Relevant bibliographies by topics / Dithiocarbamates

Contents

  1. Journal articles
  2. Dissertations / Theses
  3. Books
  4. Book chapters
  5. Conference papers

Academic literature on the topic 'Dithiocarbamates'

Author: Grafiati
Published: 4 June 2021
Last updated: 25 July 2025

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Journal articles on the topic "Dithiocarbamates"

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Halimehjani, Azim Ziyaei, Reza Mohtasham, Abbas Shockravi, and Jürgen Martens. "Multicomponent synthesis of dithiocarbamates starting from vinyl sulfones/sulfoxides and their use in polymerization reactions." RSC Advances 6, no. 79 (2016): 75223–26. http://dx.doi.org/10.1039/c6ra15616a.

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Pedras, M. Soledade, and Francis I. Okanga. "Metabolism of analogs of the phytoalexin brassinin by plant pathogenic fungi." Canadian Journal of Chemistry 78, no. 3 (2000): 338–46. http://dx.doi.org/10.1139/v00-024.

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he metabolism of analogs of the cruciferous phytoalexin brassinin by the phytopathogenic fungi Phoma lingam (Tode ex Fr.) "virulent" and "avirulent" groups (sexual stage Leptosphaeria maculans (Desm.) Ces. et de Not.) and Alternaria brassicae (Berk.) Sacc. is reported. It was established that each pathogen detoxified methyl tryptamine dithiocarbamate, although yielding different metabolic products. While the biotransformation by virulent P. lingam proceeded to yield methyl 3a-hydroxy-3,3a,8,8a-tetrahydropyrrolo[2,3-b]indol-1(2H)-yl carbodithioate and indole-3-acetic acid as final products, avi
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Maurya, Chandan, and Sangeeta Bajpai. "Biological Applications of Metal Complexes of Dithiocarbamates." Journal of Applied Science and Education (JASE) 2, no. 1 (2022): 1–16. http://dx.doi.org/10.54060/jase/002.01.002.

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Dithiocarbamates are organosulphur ligands and form chelate compounds with metals. Their uses are reported in the field of accelerating vulcanization, pesticide, material science, organic synthesis, etc. Recent research demonstrated the potential of metal complexes of these ligands as good antifungal, antibacterial, and antitumor agents. Dithiocarbamate complexes have also been reported to use as a plasmonic sensor, as an inhibitor of proteasome, and for antioxidant and antileishmanial activity. This brief review presents the biological activities of metal complexes of dithiocarbamate.
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Oliveira, Johny Wysllas de Freitas, Hugo Alexandre Oliveira Rocha, Wendy Marina Toscano Queiroz de Medeiros, and Marcelo Sousa Silva. "Application of Dithiocarbamates as Potential New Antitrypanosomatids-Drugs: Approach Chemistry, Functional and Biological." Molecules 24, no. 15 (2019): 2806. http://dx.doi.org/10.3390/molecules24152806.

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Dithiocarbamates represent a class of compounds that were evaluated in different biomedical applications because of their chemical versatility. For this reason, several pharmacological activities have already been attributed to these compounds, such as antiparasitic, antiviral, antifungal activities, among others. Therefore, compounds that are based on dithiocarbamates have been evaluated in different in vivo and in vitro models as potential new antimicrobials. Thus, the purpose of this review is to present the possibilities of using dithiocarbamate compounds as potential new antitrypanosomati
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Tella, Toluwani, Carolina H. Pohl, and Ayansina Ayangbenro. "A review of the therapeutic properties of dithiocarbamates." F1000Research 11 (February 28, 2022): 243. http://dx.doi.org/10.12688/f1000research.109553.1.

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The persistence of infectious diseases that continue to plague the world, as well as the formation of harmful substances within the human body, such as free radicals and reactive oxygen species (ROS) have sparked new research. Thus, the need for innovative approaches for developing new or modification of existing therapeutic agents. The design of biologically important metal complexes of dithiocarbamates (DTCs) has been made possible by recent advancements in innovative research. Dithiocarbamates are reduced thiuram disulfides with excellent complexing capabilities and have various application
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Ahmad, Jimmy, Fiona N. F. How, Siti Nadiah Abdul Halim, Mukesh M. Jotani, See Mun Lee, and Edward R. T. Tiekink. "A new structural motif for cadmium dithiocarbamates: crystal structures and Hirshfeld surface analyses of homoleptic zinc and cadmium morpholine dithiocarbamates." Zeitschrift für Kristallographie - Crystalline Materials 234, no. 5 (2019): 341–49. http://dx.doi.org/10.1515/zkri-2018-2141.

