Academic literature on the topic 'Dissertations, Academic Drinking Water'

Universal access to clean and safe drinking water is essential for life maintenance since exposure to poor quality water is harmful to health. Drinking water quality is part of public health actions and, together with sanitation, a human right essential for life and a sustainable development goal. Moreover, an independent surveillance system conducted by the Ministry of Health or government agencies is needed for the safety of drinking water quality. We propose a scoping review protocol to identify and map worldwide surveillance actions and initiatives of drinking water quality implemented by government agencies or public health services. This scoping review protocol is based on the Joanna Briggs Institute manual and guided by the PRISMA-ScR. Articles, theses, dissertations, and official documents consulted in the following databases will be included: Medline/PubMed, Scopus, LILACS, Web of Science, Embase, Engineering Village, and gray literature. No date limit or language will be determined. The authors will develop a worksheet for data extraction. Quantitative (simple descriptive statistics) and qualitative data (thematic analysis) will be analyzed. The final scoping review will present the main findings, impacts, challenges, limitations, and possible research gaps related to surveillance of drinking water quality on population health.

An experiment was conducted to explore the drinking water quality at some selected academic institutions of Tangail municipality during the period of August to September, 2012. For this, an investigation was carried out to study the standard water quality parameters such as pH, EC, TDS, Pb, As, Fe and E. coli concentration of the five academic institutions. In general, there were no major differences found in pH, EC and TDS values among the studied stations and not exceeded the recommended thresholds. In case of heavy metal content, very trace amount of Arsenic (0.0071ppm) was recorded from all selected institutions. In contrast, average lead concentration (0.307xppm) was much higher than all acceptable standard limits and most risky position was taken by station-3 (0.46ppm). Similar to Pb, average Fe concentration (0.255ppm) was five times higher than the acceptable value of EU standard but not exceeded BD standard value. All the samples were E.Coli bacteria free.DOI: http://dx.doi.org/10.3329/jesnr.v6i1.22074 J. Environ. Sci. & Natural Resources, 6(1): 247-252 2013

Abstract Drinking water is an important source of lead exposure, and definitively characterizing the sources of lead in drinking water, particularly in large institutional settings, can be time-consuming and costly. This study examined lead concentrations in drinking water at a large university, focusing on variability in first-draw samples and variability with dispensed volume. Over 350 sources were sampled twice by independent groups, and while 78% of these samples were within 2.5 μg/L, almost 10% differed by >10 μg/L. In both sampling events, approximately 50% of sources had lead concentrations >1 μg/L, 6% were >15 μg/L, and 30% were between 1 and 15 μg/L. The highest lead concentration detected was 400 μg/L, with five sources >100 μg/L. Nine sources were sampled more intensively and six had first-draw sample ranges >5 μg/L. Lead concentration versus dispensed volume profiles indicated that while most sources had decreasing lead concentrations after the first draw, others had maximum lead concentrations at higher dispensed volumes. The variability observed suggests that assessments using only one or two samples per source may not identify all sources with elevated lead concentrations, and management strategies should account for this possibility.

Is drinking water safe? A neglected source of asbestos fibres For decades the health risks of asbestos have been discussed among academics, companies and countries, but nowadays its harmfulness is recognised worldwide. Still in 1997, when asbestos use was banned in French, Canada (the main producer of chrysotile) sustained its innocuity; 3 years later, the carcinogenicity of chrysotile was set off by the World Trade Organization. In this academic article, Prof. Giovanni Brandi and Dr. Simona Tavolari investigate the prevalence of asbestos fibres in drinking water around the world.

Purpose Although access to safe drinking water is one of the most important health-related infrastructure programs in the world, drinking water remains a large problem in China today, especially in rural areas. Despite increased government investment in water resource protection and management, there is still an absence of academic studies that are able to document what path the investment has taken and whether it has had any tangible impact. The purpose of this paper is to analyze the impact of drinking water investment on drinking water in China. Design/methodology/approach The authors make use of nationally representative data from 2005 and 2012 to measure the impact of drinking water investment among 2,028 rural households in 101 villages across five provinces. Both ordinary least squares regression and probit regression are used to analyze the correlates and the impact of drinking water investment. Findings The authors demonstrate that water quality was likely a significant problem in 2004 but that China’s investment into drinking water appears to have resulted in initial improvements during the study period. The authors show that the most significant change came about in terms of hardware: villages that received more drinking water investment now have more piped tap water and more access to water treatment infrastructure (disinfecting and filtering facilities). High rates of rural resident satisfaction with drinking water suggest the effects of drinking water investment are being felt at the village level. Originality/value To the authors’ knowledge, this is the first empirical study on drinking water investment over time in rural China using nationally representative data.

IntroductionAlcohol consumption is a considerable public health problem that is especially harmful to young people. To develop effective prevention programmes targeted at adolescents, it is important to understand the social mechanisms triggering alcohol consumption. Among such mechanisms, peer influence plays an important role. The effects of peer influence are very difficult to evaluate because of the entanglement with social selection, that is, a tendency of people to befriend others with similar behaviour. The recently developed stochastic actor-oriented models (SAOM) approach is designed to disentangle social influence from social selection. The aim of this study is to conduct a systematic review and meta-analysis of studies employing SAOM methodology to evaluate the effects of social influence on adolescent drinking behaviour.Methods and analysisIn order to analyse the co-evolution of alcohol consumption and adolescent friendship networks, we will collect articles that use SAOM methodology through systematic electronic searches in Web of Science, Scopus, PubMed, The Cochrane Library (Cochrane Database of Systematic Reviews, Cochrane Central Register of Controlled Trials), EBSCOhost (MEDLINE, SocINDEX, Academic Source, ERIC), ProQuest (ProQuest Dissertations and Theses Global), PsycINFO (PsycNET), Excerpta Medica database (Embase) and Cumulative Index to Nursing and Allied Health Literature (CINAHL). We will collect the literature from academic journals, dissertations/theses, reports and conference materials. Three reviewers will retrieve and independently assess potentially relevant material in terms of whether they comply with prespecified criteria. Subsequently, we will summarise the results of the studies in a systematic review. If a sufficient number of studies can be found, SAOM quantitative results will be extracted and meta-analysed. The project will go from 1 December 2018 to 1 December 2019.Ethics and disseminationEthical approval will not be required as our work is based on published studies. A list of all the studies included in this work will be available for review. We plan dissemination in a peer-reviewed international scientific journal and through conference presentations. Our review will highlight the peer effect of peers in adolescent drinking behaviour and provide guidance for developing effective prevention and intervention programmes. We expect it to be informative for policy and practice, decision-making as well as for further research in public health and sociology of adolescents.PROSPERO registration numberCRD42019119836.

