Academic literature on the topic 'Ditopic ligand'

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Journal articles on the topic "Ditopic ligand"

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Jouvenot, Damien, Edith C. Glazer, and Yitzhak Tor. "Photodimerizable Ditopic Ligand." Organic Letters 8, no. 10 (2006): 1987–90. http://dx.doi.org/10.1021/ol060253i.

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Bonanno, N. M., A. J. Lough, K. E. Prosser, C. J. Walsby, P. K. Poddutoori, and M. T. Lemaire. "A stable open-shell redox active ditopic ligand." Dalton Transactions 45, no. 13 (2016): 5460–63. http://dx.doi.org/10.1039/c5dt04061b.

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Kariuki, Benson M., James A. Platts, and Paul D. Newman. "A hybrid bipy–NHC ligand for the construction of group 11 mixed-metal bimetallic complexes." RSC Advances 11, no. 54 (2021): 34170–73. http://dx.doi.org/10.1039/d1ra06581e.

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Duerrbeck, Andre, Sergey Gorelik, Jonathan Hobley, Ji'En Wu, Andy Hor, and Nicholas Long. "Highly emissive, solution-processable and dynamic Eu(iii)-containing coordination polymers." Chemical Communications 51, no. 41 (2015): 8656–59. http://dx.doi.org/10.1039/c5cc01793a.

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Hayvali, Zeliha, Necla Gündüz, Zeynel Kilic, and Edwin Weber. "Synthesis, Complex Formation and Spectral Investigation of New Tritopic Bis(Crown Ether) Compounds Containing Recognition Sites for Sodium and Nickel Guest Cations*." Zeitschrift für Naturforschung B 55, no. 10 (2000): 975–81. http://dx.doi.org/10.1515/znb-2000-1015.

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AbstractNew bis(crown ether) ligands (1 - 3) of Schiff base type containing recognition sites for sodium and nickel guest cations have been synthesized by the condensation of two equivalents of 4′-formyl-5′-hydroxy(benzo-15-crown-5)with 1,5-diamino-3-azapentane, 1,8-diamino-3,6- diazaoctane or 1,8-diamino-3,6-dioxaoctane. Homonuclear ditopic crystalline 2:1 (Na+:ligand) complexes (1a - 3a) of the ligands with NaClO4 have been prepared. Heteronuclear tritopic crystalline 2:1:1 (Na⊕ : Ni2⊕ : ligand) complexes (2b and 3b) have also been synthesized from the reactions of the ditopic complexes (2a
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Soldevila-Sanmartín, Joan, Teresa Calvet, Merce Font-Bardia, Concepción Domingo, José A. Ayllón, and Josefina Pons. "Modulatingp-hydroxycinnamate behavior as a ditopic linker or photoacid in copper(ii) complexes with an auxiliary pyridine ligand." Dalton Transactions 47, no. 18 (2018): 6479–93. http://dx.doi.org/10.1039/c8dt00645h.

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Bonanno, Nico M., Zackery Watts, Cole Mauws, et al. "Valence tautomerism in a [2 × 2] Co4 grid complex containing a ditopic arylazo ligand." Chemical Communications 57, no. 50 (2021): 6213–16. http://dx.doi.org/10.1039/d1cc01991k.

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Hossain, Sayed Muktar, Avinash Lakma, Rabindra Nath Pradhan, Serhiy Demeshko, and Akhilesh Kumar Singh. "Valence directed binding mode of [2 × 2] iron grids of an unsymmetrical picolinic hydrazone based ligand." Dalton Transactions 46, no. 37 (2017): 12612–18. http://dx.doi.org/10.1039/c7dt02433a.

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Renard, Nicolas, Eric Brenner, Dominique Matt, and Christophe Gourlaouen. "Adaptive Behavior of a Ditopic Phosphine Ligand." European Journal of Inorganic Chemistry 2019, no. 25 (2019): 2996–3004. http://dx.doi.org/10.1002/ejic.201900571.

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Blanco-Gómez, Arturo, Tamara Rama, Olaya Domarco, et al. "Amplification of a metallacyclic receptor out of a dynamic combinatorial library." Dalton Transactions 46, no. 45 (2017): 15671–75. http://dx.doi.org/10.1039/c7dt03379f.

