel methods to produce monodisperse solutions, and investigating the kinetics of water soluble ligated gold nanoclusters. The addition of ligands to solutions of Au have shown to produce small (<

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4

Leonard, Thomas Ralph. "New diphosphanes and their application in the synthesis of rigid backboned diphosphines." Thesis, University of Bristol, 2010. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.529843.

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5

Lam, Tun Chiao Hubert. "Synthesis of chiral amino (amido) diphosphines and applications in palladium catalyzed asymmetric processes." Thesis, King's College London (University of London), 2003. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.398250.

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6

Ekanayake, Dewmi A. "Copper Hydride Clusters Stabilized by NH-Centered Diphosphines: Synthesis, Structures, and Implications in Catalysis." University of Cincinnati / OhioLINK, 2021. http://rave.ohiolink.edu/etdc/view?acc_num=ucin1626356614867446.

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7

Marsh, Paul Samuel. "Synthesis, characterisation and precious metal chemistry of symmetrical and unsymmetrical diphosphines based on 9-phosphabicyclononanes." Thesis, University of Bristol, 2003. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.289719.

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8

Zwart, Guilhem. "Hydrogénolyse de (pseudo-)haloboranes et de chlorophosphines." Electronic Thesis or Diss., université Paris-Saclay, 2024. http://www.theses.fr/2024UPASF049.

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Cette thèse examine les défis posés par l’accès incertain aux éléments chimiques, exacerbée par un paradigme économique linéaire de leur exploitation. L’étude se concentre sur le bore et le phosphore, dont l’utilisation et le recyclage restent sous-étudiés. Le bore, crucial dans diverses industries, nécessite des processus énergivores pour être transformé en hydroboranes actifs, utilisés en chimie fine. Deux voies existent pour leur synthèse : la méthode industrielle à partir de borate, et la réaction de BCl₃ avec un donneur d’hydrure. Utiliser H₂ comme agent réducteur pourrait améliorer ces p

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9

Gramage-Doria, Rafael. "Large cavity cyclodextrin-based macrocyclic ligands : synthesis, coordination and catalytic properties." Phd thesis, Université de Strasbourg, 2012. http://tel.archives-ouvertes.fr/tel-00767168.

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Cyclodextrins (CDs) are cyclic oligosaccharides of various sizes containing several α-(1→4)-linked D-(+)- glucopyranose units. The commercially available ones comprise six, seven or eight glucose units, named respectively α-CD, β-CD and γ-CD. Their truncated cone-like and well-defined cavity are particularly attractive for the encapsulation of a variety of substrates. As such, they found numerous applications in many areas of chemistry. A recent development, from which the present work is inspired, consisted in covalently linking transition metals to CD cavities in order to perform and study c

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10

Fiedler, Tobias [Verfasser], and John A. [Akademischer Betreuer] Gladysz. "Syntheses of Gyroscope-like Osmium Complexes and Cage-like Diphosphines = Synthese gyroskopartiger Osmiumkomplexe und käfigartiger Diphosphine / Tobias Fiedler. Betreuer: John A. Gladysz." Erlangen : Universitätsbibliothek der Universität Erlangen-Nürnberg, 2011. http://d-nb.info/1015475116/34.

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11

Salomon, Christine. "Nouvelle synthèse stéréosélective de diphosphines à pont méthano P-stéréogéniques : applications en catalyse asymétrique et pour la préparation de clusters ou de polymères de coordination chiraux." Thesis, Dijon, 2010. http://www.theses.fr/2010DIJOS010/document.

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Ce mémoire porte sur la synthèse asymétrique de ligands à pont méthano P-stéréogénique, ainsi que sur leurs applications en catalyse asymétrique, en chimie de coordination et pour la préparation de polymères de coordination avec des métaux de transition. Les diphosphines P-stéréogéniques sont synthétisées par création d'une liaison phosphore-carbone au niveau du pont méthano, à partir d'un anion formé en position α d'une méthylphosphines borane. Plusieurs stratégies ont été étudiées selon que l'électrophile est un complexe d’oxazaphospholidine borane, un phosphinite borane ou une chlorophosphi

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12

Kandala, Srikanth Richmond Michael G. "Synthesis and characterization of diphosphine ligands and diphosphine substituted osmium and ruthenium clusters." [Denton, Tex.] : University of North Texas, 2007. http://digital.library.unt.edu/permalink/meta-dc-3955.

