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1

Khakdaman, H., Y. Bourgault, and M. Ternan. "Computational modeling of a direct propane fuel cell." Journal of Power Sources 196, no. 6 (March 2011): 3186–94. http://dx.doi.org/10.1016/j.jpowsour.2010.11.115.

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2

Khakdaman, Hamidreza, Yves Bourgault, and Marten Ternan. "A Mathematical Model of a Direct Propane Fuel Cell." Journal of Chemistry 2015 (2015): 1–13. http://dx.doi.org/10.1155/2015/102313.

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A rigorous mathematical model for direct propane fuel cells (DPFCs) was developed. Compared to previous models, it provides better values for the current density and the propane concentration at the exit from the anode. This is the first DPFC model to correctly account for proton transport based on the combination of the chemical potential gradient and the electrical potential gradient. The force per unit charge from the chemical potential gradient (concentration gradient) that pushes protons from the anode to the cathode is greater than that from the electrical potential gradient that pushes them in the opposite direction. By including the chemical potential gradient, we learn that the proton concentration gradient is really much different than that predicted using the previous models that neglected the chemical potential gradient. Also inclusion of the chemical potential gradient made this model the first one having an overpotential gradient (calculated from the electrical potential gradient) with the correct slope. That is important because the overpotential is exponentially related to the reaction rate (current density). The model described here provides a relationship between the conditions inside the fuel cell (proton concentration, overpotential) and its performance as measured externally by current density and propane concentration.
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3

Wang, Kang, Pingying Zeng, and Jeongmin Ahn. "High performance direct flame fuel cell using a propane flame." Proceedings of the Combustion Institute 33, no. 2 (January 2011): 3431–37. http://dx.doi.org/10.1016/j.proci.2010.07.047.

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4

Psofogiannakis, G., Y. Bourgault, B. E. Conway, and M. Ternan. "Mathematical model for a direct propane phosphoric acid fuel cell." Journal of Applied Electrochemistry 36, no. 1 (October 22, 2005): 115–30. http://dx.doi.org/10.1007/s10800-005-9044-4.

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5

Huang, Ta-Jen, Chen-Yi Wu, and Chun-Hsiu Wang. "Fuel processing in direct propane solid oxide fuel cell and carbon dioxide reforming of propane over Ni–YSZ." Fuel Processing Technology 92, no. 8 (August 2011): 1611–16. http://dx.doi.org/10.1016/j.fuproc.2011.04.007.

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6

Vafaeyan, Shadi, Alain St-Amant, and Marten Ternan. "Nickel Alloy Catalysts for the Anode of a High Temperature PEM Direct Propane Fuel Cell." Journal of Chemistry 2014 (2014): 1–8. http://dx.doi.org/10.1155/2014/151638.

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High temperature polymer electrode membrane fuel cells that use hydrocarbon as the fuel have many theoretical advantages over those that use hydrogen. For example, nonprecious metal catalysts can replace platinum. In this work, two of the four propane fuel cell reactions, propane dehydrogenation and water dissociation, were examined using nickel alloy catalysts. The adsorption energies of both propane and water decreased as the Fe content of Ni/Fe alloys increased. In contrast, they both increased as the Cu content of Ni/Cu alloys increased. The activation energy for the dehydrogenation of propane (a nonpolar molecule) changed very little, even though the adsorption energy changed substantially as a function of alloy composition. In contrast, the activation energy for dissociation of water (a molecule that can be polarized) decreased markedly as the energy of adsorption decreased. The different relationship between activation energy and adsorption energy for propane dehydrogenation and water dissociation alloys was attributed to propane being a nonpolar molecule and water being a molecule that can be polarized.
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7

Khakdaman, Hamidreza, Yves Bourgault, and Marten Ternan. "Direct Propane Fuel Cell Anode with Interdigitated Flow Fields: Two-Dimensional Model." Industrial & Engineering Chemistry Research 49, no. 3 (February 3, 2010): 1079–85. http://dx.doi.org/10.1021/ie900727p.

