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Journal articles on the topic 'Dithiocarbamates'

Author: Grafiati

Published: 4 June 2021

Last updated: 25 July 2025

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1

Halimehjani, Azim Ziyaei, Reza Mohtasham, Abbas Shockravi, and Jürgen Martens. "Multicomponent synthesis of dithiocarbamates starting from vinyl sulfones/sulfoxides and their use in polymerization reactions." RSC Advances 6, no. 79 (2016): 75223–26. http://dx.doi.org/10.1039/c6ra15616a.

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2

Pedras, M. Soledade, and Francis I. Okanga. "Metabolism of analogs of the phytoalexin brassinin by plant pathogenic fungi." Canadian Journal of Chemistry 78, no. 3 (2000): 338–46. http://dx.doi.org/10.1139/v00-024.

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he metabolism of analogs of the cruciferous phytoalexin brassinin by the phytopathogenic fungi Phoma lingam (Tode ex Fr.) "virulent" and "avirulent" groups (sexual stage Leptosphaeria maculans (Desm.) Ces. et de Not.) and Alternaria brassicae (Berk.) Sacc. is reported. It was established that each pathogen detoxified methyl tryptamine dithiocarbamate, although yielding different metabolic products. While the biotransformation by virulent P. lingam proceeded to yield methyl 3a-hydroxy-3,3a,8,8a-tetrahydropyrrolo[2,3-b]indol-1(2H)-yl carbodithioate and indole-3-acetic acid as final products, avi

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3

Maurya, Chandan, and Sangeeta Bajpai. "Biological Applications of Metal Complexes of Dithiocarbamates." Journal of Applied Science and Education (JASE) 2, no. 1 (2022): 1–16. http://dx.doi.org/10.54060/jase/002.01.002.

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Dithiocarbamates are organosulphur ligands and form chelate compounds with metals. Their uses are reported in the field of accelerating vulcanization, pesticide, material science, organic synthesis, etc. Recent research demonstrated the potential of metal complexes of these ligands as good antifungal, antibacterial, and antitumor agents. Dithiocarbamate complexes have also been reported to use as a plasmonic sensor, as an inhibitor of proteasome, and for antioxidant and antileishmanial activity. This brief review presents the biological activities of metal complexes of dithiocarbamate.

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4

Oliveira, Johny Wysllas de Freitas, Hugo Alexandre Oliveira Rocha, Wendy Marina Toscano Queiroz de Medeiros, and Marcelo Sousa Silva. "Application of Dithiocarbamates as Potential New Antitrypanosomatids-Drugs: Approach Chemistry, Functional and Biological." Molecules 24, no. 15 (2019): 2806. http://dx.doi.org/10.3390/molecules24152806.

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Dithiocarbamates represent a class of compounds that were evaluated in different biomedical applications because of their chemical versatility. For this reason, several pharmacological activities have already been attributed to these compounds, such as antiparasitic, antiviral, antifungal activities, among others. Therefore, compounds that are based on dithiocarbamates have been evaluated in different in vivo and in vitro models as potential new antimicrobials. Thus, the purpose of this review is to present the possibilities of using dithiocarbamate compounds as potential new antitrypanosomati

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5

Tella, Toluwani, Carolina H. Pohl, and Ayansina Ayangbenro. "A review of the therapeutic properties of dithiocarbamates." F1000Research 11 (February 28, 2022): 243. http://dx.doi.org/10.12688/f1000research.109553.1.

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The persistence of infectious diseases that continue to plague the world, as well as the formation of harmful substances within the human body, such as free radicals and reactive oxygen species (ROS) have sparked new research. Thus, the need for innovative approaches for developing new or modification of existing therapeutic agents. The design of biologically important metal complexes of dithiocarbamates (DTCs) has been made possible by recent advancements in innovative research. Dithiocarbamates are reduced thiuram disulfides with excellent complexing capabilities and have various application

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6

Ahmad, Jimmy, Fiona N. F. How, Siti Nadiah Abdul Halim, Mukesh M. Jotani, See Mun Lee, and Edward R. T. Tiekink. "A new structural motif for cadmium dithiocarbamates: crystal structures and Hirshfeld surface analyses of homoleptic zinc and cadmium morpholine dithiocarbamates." Zeitschrift für Kristallographie - Crystalline Materials 234, no. 5 (2019): 341–49. http://dx.doi.org/10.1515/zkri-2018-2141.

