Academic literature on the topic 'Divinylbenzen'

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Journal articles on the topic "Divinylbenzen"

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Mix, Hermann. "Herstellung von p-Lithiummethylstyren-Divinylbenzen-Copolymeren: Eine Schlüsselsubstanz für funktionalisierte Polystyrenträger." Zeitschrift für Chemie 19, no. 4 (August 31, 2010): 148–49. http://dx.doi.org/10.1002/zfch.19790190418.

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Bischof, J., K. G. Häusler, G. Popov, K. Häupke, and G. Schwachula. "Charakterisierung von vernetzten Polymeren mittels Verdampfungsanalyse. VII. Poröse Adsorberpolymere auf Ethylstyren-Divinylbenzen-Basis." Acta Polymerica 40, no. 7 (July 1989): 468–73. http://dx.doi.org/10.1002/actp.1989.010400712.

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Silva, Carla, Paulo Rocha, Thiago Aversa, and Elizabete Lucas. "Removal of Petroleum from Aqueous Systems by Poly(divinylbenzene) and Poly(methyl methacrylate-divinylbenzene) Resins: Isothermal and Kinetic Studies." Chemistry & Chemical Technology 13, no. 3 (July 15, 2019): 399–406. http://dx.doi.org/10.23939/chcht13.03.399.

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Jin, Fu Qiang, Yan Li, Su Qin Hu, Bo Jiang, and Xiao Dong Zhang. "Poly(styrene-Divinylbenzene) Microspheres Prepared by Seed Swelling Polymerization in the Presence of Tung Oil Methyl Esters." Materials Science Forum 675-677 (February 2011): 341–44. http://dx.doi.org/10.4028/www.scientific.net/msf.675-677.341.

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Poly(styrene-divinylbenzene) microspheres were prepared by seed swelling polymerization in the presence of tung oil methyl esters. First, the core monodisperse polystyrene microspheres were prepared by a dispersion polymerization method. Using polystyrene microspheres as seed, tung oil methyl esters as a functional monomer, divinylbenzene as crosslinker, poly(styrene-divinylbenzene) microspheres were prepared by seed swelling polymerization. Then they were characterized by using FT-IR spectroscopy, TG/DSC and optical microscopy. Results showed that the tung oil methyl esters did participate in the copolymerization of styrene and divinylbenzene.
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Aprilita, Nurul Hidayat, Rania Bakry, Christian W. Huck, and Guenther K. Bonn. "POLY(GLYCIDYL METHACRYLATE-DIVINYLBENZENE) MONOLITHIC CAPILLARY AS A STATIONARY PHASE FOR THE REVERSED-PHASE CHROMATOGRAPHIC SEPARATION OF PROTEINS." Indonesian Journal of Chemistry 5, no. 1 (June 14, 2010): 1–6. http://dx.doi.org/10.22146/ijc.21830.

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Capillary column with monolithic stationary phase was prepared from silanized fused-silica capillary of 200 µm I.D. by in situ free radical polymerization of divinylbenzene with glycidy methacrylate in the presence of decanol and tetrahydrofuran as porogens. The hydrodynamic and chromatographic properties of this monolith, such as backpressure at different flow-rate, pore size distribution, van Deemter plot and the effect of varying gradient-rate were investigated. Poly(glycidyl methacrylate-divinylbenzene) monolithic capillary has been used successfully for the reversed-phase chromatographic separation of proteins. Keywords: monolithic stationary phase, poly(glycidyl methacrylate-divinylbenzene), proteins
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Kim, Yang Soo, David Sudol, Victoria Dimonie, and Mohammed El-Aasser. "Preparation of Hollow Polystyrene Nanocapsules via a Miniemulsion Polymerization Process." Key Engineering Materials 306-308 (March 2006): 1091–96. http://dx.doi.org/10.4028/www.scientific.net/kem.306-308.1091.