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13

STEPHAN, MASSOUD. "Synthese enantioselective de mono et diphosphines tertiaires." Paris 6, 1991. http://www.theses.fr/1991PA066345.

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Une synthese asymetrique efficace de mono et diphosphines tertiaires ou l'atome de phosphore est porteur de la chiralite est decrite en serie complexee. Son principe repose sur: 1) la separation diastereoselective d'un complexe borane d'oxazaphospholidine derive de l'ephedrine; 2) l'ouverture regio et stereospecifique de l'heterocycle complexe par les organometalliques. L'aminophosphine-borane obtenue est transformee en chlorophosphine ou en phosphinite-borane, respectivement par reaction avec l'acide chlorhydrique ou par methanolyse. Les phosphinites-borane reagissent avec les organolithiens

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14

Crabtree, Simon Peter. "Synthesis, structure and reaction studies of diphosphine rhodium complexes." Thesis, Durham University, 1996. http://etheses.dur.ac.uk/5299/.

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A series of complexes of the type [Rh(diphos)(C(_7)H(_8))](BF(_4)) (1) have been synthesised and two of these species [diphos = Bu(^1)(_2)P(CH(_2))(_2)PBu(^1)(_2), Cy(_2)P(l,2-trans-cyclopentane)PCy(_2)] have been characterised by X-ray crystallography. The influence of the chelating diphosphine on the structural characteristics and NMR parameters of these compounds has been investigated. Complexes of the type (1) are active catalysts for the hydroformylation of l-hexene(120ºC, 450psi 2:1 H(_2):C0). However, they are inactive for the related hydroesterification process and this is attributed t

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15

Kandala, Srikanth. "Synthesis and characterization of diphosphine ligand substituted osmium and ruthenium clusters." Thesis, University of North Texas, 2007. https://digital.library.unt.edu/ark:/67531/metadc3955/.

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The kinetics for the bridge-to-chelate isomerization of the dppe ligand in H4Ru4(CO)10(dppe) have been investigated by UV-vis and NMR spectroscopies over the temperature range of 308-328 K. The isomerization of the ligand-bridged cluster 1,2-H4Ru4(CO)10(dppe) was found to be reversible by 31P NMR spectroscopy, affording a Keq = 15.7 at 323 K in favor of the chelating dppe isomer. The forward (k1) and reverse (k-1) first-order rate constants for the reaction have been measured in different solvents and in the presence of ligand trapping agents (CO and PPh3). On the basis of the activation pa

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16

LE, GOASTER CELINE. "Synthese asymetrique de nouvelles diphosphines fonctionnalisees et de bis-1,3-oxaphospholanes." Rennes 1, 1997. http://www.theses.fr/1997REN10163.

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Le travail presente dans ce memoire est consacre a la synthese de nouvelles diphosphines optiquement actives, pouvant servir de ligand de metaux de transition dans des reactions de catalyse asymetrique. Dans la premiere partie, nous avons rappele les principaux resultats obtenus recemment dans le domaine des diphosphines optiquement actives et des complexe phosphine-boranes. Dans la deuxieme partie, nous avons decrit la synthese diastereoselective de trois complexes diphosphine-bisboranes fonctionnalises de formule : (2,2-dimethyl-4,5-bis(1-diphenylphosphino-2-methoxycarbonylethyl)-1,3-dioxola

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17

Fraze, Kendra Eileen. "Synthesis, electrochemistry, and thermodynamics of mononuclear and dinuclear nickel(II) diphosphine complexes." Connect to online resource, 2007. http://gateway.proquest.com/openurl?url_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:dissertation&res_dat=xri:pqdiss&rft_dat=xri:pqdiss:3273652.

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18

Newman, C. R. "A new conformationally flexible diphosphine, NUPHOS, synthesis and applications in asymmetric catalysis." Thesis, Queen's University Belfast, 2005. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.426656.

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19

Merdes, Rachid. "Syntheses asymetriques de diphosphines tertiaires chirales et quelques applications a la catalyse homogene." Paris 6, 1993. http://www.theses.fr/1993PA066428.

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Ce travail porte sur la mise au point de nouvelles syntheses asymetriques de diphosphines ou la chiralite est portee par l'atome de phosphore. Plusieurs voies ont ete etudiees, soit par creation d'une liaison cc ou d'une liaison cp entre deux complexes de methylphosphine borane, ou bien par creation de deux liaisons csi en utilisant un agent de couplage dichlorosilane, ou encore deux liaisons cp en faisant reagir deux equivalents d'un organometallique sur un complexe diphosphinite. Une autre approche a ete exploree, consistant a faire reagir un dianion sur deux equivalents d'organophosphores.