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8

Ihara, Manabu, and Shinichi Hasegawa. "Quickly Rechargeable Direct Carbon Solid Oxide Fuel Cell with Propane for Recharging." Journal of The Electrochemical Society 153, no. 8 (2006): A1544. http://dx.doi.org/10.1149/1.2203948.

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9

Parackal, Bhavana, Hamidreza Khakdaman, Yves Bourgault, and Marten Ternan. "An Investigation of Direct Hydrocarbon (Propane) Fuel Cell Performance Using Mathematical Modeling." International Journal of Electrochemistry 2018 (December 2, 2018): 1–18. http://dx.doi.org/10.1155/2018/5919874.

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An improved mathematical model was used to extend polarization curves for direct propane fuel cells (DPFCs) to larger current densities than could be obtained with any of the previous models. DPFC performance was then evaluated using eleven different variables. The variables related to transport phenomena had little effect on DPFC polarization curves. The variables that had the greatest influence on DPFC polarization curves were all related to reaction rate phenomena. Reaction rate phenomena were dominant over the entire DPFC polarization curve up to 100 mA/cm2, which is a value that approaches the limiting current densities of DPFCs. Previously it was known that DPFCs are much different than hydrogen proton exchange membrane fuel cells (PEMFCs). This is the first work to show the reason for that difference. Reaction rate phenomena are dominant in DPFCs up to the limiting current density. In contrast the dominant phenomenon in hydrogen PEMFCs changes from reaction rate phenomena to proton migration through the electrolyte and to gas diffusion at the cathode as the current density increases up to the limiting current density.
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10

Kronemayer, Helmut, Daniel Barzan, Michio Horiuchi, Shigeaki Suganuma, Yasue Tokutake, Christof Schulz, and Wolfgang G. Bessler. "A direct-flame solid oxide fuel cell (DFFC) operated on methane, propane, and butane." Journal of Power Sources 166, no. 1 (March 2007): 120–26. http://dx.doi.org/10.1016/j.jpowsour.2006.12.074.

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11

Danilov, Valery, Peter De Schepper, and Joeri Denayer. "A TSR model for direct propane fuel cell with equilibrium adsorption and desorption processes." Renewable Energy 83 (November 2015): 1084–96. http://dx.doi.org/10.1016/j.renene.2015.05.055.

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12

Zhang, Yapeng, Fangyong Yu, Xiaoqiang Wang, Qian Zhou, Jiang Liu, and Meilin Liu. "Direct operation of Ag-based anode solid oxide fuel cells on propane." Journal of Power Sources 366 (October 2017): 56–64. http://dx.doi.org/10.1016/j.jpowsour.2017.08.111.

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13

Rodríguez Varela, F. J., and O. Savadogo. "Real-Time Mass Spectrometric Analysis of the Anode Exhaust Gases of a Direct Propane Fuel Cell." Journal of The Electrochemical Society 152, no. 9 (2005): A1755. http://dx.doi.org/10.1149/1.1973100.

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14

Lo Faro, Massimiliano, Sabrina Campagna Zignani, and Antonino Salvatore Aricò. "Lanthanum Ferrites-Based Exsolved Perovskites as Fuel-Flexible Anode for Solid Oxide Fuel Cells." Materials 13, no. 14 (July 20, 2020): 3231. http://dx.doi.org/10.3390/ma13143231.