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Abstract The crystal and molecular structures of two homoleptic morpholine-derived dithiocarbamates of zinc, binuclear {Zn[S2CN(CH2CH2)2O)2]2}2 (1), and cadmium, one-dimensional coordination polymer {Cd[S2CN(CH2CH2)2O)2]2}2 (2), are described. In 1, a centrosymmetric binuclear molecule is found as there are equal numbers of chelating and bidentate bridging dithiocarbamate ligands; weak transannular Zn···S interactions are found within the resultant eight-membered {···SCSZn}2 ring which has the form of a chair. The resultant 4+1 S5 donor set is highly distorted with the geometry tending towards

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7

Begum, B., A. Sarker, AKM Lutfor Rahman, and NC Bhoumik. "Synthesis and characterization of mixed ligand catecholato-bis (diamine-mono-dithiocarbamato) vanadium (IV) complexes." Bangladesh Journal of Scientific and Industrial Research 52, no. 2 (2017): 89–96. http://dx.doi.org/10.3329/bjsir.v52i2.32913.

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Diamine-mono-dithiocarbamates are mono-basic bidentate ligand forming stable complexes with transition metals. Mixed ligand catecholato-bis (diamine-mono-dithiocarbamato) vanadium (IV) complexes were synthesized and characterized using FT-IR, UV-visible and 1H-NMR spectroscopic techniques. The formation of vanadium complexes was con?rmed by the disappearance of ?S-H band in the complexes which was present in the ligands and incidence of ?V-S and ?V-O band in FT-IR spectra of the complexes. The mono-dithiocarbamate with one uncoordinated ?NH/NH2 group was indicated by the presence of ?N-H vibra

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8

Versloot, P., J. G. Haasnoot, J. Reedijk, M. van Duin, and J. Put. "Sulfur Vulcanization of Simple Model Olefins, Part IV: Vulcanizations of 2,3-Dimethyl-2-Butene with TMTD and Activated Zinc Dithiocarbamate/Xanthate Accelerators at Different Temperatures." Rubber Chemistry and Technology 68, no. 4 (1995): 563–72. http://dx.doi.org/10.5254/1.3538757.

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Abstract The mechanism of the accelerated sulfur vulcanization of rubber was studied by the use of 2,3-dimethyl-2-butene (C6H12, TME) as a simple, low-molecular model alkene. Treatment of TME with a mixture of ZnO, S8 and the classical accelerator TMTD at temperatures above 100°C yields a mixture of addition products ((C6H11—Sn—C6H11) ). In the temperature range of 50 up to 100 °C only intermediate products, C6H11—Sn—S(S)CN(CH3)2 are obtained. Room temperature vulcanization is feasible using highly reactive accelerators, such as xanthate derivatives. These derivatives result in formation of th

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9

Dogheim, Salwa M., Sohair A. Gad Alla, Ashraf M. El-Marsafy, and Safaa M. Fahmy. "Monitoring Pesticide Residues in Egyptian Fruits and Vegetables in 1995." Journal of AOAC INTERNATIONAL 82, no. 4 (1999): 948–55. http://dx.doi.org/10.1093/jaoac/82.4.948.

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Abstract Organophosphorus, dithiocarbamates, and some synthetic pyrethroids pesticides, which are commonly used in Egypt for pest control, were monitored, as well as persistent organochlorines, which had been prohibited from use several years ago. Fruit and vegetable samples (397) were collected from 8 local markets and examined for 52 pesticides. Of all analyzed samples, 42.8% contained detectable residues, of which 1.76% exceeded their maximum residue limits (MRLs). The rates of contamination with the different pesticides were 0-86%. However, violation rates among contaminated products were

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10

Odularu, Ayodele T., and Peter A. Ajibade. "Dithiocarbamates: Challenges, Control, and Approaches to Excellent Yield, Characterization, and Their Biological Applications." Bioinorganic Chemistry and Applications 2019 (February 6, 2019): 1–15. http://dx.doi.org/10.1155/2019/8260496.

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Progresses made in previous researches on syntheses of dithiocarbamates led to increase in further researches. This paper reviews concisely the challenges experienced during the synthesis of dithiocarbamate and mechanisms to overcome them in order to obtain accurate results. Aspects of its precursor’s uses to synthesize adducts, nanoparticles, and nanocomposites are reported. Some common characterization techniques used for the synthesized products were assessed. Biological applications are also reported.

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11

R. Mohammed, Eman, Intesar A. Sulleman, Shakir M. Saied, and Assim A. Sabah. "Synthesis of novel complexes derived from methyl or benzyl 4-amino antipyrinyl dithiocarbamtes with divalent Mn(II), Co(II), Ni(II), Zn(II) and Cu(II)." Bulletin of the Chemical Society of Ethiopia 39, no. 3 (2024): 447–57. https://doi.org/10.4314/bcse.v39i3.5.