Abstract Identifying the demographic factors that affect patterns is very important for determining drinking water sources within a community. Previous empirical studies mainly focussed on demographic factors affecting water demand in urban and semi-urban areas facing water shortage with little rainfall. However, studies on water consumption in tropical regions (average annual ∼4,000 mm) is limited. This study aims to investigate relationships between drinking water patterns and demographic factors for Kuching community, Sarawak, Malaysia. Survey data were collected from 100 respondents using structured questionnaires through mail, drop-off and telephone surveys in March–December 2016. Results revealed that drinking water patterns are significantly correlated with source, income and education level. 46% of respondents preferred tap water as their drinking water source, followed by 31% for in-home water-treatment devices, 19% chose bottled water and only 4% still drink raw water. In terms of income and education level, 25% of respondents with diploma, degree and postgraduate academic qualifications, quantified as higher income group, installed in-home water-treatment devices. 21% of respondents with monthly income more than RM2500 also initiated installation of in-home water-treatment devices. In contrast, age, gender and religion were found to have little affect on drinking-water consumption patterns.

Green Campus is a campus environment that is designed to increase energy efficiency, preserve resource and improve the quality of the environment. One of the important elements to support the green campus program is the existence of drinking water supply system.Universitas Gadjah Mada Drinking Water Supply System (UGM-DWSS) is a drinking water or potable water supply service to supply drinking water for the campus. This research aims at analyzing UGM-DWSS potential and its performance to support Green Campus. This research was based on primary data collection in UGM campus. Data collection techniques consist of observation of UGM-DWSS facilities, interview with UGM-DWSS water managers and users, and questionnaires distribution to UGM academic community. The daily water production of UGM-DWSS was 10 l/s drinking water. Every day the water discharge distributed from UGM-DWSS to 49 water fountains and 12 water dispensers was1.71 l/s, while the estimated daily water consumption rate was0.07l/s. It is assumed that those who did not consume water from UGM-DWSS facilities bought plastic drinking water bottle. Every day, it is estimated that the number of generated plastic drinking water bottle waste was 19,168 bottles with capacity 600 ml/bottle. Indeed, by comparing to the total water production capacity being produced daily, the idle capacity was 99.3 %.The tendency of negative response from the majority of UGM inhabitants for using UGM –DWSS was due to hesitation about water quality, continuity of water supply, and ease of access to the nearby water fountains and water dispensers. Improvement of UGM-DWSS facilities that are supported by massive socialization programs including innovation to utilize produced drinking water is recommended to optimize the role of UGM-DWSS to create Green Campus.

This article provides updated status of the arsenic affected rural habitations in India, summarizes the policy initiatives of the Ministry of Drinking Water & Sanitation (Government of India), reviews the technologies for arsenic treatment and analyses the progress made by states in tackling arsenic problems in rural habitations. It also provides a list of constraints based on experiences and recommends suggested measures to tackle arsenic problems in an holistic manner. It is expected that the paper would be useful for policy formulators in states, non-government organizations, researchers of academic and scientific institutions and programme managers working in the area of arsenic mitigation in drinking water, especially in developing countries, as it provides better insights compared to other available information in India on mitigating arsenic problems in drinking water in rural areas.

This thesis documents the relationship among the major water quality parametersduring a nitrification episode. Nitrification unexpectedly occurred in a chloraminated pilotdrinking water distribution system practicing with a 4.0 mg/L as Cl[subscript 2] residual dosed at 4.5:1Cl[subscript 2]:NH[subscript 3]-N. Surface, ground and sea water were treated and disinfected withmonochloramines to produce finished water quality similar to regional utility water quality.PVC, galvanized, unlined cast iron and lined iron pipes were harvested from regionaldistribution systems and used to build eighteen pilot distribution systems (PDSs). The PDSswere operated at a 5-day hydraulic residence time (HRT) and ambient temperatures.As seasonal temperatures increased the rate of monochloramine dissipation increaseduntil effluent PDS residuals were zero. PDSs effluent water quality parameters chloraminesresidual, dissolved oxygen, heterotrophic plate counts (HPCs), pH, alkalinity, and nitrogenspecies were monitored and found to vary as expected by stoichiometry associated withtheoretical biological reactions excepting alkalinity. Nitrification was confirmed in thePDSs. The occurrence in the PDSs was not isolated to any particular source water.Ammonia for nitrification came from degraded chloramines, which was common among allfinished waters. Consistent with nitrification trends of dissolved oxygen consumption,ammonia consumption, nitrite and nitrate production were clearly observed in the PDSs bulkwater quality profiles. Trends of pH and alkalinity were less apparent. To controlnitrification: residual was increased to 4.5 mg/L as Cl[subscript 2] at 5:1 Cl[subscript 2]:NH[subscript 3]-N dosing ratio, and theHRT was reduced from 5 to 2 days. Elimination of the nitrification episode was achieved after a 1 week free chlorine burn.<br>M.S.<br>Department of Civil and Environmental Engineering<br>Engineering and Computer Science<br>Civil and Environmental Engineering