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Hollow polystyrene nanocapsules with sizes of ~100 nm have been prepared via a miniemulsion polymerization process by applying the encapsulation of a nonsolvent (i.e., isooctane). Divinylbenzene has been added to styrene as a cross-linking comonomer in order to improve a structural stability of the hollow polymer capsules. Morphology variation of nanocapsules with concentrations of divinylbenzene and also isooctane has been studied using transmission electron microscopy analysis. Kinetic study on the miniemulsion polymerization of styrene in the presence of divinylbenzene and isooctane has been carried out using fractional conversion data determined by the gravimetric analysis.
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Aprilita, Nurul Hidayat, Rania Bakry, Christian W. Huck, and Guenther K. Bonn. "MONOLITHIC DISK FOR THE FAST CHROMATOGRAPHIC SEPARATION." Indonesian Journal of Chemistry 5, no. 2 (June 14, 2010): 108–14. http://dx.doi.org/10.22146/ijc.21815.

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Poly(styrene/divinylbenzene) (PS/DVB) monolithic disk was prepared by in situ free-radical copolymerization of styrene and divinylbenzene in the presence of decanol and tetrahydrofuran as porogens. PS/DVB monolithic disks were produced in two different lengths 1.5 mm and 3 mm. The disks were used in reversed phase chromatography of proteins with 0.2 % trifuoroacetic acid (TFA) and 0.2 % TFA in acetonitrile as mobile phase A and B, respectively. The effect of gradient rate, flow rate, temperature and disk length on the separation of proteins were also studied. PS/DVB monolithic disks allow the rapid separation of proteins in reversed phase chromatography. Keywords: monolithic disk, poly(styrene/divinylbenzene), proteins
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Elbayoumy, Elsayed, Yuting Wang, Jamil Rahman, Claudio Trombini, Masayoshi Bando, Zhiyi Song, Mostafa A. Diab, Farid S. Mohamed, Naofumi Naga, and Tamaki Nakano. "Pd Nanoparticles-Loaded Vinyl Polymer Gels: Preparation, Structure and Catalysis." Catalysts 11, no. 1 (January 18, 2021): 137. http://dx.doi.org/10.3390/catal11010137.

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Four vinyl polymer gels (VPGs) were synthesized by free radical polymerization of divinylbenzene, ethane-1,2-diyl dimethacrylate, and copolymerization of divinylbenzene with styrene, and ethane-1,2-diyl dimethacrylate with methyl methacrylate, as supports for palladium nanoparticles. VPGs obtained from divinylbenzene and from divinylbenzene with styrene had spherical shapes while those obtained from ethane-1,2-diyl dimethacrylate and from ethane-1,2-diyl dimethacrylate with methyl methacrylate did not have any specific shapes. Pd(OAc)2 was impregnated onto VPGs and reduced to form Pd0 nanoparticles within VPGs. The structures of Pd0-loaded VPGs were analyzed by XRD, TEM, and nitrogen gas adsorption. Pd0-loaded VPGs had nanocrystals of Pd0 within and on the surface of the polymeric supports. Pd0/VPGs efficiently catalyzed the oxidation/disproportionation of benzyl alcohol into benzaldehyde/toluene, where activity and selectivity between benzaldehyde and toluene varied, depending on the structure of VPG and the weight percentage loading of Pd0. The catalysts were stable and Pd leaching to liquid phase did not occur. The catalysts were separated and reused for five times without any significant decrease in the catalytic activity.
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Chansatidkosol, Siraprapa, Praneet Opanasopit, and Prasert Akkaramongkolporn. "Tablet Disintegrant Derived from Crosslinked Methacrylic Acid and Divinylbenzene Copolymers." Advanced Materials Research 1060 (December 2014): 168–71. http://dx.doi.org/10.4028/www.scientific.net/amr.1060.168.

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Methacrylic acid copolymers crosslinked with 0.25-16 % divinylbenzene were synthesized by free radical polymerization using benzoyl peroxide as an initiator. The products were washed, dried and passed through a 80-mesh sieve prior to determining their infrared spectra, swelling capacity in water and disintegrant efficacy for microcrystalline cellulose (MCC) placebo tablet. The crosslinked methacrylic acid and divinylbenzene copolymers were successfully prepared as indicated by IR spectra, yielding around 50-80 %. The sieved particles of copolymers were white to faint yellow. In contact with water, they hydrated and swelled, where their swelling capacity was lowered with increasing the level of crosslink (divinylbenzene) in the copolymer structure. The copolymer with 0.25 % crosslink caused the MCC tablet to disintegrate fastest (1.2 min), corresponding to its highest swelling capacity. The disintegration efficacy increased with an increase in copolymer concentrations, but decreased with an increase in compression forces.
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Salman, Salman R., Mustafa M. F. Al-Jarrah, and E. Ahmed. "Photopolymerization of p-divinylbenzene." Journal of Polymer Science: Polymer Letters Edition 26, no. 2 (February 1988): 99–102. http://dx.doi.org/10.1002/pol.1988.140260207.