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Abstract The crystal and molecular structures of two homoleptic morpholine-derived dithiocarbamates of zinc, binuclear {Zn[S2CN(CH2CH2)2O)2]2}2 (1), and cadmium, one-dimensional coordination polymer {Cd[S2CN(CH2CH2)2O)2]2}2 (2), are described. In 1, a centrosymmetric binuclear molecule is found as there are equal numbers of chelating and bidentate bridging dithiocarbamate ligands; weak transannular Zn···S interactions are found within the resultant eight-membered {···SCSZn}2 ring which has the form of a chair. The resultant 4+1 S5 donor set is highly distorted with the geometry tending towards
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Begum, B., A. Sarker, AKM Lutfor Rahman, and NC Bhoumik. "Synthesis and characterization of mixed ligand catecholato-bis (diamine-mono-dithiocarbamato) vanadium (IV) complexes." Bangladesh Journal of Scientific and Industrial Research 52, no. 2 (2017): 89–96. http://dx.doi.org/10.3329/bjsir.v52i2.32913.

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Diamine-mono-dithiocarbamates are mono-basic bidentate ligand forming stable complexes with transition metals. Mixed ligand catecholato-bis (diamine-mono-dithiocarbamato) vanadium (IV) complexes were synthesized and characterized using FT-IR, UV-visible and 1H-NMR spectroscopic techniques. The formation of vanadium complexes was con?rmed by the disappearance of ?S-H band in the complexes which was present in the ligands and incidence of ?V-S and ?V-O band in FT-IR spectra of the complexes. The mono-dithiocarbamate with one uncoordinated ?NH/NH2 group was indicated by the presence of ?N-H vibra
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Versloot, P., J. G. Haasnoot, J. Reedijk, M. van Duin, and J. Put. "Sulfur Vulcanization of Simple Model Olefins, Part IV: Vulcanizations of 2,3-Dimethyl-2-Butene with TMTD and Activated Zinc Dithiocarbamate/Xanthate Accelerators at Different Temperatures." Rubber Chemistry and Technology 68, no. 4 (1995): 563–72. http://dx.doi.org/10.5254/1.3538757.

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Abstract The mechanism of the accelerated sulfur vulcanization of rubber was studied by the use of 2,3-dimethyl-2-butene (C6H12, TME) as a simple, low-molecular model alkene. Treatment of TME with a mixture of ZnO, S8 and the classical accelerator TMTD at temperatures above 100°C yields a mixture of addition products ((C6H11—Sn—C6H11) ). In the temperature range of 50 up to 100 °C only intermediate products, C6H11—Sn—S(S)CN(CH3)2 are obtained. Room temperature vulcanization is feasible using highly reactive accelerators, such as xanthate derivatives. These derivatives result in formation of th
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Dogheim, Salwa M., Sohair A. Gad Alla, Ashraf M. El-Marsafy, and Safaa M. Fahmy. "Monitoring Pesticide Residues in Egyptian Fruits and Vegetables in 1995." Journal of AOAC INTERNATIONAL 82, no. 4 (1999): 948–55. http://dx.doi.org/10.1093/jaoac/82.4.948.

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Abstract Organophosphorus, dithiocarbamates, and some synthetic pyrethroids pesticides, which are commonly used in Egypt for pest control, were monitored, as well as persistent organochlorines, which had been prohibited from use several years ago. Fruit and vegetable samples (397) were collected from 8 local markets and examined for 52 pesticides. Of all analyzed samples, 42.8% contained detectable residues, of which 1.76% exceeded their maximum residue limits (MRLs). The rates of contamination with the different pesticides were 0-86%. However, violation rates among contaminated products were
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Odularu, Ayodele T., and Peter A. Ajibade. "Dithiocarbamates: Challenges, Control, and Approaches to Excellent Yield, Characterization, and Their Biological Applications." Bioinorganic Chemistry and Applications 2019 (February 6, 2019): 1–15. http://dx.doi.org/10.1155/2019/8260496.