The formation of an objectionable "swampy" odour in drinking water distribution systems in Perth, Western Australia, was first described by Wajon and co-authors in the mid-1980s (Wajon et al., 1985; Wajon et al., 1986; Wajon et al, 1988). These authors established that the odour, variously described as "swampy", "sewage" or "cooked vegetable" was caused by dimethyltrisulfide (DMTS) which has an odour threshold concentration of 10 nanograms per litre (ng/L). Investigations described in the present Thesis extend the work of Wajon and co-workers in attempting to establish the origin and cause of DMTS formation in Perth drinking water distribution systems.The DMTS problem appeared to be confined to water originating from a particular type of groundwater, specifically groundwater sourced from shallow, unconfined aquifers, which contain relatively high concentrations of sulfide, dissolved natural organic matter (NOM) and dissolved iron. DMTS was not present in the groundwater, but only formed in the distribution system, after treatment of groundwater via alum coagulation-filtration and oxidation processes. One objective of the present work was to determine the reasons for the observed association between DMTS formation and this specific groundwater type. A primary focus was to investigate the chemistry and biochemistry of sulfur species and NOM which might act as precursors to DMTS. The work was driven by the view that increased understanding of the problem might lead to more effective and acceptable treatment solutions than those presently in use.The observation that DMTS forms in distributed water that originates from groundwater, but not in water from surface sources has led to the hypothesis that groundwater NOM may contain precursor(s) to DMTS For example, it was proposed that methyl esters and ethers within humic substances might be a source of methyl groups that ++<br>could participate in DMTS formation in distributed water (Wajon and Heitz, 1995; Wajon and Wilmot, 1992). Further, comparison of levels of reduced sulfur with levels of dissolved organic carbon (DOC) in groundwaters feeding Wanneroo GWTP revealed that a positive correlation between these two parameters existed. This observation provided further impetus to examine the nature of NOM in these groundwater systems. In the present study (discussed in Chapter 3), NOM from two Perth drinking water sources was isolated and characterised, with the aim of identifying major differences in structure and/or functional groups that might influence DMTS formation. NOM was isolated from water samples using ultrafiltration, and characterised using pyrolysis gas chromatography-mass spectrometry (Py-GC-MS) and offline- thermochemolysis/methylation (TCM). Pyrolysis of groundwater NOM yielded a high proportion of organosulfur compounds, primarily methyl thiophenes and sulfur gases, but did not yield detectable amounts of methoxy-aromatic compounds. Analysis by TCM yielded sulfur compounds tentatively identified as the methyl esters of methylthiopropanoate and methylthiobutanoate, compounds that may arise as degradation products of dimethylsulfoniopropionate (DMSP), an algal odmoregulator Compounds such as DMPS could potentially undergo reactions to form DMTS in distributed water.The task of investigating the formation of nanogram-per-litre concentrations of DMTS demanded the development of new analytical procedures that could be used to determine similarly low concentrations of DMTS precursors. Evidence existed to suggest that inorganic polysulfides could be plausible precursor compounds, and since no technique existed to analyse and quantify individual polysulfide homologues a new technique needed to be developed and verified. The technique, first used in a semiquantitative manner by ++<br>Wajon and Heitz (1995), utilizes methyl iodide to derivatise polysulfides in-situ. The technique was developed further and shown to be quantitative and specific for inorganic polysulfides. Further, a new procedure for the determination of d i methyl polysulfides (DMPSs; CH3SnCH3, where n = 2-5), based on purge and trap was developed. In this new procedure analytes were trapped on a "Grob" activated charcoal tube, which was integrated into a commercially available, automated purge and trap instrument. Perdeuterated analogues of the DMPS analytes were synthesized and used as internal standards. These modifications resulted in a more rapid and robust procedure than the previously used procedures, vii which were based on closed loop stripping analysis (CLSA). Validation of the precision, accuracy, linearity and robustness of the new procedures for both inorganic polysulfides and dimethylpolysulfides is described in Chapter 4.Previous authors (Wajon and Heitz, 1995; Wajon and Wilmot, 1992; Wilmot and Wajon, 1997) hypothesized that DMTS could arise in the distribution system from residual polysulfides or other reduced sulfur compounds originating from groundwater. The latter authors showed that a small proportion of sulfide in the groundwater was not completely oxidised to sulfate during the water treatment process and proposed that this residual reduced sulfur fraction, which they referred to as non-sulfide reduced sulfur (NSRS) could contain precursors to DMTS. In a review of the chemistry of sulfide oxidation (Chapter 2) it was shown that the most likely forms of sulfur comprising the NSRS that enters the Wanneroo distribution system are organosulfur compounds and elemental sulfur, probably associated with organic matter in the form of a sulfur sol.Analysis of inorganic polysulfides in treated water, using the newly described method in Chapter 4, revealed that small ++<br>amounts of these compounds (20-80 ng/L) were occasionally present in some samples. However, it was concluded that, since inorganic polysulfides could not survive water treatment processes, these compounds probably arose from traces of biofilm or pipe sediment that may have entered the water during sampling. It was proposed that the presence of biofilm particulates in water samples probably also accounted for observations that DMTS appeared to form in some water samples during storage of the sample. These studies are discussed in Chapter 5.The primary method of control of DMTS formation in the distribution system has been to maintain free chlorine residuals. However, the mechanisms by which this occurs have not been studied; the effectiveness of DMTS oxidation by chlorine, or how chlorine affects microbial processes that might form DMTS is not known. These issues are addressed in the final section of Chapter 5. Experiments to determine the effectiveness of oxidation of dimethyldisulfide (DMDS) and DIVITS (5 mu g/L) by free chlorine (0.2 to 0.6 mg/L) in distributed water showed that these substances are rapidly and completely oxidised in water containing a chlorine residual of more than 0.4 mg/L. However, slow regeneration of traces of DMDS and DIVITS after dissipation of free chlorine to non-detectable levels showed that these compounds were incompletely oxidised at the lower chlorine concentrations~ This provides some rationale for field observations that DIVITS occurs even where low, but measurable, chlorine residuals appear to exist (<0.2 mg/L).As was established in a review of the chemistry of reduced sulfur compounds Chapter 2), reducing conditions not present in the oxic bulk water are required for DMTS to form and to persist. It was therefore proposed that microbial reduction processes could generate anoxic microniches in the distribution system, within which ++<br>DMTS production could occur. This hypothesis was investigated in Chapter 6; the new methods for analysis of organic and inorganic polysulfides were applied to the study of biofilms and deposits of colloidal material found in distribution pipes and storage reservoirs. The study demonstrated that these materials contained concentrations of methylated and inorganic polysulfides four to six orders of magnitude higher than those ever found in the bulk water phase. The results indicated that reducing conditions most probably exist within the biofilms and pipewall deposits, where these polysulfides were formed. The iron-rich pipe slimes appeared to protect the sulfur compounds against the oxidative effects of chlorine and dissolved oxygen. It was concluded that the organic and inorganic polysulfides most probably arise through microbial sulfate reduction processes that occur in anoxic microenvironments within the slimes and deposits.Microbial processes that lead to the formation of polysulfides and dimethylpolysuifides under conditions approximately representative of those in distribution systems were investigated in work described in Chapter 7. The aim of this work was to investigate the role of biofilms in the formation of DMTS and to determine the nature of chemical precursors which might stimulate these processes. Biofilms, artificially generated on synthetic supports within chambers filled with water from Wanneroo GWTP, were exposed to compounds thought to be potential DMTS precursors. The response of the systems in terms of production of methylated sulfur compounds was monitored. Conclusions of the study were that, under the test conditions, production of DMDS and DMTS could occur via several mechanisms and that these dimethyloligosulfides could be formed even without the addition of compounds containing sulfur or methyl moieties. DMTS did not form in the absence of ++<br>biofilms and it was therefore concluded that minimisation of biofilm activity was a key in preventing DMTS formation. Outcomes of the work imply that environments within distribution systems are complex and dynamic, as perhaps manifested by the intermittent nature of the DMTS problem.Finally, in Chapter 8 the conclusions to the present studies are summarised. It is shown how they underpin the rationale for proposed new treatment solutions aimed at preventing DMTS problems in the Wanneroo zone, primarily by minimising microbial activity and biofilm formation within distribution systems.