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Dissertations / Theses on the topic "Divinylbenzen"

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Gehrke, Maik. "Funktionalisierung von Polystyren-Divinylbenzen-Harzen zur selektiven Festphasenextraktion von Aromastoffen." [S.l. : s.n.], 2000. http://deposit.ddb.de/cgi-bin/dokserv?idn=959276637.

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Šálek, Petr. "Příprava a charakterizace magnetických nosičů z hypersíťovaných polystyrenových mikročástic a jejich použití v biosenzoru." Doctoral thesis, Vysoké učení technické v Brně. Fakulta chemická, 2012. http://www.nusl.cz/ntk/nusl-233348.

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With the aim to develop and characterize a functionalized highly magnetic polymer carrier of micrometer size and of a narrow particle size distribution that will be suitable for biological application, hypercrosslinked microspheres were prepared. Simultaneously, the relation between structure and properties of product was observed. Condition of dispersion polymerization were optimized to obtain starting monodisperse poly(styrene-co-divinylbenzene) [P(St-DVB)] microspheres. The P(St-DVB) microspheres of different degree of crosslinking were prepared and effect of some polymerization parameters such as type of solvent, initiator, concentration and mode of DVB addition on morphology, size and particle size distribution were investigated. The starting microspheres were hypercrosslinked to obtain microporous inner structure. Hyperosslinked particles had very large specific surface area (> 1000 m2/g) and a high content of micropores (ca. 0.6 ml/g). First, P(St-DVB) microspheres were chloromethylated using three different chloromethylation agents to regulate their porous properties. Hypercrosslinking was achieved by the addition of stannic chloride as a catalyst and by increasing a temperature. The hypercrosslinked microspheres were then functionalized with sulfo- or aminogroups. The functional groups captured precipitated iron oxide inside the porous structure of the microspheres and also served as a reactive site for intended immobilization of the protein. A solution of ferrous and ferric chloride was imbibed under vacuum into the porous structure and the iron oxide was precipitated by an aqueous ammonia solution. Finally, the magnetic functionalized hypercrosslinked micropsheres were integrated into a biosensor for qualitative detection of ovalbumin.
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Alger, Luke. "Dispersion polymerisation of divinylbenzene." Thesis, Loughborough University, 2004. https://dspace.lboro.ac.uk/2134/34134.

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Particles containing 55% divinylbenzene (DVB) have been prepared using dispersion polymerisation. The steric stabilisers that have been utilised are partially hydrolysed poly(vinyl acetate)s, poly(ethylene oxide) and a poly(ethylene oxide) macromonomer in methanolic media. The concentrations of stabiliser, monomer and initiator have been varied to investigate the influence that they have on the particle size and the particle size distribution. The particles have been characterised by scanning electron microscopy (SEM) for a visual impression of the particles in addition to laser diffraction particle size analysis and hydrodynamic chromatography (HDC) for particle size.
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Füssler, Rainer. "Ausschluss- und ionenchromatographische Untersuchungen zur Porenstruktur von PS-DVB-Copolymeren als Trägermaterial für die Ionenchromatographie." [S.l. : s.n.], 2001. http://deposit.ddb.de/cgi-bin/dokserv?idn=963203339.

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Narwark, Oliver. "Spektroskopische Charakterisierung und Bestimmung der Morphologie von substituierten 1,4-Divinylbenzol-Oligomeren." [S.l. : s.n.], 2002. http://deposit.ddb.de/cgi-bin/dokserv?idn=965366758.

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Fleming, James S. "d'8-metal complexes of 1,8-divinylnaphthalene and 1,2-divinylbenzene." Thesis, University of Bristol, 1993. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.385969.

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Abdallah, Wisam. "Production And Characterization Of Activated Carbon From Sulphonated Styrene Divinylbenzene Copolymer." Master's thesis, METU, 2004. http://etd.lib.metu.edu.tr/upload/12605498/index.pdf.