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Progresses made in previous researches on syntheses of dithiocarbamates led to increase in further researches. This paper reviews concisely the challenges experienced during the synthesis of dithiocarbamate and mechanisms to overcome them in order to obtain accurate results. Aspects of its precursor’s uses to synthesize adducts, nanoparticles, and nanocomposites are reported. Some common characterization techniques used for the synthesized products were assessed. Biological applications are also reported.
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Dissertations / Theses on the topic "Dithiocarbamates"

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McMaster, Claire. "Radical mediated reactions of dithiocarbamates." Thesis, University of Birmingham, 2013. http://etheses.bham.ac.uk//id/eprint/3886/.

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Chapter one reviews the use of acyl radicals and the various functional groups from which they have been derived. The earlier work on the use of dithiocarbamates as a source of acyl radicals has been progressed. Systems with the potential to follow either a 6-exo or competing 7-endo cyclisation pathway have been made. Chapter two is about the radical mediated reduction of the dithiocarbamate group. Previously reported dithiocarbamate group transfer reactions are reviewed along with existing methods for the reductive removal of the dtihiocarbamate and related xanthate groups. The development of
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Cox, Michael Jason. "Zinc, cadmium and mercury 1,1-dithiolates /." Title page, abstract and contents only, 1999. http://web4.library.adelaide.edu.au/theses/09PH/09phc8775.pdf.

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Ahmed, Mohammed A. K. "Synthesis and physical investigation of tellurium dithiocarbamates." Thesis, Aston University, 1985. http://publications.aston.ac.uk/11726/.

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Exarchos, George. "Reactions between metal sulfur chelate complexes and class B metal centres." Thesis, King's College London (University of London), 1999. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.312991.

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Fiddy, J. M. "A Moessbauer effect study of iron(III) dithiocarbamates." Thesis, University of Liverpool, 1989. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.233819.

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Roe, Stephen Mark. "Structural studies of main group metal carboxylates and dithiocarbamates." Thesis, University of Warwick, 1989. http://wrap.warwick.ac.uk/56212/.

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The work contained in this thesis describes the crystal structures of a number of tin(IV) and tellurium(IV) carboxylates and dithiocarbamates. The results show the regularity at which these types of compounds form secondary bonds (weak interactions), and the effect of the lone pair of tellurium(IV) on the geometries formed. The area has been studied through the determination of the following crystal structures: i) monocarboxylates: Ph3SnOCOCH2Cl, Ph3SnOCOCHCh, Ph3SnOCOCCh.MeOH. Ph3SnOCOCCh and Ph3TeOCOCCh. ii) dicarboxulates : Ph2Sn(OCOCH3)2, Ph2Sn(OCOCH2CI)2 and Ph2Te(OCOCCI3)2 iii) dithiocar
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Duffour, Jacqueline. "Résidus des dithiocarbamates et de l'éthylènethiourée : aspects toxicologiques et analytiques." Montpellier 1, 1991. http://www.theses.fr/1991MON13511.

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Boisdé, Frédéric. "Sur la mise au point de dosages immunoenzymatiques de pesticides et de leurs dérivés : le cas des dithiocarbamates et de l'éthylènethiourée." Brest, 2003. http://www.theses.fr/2002BRES2038.

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La méthode officielle utilisée à ce jour pour le dosage des résidus de dithiocarbamates consiste en une hydrolyse acide des échantillons puis, après distillation, d'un dosage spectrophotométrique du disulfure de carbone (CS2) libéré. Ce procédé présente de nombreuses limites comme une faible reproductibilité, un seuil de détection inadapté à certains dosages et une absence de spécificité. Les méthodes classiques de dosage (chromatographies gazeuse et liquide) sont elles sensibles et spécifiques, mais nécessitent un matériel coûteux, manipulé par un personnel qualifié. De ce fait, les méthodes
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Stephens, Alan Nicholas. "Niobium dithiocarbamates : structural and solution studies in relation to a bridged-dinitrogen complex." Thesis, University of Sussex, 1988. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.236255.

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Xu, Ximing. "Arylamines N-acétyltransférases : liaison du cofacteur, mécanisme catalytique et inhibition par les dithiocarbamates." Paris 7, 2014. http://www.theses.fr/2014PA077091.