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20

Paavola, Sari. "Synthesis and characterisation of 1,2-diphosphino-o-carborane metal complexes." Helsinki : University of Helsinki, 2002. http://ethesis.helsinki.fi/julkaisut/mat/kemia/vk/paavola/.

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21

MICHAUD, GUILLAUME. "Synthese de nouvelles diphosphines atropoisomeres dissymetriques caracteristiques et evaluation en hydrogenation asymetrique." Paris 6, 2001. http://www.theses.fr/2001PA066340.

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L'objet de ce travail a ete la synthese de nouvelles diphosphines atropoisomeres pour des applications en catalyse enantioselective. Dans une premiere partie, nous nous sommes interesses a la synthese d'une diphosphine derivee du motif biphenanthrene. Nous n'avons pu preparer la molecule cible, le 10,10'-diphenylphosphino-9,9'-biphenanthrene : l'encombrement de la position 10 du biphenanthrene etant tres important, sa faible reactivite empeche l'introduction des groupements diphenylphosphino. Dans une seconde partie, nous avons defini une approche originale et generale a de nouvelles diphosphi

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22

La, PenseÌe Annemarie Agnes. "Homoleptic diarsine and diphosphine complexes of iron(II), ruthenium(II) and rhodium(III) : synthesis and electrochemistry." Thesis, University of Liverpool, 2002. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.250371.

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23

Supplee, Carolyn. "Synthesis and characterization of bimetallic palladium and platinum complexes resulting from chelating tertiary/secondary diphosphine ligands /." The Ohio State University, 1989. http://rave.ohiolink.edu/etdc/view?acc_num=osu1487599963591294.

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24

Almotawa, Ruaa Mohammed. "Silver(I) and Copper(I) Complexes from Homoleptic to Heteroleptic: Synthesis, Structure and Characterization." Thesis, University of North Texas, 2018. https://digital.library.unt.edu/ark:/67531/metadc1404512/.

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A plethora of novel scientific phenomena and practical applications, such as solid-state molecular solar cells and other optoelectronic devices for energy harvesting and lighting technologies, have catalyzed us to synthesize novel compounds with tunable properties. Synthetic routes, single crystal structures, and spectral and materials properties are described. Reactions of Ag(I) and Cu(I) precursors with various types of ligands -- including the azolates, diimines, and diiphosphines -- lead to the corresponding complexes in high yield. Varying the metal ions, ligands, synthetic methods, solve

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25

Tang, Pui-ling, and 鄧佩玲. "Synthesis, luminescence and host-guest chemistry of mono- and dinuclear platinum(II) complexes of pyridyl and diphosphine ligands." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 2002. http://hub.hku.hk/bib/B31243654.

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26

Tang, Pui-ling. "Synthesis, luminescence and host-guest chemistry of mono- and dinuclear platinum(II) complexes of pyridyl and diphosphine ligands /." Hong Kong : University of Hong Kong, 2002. http://sunzi.lib.hku.hk/hkuto/record.jsp?B25155040.

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27

Crosman, George Adrian. "Immobilization of Rh-diphosphine complexes on mesostructured materials and their application to asymmetric hydrogenation and hydroboration." Aachen Shaker, 2009. http://d-nb.info/999464981/04.

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28

Nyamwihura, Rogers. "Synthesis of Gold Complexes From Diphosphine Ligands and Screening Reactions of Heterocyclic Acetylacetonato (ACAC) Ligands with Transitional Metal Complexes." Thesis, University of North Texas, 2015. https://digital.library.unt.edu/ark:/67531/metadc804890/.

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Syntheses of diphosphine gold (I) complexes from gold THT and two ligands, 4, 5-bis (diphenylphosphino)-4-cyclopenten-1, 3-dione (BPCD) and 2,3-bis(diphenylphosphino)-N-phenylmaleimide (BPPM), were done separately. The reactions happened under ice conditions followed by room temperature conditions and produced two diphosphine gold (I) complexes in moderated yield. Spectroscopic results including nuclear magnetic resonance (NMR) and X-ray crystallography were used to study and determine the structures of the products formed. Moreover, X-rays of all newly synthesized diphosphine gold (I) comple

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29

Koner, Abhishek [Verfasser]. "On the imidazole-2-thione-based route to tricyclic 1,4-diphosphinines: synthesis, structures and reactions / Abhishek Koner." Bonn : Universitäts- und Landesbibliothek Bonn, 2018. http://d-nb.info/1154485862/34.