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We present herein the Pt(ii)-directed self-assembly in water of a new conformationally flexible N-monoalkyl-4,4-bipyridinium-based ditopic ligand into a library of six different metallacyclic structures.
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Dissertations / Theses on the topic "Ditopic ligand"

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ALBISETTI, A. FIGINI. "Structural and Thermodiffractometric Studies of Coordination Polymers Containing Ditopic Exobidentate Nitrogen Ligand." Doctoral thesis, Università degli Studi di Milano, 2008. http://hdl.handle.net/2434/57743.

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Rahm, Fredrik. "Chiral Pyridine-Containing Ligands for Asymmetric Catalysis. Synthesis and Applications." Doctoral thesis, KTH, Chemistry, 2003. http://urn.kb.se/resolve?urn=urn:nbn:se:kth:diva-3564.

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<p>This thesis deals with the design and syntheses of chiral,enantiopure pyridinecontaining ligands and their applicationsin asymmetric catalyis.</p><p>Chiral pyridyl pyrrolidine ligands and pyridyl oxazolineligands were synthesized and employed in thepalladium-catalysed allylic alkylation of 1,3-diphenyl-2-propenyl acetate with dimethyl malonate. Theinfluence of the steric properties of the ligands wereinvestigated.</p><p>Ditopic ligands, containing crown ether units as structuralelements, were synthesized and some of the ligands were used asligands in the palladiumcatalysed allylic alkylatio
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Turner, Thomas P. W. "Bifunctional unsymmetrical ditopic ligands for alkene methoxycarbonylation." Thesis, University of Bristol, 2012. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.658207.

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A series of unsymmetrical xylenyl-backboned diphosphine ligands are reported: o-C6H4(CH2ptSU2)(CH2PRR'), R = Ph, R' = 2-Py (L1) and O-C6H4(CH2ptSU2)(CH2PR2), R = 2-Py (L2), R = 2-(3-Me-Py) (L3), R = 2-(4- Me-Py) (L4), R = 2-(6-Me-Py) (Ls) and R = 2-Pyrim (Ls). The ligands have all been characterised by 31p, 1H and 13C NMR spectroscopy and high resolution mass spectrometry. Studies of [PtCI(CH3)(L)] and [PdCI(CH3)(L)] (L = L1-LS) have shown that the favoured isomers have the more strongly a-donating CH3 ligand trans to the bulkier ptSU2 donor. Studies with [PdCI2(L)], [PtCI2(L)] and [Pt(CH3h(L)
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Smith, Kate Jennifer. "Ditopic ligands for the extraction of divalent metal salts." Thesis, University of Edinburgh, 2004. http://hdl.handle.net/1842/12982.

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This thesis extends earlier work at the University of Edinburgh aimed at opening up new flowsheets for the hydrometallurgical recovery of base metals using tetradentate ligands which are capable of transporting metal salts {both a metal cation and its attendant anion(s)}. Prototypes were based on salicylaldimine derivatives of diamines, “salen” ligands in which coordination of a metal dication releases the two phenolic protons which are captured by pendant secondary amine groups generating a preorganised dicationic binding site for the anion(s). The thesis initially deals with the design, synt
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Dussart, Caitlyn. "Chiral self-recognition study of metallic complexes : towards coordination polymers." Electronic Thesis or Diss., Strasbourg, 2024. http://www.theses.fr/2024STRAE006.

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Les assemblages polymériques métallo-supramoléculaires constituent une nouvelle classe de matériaux apparue au cours des dernières décennies. Ces matériaux présentent un large éventail de propriétés qui dépendent de la nature des métaux et des ligands ditopiques utilisés. La réversibilité des liaisons de coordination offre également un caractère dynamique au système qui peut répondre à un stimulus externe. En introduisant de la chiralité dans ces systèmes moléculaires, nous pouvons étudier la capacité de ces structures moléculaires à s’associer ou à se désolidariser pour former des espèces hom
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Santillan, Guillermo A. "Coordination polymers and building blocks based on ditopic heteroscorpionate ligands." Diss., [La Jolla] : [San Diego] : University of California, San Diego ; San Diego State University, 2009. http://wwwlib.umi.com/cr/ucsd/fullcit?p3379543.