Biostability and related issues (e.g. nitrification) were investigated for 18 months in 18 pilot distribution systems, under various water quality scenarios. This study specifically investigated the impact of steady-state water changes on HPC levels in chlorinated and chloraminated distribution systems. Chlorination was more effective than chloramination in reducing HPC levels (1-2 log difference). There was a rapid increase in HPC corresponding to the change in steady-state water quality, which was observed in all PDS. Modeling effort demonstrated that HPC levels reached a maximum within five days after water quality change and return to initial level ten days after the change. Since alkalinity was used as a tracer of the steady-state water quality change, time to reach maximum HPC was related to a mixing model using alkalinity as a surrogate that confirmed alkalinity transition was complete in approximately eight days. Biostability was assessed by HPC levels, since no coliform were ever detected. It was observed that HPC levels would be above four logs if residual droped below 0.1-0.2 mg/L as Cl?, which is below the regulatory minimum of 0.6 mg/L as Cl?. Therefore bacterial proliferation is more likely to be controlled in distribution systems as long as residual regulatory requirements are met. An empirical modeling effort showed that residual, pipe material and temperature were the most important parameters in controlling HPC levels in distribution systems, residual being the only parameter that can be practically used by utilities to control biological stability in their distribution systems. Use of less reactive (i.e. with less chlorine demand) pipes is recommended in order to prevent residual depletion and subsequent bacterial proliferation.This study is investigated biofilm growth simultaneously with suspended growth under a wide range of water quality scenarios and pipe materials. It was found that increasing the degree of treatment led to reduction of biofilm density, except for reverse osmosis treated groundwater, which exerted the highest biofilm density of all waters. Biofilm densities on corrodible, highly reactive materials (e.g. unlined cast iron and galvanized steel) were significantly greater than on PVC and lined cast iron. Biofilm modeling showed that attached bacteria were most affected by temperature and much less by HRT, bulk HPC and residual. The model predicts biofilms will always be active for environments common to drinking water distribution systems. As American utilities do not control biofilms with extensive and costly AOC reduction, American utilities must maintain a strong residual to maintain biological integrity and stability in drinking water distribution systems.Nitrite and nitrate were considered the most suitable indicators for utilities to predict onset of a nitrification episode in the distribution system bulk liquid. DO and ammonia were correlated to production of nitrite and nitrate and therefore could be related to nitrification. However since ammonia and DO consumptions can be caused by other phenomena than nitrification (e.g. oxidation by disinfectant to nitrite and reduction at the pipe wall, respectively), these parameters are not considered indicators of nitrification.Ammonia-Oxidizing Bacteria (AOB) densities in the bulk phase correlated well with nitrite and nitrate production, reinforcing the fact that nitrite and nitrate are good monitoring tools to predict nitrification. Chloramine residual proved to be helpful in reducing nitrification in the bulk phase but has little effect on biofilm densities. As DO has been related to bacterial proliferation and nitrification, it can be a useful and inexpensive option for utilities in predicting biological instability, if monitored in conjunction with residual, nitrite and nitrate. Autotrophic (i.e. AOB) and heterotrophic (i.e. HPC) organisms were correlated in the bulk phase and biofilms.<br>Ph.D.<br>Department of Civil and Environmental Engineering<br>Engineering and Computer Science<br>Civil and Environmental Engineering

This dissertation consists of five papers concerning nitrification in chloraminated drinking water distribution systems in a one and a half year field study. Seven finished waters were produced from different treatment processes and distributed to eighteen pilot distribution systems (PDSs) that were made pipes taken from actual distribution systems. Unlined cast iron (UCI), galvanized steel (G), lined cast iron (LCI), and PVC pipes were used to build the PDSs. All finished waters were stabilized and chloraminated before entering the PDSs. This dissertation consists of five major parts. (1) System variations of nitrates, nitrites, DO, pH, alkalinity, temperature, chloramine residuals and hydraulic residence times (HRT) during biological nitrification are interrelated and discussed relative to nitrification, which demonstrated Stoichiometric relationships associated with conventional biochemical nitrification reactions. Ammonia is always released when chloramines are used for residual maintenance in drinking water distribution systems, which practically insures the occurrence of biological nitrification to some degree. Biological nitrification was initiated by a loss of chloramine residual brought about by increasing temperatures at a five day HRT, which was accompanied by DO loss and slightly decreased pH. Ammonia increased due to chloramine decomposition and then decreased as nitrification began. Nitrites and nitrates increased initially with time after the chloramine residual was lost but decreased if denitrification began. Dissolved oxygen limited nitrifier growth and nitrification. No significant alkalinity variation was observed during nitrification. Residual and nitrites are key parameters for monitoring nitrification in drinking water distribution systems. (2) Using Monod kinetics, a steady state plug-flow kinetics model was developed to describe the variations of ammonia, nitrite and nitrate-N concentrations in a chloraminated distribution system. Active AOB and NOB biomass in the distribution system was determined using predictive equations within the model. The kinetic model used numerical analysis and was solved by C language to predict ammonia, nitrite, nitrate variation. (3) Nitrification control strategies were investigated during an unexpected episode and controlled study in a field study. Once nitrification began, increasing chloramine dose from 4.0 to 4.5 mg/L as Cl? and Cl?:N ratio from 4/1 to 5/1 did not stop nitrification. Nitrification was significantly reduced but not stopped, when the distribution system hydraulic retention time was decreased from 5 to 2 days. A free chlorine burn for one week at 5 mg/L Cl? stopped nitrification. In a controlled nitrification study, nitrification increased with increasing free ammonia and Cl?:N ratios less than 5. Flushing with increased chloramine concentration reduced nitrification, but varying flush frequency from 1 to 2 weeks had no effect on nitrification. (4) HPC variations in a chloraminated drinking water distribution system were investigated. Results showed average residual and temperature were the only water quality variables shown to affect HPC change at a five day distribution system hydraulic residence time was five days. Once nitrification began, HPC change was correlated to HRT, average residual and generated nitrite-N in the distribution system. (5) Biostability was assessed for water treatment processes and distribution system pipe by AOCs, BDOCs, and HPCs of the bulk water, and by PEPAs of the attached biofilms. All membrane finished waters were more likely to be biologically stable as indicated by lower AOCs. RO produced the lowest AOC. The order of biofilm growth by pipe material was UCI > G > LCI > PVC. Biostability decreased as temperature increased.<br>Ph.D.<br>Department of Civil and Environmental Engineering<br>Engineering and Computer Science<br>Civil and Environmental Engineering