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Exsolved perovskites can be obtained from lanthanum ferrites, such as La0.6Sr0.4Fe0.8Co0.2O3, as result of Ni doping and thermal treatments. Ni can be simply added to the perovskite by an incipient wetness method. Thermal treatments that favor the exsolution process include calcination in air (e.g., 500 °C) and subsequent reduction in diluted H2 at 800 °C. These processes allow producing a two-phase material consisting of a Ruddlesden–Popper-type structure and a solid oxide solution e.g., α-Fe100-y-zCoyNizOx oxide. The formed electrocatalyst shows sufficient electronic conductivity under reducing environment at the Solid Oxide Fuel Cell (SOFC) anode. Outstanding catalytic properties are observed for the direct oxidation of dry fuels in SOFCs, including H2, methane, syngas, methanol, glycerol, and propane. This anode electrocatalyst can be combined with a full density electrolyte based on Gadolinia-doped ceria or with La0.8Sr0.2Ga0.8Mg0.2O3 (LSGM) or BaCe0.9Y0.1O3-δ (BYCO) to form a complete perovskite structure-based cell. Moreover, the exsolved perovskite can be used as a coating layer or catalytic pre-layer of a conventional Ni-YSZ anode. Beside the excellent catalytic activity, this material also shows proper durability and tolerance to sulfur poisoning. Research challenges and future directions are discussed. A new approach combining an exsolved perovskite and an NiCu alloy to further enhance the fuel flexibility of the composite catalyst is also considered. In this review, the preparation methods, physicochemical characteristics, and surface properties of exsoluted fine nanoparticles encapsulated on the metal-depleted perovskite, electrochemical properties for the direct oxidation of dry fuels, and related electrooxidation mechanisms are examined and discussed.
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15

Savadogo, Oumarou. "On the materials issues for pefc applications." Chemical Industry 58, no. 6 (2004): 286–94. http://dx.doi.org/10.2298/hemind0406286s.

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Current limitations related to the development of effective, durable and reliable MEA components for PEFC applications are addressed. Advancements made in the development of materials (catalysts, high temperature membranes, bipolar plates, etc.) for PEFC are shown. The effect of the catalyst on PEFC performances based on cells fed by hydrogen, direct methanol, direct propane, or direct acetal fuels are presented. The progress in cell performance and cathode research are discussed. Perspectives related to CO tolerance anodes are indicated. The effect of the membranes on the cell performance are shown and parameters which may help the development of appropriate membranes depending on the fuel are suggested. Openings for the future in materials processing and development for PEFC mass production are discussed. The development of New Materials is the key factor to meet those requirements. The aim of this paper is to present challenges related to the development of new materials for PEFC applications and perspectives related to components cost issues are discussed.
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16

Tripathi, Bijay P., and Vinod K. Shahi. "3-[[3-(Triethoxysilyl)propyl]amino]propane-1-sulfonic Acid−Poly(vinyl alcohol) Cross-Linked Zwitterionic Polymer Electrolyte Membranes for Direct Methanol Fuel Cell Applications." ACS Applied Materials & Interfaces 1, no. 5 (April 28, 2009): 1002–12. http://dx.doi.org/10.1021/am800228s.

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17

Abu-Saied, M. A., Emad Ali Soliman, Khamael M. Abualnaj, and Eman El Desouky. "Highly Conductive Polyelectrolyte Membranes Poly(vinyl alcohol)/Poly(2-acrylamido-2-methyl propane sulfonic acid) (PVA/PAMPS) for Fuel Cell Application." Polymers 13, no. 16 (August 8, 2021): 2638. http://dx.doi.org/10.3390/polym13162638.

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In this study, chemically cross-linked PVA/PAMPS membranes have been prepared to be used in direct methanol fuel cells (DMFCs). The structural properties of the resultant membrane were characterized by use FTIR and SEM. Additionally, their thermal stability was assessed using TGA. Moreover, the mechanical properties and methanol and water uptake of membrane was studied. The obtained FTIR of PVA/PAMPS membranes revealed a noticeable increase in the intensity of adsorption peaks appearing at 1062 and 1220 cm−1, which correspond to sulfonic groups with the increasing proportion of PAMPS. The thermograms of these polyelectrolyte membranes showed that their thermal stability was lower than that of PVA membrane, and total weight loss gradually decreased with increasing the PAMPS. Additionally, the functional properties and efficiency of these polyelectrolyte membranes were significantly improved with increasing PAMPS proportion in these blends. The IEC of polymer blend membrane prepared using PVA/PAMPS ratio of 1:1 was 2.64 meq/g. The same membrane recorded also a methanol permeability coefficient of 2.5 × 10−8 cm2/s and thus, its efficiency factor was 4 × 105 greater than that previously reported for the commercial polyelectrolyte membrane, Nafion® (2.6 × 105). No significant increase in this efficiency factor was observed with a further amount of PAMPS. These results proved that the PVA:PAMPS ratio of 1:1 represents the optimum mass ratio to develop the cost-effective and efficient PVA/PAMPS blend membranes for DMFCs applications.
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18

Dumé, Belle. "Propane powers fuel cell." Physics World 18, no. 7 (July 2005): 7. http://dx.doi.org/10.1088/2058-7058/18/7/9.