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Two new ligands, methyl 4-amino antipyrinyl dithiocarbamates (MAC) and benzyl 4-amino antipyrinyl dithiocarbamates (BAC), were synthesized from 4-amino antipyrine and corresponding methyl or benzyl halides with potassium hydroxide in dimethylformamide. Then they were coordinated with five divalent transition metals: M = Mn, Co, Ni, Zn, and Cu(II) to produce ten novel complexes, [M(MAC)2]Cl2 I(a-e) and [M(BAC)2]Cl2 II(a-e), which were characterized by some physical properties and spectral methods, elemental analyses, molar conductance, and magnetic susceptibility, in addition to 1H NMR, FT-IR a

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12

Gallio, Andrea E., Leonardo Brustolin, Nicolò Pettenuzzo, and Dolores Fregona. "Binuclear Heteroleptic Ru(III) Dithiocarbamate Complexes: A Step towards Tunable Antiproliferative Agents." Inorganics 10, no. 3 (2022): 37. http://dx.doi.org/10.3390/inorganics10030037.

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Binuclear dithiocarbamate complexes of Ru(III) are promising candidates in the search for outstanding metal-based anticancer agents. While different dithiocarbamates have shown ligand-dependent cytotoxicity in homoleptic binuclear Ru(III) complexes, the properties of heteroleptic analogues with different dithiocarbamate (DTC) ligands have yet to be explored. We herein propose the introduction of heteroleptic ligands as tunable features for the development of improved ruthenium-based antiproliferative agents and report a synthetic strategy for their synthesis as well as the evaluation of the cy

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13

Tiekink, Edward R. T. "On the Coordination Role of Pyridyl-Nitrogen in the Structural Chemistry of Pyridyl-Substituted Dithiocarbamate Ligands." Crystals 11, no. 3 (2021): 286. http://dx.doi.org/10.3390/cryst11030286.

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A search of the Cambridge Structural Database was conducted for pyridyl-substituted dithiocarbamate ligands. This entailed molecules containing both an NCS2− residue and pyridyl group(s), in order to study their complexation behavior in their transition metal and main group element crystals, i.e., d- and p-block elements. In all, 73 different structures were identified with 30 distinct dithiocarbamate ligands. As a general observation, the structures of the transition metal dithiocarbamates resembled those of their non-pyridyl derivatives, there being no role for the pyridyl-nitrogen atom in c

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14

Bala, Veenu. "Dithiocarbamates." Synlett 25, no. 05 (2014): 746–47. http://dx.doi.org/10.1055/s-0033-1340637.

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15

Hogarth, Graeme, and Damian C. Onwudiwe. "Copper Dithiocarbamates: Coordination Chemistry and Applications in Materials Science, Biosciences and Beyond." Inorganics 9, no. 9 (2021): 70. http://dx.doi.org/10.3390/inorganics9090070.

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Copper dithiocarbamate complexes have been known for ca. 120 years and find relevance in biology and medicine, especially as anticancer agents and applications in materials science as a single-source precursor (SSPs) to nanoscale copper sulfides. Dithiocarbamates support Cu(I), Cu(II) and Cu(III) and show a rich and diverse coordination chemistry. Homoleptic [Cu(S2CNR2)2] are most common, being known for hundreds of substituents. All contain a Cu(II) centre, being either monomeric (distorted square planar) or dimeric (distorted trigonal bipyramidal) in the solid state, the latter being held to

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16

Thebti, Amal, Ines Chniti, Med Abderrahmane Sanhoury, Ikram Chehidi, Hadda Imene Ouzari, and Abdellatif Boudabous. "Antimicrobial Activity of Highly Fluorinated Thiocarbamates and Dithiocarbamates." Current Chemical Biology 13, no. 2 (2019): 120–28. http://dx.doi.org/10.2174/2212796812666180907153901.

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Background:The widespread occurrence of resistance to current antibiotics has triggered increasing research efforts to design and develop innovative antibacterial and antifungal agents that could overcome such antimicrobial resistance.Objective:The aim of this work was the in vitro evaluation of twelve highly fluorinated Nmonosubstituted thiocarbamates and dithiocarbamates and six non-fluorinated analogs against nine bacterial strains and three fungal species.Methods:The in vitro antimicrobial activity against the tested microrganisms was evaluated using the microdilution broth method.Results:

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17

Halimehjani, Azim Ziyaei, Martin Dračínský, and Petr Beier. "One-pot three-component route for the synthesis of S-trifluoromethyl dithiocarbamates using Togni’s reagent." Beilstein Journal of Organic Chemistry 13 (November 24, 2017): 2502–8. http://dx.doi.org/10.3762/bjoc.13.247.