The formation of an objectionable "swampy" odour in drinking water distribution systems in Perth, Western Australia, was first described by Wajon and co-authors in the mid-1980s (Wajon et al., 1985; Wajon et al., 1986; Wajon et al, 1988). These authors established that the odour, variously described as "swampy", "sewage" or "cooked vegetable" was caused by dimethyltrisulfide (DMTS) which has an odour threshold concentration of 10 nanograms per litre (ng/L). Investigations described in the present Thesis extend the work of Wajon and co-workers in attempting to establish the origin and cause of DMTS formation in Perth drinking water distribution systems.The DMTS problem appeared to be confined to water originating from a particular type of groundwater, specifically groundwater sourced from shallow, unconfined aquifers, which contain relatively high concentrations of sulfide, dissolved natural organic matter (NOM) and dissolved iron. DMTS was not present in the groundwater, but only formed in the distribution system, after treatment of groundwater via alum coagulation-filtration and oxidation processes. One objective of the present work was to determine the reasons for the observed association between DMTS formation and this specific groundwater type. A primary focus was to investigate the chemistry and biochemistry of sulfur species and NOM which might act as precursors to DMTS. The work was driven by the view that increased understanding of the problem might lead to more effective and acceptable treatment solutions than those presently in use.The observation that DMTS forms in distributed water that originates from groundwater, but not in water from surface sources has led to the hypothesis that groundwater NOM may contain precursor(s) to DMTS For example, it was proposed that methyl esters and ethers within humic substances might be a source of methyl groups that could participate in DMTS formation in distributed water (Wajon and Heitz, 1995; Wajon and Wilmot, 1992). Further, comparison of levels of reduced sulfur with levels of dissolved organic carbon (DOC) in groundwaters feeding Wanneroo GWTP revealed that a positive correlation between these two parameters existed. This observation provided further impetus to examine the nature of NOM in these groundwater systems. In the present study (discussed in Chapter 3), NOM from two Perth drinking water sources was isolated and characterised, with the aim of identifying major differences in structure and/or functional groups that might influence DMTS formation. NOM was isolated from water samples using ultrafiltration, and characterised using pyrolysis gas chromatography-mass spectrometry (Py-GC-MS) and offline- thermochemolysis/methylation (TCM). Pyrolysis of groundwater NOM yielded a high proportion of organosulfur compounds, primarily methyl thiophenes and sulfur gases, but did not yield detectable amounts of methoxy-aromatic compounds. Analysis by TCM yielded sulfur compounds tentatively identified as the methyl esters of methylthiopropanoate and methylthiobutanoate, compounds that may arise as degradation products of dimethylsulfoniopropionate (DMSP), an algal odmoregulator Compounds such as DMPS could potentially undergo reactions to form DMTS in distributed water.The task of investigating the formation of nanogram-per-litre concentrations of DMTS demanded the development of new analytical procedures that could be used to determine similarly low concentrations of DMTS precursors. Evidence existed to suggest that inorganic polysulfides could be plausible precursor compounds, and since no technique existed to analyse and quantify individual polysulfide homologues a new technique needed to be developed and verified. The technique, first used in a semiquantitative manner by Wajon and Heitz (1995), utilizes methyl iodide to derivatise polysulfides in-situ. The technique was developed further and shown to be quantitative and specific for inorganic polysulfides. Further, a new procedure for the determination of d i methyl polysulfides (DMPSs; CH3SnCH3, where n = 2-5), based on purge and trap was developed. In this new procedure analytes were trapped on a "Grob" activated charcoal tube, which was integrated into a commercially available, automated purge and trap instrument. Perdeuterated analogues of the DMPS analytes were synthesized and used as internal standards. These modifications resulted in a more rapid and robust procedure than the previously used procedures, vii which were based on closed loop stripping analysis (CLSA). Validation of the precision, accuracy, linearity and robustness of the new procedures for both inorganic polysulfides and dimethylpolysulfides is described in Chapter 4.Previous authors (Wajon and Heitz, 1995; Wajon and Wilmot, 1992; Wilmot and Wajon, 1997) hypothesized that DMTS could arise in the distribution system from residual polysulfides or other reduced sulfur compounds originating from groundwater. The latter authors showed that a small proportion of sulfide in the groundwater was not completely oxidised to sulfate during the water treatment process and proposed that this residual reduced sulfur fraction, which they referred to as non-sulfide reduced sulfur (NSRS) could contain precursors to DMTS. In a review of the chemistry of sulfide oxidation (Chapter 2) it was shown that the most likely forms of sulfur comprising the NSRS that enters the Wanneroo distribution system are organosulfur compounds and elemental sulfur, probably associated with organic matter in the form of a sulfur sol.Analysis of inorganic polysulfides in treated water, using the newly described method in Chapter 4, revealed that small amounts of these compounds (20-80 ng/L) were occasionally present in some samples. However, it was concluded that, since inorganic polysulfides could not survive water treatment processes, these compounds probably arose from traces of biofilm or pipe sediment that may have entered the water during sampling. It was proposed that the presence of biofilm particulates in water samples probably also accounted for observations that DMTS appeared to form in some water samples during storage of the sample. These studies are discussed in Chapter 5.The primary method of control of DMTS formation in the distribution system has been to maintain free chlorine residuals. However, the mechanisms by which this occurs have not been studied; the effectiveness of DMTS oxidation by chlorine, or how chlorine affects microbial processes that might form DMTS is not known. These issues are addressed in the final section of Chapter 5. Experiments to determine the effectiveness of oxidation of dimethyldisulfide (DMDS) and DIVITS (5 mu g/L) by free chlorine (0.2 to 0.6 mg/L) in distributed water showed that these substances are rapidly and completely oxidised in water containing a chlorine residual of more than 0.4 mg/L. However, slow regeneration of traces of DMDS and DIVITS after dissipation of free chlorine to non-detectable levels showed that these compounds were incompletely oxidised at the lower chlorine concentrations~ This provides some rationale for field observations that DIVITS occurs even where low, but measurable, chlorine residuals appear to exist (<0.2 mg/L).As was established in a review of the chemistry of reduced sulfur compounds Chapter 2), reducing conditions not present in the oxic bulk water are required for DMTS to form and to persist. It was therefore proposed that microbial reduction processes could generate anoxic microniches in the distribution system, within which DMTS production could occur. This hypothesis was investigated in Chapter 6; the new methods for analysis of organic and inorganic polysulfides were applied to the study of biofilms and deposits of colloidal material found in distribution pipes and storage reservoirs. The study demonstrated that these materials contained concentrations of methylated and inorganic polysulfides four to six orders of magnitude higher than those ever found in the bulk water phase. The results indicated that reducing conditions most probably exist within the biofilms and pipewall deposits, where these polysulfides were formed. The iron-rich pipe slimes appeared to protect the sulfur compounds against the oxidative effects of chlorine and dissolved oxygen. It was concluded that the organic and inorganic polysulfides most probably arise through microbial sulfate reduction processes that occur in anoxic microenvironments within the slimes and deposits.Microbial processes that lead to the formation of polysulfides and dimethylpolysuifides under conditions approximately representative of those in distribution systems were investigated in work described in Chapter 7. The aim of this work was to investigate the role of biofilms in the formation of DMTS and to determine the nature of chemical precursors which might stimulate these processes. Biofilms, artificially generated on synthetic supports within chambers filled with water from Wanneroo GWTP, were exposed to compounds thought to be potential DMTS precursors. The response of the systems in terms of production of methylated sulfur compounds was monitored. Conclusions of the study were that, under the test conditions, production of DMDS and DMTS could occur via several mechanisms and that these dimethyloligosulfides could be formed even without the addition of compounds containing sulfur or methyl moieties. DMTS did not form in the absence of biofilms and it was therefore concluded that minimisation of biofilm activity was a key in preventing DMTS formation. Outcomes of the work imply that environments within distribution systems are complex and dynamic, as perhaps manifested by the intermittent nature of the DMTS problem.Finally, in Chapter 8 the conclusions to the present studies are summarised. It is shown how they underpin the rationale for proposed new treatment solutions aimed at preventing DMTS problems in the Wanneroo zone, primarily by minimising microbial activity and biofilm formation within distribution systems.