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19

Feng, Yu, Jingli Luo, and Karl T. Chuang. "Propane Dehydrogenation in a Proton-conducting Fuel Cell." Journal of Physical Chemistry C 112, no. 26 (June 6, 2008): 9943–49. http://dx.doi.org/10.1021/jp710141c.

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20

Xu, Changwei, Pei-Kang Shen, Dingsheng Yuan, and Shuangyin Wang. "Direct Alcohol Fuel Cell." International Journal of Electrochemistry 2011 (2011): 1. http://dx.doi.org/10.4061/2011/736594.

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21

Dudek, Magdalena, and Piotr Tomczyk. "Composite fuel for direct carbon fuel cell." Catalysis Today 176, no. 1 (November 2011): 388–92. http://dx.doi.org/10.1016/j.cattod.2010.11.029.

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22

Feng, Yu, Jing-Li Luo, and Karl T. Chuang. "Carbon deposition during propane dehydrogenation in a fuel cell." Journal of Power Sources 167, no. 2 (May 2007): 486–90. http://dx.doi.org/10.1016/j.jpowsour.2007.02.052.

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23

KAPUSTA, Łukasz. "Numerical simulations of dual fuel combustion in a heavy duty compression ignition engine." Combustion Engines 163, no. 4 (November 1, 2015): 47–56. http://dx.doi.org/10.19206/ce-116856.

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In this study dual fuel direct injection was studied in terms of utilizing in compression ignition engines gaseous fuels with high octane number which are stored in liquid form, specifically liquid propane. Due to the fact that propane is not as much knock-resistant as natural gas, instead of conventional dual fuel system a system based on simultaneous direct injection of two fuel was selected as the most promissing one. Dual fuel operation was compared with pure diesel operation. The performed simulations showed huge potential of dual fuel system for burning light hydrocarbons in heavy duty compression ignition engines. However, further secondary fuel injection system optimization is required in order to improve atomization and lower the emissions.
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24

Zerbinati, Orfeo, Ali Mardan, and Mark M. Richter. "A direct methanol fuel cell." Journal of Chemical Education 79, no. 7 (July 2002): 829. http://dx.doi.org/10.1021/ed079p829.

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25

Sarangapani, Srinivasan, Frank Luczak, Mohammad Enayetullah, Tom Vitella, and Paul Osenar. "Alkaline Direct Methanol Fuel Cell." ECS Transactions 1, no. 32 (December 21, 2019): 11–22. http://dx.doi.org/10.1149/1.2209385.

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26

Kulikovsky, A. A., H. Schmitz, and K. Wippermann. "Direct Methanol–Hydrogen Fuel Cell." Electrochemical and Solid-State Letters 10, no. 8 (2007): B126. http://dx.doi.org/10.1149/1.2745083.

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27

Morin, B., D. Van Laethem, C. Turpin, O. Rallières, S. Astier, A. Jaafar, O. Verdu, M. Plantevin, and V. Chaudron. "Direct Hybridization Fuel Cell - Ultracapacitors." Fuel Cells 14, no. 3 (June 2014): 500–507. http://dx.doi.org/10.1002/fuce.201300218.

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28

Yuh, Chao-Yi, Abdelkader Hilmi, Mohammad Farooque, T. Leo, and G. Xu. "Direct Fuel Cell Materials Experience." ECS Transactions 17, no. 1 (December 18, 2019): 637–54. http://dx.doi.org/10.1149/1.3142794.