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A one-pot three-component route for the synthesis of S-trifluoromethyl dithiocarbamates by the reaction of secondary amines, carbon disulfide and Togni’s reagent is described. The reactions proceed in moderate to good yields. A similar reaction using a primary aliphatic amine afforded the corresponding isothiocyanate in high yield. A variable temperature NMR study revealed a rotational barrier of 14.6, 18.8, and 15.9 kcal/mol for the C–N bond in the dithiocarbamate moiety of piperidine, pyrrolidine, and diethylamine adducts, respectively. In addition, the calculated barriers of rotation are in

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18

Humeres, Eduardo, Byung Sun Lee, and Nito Angelo Debacher. "Mechanisms of Acid Decomposition of Dithiocarbamates. 5. Piperidyl Dithiocarbamate and Analogues." Journal of Organic Chemistry 73, no. 18 (2008): 7189–96. http://dx.doi.org/10.1021/jo801015t.

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19

Saiyed, Tanzimjahan A., Jerry O. Adeyemi, and Damian C. Onwudiwe. "The structural chemistry of zinc(ii) and nickel(ii) dithiocarbamate complexes." Open Chemistry 19, no. 1 (2021): 974–86. http://dx.doi.org/10.1515/chem-2021-0080.

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Abstract Dithiocarbamate complexes are of immense interest due to their diverse structural properties and extensive application in various areas. They possess two sulfur atoms that often act as the binding sites for metal coordination in a monodentate, bidentate, or anisodentate fashion. These different coordination modes enhance the possibility for complex formation and make them useful in different areas especially in biomedical fields. A synergy exists in the metal ions and dithiocarbamate moieties, which tends to exert better properties than the respective individual components of the comp

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20

Abd Aziz, Nurul Amalina, Normah Awang, Kok Meng Chan, Nurul Farahana Kamaludin, and Nur Najmi Mohamad Anuar. "Organotin (IV) Dithiocarbamate Compounds as Anticancer Agents: A Review of Syntheses and Cytotoxicity Studies." Molecules 28, no. 15 (2023): 5841. http://dx.doi.org/10.3390/molecules28155841.

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Organotin (IV) dithiocarbamate has recently received attention as a therapeutic agent among organotin (IV) compounds. The individual properties of the organotin (IV) and dithiocarbamate moieties in the hybrid complex form a synergy of action that stimulates increased biological activity. Organotin (IV) components have been shown to play a crucial role in cytotoxicity. The biological effects of organotin compounds are believed to be influenced by the number of Sn-C bonds and the number and nature of alkyl or aryl substituents within the organotin structure. Ligands target and react with molecul

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21

Katritzky, Alan R., Shailendra Singh, Prabhu P. Mohapatra, Nicole Clemens, and Kostyantyn Kirichenko. "Synthesis of functionalised dithiocarbamates via N-(1-benzotriazolylalkyl)dithiocarbamates." Arkivoc 2005, no. 9 (2005): 63–79. http://dx.doi.org/10.3998/ark.5550190.0006.908.

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22

Humeres, Eduardo, Nito A. Debacher, M. Marta de S. Sierra, José Dimas Franco, and Aldo Schutz. "Mechanisms of Acid Decomposition of Dithiocarbamates. 1. Alkyl Dithiocarbamates." Journal of Organic Chemistry 63, no. 5 (1998): 1598–603. http://dx.doi.org/10.1021/jo971869b.

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23

Kiw, Yu Min, Pierre Adam, Philippe Schaeffer, Benoît Thiébaut, Chantal Boyer, and Nicolas Obrecht. "Molecular evidence for improved tribological performances of MoDTC induced by methylene-bis(dithiocarbamates) in engine lubricants." RSC Advances 12, no. 36 (2022): 23083–90. http://dx.doi.org/10.1039/d2ra03036e.

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A newly-discovered ligand transfer from methylene-bis(dithiocarbamates) to molybdenum dithiocarbamates (MoDTC) leads to MoDTC regeneration and results in enhanced fuel economy upon engine functioning.

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24

Borràs, Jordi, Julie Foster, Roxana Kashani, et al. "New Bioconjugated Technetium and Rhenium Folates Synthesized by Transmetallation Reaction with Zinc Derivatives." Molecules 26, no. 8 (2021): 2373. http://dx.doi.org/10.3390/molecules26082373.

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The zinc dithiocarbamates functionalized with folic acid 2Zn and 3Zn were synthesized with a simple straightforward method, using an appropriated folic acid derivative and a functionalized zinc dithiocarbamate (1Zn). Zinc complexes 2Zn and 3Zn show very low solubilities in water, making them useful for preparing Tc-99m radiopharmaceuticals with a potentially high molar activity. Thus, the transmetallation reaction in water medium between the zinc complexes 2Zn or 3Zn and the cation fac-[99mTc(H2O)3(CO)3]+, in the presence of the monodentate ligand TPPTS, leads to the formation of the 2 + 1 com

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25

Oladipo, Segun D., and Bernard Omondi. "N,N′-Diarylformamidine Dithiocarbamate Ag(I) Cluster and Coordination Polymer." Molbank 2022, no. 1 (2022): M1327. http://dx.doi.org/10.3390/m1327.