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Les principaux objectifs de cette thèse visent à mieux comprendre les relations structure/fonction de la famille de arylamine N-acétyltransférases (NAT) et comment ces enzymes peuvent être inhibées par un groupe important de pesticides: thiocarbamates. Afin d'obtenir de nouvelles informations sur les mécanismes moléculaires qui régissent la fixation de la AcCoA aux NAT, la première partie de mon travail a été consacrée à la détermination de la structure cristalline d'une isoforme NAT de Mesorhizobium loti ((RHILO) NAT1) en complexe avec CoA. La deuxième partie de mon travail a consisté à compr
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Books on the topic "Dithiocarbamates"

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Ahmed, Mohammed Amin Karim. Synthesis and physical investigation of tellurium dithiocarbamates. University of Aston. Department of Chemistry, 1985.

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F, Hepp Aloysius, and United States. National Aeronautics and Space Administration., eds. One-step synthesis of dithiocarbamates from metal powders. National Aeronautics and Space Administration, 1993.

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F, Hepp Aloysius, and United States. National Aeronautics and Space Administration., eds. One-step synthesis of dithiocarbamates from metal powders. National Aeronautics and Space Administration, 1993.

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F, Hepp Aloysius, and United States. National Aeronautics and Space Administration., eds. One-step synthesis of dithiocarbamates from metal powders. National Aeronautics and Space Administration, 1993.

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Roe, Stephen Mark. Structural studies of main group metal carboxylates and dithiocarbamates. typescript, 1989.

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M, Engel Tina, and Environmental Monitoring and Support Laboratory (Cincinnati, Ohio), eds. Determination of dithiocarbamate pesticides in wastewaters. U.S. Environmental Protection Agency, Environmental Monitoring and Support Laboratory, 1985.

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International Program on Chemical Safety., United Nations Environment Programme, International Labour Organisation, and World Health Organization, eds. Dithiocarbamate pesticides, ethylenethiourea, and propylenethiourea: A general introduction. World Health Organization, 1988.

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1933-, Gessner Teresa, ed. Disulfiram and its metabolite diethyldithiocarbamate: Pharmacology and status in the treatment of alcoholism, HIV infections, AIDS and heavy metal toxicity. Chapman & Hall, 1992.

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One-step synthesis of dithiocarbamates from metal powders. National Aeronautics and Space Administration, 1993.

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Parker, Philip M. The 2007 Import and Export Market for Thiocarbamates and Dithiocarbamates in China. ICON Group International, Inc., 2006.

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Book chapters on the topic "Dithiocarbamates"

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Baghat, Khaled, and János Mink. "Vibrational Spectra of Metal Dithiocarbamates." In Progress in Fourier Transform Spectroscopy. Springer Vienna, 1997. http://dx.doi.org/10.1007/978-3-7091-6840-0_36.

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Hogarth, Graeme. "Transition Metal Dithiocarbamates: 1978-2003." In Progress in Inorganic Chemistry. John Wiley & Sons, Inc., 2005. http://dx.doi.org/10.1002/0471725587.ch2.

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Foss, Olav, and John J. Pitha. "Xanthates and Dithiocarbamates of Selenium(II) and Tellurium(II)." In Inorganic Syntheses. John Wiley & Sons, Inc., 2007. http://dx.doi.org/10.1002/9780470132357.ch32.

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Malepu, Vidyasagar, Christy D. Petruczok, TuTrinh Tran, Tianxi Zhang, Mahesh Thopasridharan, and Devon A. Shipp. "RAFT Polymerization of Vinyl Acetate, Styrene and Acrylates UsingN,N-Dithiocarbamates." In ACS Symposium Series. American Chemical Society, 2009. http://dx.doi.org/10.1021/bk-2009-1024.ch003.

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Onuska, Francis I. "Mass Spectrometry of Carbamates, Thiocarbamates, Dithiocarbamates, Urea, Thiourea, and Carboxanilide Pesticides." In Mass Spectrometry in Environmental Sciences. Springer US, 1985. http://dx.doi.org/10.1007/978-1-4613-2361-7_17.

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Eybl, V., D. Kotyzová, J. Koutenský, D. Waitzová, and M. M. Jones. "The Influence of Some Dithiocarbamates on Oxidative Drug Metabolism: Interaction with Cadmium." In Mechanisms and Models in Toxicology. Springer Berlin Heidelberg, 1987. http://dx.doi.org/10.1007/978-3-642-72558-6_33.