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Activated Carbon was produced from strong cation-exchange resins, sulphonated styrene divinylbenzene copolymers originally in H+ form, by means of carbonization and steam activation in an electrical furnace. One macroporous resin produced by BAYER Chemicals Inc., Lewatit MonoPlus SP 112 H, was used in the research. Products of carbonization and activation were characterized by using BET, Mercury Porosimetry, Helium Pycnometry and SEM techniques. The effect of carbonization time and temperature on the BET surface areas of the resins were also investigated. Two sets of carbonization experiments (Set 1 and 2) were performed in which time and temperature were varied in order to study their effects on the BET surface areas of the products. In activation experiments (Set 3), carbonized ion-exchangers (600 oC, 1 hr) were activated with steam at 900°
C, changing the time of activation and the steam flow rate. The temperatures of the water bath used for steam generation were selected as 60°
C, 80°
C and 90°
C. The pore structures of activated carbons were determined by proper techniques. The volume and area of macropores in the pore diameter range of 8180-50 nm were determined by mercury intrusion porosimetry. Mesopore (in the range of 50-2 nm) areas and volumes were determined by N2 gas adsorption technique at -195.6oC, BET surface areas of the samples were also determined, in the relative pressure range of 0.05 to 0.02, by the same technique. The pore volume and the area of the micropores with diameters less than 2 nm were determined by CO2 adsorption measurements at 0oC by the application of Dubinin Radushkevich equation. In the experiments of Sets 1 and 2, the BET surface area results of the six different carbonization times ranging from 0.5 to 3 hours gave almost the same value with a maximum deviation of 5% from the average showing almost no effect on the areas of the products. In the experiments of Set 3 , the sample activated at 800°
C for 6 hrs had the highest BET area, 2130 m2/g, and the one activated at 800°
C for 1 hr had the lowest BET area 636 m2/g. N2 adsorption/ desorption isotherms showed no distinct hysteresis indicating a cylindrical geometry of the pores. Adsorption isotherms further indicated that the pores are both highly microporous and mesoporous. N2 (BET) and CO2 (D-R) surface areas of the samples were in the range of 636-2130m2/g and 853-1858 m2/g, respectively. Surface areas of the samples consisted of about 8-53% mesopores and 47-92% micropores.
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Hubbard, K. Lise (Kirsten Lise-Lotte). "The study of poly(Divinylbenzene-co-ethylvinylbenzene) and modifications to the pendant vinylbenzene groups /." Thesis, McGill University, 1997. http://digitool.Library.McGill.CA:80/R/?func=dbin-jump-full&object_id=34644.

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Cross-linked resins of poly(divinylbenzene-co-ethylvinylbenzene) were characterized and modified by a variety of reactions with the pendant vinylbenzene groups. Laboratory-prepared resins of a known composition were compared and contrasted to a commercial version with regard to surface area, porosity, and vinylbenzene content. The commercial resin, Amberlite XAD-4 (Rohm and Haas Company), had a higher surface area (831 m2 /g), porosity (1.18 mL/g), and accessible vinylbenzene groups (2.5 mmol/g, degree of functionalization 33%). Modifications of both resins by radical addition of a variety of thiols led to higher conversions (of vinylbenzene groups to modified groups) with use of the commercial resin (as high as 76%). Further modifications were done strictly with XAD-4. Some thiol additions to XAD-4 were done with water as the solvent, with conversions as high as 43%. Disulfides were added across the vinylbenzene groups of XAD-4 with iodine catalysis, with conversions as high as 55%. This simple one-step reaction has never been done with a polymer system before. XAD-4 was completely epoxidized using a solution of dimethyldioxirane in acetone, and completely brominated to form a resin with (1,2-dibromoethyl)benzene groups (3.76 mmol Br/g). Resins with (1-hydroxy-2-bromoethyl)benzene groups (1.5 mmol/g) were prepared by reaction of XAD-4 with N-bromosuccinimide and water, with 73% conversion. Resins with thiol groups (2.5 mmol S/g) were prepared by a one-pot reaction of brominated XAD-4 with N,N-dimethylthioformamide followed by methanolysis. From one commercially-available resin, several polymers with a variety of functional groups have thus been prepared by simple one- to three-step modifications.
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Downey, Jeffrey S. "Precipitation polymerization of divinylbenzene to monodisperse microspheres : an investigation of the particle formation mechanism /." *McMaster only, 2000.