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An Ag(I)formamidine cluster Ag6L16 (1) and an Ag(I)formamidine coordination polymer Ag7(L2)2 2 (L1 = N,N′-bis(2,6-disopropylphenyl) formamidine dithiocarbamate and L2 = N,N′-mesityl formamidine dithiocarbamate) have been synthesized from the reactions of L1 and L2 with AgNO3 respectively. The complexes were characterized using spectroscopic and analytical methods, including single-crystal X-ray diffraction. In the structure of 1, a six vertex distorted square bi-pyramidal octahedron is formed from an Ag6 core. The N,N′-bis(2,6-disopropylphenyl) formamidine dithiocarbamate ligands stabilize thi

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26

Yeo, Chien Ing, Edward R. T. Tiekink, and Jactty Chew. "Insights into the Antimicrobial Potential of Dithiocarbamate Anions and Metal-Based Species." Inorganics 9, no. 6 (2021): 48. http://dx.doi.org/10.3390/inorganics9060048.

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Bacterial infection remains a worldwide problem that requires urgent addressing. Overuse and poor disposal of antibacterial agents abet the emergence of bacterial resistance mechanisms. There is a clear need for new approaches for the development of antibacterial therapeutics. Herein, the antibacterial potential of molecules based on dithiocarbamate anions, of general formula R(R’)NCS2(−), and metal salts of transition metals and main group elements, is summarized. Preclinical studies show a broad range of antibacterial potential, and these investigations are supported by appraisals of possibl

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27

Mohamad, Rapidah, Normah Awang, Nurul Farahana Kamaludin, Mukesh M. Jotani та Edward R. T. Tiekink. "[N-Benzyl-N-(2-phenylethyl)dithiocarbamato-κ2S,S′]triphenyltin(IV) and [bis(2-methoxyethyl)dithiocarbamato-κ2S,S′]triphenyltin(IV): crystal structures and Hirshfeld surface analysis". Acta Crystallographica Section E Crystallographic Communications 72, № 10 (2016): 1480–87. http://dx.doi.org/10.1107/s2056989016014985.

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The crystal and molecular structures of two triphenyltin dithiocarbamates, [Sn(C6H5)3(C16H16NS2)], (I), and [Sn(C6H5)3(C7H14NO2S2)], (II), are described. In (I), the dithiocarbamate ligand coordinates the SnIVatom in an asymmetric manner, leading to a highly distorted trigonal–bipyramidal coordination geometry defined by a C3S2donor set with the weakly bound S atom approximatelytransto one of theipso-C atoms. A similar structure is found in (II), but the dithiocarbamate ligand coordinates in an even more asymmetric fashion. The packing in (I) features supramolecular chains along thecaxis susta

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28

Liesivuori, Jyrki, and Kai Savolainen. "Chapter 5 Dithiocarbamates." Toxicology 91, no. 1 (1994): 37–42. http://dx.doi.org/10.1016/0300-483x(94)90238-0.

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29

Khajavali, S., A. Jayaraju, and J. Sreeramulu. "Synthesis, Characterization and Biological activities of 2-Amino-3-Methyl pyridine New Dithiocarbamate metal complexes." Journal of Drug Delivery and Therapeutics 9, no. 3-s (2019): 36–39. http://dx.doi.org/10.22270/jddt.v9i3-s.2742.

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Dithiocarbamates are a class of sulfur-based metal-chelating compounds with various applications in medicine. A new series of new transition metal [Cu(II), and Ni(II)] complexes of dithiocarbamates were synthesized from 2-Amino-3-Methyl pyridine and Carbon disulfide and further characterized. The investigation of these complexes confirmed that the stability of metal–ligands coordination through, S&S,N atoms as bidendate chelates.. It is necessary to understand the binding properties in developing new potential Protein targeting against neurological disorders. Keywords:2-Amino-3-Methylpyrid

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Kociok-Köhn, Gabriele, Kieran C. Molloy, and Anna L. Sudlow. "Molecular routes to Cu2ZnSnS4: A comparison of approaches to bulk and thin-film materials." Canadian Journal of Chemistry 92, no. 6 (2014): 514–24. http://dx.doi.org/10.1139/cjc-2013-0497.