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30

Sivakumar, V. "Influence Of The Bite Angles Of Chelating Diphosphine Ligands In The Chemistry Of Ruthenium Hydride And Dihydrogen Complexes." Thesis, Indian Institute of Science, 2006. https://etd.iisc.ac.in/handle/2005/293.

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The bite angle of a diphosphine ligand plays an important role in determining the reactivity of a transition metal complex. The coordinated dihydrogen on a transition metal center can be activated toward homolysis or heterolysis depending upon the nature of the metal center and the ancillary ligand environment. The present work deals with our investigations on the effect of the bite angle of the chelating diphosphine ligands in the chemistry of certain ruthenium hydride and dihydrogen complexes. Protonation of the ds-[Ru(H)2(dppm)(PPh3)2] (dppm = Ph2PCH2PPh2) using HBF4-Et2O resulted in the

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31

Sivakumar, V. "Influence Of The Bite Angles Of Chelating Diphosphine Ligands In The Chemistry Of Ruthenium Hydride And Dihydrogen Complexes." Thesis, Indian Institute of Science, 2006. http://hdl.handle.net/2005/293.

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The bite angle of a diphosphine ligand plays an important role in determining the reactivity of a transition metal complex. The coordinated dihydrogen on a transition metal center can be activated toward homolysis or heterolysis depending upon the nature of the metal center and the ancillary ligand environment. The present work deals with our investigations on the effect of the bite angle of the chelating diphosphine ligands in the chemistry of certain ruthenium hydride and dihydrogen complexes. Protonation of the ds-[Ru(H)2(dppm)(PPh3)2] (dppm = Ph2PCH2PPh2) using HBF4-Et2O resulted in the d

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32

Jacobsen, George M. "Synthesis, characterization, and reactivity of iron(II) and cobalt(II) complexes containing diphosphine ligands that feature a pendant amine base." Connect to online resource, 2007. http://gateway.proquest.com/openurl?url_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:dissertation&res_dat=xri:pqdiss&rft_dat=xri:pqdiss:3256473.

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33

Wu, Guanmin. "Synthesis, characterization, and kinetics of isomerization, C-H and P-C bond activation for unsaturated diphosphine-coordinated triosmium carbonyl clusters." Thesis, University of North Texas, 2008. https://digital.library.unt.edu/ark:/67531/metadc6037/.

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Substitution of MeCN ligands in the activated cluster Os3(CO)10(MeCN)2 by the unsaturated diphosphine ligands (Z)-Ph2PCH=CHPPh2 (cDPPEn) or 4,5-bis(diphenylphosphino)-4-cyclopenten-1,3-dione (bpcd) proceeds rapidly at room temperature to furnish the ligand-bridged cluster 1,2-Os3(CO)10(P-P) (P-P represents cDPPEn or bpcd). Heating 1,2-Os3(CO)10(P-P) leads to the formation of the thermodynamically more stable chelating isomer 1,1-Os3(CO)10(P-P). Each compound of Os3(CO)10(P-P) has been characterized by x-ray diffraction, IR, 31P NMR and 1H NMR. Ligand isomerization kinetics have been investiga

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34

Wu, Guanmin Richmond Michael G. "Synthesis characterization, and kinetics of isomerization, C-H and P-C bond activation for unsaturated diphosphine-coordinated triosmium carbonyl clusters." [Denton, Tex.] : University of North Texas, 2008. http://digital.library.unt.edu/permalink/meta-dc-6037.

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35

Samuels, Michiel C. "Solid phase strategies for the preparation of phosphorus ligand libraries." Thesis, University of St Andrews, 2014. http://hdl.handle.net/10023/6357.