This item is only available in print in the UCF Libraries. If this is your Honors Thesis, you can help us make it available online for use by researchers around the world by following the instructions on the distribution consent form at http://library.ucf.edu/Systems/DigitalInitiatives/DigitalCollections/InternetDistributionConsentAgreementForm.pdf You may also contact the project coordinator, Kerri Bottorff, at kerri.bottorff@ucf.edu for more information.<br>Bachelors<br>Engineering and Computer Science<br>Environmental Engineering

This integrative review of the literature focused on sodium (Na) content in drinking water (H?O) supplies and the subsequent effect on blood pressure levels in children. Studies for this review were drawn from the Cumulative Index of Nursing and Allied Health, PubMED, Science and Technology Databases, PsychInfo, United States (US) Environmental Protection Agency (EPA) and EPA in Florida websites. Criterion for inclusion in the data base searches were hypertension, high blood pressure, sodium in drinking water, drinking water salinity, children or preg'. Subsequently, further article selection criteria included children (under 18 years of age) and published in the English language (N=59). Findings of the review as summarized in this thesis could guide nursing research, education, policy and practice related to primary, secondary and tertiary interventions associated with sodium levels in drinking as a contributing factor to blood pressure levels in children.<br>B.S.N.<br>Bachelors<br>Nursing<br>Nursing

Drinking water distribution systems are inherently vulnerable to malicious contaminant events with environmental health concerns such as total trihalomethanes (TTHMs), lead, and chlorine residual. In response to the needs for long-term monitoring, one of the most significant challenges currently facing the water industry is to investigate the sensor placement strategies with modern concepts of and approaches to risk management. This study develops a Rule-based Decision Support System (RBDSS) to generate sensor deployment strategies with no computational burden as we oftentimes encountered via large-scale optimization analyses. Three rules were derived to address the efficacy and efficiency characteristics and they include: 1) intensity, 2) accessibility, and 3) complexity rules. To retrieve the information of population exposure, the well-calibrated EPANET model was applied for the purpose of demonstration of vulnerability assessment. Graph theory was applied to retrieve the implication of complexity rule eliminating the need to deal with temporal variability. In case study 1, implementation potential was assessed by using a small-scale drinking water network in rural Kentucky, the United States with the sensitivity analysis. The RBDSS was also applied to two networks, a small-scale and large-scale network, in "The Battle of the Water Sensor Network" (BWSN) in order to compare its performances with the other models. In case study 2, the RBDSS has been modified by implementing four objective indexes, the expected time of detection (Z1), the expected population affected prior to detection (Z2), the expected consumption of contaminant water prior to detection, and the detection likelihood (Z4), are being used to evaluate RBDSS's performance and compare to other models in Network 1 analysis in BWSN. Lastly, the implementation of weighted optimization is applied to the large water distribution analysis in case study 3, Network 2 in BWSN.<br>ID: 029809979; System requirements: World Wide Web browser and PDF reader.; Mode of access: World Wide Web.; Errors in paging: p. 46 followed by 57-84; page number 64 repeats.; Thesis (M.S.Env.E.)--University of Central Florida, 2011.; Includes bibliographical references (p. 80-84).<br>M.S.Env.E.<br>Masters<br>Civil, Environmental and Construction Engineering<br>Engineering and Computer Science<br>Environmental Engineering