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Miller, Philip W. "Production and Reaction of [11C]Carbon Disulfide for the Synthesis of [11C]Dithiocarbamates." In Radiochemical Syntheses. John Wiley & Sons, Inc, 2015. http://dx.doi.org/10.1002/9781118834114.ch18.

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Papadopoulou-Mourkidou, Euphemia, Emmanuil Nikolaos Papadakis, and Zisis Vryzas. "Application of Microwave-Assisted Extraction for the Analysis of Dithiocarbamates in Food Matrices." In Pesticide Protocols. Humana Press, 2006. http://dx.doi.org/10.1385/1-59259-929-x:319.

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Maia, Luisa B., and José J. G. Moura. "Detection of Nitric Oxide by Electron Paramagnetic Resonance Spectroscopy: Spin-Trapping with Iron-Dithiocarbamates." In Methods in Molecular Biology. Springer New York, 2016. http://dx.doi.org/10.1007/978-1-4939-3600-7_8.

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Mathes, Roger A., H. S. Booth, and R. D. Kirk. "Ammonium Dithiocarbamate." In Inorganic Syntheses. John Wiley & Sons, Inc., 2007. http://dx.doi.org/10.1002/9780470132340.ch12.

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Conference papers on the topic "Dithiocarbamates"

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Ellor, J. A., G. A. Gehring, and Barry C. Syrett. "An Investigation of Water Treatments for Mitigating Sulfide-Related Corrosion of Copper Alloy Condenser Tubes." In CORROSION 1986. NACE International, 1986. https://doi.org/10.5006/c1986-86225.

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Abstract This paper presents the results of a study investigating selected water treatments that might be used to control sulfide-accelerated corrosion. The water treatments selected for evaluation included ferrous sulfate, benzotriazole, sodium dimethyl-dithiocarbamate, high molecular weight polyacrylamide, and Calgon CL-5. The study also evaluated the interaction and effect of sulfide, dissolved oxygen and temperature on the corrosion of copper alloy tubes under simulated condenser flow conditions. The program included three condenser tube alloys--aluminum brass, 70/30 copper-nickel, and 90/
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Macziek, Maik, Steffen Stitz, and Matthias Langer. "The Behaviour of the CuNi90/10 Protective Layer under Brackish Water Conditions." In CORROSION 2019. NACE International, 2019. https://doi.org/10.5006/c2019-12845.

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Absrract CuNi90/10 has been used for many decades as a corrosion resistant alloy for seawater applications. Its corrosion resistance mainly results from the formation of a stable, thin and very adhesive protective layer that forms in contact with seawater. The formation of this protective layer can take up to several weeks depending on environmental influences such as temperature, oxygen content or pH value. There is a delay in the formation of a natural protective layer particularly in the case of brackish water. During this time the material is susceptible to corrosion. For this reason, effo
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Farina, Y., M. Sanuddin, B. M. Yamin, et al. "Structure of Biologically Active Organotin(IV) Dithiocarbamates." In NEUTRON AND X-RAY SCATTERING 2007: The International Conference. AIP, 2008. http://dx.doi.org/10.1063/1.2906071.

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Antonijević, Marko, Milica Kosović Perutović, Zorica Leka, and Zoran Marković. "Exploring the Pharmacokinetic Properties of (NH4)4[Fe(idadtc)2]: In Silico Biological screening and ADMET analysis." In 2nd International Conference on Chemo and Bioinformatics. Institute for Information Technologies, University of Kragujevac, 2023. http://dx.doi.org/10.46793/iccbi23.213a.

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Carbonic anhydrases (CA) have been identified in the early ‘50s as potential targets for the treatment of numerous diseases, including cancer, glaucoma, epilepsy, etc. Current inhibitors, i.e., treatment options, offer high efficacy coupled with a high probability of various side-effects. On the other hand, dithiocarbamates and their metal complexes are known for being good CA inhibitors. In this paper, a novel Fe (II) dithiocarbamato complex was investigated for its biological and pharmacological properties using a combination of different in silico methodologies. It was found that this water
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Onouchi, Hisanari, Isao Tanaka, Ian Elliott, and Nicole Ketterer. "Understanding degradation of engine oil additives and its effect on abnormal combustion in a gasoline engine." In 2023 JSAE/SAE Powertrains, Energy and Lubricants International Meeting. Society of Automotive Engineers of Japan, 2023. http://dx.doi.org/10.4271/2023-32-0035.