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Thesis (Ph. D.)--University of California, San Diego and San Diego State University, 2009.<br>Title from first page of PDF file (viewed November 17, 2009). Available via ProQuest Digital Dissertations. Vita. Includes bibliographical references.
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Galbraith, Stuart G. "Ditopic ligands for the selective solvent extraction of transition metal sulfates." Thesis, University of Edinburgh, 2004. http://hdl.handle.net/1842/10911.

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The thesis considers the development of new reagents which could transport transition metal <i>salts</i> in extractive hydrometallurgy and addresses the ligand design features which are needed to control the strength and selectivity of binding of both a particular metal cation and its attendant anions(s). Extractive metallurgy of base metals is surveyed in chapter 1 and suggests that more efficient recovery processes are needed. One new approach, which could lead to much better materials balances in many cases, is to use hydrometallurgical techniques which involve co-extraction and transport o
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Bokolinis, Georgios. "The synthesis of novel ditopic ligands for supramolecular chemistry and sensor applications." Thesis, University of Huddersfield, 2006. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.430296.

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Gordon, Ross John. "Improved mass transport efficiency in copper solvent extraction." Thesis, University of Edinburgh, 2009. http://hdl.handle.net/1842/5673.

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This thesis considers methods which can be employed to increase the mass of copper transferred into and out of the organic phase during the load and strip stages of commercial solvent extraction processes. Conventional 5-alkylsalicylaldoxime reagents transfer 1 mol of divalent copper per 2 mol of ligand in a neutral complex of the type [Cu(L-H)2] via a pH-swing process. New triacidic ligands have been designed which triple the molar transport of copper to form [Cu3(L-3H)2]. Until recently copper recovery by solvent extraction has been confined to oxidic ores which are leached with sulfuric aci
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Zanardi, Alessandro. "N-heterocyclic-carbene-based Ditopic and Hemicleaveable ligands for the design of improved catalysts." Doctoral thesis, Universitat Jaume I, 2010. http://hdl.handle.net/10803/669141.

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La presente memoria ha profundizado en el diseño de nuevos catalizadores al utilizar dos nuevos tipos de ligandos diferenciados: triazolil-di-ilideno y bis-alquenil-NHCs. El uso del ligando trimetiltriazolil-di-ilideno, ha permitido obtener series de compuestos de tipo homo- y hetero-bimetálicos, estableciéndose criterios claros de coordinación que garantizan que el mismo ligando se puede utilizar de manera amplia en su coordinación a prácticamente cualquier par de fragmentos metálicos. La preparación y la caracterización de los compuestos heterobimetálicos establece un gran avance en el di
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Book chapters on the topic "Ditopic ligand"

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Pardasani, R. T., and P. Pardasani. "Magnetic properties of tetranuclear cobalt(II) complex with ditopic ligand." In Magnetic Properties of Paramagnetic Compounds, Magnetic Susceptibility Data, Volume 5. Springer Berlin Heidelberg, 2022. http://dx.doi.org/10.1007/978-3-662-65098-1_259.

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Walczak, Rafał, Iga Zuba, Wojciech Starosta, and Jianwei Ren. "Post-synthetic modification of zirconium terephthalate sorbents and their application for sorption of selected toxic elements from water." In Waste PET-MOF-Cleanwater: Waste PET-Derived Metal-Organic Framework (MOFs) as Cost-Effective Adsorbents for Removal of Hazardous Elements from Polluted Water. UJ Press, 2022. http://dx.doi.org/10.36615/9781776419463-08.

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Metal-organic Framework (MOF) porous materials have been a subject of interest for about two decades. The discovered recipe for their synthesis consisting of a combination of highly tunable metal nodes and ditopic or multitopic ligands resulted in the exponential growth of new structures. At present, a wealth of material on synthesis, structural, and functional properties have been accumulated. It shows a potentially wide range of applications in the field of gas storage, separation of gaseous mixtures, catalysis, drug delivery, energy, and environment protection. The unique features of MOFs,
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Conference papers on the topic "Ditopic ligand"

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Sanmartín-Matalobos, Jesús, Ana García-Deibe, Martín Amoza, et al. "Computational and Experimental Studies Into the Conformations of a Triptycene-Based Ditopic Ligand." In The 18th International Electronic Conference on Synthetic Organic Chemistry. MDPI, 2014. http://dx.doi.org/10.3390/ecsoc-18-e007.

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