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29

Jiang, Junhua, and Andrzej Wieckowski. "Prospective direct formate fuel cell." Electrochemistry Communications 18 (January 2012): 41–43. http://dx.doi.org/10.1016/j.elecom.2012.02.017.

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30

Su, Xin, Fujun Zhang, Yanxia Yin, Baofeng Tu, and Mojie Cheng. "Thermodynamic analysis and fuel processing strategies for propane-fueled solid oxide fuel cell." Energy Conversion and Management 204 (January 2020): 112279. http://dx.doi.org/10.1016/j.enconman.2019.112279.

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31

Moyer, David K., and Franklin H. Holcomb. "Carbonate Direct Fuel Cell Operation on Dual Fuel." Cogeneration & Distributed Generation Journal 22, no. 2 (April 2007): 51–60. http://dx.doi.org/10.1080/15453660709509113.

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32

Tran, K., T. Q. Nguyen, A. M. Bartrom, A. Sadiki, and J. L. Haan. "A Fuel-Flexible Alkaline Direct Liquid Fuel Cell." Fuel Cells 14, no. 6 (September 15, 2014): 834–41. http://dx.doi.org/10.1002/fuce.201300291.

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33

Tsutsumi, Yasuyuki, Takashi Moriyama, and Motoaki Komata. "Direct Fuel Cell Performance using Dimethyl Ether Fuel." IEEJ Transactions on Power and Energy 120, no. 4 (2000): 637–42. http://dx.doi.org/10.1541/ieejpes1990.120.4_637.

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34

Srichai, S., and S. Heng. "The Direct Ethanol Fuel Cell Performance." Advanced Materials Research 979 (June 2014): 79–82. http://dx.doi.org/10.4028/www.scientific.net/amr.979.79.

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The effect on performance of single direct ethanol cell due to ethanol solution concentrations (5%, 10% and 15% by volume, ambient temperature (and), continuously changing of ambient temperature ( and), load resistance ( and) and air circulation through the cell were investigated experimentally in this research. The results showed that fuel cells have a high performance at high concentration of ethanol solution, high ambient temperature or operated in the wide range of continuously changing of ambient temperature. The performance was measured by the amount of the initial voltage, current and power obtained from fuel cell. But increasing air circulation through the fuel cell does not affect the performance of cell. The voltage and power drop obtained from the fuel cell increase with varying resistance load. But the current decreases with increases resistance load.
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35

Monroe, DN, DJ Richard, AD Martin, DN Leonard, and PE Russell. "Direct Methanol Fuel Cell Materials Characterization." Microscopy and Microanalysis 15, S2 (July 2009): 1432–33. http://dx.doi.org/10.1017/s1431927609098493.

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36

Farooque, M., A. Hilmi, R. Venkataraman, and C. Y. Yuh. "Direct Fuel Cell DFC Durability Progress." ECS Transactions 51, no. 1 (June 26, 2013): 27–35. http://dx.doi.org/10.1149/05101.0027ecst.

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37

Farooque, Mohammad, Anthony Leo, R. Pawlaczyk, Anthony Rauseo, and Ramakrishnan Venkataraman. "Direct Fuel Cell Stack Module Evolution." ECS Transactions 26, no. 1 (December 17, 2019): 373–83. http://dx.doi.org/10.1149/1.3429010.

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38

Kuliyev, Sadig A., Sila Aksongur, Mahmut D. Mat, Beycan Ibrahimoğlu, and Mustafa D. Kozlu. "Direct Methanol Solid Oxide Fuel Cell." ECS Transactions 25, no. 2 (December 17, 2019): 1093–98. http://dx.doi.org/10.1149/1.3205636.

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39

Kouchachvili, Lia, and Michio Ikura. "Performance of direct carbon fuel cell." International Journal of Hydrogen Energy 36, no. 16 (August 2011): 10263–68. http://dx.doi.org/10.1016/j.ijhydene.2010.10.036.