University of Central Florida College of Engineering Thesis<br>Cryptosporidium parvum is a common surface water contaminant that can cause illness in human beings. The presence of this etiological agent in groundwater identifies the groundwater as under the direct influence (GWUDI) of surface water. Currently the determination of SWUDI water sources requires an expensive, labor-intensive laboratory procedure call the Microscopic Particulate Analysis (MPA). The results of the MPA provide a risk index that rates the degree of surface water contamination. The objective of this study is to identify other methods of identifying GWUDI of surface waters, such as well characteristics and hydrogeologic factors which may contribute to higher MPA risk indices. In order to determine which public water systems that are GWUDI, a total of sixty-two wells a water treatment systems suspected of bein GWUDI were investigated. The wells sampled were distributed across seven countried in the Central Florida region. Water samples were collected and analyzed at the Department of Health Laboratory in Tampa, Florida using the MPA. The study also investigated the well characteristics and the hydrogeology of the well locations. The results also showed that 13% of the wells sampled were in the high risk range while 29% and 58% of the wells sampled were within the moderate and low risk ranges, respectively. It was also observed that some well characteristics and the hydrogeology of an area generally influence the MPA risk index. The results also suggested that older well tend to have higher risk. Karst regions were observed to be susceptible to a higher risk than sandy areas.<br>M.S.<br>Masters<br>Civil and Environmental Engineering<br>Engineering<br>Water Resources Engineering<br>186 p.<br>xi, 186 leaves, bound : ill. ; 28 cm.

Thesis submitted in partial fulfilment of the requirements for the degree of MAGISTER TECHNOLOGIAE: CHEMICAL ENGINEERING in the FACULTY OF ENGINEERING at the CAPE PENINSULA UNIVERSITY OF TECHNOLOGY 2013<br>This study focused on quantifying two types of internationally regulated contaminants found in drinking water: 1) Trihalomethanes (THMs) and 2) Perfluorinated compounds (PFCs). The first contaminants monitored were THMs, classified as a group of chemicals that are formed along with others during the disinfection of water using liquid chlorine, chlorine dioxide or chlorine gas. Hence, the resulting compounds are called disinfection by-products (DBPs). The disinfectant reacts with natural organic matter in water to form common THMs, which include chloroform (CHCl3 or CF), bromodichloromethane (CHCl2Br or BDCM), dibromochloromethane (CHClBr2 or DBCM) and bromoform (CHBr3 or BF), with chloroform being the most common in chlorinated water systems. The current study has focused on THMs for two primary reasons: 1) THMs have raised significant concern as a result of evidence that associate their presence in drinking water with potential adverse human health effects, including cancer and 2) the levels of THMs in drinking water post-treatment is not monitored regularly in South Africa and thus far, there is inadequate and limited information about their concentration levels for drinking water treatment plants (DWTPs) and distribution stations (DWDSs) of the Western Cape, South Africa before, distribution to various suburbs, including townships. THMs normally occur at higher levels than any other known DBPs and their presence in treated water is a representative of the occurrence of many other DBPs. THMs were quantified in chlorinated drinking water obtained from seven (7) DWTPs, namely; Atlantis, Blackheath, Faure, Brooklands, Steenbras, Voelvlei and Wemmershoek, and one DWDS in Plattekloof. This included determining THMs concentration in tap water collected from various suburbs including townships, to assist local authorities in obtaining information on their concentration and whether or not the presence of residual chlorine and organic matter on post-treatment results has increased THMs at the point of use. THM analysis was performed using liquid-liquid extraction/gas chromatography with electron capture detector (LLE-GC-ECD) analytical process according to the EPA method 501.2, which was used with minor modifications. The instrument operational conditions were as follows: Column → DB5-26, 30 mm, 0.53 mm, 1.0 μm df HP-1 (Agilent Technologies, USA); Carrier gas → Helium at a constant inlet pressure of 15 kPa; Make-up gas → 99.9% Nitrogen gas at 60 L/min; Injector temperature → 40°C; Oven temperature → 270°C and Detector temperature → 300°C. Since natural organic matter (NOM) in raw water is a precursor for THM formation, NOM analysis was performed as total organic carbon (TOC) using Spectroquant TOC test kits. Other drinking water quality parameters analysed were pH, residual free chlorine, conductivity and total dissolved solids (TDS). The average Total THM concentrations detected from seven of the DWTPs, including the DWDS, ranged from 26.52 μg/L (for Plattekloof) to 32.82 μg/L (for Brooklands), with the observed concentrations being comparable. The average chloroform concentrations were the highest in all the water samples, ranging from 11.74 μg/L (for Plattekloof) to 22.29 μg/L (for Voelvlei), while DBCM had the lowest concentration. The only DWTP that was not comparable with the seven DWTPs was Atlantis, with the highest average TTHM concentration of 83.48 μg/L and a chloroform concentration of 46.06 μg/L. From the tap water samples collected from 14 Western Cape suburbs, the average TTHM concentrations ranged from 5.30 ug/L (for Mandalay) to 13.12 μg/L (for Browns Farm, Philippi), and all these concentrations were lower than the TTHM concentrations detected in the water samples from the DWTP. Overall, the average total THM and individual THM species concentrations were below the recommended SANS 241:2011 and WHO drinking water guideline limits. This included the observed pH (6.39 to 7.73), residual free chlorine (0.22 to 1.06 mg/L), conductivity (121 to 444 μS/cm), TDS (93.93 to 344.35 mg/L) and TOC (0.38 to 1.20 mg/L). All these water quality parameters were within the specification limits stipulated in SANS 241. However, the average residual free chlorine concentration for Atlantis was very low (0.06 mg/L), which was below the WHO minimum residual free chlorine concentration guideline value of 0.2 mg/L for a distribution network – an indication that suggested the need for a re-chlorination station prior to distribution to households. Low chlorine content might result in the formation of unwanted biofilms in the distribution network, thus reducing the organoleptic properties of the water. Additionally, there was no direct link between several water quality parameters quantified (i.e. pH, TOC and water temperature) to TTHM formation. However, a high chlorine dose was observed to result directly in a higher concentration of chloroform in treated water prior to distribution. The second contaminants monitored were Perfluorinated compounds (PFCs), which are non-biodegradable, persistent and toxic organic chemicals known for their ability to contaminate environmental matrices, including drinking water sources. In recent years, many researchers considered it essential to identify and quantify PFC levels in drinking water worldwide with the main focus being on the two most abundant PFCs; namely Perfluorooctanoic acid (PFOA) and Perfluorooctane sulfonate (PFOS). Their toxic effects to human health, plants and wildlife were also evaluated, classifying them as possible carcinogens. We know from the literature reviewed that, although the presence of PFCs in drinking water has been documented worldwide, there is limited information about their presence specifically in South African drinking water sources, even about less studied PFCs such as Perfluoroheptanoic acid (PFHpA), Perfluorododecanoic acid (PFDoA), Perfluorononanoic acid (PFNA), Perfluoroundecanoic acid (PFUA), Perfluorodecanoic acid (PFDeA) and the well-known PFOA including PFOS. Although several other PFCs have been detected in water sources and reported in various studies, the USEPA only issued drinking water guideline limits for Perfluorooctanoic acid (PFOA) and Perfluorooctane sulfonate (PFOS) of 400 ng/L and 200 ng/L, respectively, with no mention of the other PFCs. However, these PFCs have similar properties to those of PFOA and PFOS as they have been shown to impose similar detrimental health effects on human health. This study thus focused on the detection of PFCs in both raw and treated drinking water in the Western Cape DWTPs such as Atlantis, Blackheath, Faure, Brooklands, Steenbras, Voelvlei and Wemmershoek, and one DWDS in Plattekloof. Water samples (raw and treated water) used in this study for PFC analysis were collected in 2L polypropylene screw capped bottles. PFC analysis was performed in four sample batches for each location collected through the period of October to December 2012 (summer). PFCs were analysed in accordance with a modified EPA method 537, which entails solid phase extraction (SPE) followed by analysis using a liquid chromatography/tandem mass spectrometer (LC/MS/MS). The slight modification was with the water sample volume used for extraction, which was increased from 250 mL to 500 mL. The instrument used was an HPLC - Ultimate 3000 Dionex HPLC system and MS model - Amazon SL Ion Trap, with the following MS/MS operational conditions and Ion mode: MS Interface → ESI; Dry temp → 350C; Nebulizing pressure → 60 psi; Dry gas flow → 10 L/min; Ionisation mode → negative; capillary voltage → +4500V; End plate offset → −500V while the separation column was a Waters Sunfire C18, 5 μm, 4.6 × 150 mm column (Supplier: Waters, Dublin, Ireland) with an operational temperature of 30C. From the results obtained in this study, seven different PFCs (i.e. PFHpA, PFDoA, PFNA, PFUA, PFDeA, PFOA and PFOS), were detected in raw and treated water with PFOA and PFOS being the least detected PFCs as they were detected only in raw water (PFOA) from Faure, as well as raw and treated water (PFOS) from Brooklands. The highest concentration observed in treated water was for PFHpA, which was quantified at a maximum average concentration of 43.80 ng/L (Plattekloof). The maximum average concentrations of other PFCs detected were as follows: PFDoA - 4.415 ng/L for Faure raw water; PFNA - 2.922 ng/L for Plattekloof outlet; PFUA - 7.965 ng/L for Brooklands treated water and PFDeA - 2.744 ng/L for Faure raw water. Another observation from the results was that the concentration of the majority of the PFCs detected in treated water was higher than that quantified in raw water, suggesting possible contamination by materials used during water treatment. In conclusion, THMs detected in treated water from various DWTPs and one DWDS in the Western Cape met the required local and international drinking water quality guidelines, while the presence of PFOS, PFOA, PFHpA, PFDoA, PFNA, PFUA and PFDeA in treated water requires that local water professionals continue to monitor their presence to ensure that measures for their reduction are in place. Furthermore, the National standards (SANS 241) for municipal drinking water guidelines must be updated to include the monitoring of PFCs, including the lesser known and less studied PFCs such as PFHpA, PFDoA, PFNA, PFUA and PFDeA.