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Catalysis plays a key role in chemical conversions by making them faster and more selective. Despite its widespread use and decades of academic and industrial research, limited catalyst selectivity and stability still call for major improvements in catalyst performance to meet the demands of a sustainable society. Phosphine ligands are ubiquitous in transition metal chemistry and lead to extremely reactive and versatile homogeneous catalysts. Fast development of tailor-made catalysts and catalyst recovery are key issues in (asymmetric) homogeneous catalysis. Therefore libraries of ligands have

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36

Fernandez, Cristina Carcedo. "Chiral diphosphine ligands derived from 1, 4:3, 6-dianhydro-d-mannitol : synthesis, co-ordination to transition metals and catalytic applications." Thesis, Cardiff University, 2005. http://orca.cf.ac.uk/54551/.

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The synthesis of a new chiral diphosphine, l,4:3,6-dianhydro-2,5-bis(diphenylphosphino)-D-mannitol (ddppm) is reported, ddppm is derived from the commercially available C2-symmetric l,4:3,6-dianhydro-D-mannitol (Isomannide). This new ligand exhibits a bend butterfly-like geometry with the two-phosphine groups on the concave side. PPh, I PPh, H H ddppm The chelating ability of ddppm is demonstrated with the synthesis of several complexes with transition metals such as Cu, Pd, Pt, Rh, Ru and Ir. Some of these complexes have been successfully crystallized and tested in different catalytic reactio

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37

Mayberry, Darrell D. "Synthesis, Characterization, and Reactivity of Prochiral Ruthenium Clusters and Bimetallic Rhenium Complexes with an Unsymmetrical Diphosphine and Hard-Soft Donor Ligands." Thesis, University of North Texas, 2019. https://digital.library.unt.edu/ark:/67531/metadc1538707/.

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The reaction of [BrRe(CO)₄]₂ with 2-(diphenylphosphino)pyridine (PN) and 6-(diphenylphosphino)-2-formylpyridine (PON) was investigated. The reactions were regiospecific and exclusively produced the phosphorus-coordinated products, BrRe(CO)₄(κᵖ-PN) and BrRe(CO)₄(κᴾ-PON). The kinetics for the chelate ring closure (κᴾ→ κᴾᴺ) in BrRe(CO)₄(κᴾ-PN) were confirmed to occur by dissociative CO loss. The reaction of [BrRe(CO)₄]₂ with 2-(diphenylphosphino)pyridine (PN) was modeled computationally by DFT calculations. The preferred reaction pathway for the substitution reaction was determined to occur by di

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38

Poola, Bhaskar. "Synthesis and characterization of quinoxaline-functionalized, cage-annulated oxa- and thiacrown ethers and reaction chemistry of the diphosphine ligand 2,3-bis(diphenylphosphino)-N-p-tolylmaleimide (bmi) at triosmium carbonyl clusters." Thesis, University of North Texas, 2006. https://digital.library.unt.edu/ark:/67531/metadc5608/.

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Quinoxaline-functionalized, cage-annulated oxa- and thiacrown ethers have been synthesized as possible specific metal host systems. The synthesis and characterization of quinoxaline-functionalized, cage-annulated oxa- and thiacrown ethers have been described. The characterization of these host systems have been fully achieved in solution by using various techniques such as IR, 1H NMR, and 13C NMR spectroscopic methods, high-resolution mass spectrometry (HRMS), elemental microanalysis, and X-ray crystallographic analysis in case of one quinoxaline-functionalized, cage-annulated oxacrown ether c

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39

Liu, Jie. "Substitution chemistry of the cobalt complexes RCCo3(CO)9 (R = H, CHO) with the diphosphine ligand: 4,5-bis(diphenylphosphino)-4-cyclopenten-1,3-dione (bpcd). Syntheses, X-ray structures and reactivity." Thesis, University of North Texas, 2001. https://digital.library.unt.edu/ark:/67531/metadc3043/.

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The reaction between the tetrahedrane cluster RCCo3(CO)9{R = CHO (1), H (3)} and the redox-active diphosphine ligand 4,5-bis(diphenylphosphino)-4-cyclopenten-1,3- dione (bpcd) leads to the replacement of two CO groups and formation of RCCo3(CO)7(bpcd) {R = CHO (2), H (4)}. Clusters 2 and 4 are thermally unstable and readily transform into the new P-C bond cleavage cluster 5. All three clusters 2, 4, and 5 have been isolated and fully characterized in solution by IR and 31P NMR spectroscopy. VT 31P NMR data indicate that the bpcd ligand in RCCo3(CO)7(bpcd) is fluxional at 187 K in THF. Clusters

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40

Stolze, Karoline. "Synthese und Charakterisierung niedervalenter Actinoidphosphidtelluride und ternärer Selen-Halogenid-Komplexe des Iridiums." Doctoral thesis, Saechsische Landesbibliothek- Staats- und Universitaetsbibliothek Dresden, 2016. http://nbn-resolving.de/urn:nbn:de:bsz:14-qucosa-202233.