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A range of xanthates (R′3P)2CuS2COR [R′ = Ph, R = Et (1), i-Pr (2), t-Bu (3), t-Amyl (4); R′ = PhO, R = Et (5), R′ = n-Bu, R = Et (6), Bun (7)], M(S2COR)2 [M = Sn R = Et (8); Zn, R = Et (10), i-Pr (11), n-Pr (12), n-Bu (13), n-Hex (14)], Sn(S2COEt)4 (9), Zn(S2COEt)2.TMEDA (15) have been synthesised and their thermal decomposition profiles delineated by TGA. A parallel range of dithiocarbamates (R′3P)2CuS2CN(Me)R [R′ = Ph, R = Bun (16), Bz (17)], M[S2CN(Me)R]2 [M = Sn, R = Bun (18), Bz (19); M = Zn, R = Bun (21), Bz (22)] has been similarly assessed. Although precursor combinations have been fo

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Schreck, R., B. Meier, D. N. Männel, W. Dröge, and P. A. Baeuerle. "Dithiocarbamates as potent inhibitors of nuclear factor kappa B activation in intact cells." Journal of Experimental Medicine 175, no. 5 (1992): 1181–94. http://dx.doi.org/10.1084/jem.175.5.1181.

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Dithiocarbamates and iron chelators were recently considered for the treatment of AIDS and neurodegenerative diseases. In this study, we show that dithiocarbamates and metal chelators can potently block the activation of nuclear factor kappa B (NF-kappa B), a transcription factor involved in human immunodeficiency virus type 1 (HIV-1) expression, signaling, and immediate early gene activation during inflammatory processes. Using cell cultures, the pyrrolidine derivative of dithiocarbamate (PDTC) was investigated in detail. Micromolar amounts of PDTC reversibly suppressed the release of the inh

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32

Alam, Md Najib, Swapan Kumar Mandal, and Subhas Chandra Debnath. "EFFECT OF ZINC DITHIOCARBAMATES AND THIAZOLE-BASED ACCELERATORS ON THE VULCANIZATION OF NATURAL RUBBER." Rubber Chemistry and Technology 85, no. 1 (2012): 120–31. http://dx.doi.org/10.5254/1.3672434.

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Abstract Several zinc dithiocarbamates (ZDCs) as accelerator derived from safe amine has been exclusively studied in the presence of thiazole-based accelerators to introduce safe dithiocarbamate in the vulcanization of natural rubber. Comparison has been made between conventional unsafe zinc dimethyldithiocarbamate (ZDMC) with safe novel ZDC combined with thizole-based accelerators in the light of mechanical properties. The study reveals that thiuram disulfide and 2-mercaptobenzothiazole (MBT) are always formed from the reaction either between ZDC and dibenzothiazyledisulfide (MBTS) or between

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33

Wu, Xiang-mei, and Guo-bing Yan. "Copper-Catalyzed Synthesis of S-Aryl Dithiocarbamates from Tetraalkylthiuram Disulfides and Aryl Iodides in Water." Synlett 30, no. 05 (2019): 610–14. http://dx.doi.org/10.1055/s-0037-1612086.

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An efficient approach for the copper-catalyzed synthesis of aryl dithiocarbamates from aryl iodides and tetraalkylthiuram disulfides in water is described. Without additional ligand and organic solvent, the coupling reaction could provide a series of S-aryl dithiocarbamates in moderate to good yields.

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34

Bond, AM, R. Colton, DR Mann, and JE Moir. "Characterization of Tris(Diselenocarbamato)Cobalt(III) and Pentakis(Diselenocarbamato)Dicobalt(III) Complexes by Electrochemical, Cobalt-59 N.M.R. and Mass-Spectrometric Techniques. Comparisons With Dithiocarbamate Analogs." Australian Journal of Chemistry 39, no. 9 (1986): 1385. http://dx.doi.org/10.1071/ch9861385.

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A series of Co(RR′dsc)3 and [Co2(RR′dsc)5]+ complexes (R, R′ = two alkyl groups or one heterocyclic group; dsc = NCSe2) have been synthesized and their redox behaviour, chemical reactivity and spectroscopic properties compared with the corresponding dithiocarbamate (RR′dtc) complexes. Electrochemical oxidation of Co(RR′dsc)3 in dichloromethane at platinum electrodes occurs at potentials about 0.34 V less positive than for Co(RR′dsc)3. The formally cobalt(IV) complexes [Co(RR′dsc)3]+ can be identified as a product which is then converted into [Co2(RR′dsc)5]+ via dimerization and an internal red

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35

MENDOZA, Concepcion S., and Satsuo KAMATA. "Phenylenedimethylene Bis(dithiocarbamates) and Related Bis(dithiocarbamates) as Extractants of Silver." Analytical Sciences 13, no. 4 (1997): 661–64. http://dx.doi.org/10.2116/analsci.13.661.