The first edition of Bioanalytical Tools in Water Quality Assessment was released in 2012. The field has exploded since and the second edition updates and reviews the application of bioanalytical tools for water quality assessment including surveillance monitoring. The book focuses on applications to water quality assessment ranging from wastewater to drinking water, including recycled water, as well as treatment processes and advanced water treatment. Emerging applications for other environmental matrices are also included. Bioanalytical Tools in Water Quality Assessment, Second Edition, not only demonstrates applications but also fills in the background knowledge in toxicology/ecotoxicology needed to appreciate these applications. Each chapter summarises fundamental material in a targeted way so that information can be applied to better understand the use of bioanalytical tools in water quality assessment. The book can be used by lecturers teaching academic and professional courses and also by risk assessors, regulators, experts, consultants, researchers and managers working in the water sector. It can also be a reference manual for environmental engineers, analytical chemists and toxicologists. ISBN: 9781789061970 (Paperback) ISBN: 9781789061987 (eBook)

ABSTRACT In the midst of aggressive anti-drilling campaigns by environmental organizations and well-publicized complaints by citizens unaccustomed to oil and gas operations, rigorous studies of unconventional oil and gas development show that there are no widespread or systemic impacts on drinking water resources in the United States. In addition, air pollution and greenhouse gas emissions have significantly declined with the growth in natural gas production and its use in power generation. Furthermore, induced seismicity from subsurface waste disposal has plummeted in response to industry initiatives and new regulations. This record of environmental protection reflects the fact that U.S. hydraulic fracturing, like other oil and gas operations, is highly regulated by the states. In addition, air emissions, operations on federal lands, and subsurface injection are subject to federal regulation. Academic and government researchers have documented that chemicals and gas produced by hydraulic fracturing are not contaminating drinking water. However, as an added complication, methane occurs naturally in drinking water aquifers in some producing areas. In 2015, the U.S. Environmental Protection Agency (EPA) completed a four-year study of potential aquifer contamination from hydraulic fracturing and associated industry operations. The report found some impacts on drinking water including contamination of drinking water wells; however, the number of cases was small compared to the number of wells hydraulically fractured. The scientific peer-review and public critique of the study, which continues after more than a year, may recommend additional research. The emotionally charged, anti-fracking campaigns provided important lessons to U.S. operators: pre-drilling, baseline data on water and air quality are essential to answering public concerns; infrastructure issues such as increased truck traffic on small, local roads are important to residents; and the initial failure to disclose the composition of hydraulic fracturing fluid intensified public concern.