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Hubbard, K. Lise. "The study of poly(Divinylbenzene-co-Ethylvinylbenzene) and modifications to the pendant vinylbenzene groups." Thesis, National Library of Canada = Bibliothèque nationale du Canada, 1997. http://www.collectionscanada.ca/obj/s4/f2/dsk2/tape16/PQDD_0013/NQ36984.pdf.

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Books on the topic "Divinylbenzen"

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Zaugg, Steven D. Methods of analysis by the U.S. Geological Survey National Water Quality Laboratory: Determination of wastewater compounds by polystyrene-divinylbenzene solid-phase extraction and capillary-column gas chromatography/mass spectrometry. Denver, Colo: U.S. Dept. of the Interior, U.S. Geological Survey, 2002.

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Hubbard, K. Lise. The study of poly (Divinylbenzene-co-ethylvinylbenzene) and modifications to the pendant vinylbenzene groups. Montréal, Qué, 1997.

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T, Furlong Edward, Geological Survey (U.S.), and National Water-Quality Laboratory (U.S.), eds. Determination of human-health pharmaceuticals in filtered water by chemically modified styrene-divinylbenzene resin-based solid-phase extraction and high-performance liquid chromatography/mass spectrometry. Reston, Va: U.S. Dept. of the Interior, U.S. Geological Survey, 2008.

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Methods of analysis by the U.S. Geological Survey National Water Quality Laboratory: Extraction of nitroaromatic compounds from water by polystyrene divinylbenzene cartridge and determination by high-performance liquid chromatography. Denver, Colo: U.S. Dept. of the Interior, U.S. Geological Survey, 1994.

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D, Zaugg Steven, and Geological Survey (U.S.), eds. Methods of analysis by the U.S. Geological Survey National Water Quality Laboratory: Determination of wastewater compounds by polystyrene-divinylbenzene solid-phase extraction and capillary-column gas chromatography/mass spectrometry. Denver, CO: National Water Quality Laboratory, U.S. Geological Survey, 2002.

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Book chapters on the topic "Divinylbenzen"

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Gooch, Jan W. "Divinylbenzene." In Encyclopedic Dictionary of Polymers, 238. New York, NY: Springer New York, 2011. http://dx.doi.org/10.1007/978-1-4419-6247-8_3886.

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Bährle-Rapp, Marina. "Sodium Styrene/Acrylates/Divinylbenzene Copolymer." In Springer Lexikon Kosmetik und Körperpflege, 518. Berlin, Heidelberg: Springer Berlin Heidelberg, 2007. http://dx.doi.org/10.1007/978-3-540-71095-0_9740.

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Joseph, John M. "Selectivity of Poly(styrene-divinylbenzene) Columns." In ACS Symposium Series, 83–100. Washington, DC: American Chemical Society, 1986. http://dx.doi.org/10.1021/bk-1986-0297.ch005.

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Wohlfarth, Ch. "Solubility parameter of poly(styrene-co-divinylbenzene)." In Polymer Solutions, 1654. Berlin, Heidelberg: Springer Berlin Heidelberg, 2010. http://dx.doi.org/10.1007/978-3-642-02890-8_1005.

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Wohlfarth, Ch. "Second virial coefficient of poly(styrene-co-divinylbenzene)." In Polymer Solutions, 1125. Berlin, Heidelberg: Springer Berlin Heidelberg, 2010. http://dx.doi.org/10.1007/978-3-642-02890-8_689.

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Hoover, J. M., T. C. Ward, and J. E. McGrath. "Hydrogenated Star Block Copolymers of Butylstyrene — Isoprene and Divinylbenzene." In Advances in Polyolefins, 89–97. Boston, MA: Springer US, 1987. http://dx.doi.org/10.1007/978-1-4757-9095-5_9.

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Okubo, Masayoshi, Yuichiro Konishi, and Hideto Minami. "Production of hollow particles by suspension polymerization of divinylbenzene with nonsolvent." In Aqueous Polymer Dispersions, 54–59. Berlin, Heidelberg: Springer Berlin Heidelberg, 2004. http://dx.doi.org/10.1007/b12137.