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36

Campanale, Claudia, Mariangela Triozzi, Annamaria Ragonese, Daniela Losacco, and Carmine Massarelli. "Dithiocarbamates: Properties, Methodological Approaches and Challenges to Their Control." Toxics 11, no. 10 (2023): 851. http://dx.doi.org/10.3390/toxics11100851.

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Dithiocarbamates (DTCs) are a group of chemicals used primarily as fungicides, although they are exploited for various other applications. DTCs represent one of the oldest classes of broad-spectrum fungicides employed worldwide to control fungal diseases on many crops. Due to their ease of synthesis, low production costs (cheap and readily available starting materials) and a fungicidal activity with a multi-site mode of action, they are still among modern agriculture’s most extensively used pesticides. Although the environmental degradation in air, water, and soil is relatively rapid due to ph

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37

Hoogenraad, T. U. "DITHIOCARBAMATES AND PARKINSON'S DISEASE." Lancet 331, no. 8588 (1988): 767. http://dx.doi.org/10.1016/s0140-6736(88)91573-5.

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38

Trofimova, T. P., A. N. Pushin, Ya I. Lys, and V. M. Fedoseev. "Rearrangement of cyclic dithiocarbamates." Chemistry of Heterocyclic Compounds 42, no. 3 (2006): 419–21. http://dx.doi.org/10.1007/s10593-006-0106-2.

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39

Yin, Handong, Chunlin Ma, and Rufen Zhang. "Synthesis of Tribenzyltin Dithiocarbamates." Chinese Journal of Applied Chemistry 15, no. 2 (1998): 76–78. http://dx.doi.org/10.3724/j.issn.1000-0518.1998.2.76.

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40

Hu, Zhen, Doung Zheng, Jinghe Zheng, and Guozhi Liu. "SYNTHESIS OF NEW DITHIOCARBAMATES." Chinese Journal of Applied Chemistry 3, no. 4 (1986): 75–77. http://dx.doi.org/10.3724/j.issn.1000-0518.1986.4.75.

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Hu, Zhen, Doung Zheng, Jinghe Zheng, and Guozhi Liu. "SYNTHESIS OF NEW DITHIOCARBAMATES." Chinese Journal of Applied Chemistry 3, no. 4 (1986): 75–77. http://dx.doi.org/10.3724/j.issn.1000-0518.1986.4.7577.

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42

Yin, Handong, Chunlin Ma, and Rufen Zhang. "Synthesis of Tribenzyltin Dithiocarbamates." Chinese Journal of Applied Chemistry 15, no. 2 (1998): 76–78. http://dx.doi.org/10.3724/j.issn.1000-0518.1998.2.7678.

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43

Ujjani, Barathi, Suzanne Lyman, Donald Winkelmann, David H. Petering, William Antholine, and Mark M. Jones. "Enhancement of cytotoxicity of bleomyein by dithiocarbamates: Formation of bis(dithiocarbamato) Cu(II)." Journal of Inorganic Biochemistry 38, no. 1 (1990): 81–93. http://dx.doi.org/10.1016/0162-0134(90)85009-l.

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44

Mangelsen, Sebastian, Patrick Zimmer, Christian Näther, and Wolfgang Bensch. "Nb2S4(CS2NH2)4—A New Precursor for NbS2 and Its Transition Metal Inserted Derivatives." Inorganics 11, no. 12 (2023): 478. http://dx.doi.org/10.3390/inorganics11120478.

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Transition metal inserted NbS2 (TxNbS2) compounds receive great attention due to their intriguing and diverse magnetic and electric transport properties. Typically, these compounds are prepared by high-temperature synthesis from the elements, which is time and energy-consuming and yields highly crystalline products. So far, no route for preparing these compounds from precursors by thermal decomposition has been reported. Herein, we report the synthesis of a dithiocarbamate of niobium Nb2S4(CS2NH2)4 as a precursor for the synthesis of NbS2 by this preparative strategy. Furthermore, we demonstra

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45

Babic-Samardzija, K., V. M. Jovanovic, and S. P. Sovilj. "Molecular structure in correlation with electrochemical properties of mixed-ligand cobalt(III) complexes." Journal of the Serbian Chemical Society 73, no. 7 (2008): 761–70. http://dx.doi.org/10.2298/jsc0807761b.