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<div class="section abstract"><div class="htmlview paragraph">Engine oils and their additives are formulated to meet required performance areas such as lubrication, detergency, dispersancy, anti-wear, and so on. Understanding degradation of engine oil additives is important to formulate oils with long time durability. Engine oil additives have been found to affect abnormal combustion in turbocharged gasoline direct injection (TGDI) engines, called low speed pre-ignition (LSPI). Some of metal containing additives such as zinc dithiophosphates (ZnDTP) and molybdenum dithiocarbamates
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Zavyalova, Ludmila V., Sergey V. Svechnikov, and Vladimir G. Tchoni. "Photodetectors of slit and sandwich types based on CdS and CdS1-xSex films obtained using MOCVD method from dithiocarbamates." In Photonics West '97, edited by Gail J. Brown and Manijeh Razeghi. SPIE, 1997. http://dx.doi.org/10.1117/12.271194.

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Muthalib, Amirah Faizah Abdul, and Ibrahim Baba. "New mono-organotin (IV) dithiocarbamate complexes." In THE 2014 UKM FST POSTGRADUATE COLLOQUIUM: Proceedings of the Universiti Kebangsaan Malaysia, Faculty of Science and Technology 2014 Postgraduate Colloquium. AIP Publishing LLC, 2014. http://dx.doi.org/10.1063/1.4895202.

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Kosović Perutović, M., Z. Leka, M. Bigović, J. Mišurović, and V. Medojević. "Mechanochemistry: optimization of the synthesis of dithiocarbamate derivatives." In 2nd International Conference on Chemo and Bioinformatics. Institute for Information Technologies, University of Kragujevac, 2023. http://dx.doi.org/10.46793/iccbi23.249kp.

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As a continuation of our research in the field of synthesis and characterization of dithiocarbamate (DTC), we are developing mechanochemical protocols for the synthesis of new compounds with potential biological activity. Optimizing the methods of obtaining desired compounds is of special importance for a completely eco-friendly science, and one of the prospective strategies is mechanochemistry, recognized as a green, sustainable synthesis method. Herein we present the mechanochemical reactions of homopiperazine and CS2. The aim was to obtain homopiperazine dithiocarbamate derivative through m
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Zhang, Yi, Yan Luo, Jian-Qian Hu, Tao Zhang, and Yun-Yun Xu. "Tribological Performances and Mechanism of Bismuth Dialkyl-Dithiocarbamate Additive." In STLE/ASME 2008 International Joint Tribology Conference. ASMEDC, 2008. http://dx.doi.org/10.1115/ijtc2008-71016.

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A four-ball tester was used to evaluate the tribological performance of bismuth diamyl-dithiocarbamate in mineral oil, and compared with same types of metal additives. The results show that it exhibits better load-carrying capacities than said organic metal additives. The surface analytical tools such as X-ray photoelectron spectrometer (XPS) and Scanning electron microscopy (SEM) were used to investigate the topography, the compositions contents and the depth profile of some typical elements on the rubbing surface of worn scar. Smooth topography of worn scar further confirms that the additive
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Hassan Ahmed Al-Jubouri, Suha ,., and Hassan Ahmed Mohamed. "Preparation and Characterization the Complexes of Dithiocarbamide Derived from Amino Acids and Evaluation of Their Biological Activity." In X INTERNATIONAL CONGRESS OF PURE AND APPLIED TECHNOLOGICAL SCIENCES. Rimar Academy, 2023. http://dx.doi.org/10.47832/minarcongress10-10.

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This resaerch includes the preparation and characterization of a number of dithiocarbamate complexes of amino acids (tyrosine, and tryptophan) with a number of transitional elements Ni (II) and non-transitional elements Zn (II), Hg (II). The dithiocarbamate complexes were prepared directly in one container due to the difficulty of obtaining the ligands in a solid form. The complexes with the following general formulas were prepared: 1.Complexes with the formula [M(Tyrodtc)2], where M= Ni(II), Zn(II) ratio (metal: ligand) (2:1). 2. Complexes with the formula [M(Tryptodtc)2] where M= Zn(II), Hg(
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