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Metallpniktide und -chalkogenide erfahren zunehmend mehr Aufmerksamkeit in Chemie und Festkörperphysik. Dieses Interesse liegt unter anderem in der ungewöhnlichen Strukturchemie der Verbindungen begründet. In den Pniktogen(Pn)- bzw. Chalkogen(Q)-reichen Verbindungen dieser Systeme ist besonders häufig die Bildung der jeweiligen Oligo- oder Polyanionen bzw. Moleküle zu beobachten. Einerseits können die homoatomaren Pn–Pn- bzw. Q–Q-Bindungen zur Ausbildung niederdimensionaler Strukturmotive mit anisotropen Eigenschaften, wie bspw. Supraleitung und Metall-Halbleiter-Übergänge, führen; andererseit

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41

Alberico, Elisabetta [Verfasser]. "Optically active [(η6-arene)Cr(CO)3]-based [(eta6-arene)Cr(CO)3-based] diphosphines : synthesis and application in asymmetric homogeneous hydrogenation / vorgelegt von Elisabetta Alberico". 2003. http://d-nb.info/970879490/34.

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42

Bhowmick, Arnab. "Synthesis and characterization of transition metal cluster containing diphosphine ligands." Thesis, 2012. http://ethesis.nitrkl.ac.in/3085/2/Online_project_on_metal_clusters.pdf.

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Various metal complexes containing transitional metal elements have been prepared. Using shlenk line technique . Spectroscopic analysis by IR and NMR shows that two types of diphosphine co-ordinated metal clusters have been obtained,one having chelating mode of binding [Fe3SeTeCO)7{(PPh2)(C5H4)Fe(C5H4)(PPh2)}] ,and the another is having mono dentate co-ordination [Fe3Te2(CO)8{(PPh2) (C5H4)Fe(C5H4)(PPh2)}].

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43

Wu, Zih-Shing, and 吳梓翔. "Synthesis and Characterization of Rhenium Isocyanide Complexes and Ruthenium Diphosphine Complexes." Thesis, 2008. http://ndltd.ncl.edu.tw/handle/17291636285220419350.

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碩士<br>高雄醫學大學<br>醫藥暨應用化學研究所碩士班<br>96<br>The preparation and characterization of RuCl2(POMe)2 (POMe = diphenyl(2-methoxyphenyl)phosphine) was reported. However, the reactions of RuCl2(POMe)2 with refluxing RCN (R = Me, Et) led to loss of CH3Cl to give Ru(RCN)2(PO)2 (R = Me(1), Et(3)), which are never reported. Adding KPF6 or KBF4 in the reactions will give additional products [Ru(RCN)2(PO)(POMe)]+ (R = Me(2), Et(4)) according to the solvent selection. Complexes 2 and 4 were observed the dealkylating via loss of CH3Cl or [CH3(POMe)]+ pathways. The [CH3(POMe)]+ pathway needs excess POMe which may

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MacFarlane, Kenneth Shawn. "Synthesis, characterization, and reactivity of ruthenium(II)-diphosphine complexes for catalytic homogeneous hydrogenation." Thesis, 1995. http://hdl.handle.net/2429/4792.

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Li, Guo An, and 李國安. "supercritical fluid synthesis of copper diphosphide nanowires for energy storage applications." Thesis, 2016. http://ndltd.ncl.edu.tw/handle/386cqq.

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博士<br>國立清華大學<br>化學工程學系<br>105<br>Phosphorus-rich transition metal phosphide CuP2 nanowires were synthesized with high quality and high yield (∼60%) via the supercritical ﬂuid−liquid−solid (SFLS) growth at 410 °C and 10.2 MPa. The obtained CuP2 nanowires have a high aspect ratio and exhibit a single crystal structure of monoclinic CuP2 without any impurity phase. CuP2 nanowires have progressive improvement for semiconductors and energy storages compared with bulk CuP2. Being utilized for back-gate ﬁeld eﬀect transistor (FET) measurement, CuP2 nanowires possess a p-type behavior intrinsically wi

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Rodríguez-Bárzano, A., Rianne M. Lord, A. M. Basri, Roger M. Phillips, A. J. Blacker та P. C. McGowan. "Synthesis and anticancer activity evaluation of η5-C5(CH3)4R ruthenium complexes bearing chelating diphosphine ligands". 2014. http://hdl.handle.net/10454/9498.