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Rodriguez, A. F. R., J. A. H. Coaquira, J. G. Santos, L. B. Silveira, E. M. Marmolejo, W. Trennepohl, D. Rabelo, A. C. Oliveira, V. K. Garg, and P. C. Morais. "Characterization of magnetite nanoparticles supported in sulfonated styrene-divinylbenzene mesoporous copolymer." In ISIAME 2008, 417–23. Berlin, Heidelberg: Springer Berlin Heidelberg, 2009. http://dx.doi.org/10.1007/978-3-642-01370-6_55.

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Soldatov, V. S., and V. M. Zelenkovskii. "Computer Modeling of Strong Acid Cation Exchangers on Styrene: Divinylbenzene Matrix." In Ion Exchange Technology I, 509–45. Dordrecht: Springer Netherlands, 2012. http://dx.doi.org/10.1007/978-94-007-1700-8_16.

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Okubo, Masayoshi, Yuichiro Konishi, and Hideto Minami. "Production of hollow particles by suspension polymerization of divinylbenzene with nonsolvent." In Aqueous Polymer Dispersions, 54–59. Berlin, Heidelberg: Springer Berlin Heidelberg, 2004. http://dx.doi.org/10.1007/978-3-540-36474-0_11.

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Conference papers on the topic "Divinylbenzen"

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Cabaleiro-Lago, Enrique, Ángeles Peña-Gallego, and Jesús Rodríguez-Otero. "DFT Study of the Cyclization of 1,2-divinylbenzene snd Derivatives." In The 10th International Electronic Conference on Synthetic Organic Chemistry. Basel, Switzerland: MDPI, 2006. http://dx.doi.org/10.3390/ecsoc-10-01457.

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Fania, David F., Kamali Kannangara, Adriyan Milev, and Gary Dennis. "The importance of carbonisation atmosphere on char properties derived from poly(divinylbenzene)." In Fourth International Conference on Smart Materials and Nanotechnology in Engineering, edited by Jayantha A. Epaarachchi, Alan Kin-tak Lau, and Jinsong Leng. SPIE, 2013. http://dx.doi.org/10.1117/12.2027838.

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Norman, Seth I., and Dan A. Kimball. "A Commercial Citrus Debittering System." In ASME 1990 Citrus Engineering Conference. American Society of Mechanical Engineers, 1990. http://dx.doi.org/10.1115/cec1990-3601.

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Excessive bitterness in citrus juices has been extensively studied in the past due to a reduction in juice quality. In the late 1970’s, Australia began to commercially debitter citrus juices using cellulose acetate beads. However, due to operational problems, this plant was shutdown. Continued research has led to the first commercial debittering installation in the United States. Using a proprietary styrene/divinylbenzene hydrophylic adsorbent, a citrus debittering system was started in 1988 to debitter navel orange juice. The automatic citrus debittering system was designed for continuous operation at an operator’s selectable flow rate from between 20 to 55 gallons per minute. The determination of the economics, compositional analysis and taste of the treated products was the focus of this study. Paper published with permission.
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Yin, Yong, J. Mei Zhang, Zhao Dai, Xiu X. Sun, Shi C. Xu, Long Wang, and Guo Zheng. "Preparation of monodisperse poly(divinylbenzene- co -4-vinylpyridine) microspheres by distillation-precipitation polymerization and precipitation polymerization." In 2010 International Conference on Display and Photonics, edited by Yanwen Wu. SPIE, 2010. http://dx.doi.org/10.1117/12.869661.

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Aritonang, Barita, Tamrin Tamrin, Basuki Wirjosentono, and Eddiyanto Eddiyanto. "Functionalization of cyclic natural rubber (CNR) with oleic acid and divinylbenzene as compatibilizer in variation of dicumylperoxide." In THE 3RD INTERNATIONAL SEMINAR ON CHEMISTRY: Green Chemistry and its Role for Sustainability. Author(s), 2018. http://dx.doi.org/10.1063/1.5082465.

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Reports on the topic "Divinylbenzen"

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Methods of analysis by the U.S. Geological Survey National Water Quality Laboratory--Determination of wastewater compounds by polystyrene-divinylbenzene solid-phase extraction and capillary-column gas chromatography/mass spectrometry. US Geological Survey, 2002. http://dx.doi.org/10.3133/wri20014186.

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