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Four mixed-ligand cobalt(III) complexes (1-4) of the general formula [Co(Rdtc)cyclam](ClO4)2 and [Co(Rac)cyclam](ClO4)2 (cyclam = 1,4,8,11-tetra- azacyclotetradecane; Rdtc = thiomorpholine-(Timdtc) or 2-methylpiperidine-(2-Mepipdtc) dithiocarbamates; Rac = 1,1,1,5,5,5-hexafluoro-2,4-pentanedionato (Hfac) or 2,2,6,6-tetramethyl-3,5-heptanedionato (Tmhd), respectively) were electrochemically examined on a glassy carbon and an iron electrode in perchloric acid solution. The obtained results showed the influence of these complexes on hydrogen evolution, the oxygen reduction reaction and iron disso

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46

H., L. NIGAM, B. PANDEYA KRISHNA, . P. TRIPATHI I, R. SHUKLA P., PRASAD JAGDISH, and SRIVASTAVA KRISHNA. "Cyclic Voltammetric Studies on some Copper Dithiocarbamates." Journal of Indian Chemical Society Vol. 69, Aug 1992 (1992): 536–40. https://doi.org/10.5281/zenodo.6042214.

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Department of Chemistry, A. P. S. University, Rewa-486 003 Department of Chemistry, Allahabad University, Allahabad-211 002 <em>Manuscript received 25 September 1992</em> Cyclic voltammetry at Pt-electrode in acetone/TBAP has been carried out on Cu(R<sub>2</sub>dtc)<sub>2</sub> Cu(R<sub>2</sub>dtc)<sub>2</sub>CIO<sub>4 </sub>and<sub> </sub>Cu(R<sub>2</sub>dtc)<sub>2</sub>-py (R = - C<sub>2</sub>H<sub>5</sub>- C<sub>3</sub>H<sub>7</sub> and -C6H<sub>11</sub>) systems. Two redox couples Cu(R<sub>2</sub> dtc)\(_2^+\)+e<sup>-</sup>=Cu(R<sub>2</sub>

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47

Tamilvanan, S. "Antimony(III) Dithiocarbamates: Synthesis, Spectral, Theoretical and Biological Activities." Asian Journal of Chemistry 34, no. 5 (2022): 1080–90. http://dx.doi.org/10.14233/ajchem.2022.23526.

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Antimony(III) dithiocarbamate complexes tris(N,N-difurfuryldithiocarbamato-S,S′)antimony(III) (1) and tris(N-furfuryl-N-(2-phenylethyl)dithiocarbamato-S,S′)antimony(III) (2) have been synthesized and characterized by CHN analysis, FT-IR, 1H NMR, 13C NMR spectra and antimicrobial studies. The characteristic thioureide ν(C-N) bands occur at 1459 and 1469 cm-1 for complexes 1 and 2, respectively. 1H NMR and 13C NMR chemical shifts have been calculated using GIAO approach and the calculated chemical shifts shows good agreement with experiential shifts. The computational calculations of the antimon

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Yan, Jie, Junxing Wang, and Weijian Sheng. "Iodine-Mediated Vicinal Difunctionalization of Alkenes: A Convenient Method for Building C–Se and C–S Bonds." Synlett 29, no. 12 (2018): 1654–58. http://dx.doi.org/10.1055/s-0037-1610145.

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A novel I2-mediated procedure is developed for building C–Se and C–S bonds simultaneously from alkenes, diselenides and sodium dithiocarbamates. This difunctionalization of alkenes is carried out in the presence of I2 and air, and exhibits good characteristics such as being transition-metal-free, requiring mild reaction conditions and simple procedures. The approach provides the product β-selanylethyl dithiocarbamates with high regioselectivity and in good yields. A plausible electrophilic addition mechanism is hypothesized.

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FURUTA, Saori, Fausto ORTIZ, Xiu ZHU SUN, Hsiao-Huei WU, Andrew MASON, and Jamil MOMAND. "Copper uptake is required for pyrrolidine dithiocarbamate-mediated oxidation and protein level increase of p53 in cells." Biochemical Journal 365, no. 3 (2002): 639–48. http://dx.doi.org/10.1042/bj20011251.

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The p53 tumour-suppressor protein is a transcription factor that activates the expression of genes involved in cell cycle arrest, apoptosis and DNA repair. The p53 protein is vulnerable to oxidation at cysteine thiol groups. The metal-chelating dithiocarbamates, pyrrolidine dithiocarbamate (PDTC), diethyldithiocarbamate, ethylene(bis)dithiocarbamate and H2O2 were tested for their oxidative effects on p53 in cultured human breast cancer cells. Only PDTC oxidized p53, although all oxidants tested increased the p53 level. Inductively coupled plasma MS analysis indicated that the addition of 60μM

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Huang, Zhuo-Bin, Xiong-Jian Xia, Zi-Hao Huang, Li Xu, Xiao-Yong Zhang, and Ri-Yuan Tang. "Selective C–H dithiocarbamation of arenes and antifungal activity evaluation." Organic & Biomolecular Chemistry 18, no. 7 (2020): 1369–76. http://dx.doi.org/10.1039/c9ob02514f.

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