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yes<br>The complexes [RuCp*(PP)Cl] (Cp* = C5Me5; [1], PP = dppm; [4], PP = Xantphos), [RuCp#(PP)Cl] (Cp# = C5Me4(CH2)5OH; [2], PP = dppm; [5], PP = Xantphos) and [RuCp*(dppm)(CH3CN)][SbF6] [3] were synthesized and evaluated in vitro as anticancer agents. Compounds 1–3 gave nanomolar IC50 values against normoxic A2780 and HT-29 cell lines, and were also tested against hypoxic HT-29 cells, maintaining their high activity. Complex 3 yielded an IC50 value of 0.55 ± 0.03 μM under a 0.1% O2 concentration.

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Lin, Chien-Nan, and 林建男. "Dicyanobenzene-, Diphosphine-, and N-Heterocyclic Carbene-Bridged EFe3Cu2 (E = S, Se, Te) Complexes: Synthesis, Transformation, Semiconductivity, and Catalysis." Thesis, 2015. http://ndltd.ncl.edu.tw/handle/74844266434313295108.

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博士<br>國立臺灣師範大學<br>化學系<br>103<br>1. S/Fe/Cu/Dppx System A reversible vapochemical and mechanochemical solid-state transformation between a dppe-linked SFe3Cu2-based cluster [{(m3-S)Fe3(CO)9}Cu2(dppe)] and its 1D polymer [{(m4-S)Fe3(CO)9}Cu2(dppe)(MeCN)2]n, was demonstrated, in which polymer [{(m4-S)Fe3(CO)9}Cu2(dppe)(MeCN)2]n exhibited semi-conducting properties with an energy gap of 1.69 eV. 2. Se, Te/Fe/Cu/p-DCB System When solid reactants [EFe3(CO)9Cu2(MeCN)2] (E = Se, Te) and 1,4-dicyanobenzene (p-DCB) were mixed in 1:1 and 1:1.5 ratios and ground with drops of THF, two EFe3(CO)9Cu2-b

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Elowe, Paul Richard. "The Selective Oligomerization of Ethylene Using Chromium Diphosphine Catalysts and the Synthesis and Reactivity of Group 7 Carbonyl Derivatives Relevant to Synthesis Gas Conversion." Thesis, 2009. https://thesis.library.caltech.edu/5240/1/1_Title.pdf.

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<p>The work presented in this thesis explores two distinct fields of organometallic chemistry with a common goal of selectively transforming cheap and abundant feedstocks to value-added chemicals using homogeneous catalysts.</p> <p>Chapter 1 presents the synthesis and characterization of a series of bis(diphenylphosphino)amine ligands and their corresponding chromium(III) trichloride complexes. The isolated chromium complexes are precursors to highly active catalysts for the selective oligomerization of ethylene to 1-hexene and 1-octene. The unique feature of the ligands presented herein is

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Wang, Chih-Chin, and 王致欽. "Diphosphine-, Dipyridyl-, and N-Heterocyclic Carbene-Bridged EFe3Cu2 (E = S, Se, Te) Complexes: Synthesis, Reactivity, Optical properties, and Catalysis." Thesis, 2016. http://ndltd.ncl.edu.tw/handle/93291126112830988787.

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Tai-YenLin and 林泰言. "Syntheses and Characterization of Lead(II), Copper(I) and Iron(II) Complexes with tetradentate diphosphine-dithiolate ligand derivatives." Thesis, 2015. http://ndltd.ncl.edu.tw/handle/17925395142905230744.

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碩士<br>國立成功大學<br>化學系<br>103<br>Our laboratory has developed a series of phosphine-thiolate ligands in order to understand metal thiolate chemistry. It is anticipated the information provided from this study can bring insights for understanding the metal-sulfur chemistry in biological systems as well as in toxicity. In this thesis, diphosphine-dithiolate ligand (P2S2) was utilized for exploring metal chemistry. 31P, 207Pb NMR in solid and solution state were applied on two lead(II) compelexes, Pb(P2S2”) (1) and [Pb(P2S2”)]2·[Pb2(P2S2”)2] (2). Pb(P2S2”) (1) is a monolead(II) species binding with

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