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40

He, Zhenyu, Chaoqun Li, Chusheng Chen, Yongcheng Tong, Ting Luo, and Zhongliang Zhan. "Membrane-assisted propane partial oxidation for solid oxide fuel cell applications." Journal of Power Sources 392 (July 2018): 200–205. http://dx.doi.org/10.1016/j.jpowsour.2018.04.085.

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41

Du, Yanhai, Daan Cui, Kenneth Reifsnider, and Fanglin Chen. "Startup Characteristics of Propane-Fueled Solid Oxide Fuel Cell Hot Zones." ECS Transactions 35, no. 1 (December 16, 2019): 2735–44. http://dx.doi.org/10.1149/1.3570272.

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42

Liu, Z., Z. Mao, J. Xu, N. Hess-Mohr, and V. M. Schmidt. "Modelling of a PEM Fuel Cell System with Propane ATR Reforming." Fuel Cells 6, no. 5 (October 2006): 376–86. http://dx.doi.org/10.1002/fuce.200500104.

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43

Pi, Seuk-Hoon, Min-Je Cho, Jong-Won Lee, Seung-Bok Lee, Tak-Hyoung Lim, Seok-Joo Park, Rak-Hyun Song, and Dong-Ryul Shin. "Fabrication of Electrolyte for Direct Carbon Fuel Cell and Evaluation of Properties of Direct Carbon Fuel Cell." Korean Chemical Engineering Research 49, no. 6 (December 1, 2011): 786–89. http://dx.doi.org/10.9713/kcer.2011.49.6.786.

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44

KAJITANI, Shuichi, Takatoshi FURUKAWA, Seigo YOSHIMITU, Suguru TASHIRO, Yasuyuki TSUTSUMI, and Susumu YAMASITA. "Comparison of Direct Fuel Cell Performance Feeding Liquid Fuel and Gas Fuel." Proceedings of Ibaraki District Conference 2003 (2003): 219–20. http://dx.doi.org/10.1299/jsmeibaraki.2003.219.

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45

Tsutsumi, Yasuyuki, Yasuhiro Nakano, and Tadao Haraguchi. "Fuel Cross Leak of Direct Di-methyl-ether Fuel Cell." IEEJ Transactions on Power and Energy 124, no. 4 (2004): 661–67. http://dx.doi.org/10.1541/ieejpes.124.661.

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46

Jamard, Romain, Antoine Latour, Jeremie Salomon, Philippe Capron, and Audrey Martinent-Beaumont. "Study of fuel efficiency in a direct borohydride fuel cell." Journal of Power Sources 176, no. 1 (January 2008): 287–92. http://dx.doi.org/10.1016/j.jpowsour.2007.10.036.

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47

Jin, S., H. Choi, D. Chun, J. Lim, Y. Rhim, S. Kim, S. Lee, and J. Yoo. "Ash-Free Coal as Fuel for Direct Carbon Fuel Cell." ECS Transactions 45, no. 29 (April 2, 2013): 259–66. http://dx.doi.org/10.1149/04529.0259ecst.

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48

Lee, Injae, Sunmi Jin, Donghyuk Chun, Hokyung Choi, Sihyun Lee, Kibong Lee, and Jiho Yoo. "Ash-free coal as fuel for direct carbon fuel cell." Science China Chemistry 57, no. 7 (May 10, 2014): 1010–18. http://dx.doi.org/10.1007/s11426-014-5105-z.

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49

Leo, T. J., M. A. Raso, E. Navarro, E. Sánchez de la Blanca, M. Villanueva, and B. Moreno. "Response of a direct methanol fuel cell to fuel change." International Journal of Hydrogen Energy 35, no. 20 (October 2010): 11642–48. http://dx.doi.org/10.1016/j.ijhydene.2010.02.115.

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50

Jewulski, Janusz, Marek Skrzypkiewicz, Michal Struzik, and Iwona Lubarska-Radziejewska. "Lignite as a fuel for direct carbon fuel cell system." International Journal of Hydrogen Energy 39, no. 36 (December 2014): 21778–85. http://dx.doi.org/10.1016/j.ijhydene.2014.05.039.

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