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Journal articles on the topic 'Dodecaborate'

Author: Grafiati

Published: 4 June 2021

Last updated: 18 February 2022

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1

Semioshkin, Andrej, Olga Tsaryova, Olga Zhidkova, Vladimir Bregadze, and Dieter Wöhrle. "Reactions of oxonium derivatives of (B12H12)2- with phenoles, and synthesis and photochemical properties of a phthalocyanine containing four (B12H12)2- groups." Journal of Porphyrins and Phthalocyanines 10, no. 11 (2006): 1293–300. http://dx.doi.org/10.1142/s1088424606000661.

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The reactions of dodecahydro-closo-dodecaborate oxonium derivatives with various phenols resulted in phenoxy-undecahydro-closo-dodecaborates in high yields. Using this method, a phthalocyanine zinc(II) complex containing four ( B 12 H 12)2- species was prepared in high yield. The compound shows good photocatalytic activity. The combination of boron cages and phthalocyanines makes this compound useful for boron neutron capture therapy for cancer and photodynamic tumor therapy.

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2

Stavila, Vitalie. "Structural features of metal dodecahydro-closo-dodecaborates." Acta Crystallographica Section A Foundations and Advances 70, a1 (2014): C1026. http://dx.doi.org/10.1107/s2053273314089736.

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Metal dodecahydro-closo-dodecaborates have been recently explored as materials for hydrogen storage and as promising ionic conductors. However, their utility as hydrogen storage media is impeded by their high thermal stability, kinetic limitations, and side reactions. The high thermal and chemical stability of these materials makes them interesting for solid battery membrane applications, however more work is needed to understand the complicated phase transitions which occur in many metal dodecahydro-closo-dodecaborates. Recent literature suggests that dodecahydro-closo-dodecaborate species ar

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3

Laskova, Julia, Alexandra Kozlova, Magdalena Białek-Pietras, et al. "Reactions of closo-dodecaborate amines. Towards novel bis-(closo-dodecaborates) and closo-dodecaborate conjugates with lipids and non-natural nucleosides." Journal of Organometallic Chemistry 807 (April 2016): 29–35. http://dx.doi.org/10.1016/j.jorganchem.2016.02.009.

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4

Meyer, Franc, Jens Müller, Peter Paetzold, and Roland Boese. "Opening of an Aza-closo-dodecaborane to an Aza-nido-dodecaborate." Angewandte Chemie International Edition in English 31, no. 9 (1992): 1227–29. http://dx.doi.org/10.1002/anie.199212271.

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5

Nakamura, Hiroyuki, Shunsuke Kikuchi, Kazuki Kawai, Satomu Ishii, and Shinichi Sato. "closo-Dodecaborate-conjugated human serum albumins: preparation and in vivo selective boron delivery to tumor." Pure and Applied Chemistry 90, no. 4 (2018): 745–53. http://dx.doi.org/10.1515/pac-2017-1104.

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Abstract Maleimide-functionalized closo-dodecaborate (MID) and isothiocyanate-functionalized closo-dodecaborate (ISD) were synthesized from closo-dodecaborate via ring opening reaction of 1,4-dioxane-closo-dedecaborate complex 1 with ammonia. MID was found to possess highest conjugation efficacy to bovine serum albumin among three closo-dodecaborate derivatives, MID, ISD, and 1. The conjugation reaction of MID to human serum albumin (HSA) proceeded under PBS buffer conditions (pH 7.4). Boron distribution studies in colon 26 tumor-bearing mice revealed that HSA-MID was highly accumulated in tum

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6

Joosten, Dominik, Ingo Pantenburg, and Lars Wesemann. "Distanna-closo-dodecaborate." Angewandte Chemie International Edition 45, no. 7 (2006): 1085–87. http://dx.doi.org/10.1002/anie.200503197.

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7

Sivaev, Igor B., Vladimir I. Bregadze, and Stefan Sjöberg. "Chemistry of closo-Dodecaborate Anion [B12H12]2-: A Review." Collection of Czechoslovak Chemical Communications 67, no. 6 (2002): 679–727. http://dx.doi.org/10.1135/cccc20020679.

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Synthesis and chemical properties of the closo-dodecaborate anion [B12H12]2- and its derivatives are reviewed. Attention is also paid to potential applications of the closo-dodecaborate derivatives with emphasis on medical applications. A review with 325 references.

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8

Konieczka, Szymon Z., Michael Drisch, Katharina Edkins, Michael Hailmann, and Maik Finze. "Polyfluorinated carba-closo-dodecaboranes with amino and ammonio substituents bonded to boron." Dalton Transactions 44, no. 45 (2015): 19576–86. http://dx.doi.org/10.1039/c5dt02055g.

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The three isoelectronic inner salts 1-H-x-H<sub>3</sub>N-closo-1-CB<sub>11</sub>F<sub>10</sub> (x = 12, 7, 2) are accessible by fluorination of x-H<sub>3</sub>N-closo-1-CB<sub>11</sub>H<sub>11</sub> (x = 12, 2) and 7-H<sub>3</sub>N-12-F-closo-1-CB<sub>11</sub>H<sub>10</sub>, respectively. Deprotonation of the decafluorinated ammoniocarba-closo-dodecaboranes yields the corresponding aminocarba-closo-dodecaborate anions [1-H-x-H<sub>2</sub>N-closo-1-CB<sub>11</sub>F<sub>10</sub>]<sup>−</sup> (x = 12, 7, 2).

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9

Stopka, Pavel, and Oldřich Štrouf. "An ESR study of UV-irradiated solutions of tetramethylammonium mercaptoundecahydro-closo-dodecaborate(2-) at 77 K." Collection of Czechoslovak Chemical Communications 56, no. 3 (1991): 657–62. http://dx.doi.org/10.1135/cccc19910657.

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The superoxide anion-radicals O2·- are generated by the ultraviolet irradiation of air- or oxygen-saturated aqueous solutions of tetramethylammonium mercaptoundecahydro-closo-dodecaborate(2-) at 77 K. The superoxide anion-radicals are formed from the oxygen molecule coordinated on the mercaptoundecahydro-closo-dodecaborate dianion. In the absence of this dianion no O2·- are generated. By the irradiation in the presence of hydrogen peroxide the formation of the superoxide anion-radicals is more intensive than in the presence of oxygen only. Simultaneously with O2·- generation the corresponding

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10

Peymann, Toralf, Carolyn B. Knobler, Saeed I. Khan, and M. Frederick Hawthorne. "Dodecahydroxy-closo-dodecaborate(2−)." Journal of the American Chemical Society 123, no. 10 (2001): 2182–85. http://dx.doi.org/10.1021/ja0014887.

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11

Peymann, Toralf, Carolyn B. Knobler, Saeed I. Khan, and M. Frederick Hawthorne. "Dodecamethyl-closo-dodecaborate(2−)." Inorganic Chemistry 40, no. 6 (2001): 1291–94. http://dx.doi.org/10.1021/ic0010398.

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12

Gädt, Torben, and Lars Wesemann. "Stanna-closo-dodecaborate Chemistry." Organometallics 26, no. 10 (2007): 2474–81. http://dx.doi.org/10.1021/om061042k.

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13

Semioshkin, Andrey A., Sergey N. Osipov, Julia N. Grebenyuk, et al. "An Effective Approach to 1,2,3-Triazole-Containing 12-Vertex closo-Dodecaborates." Collection of Czechoslovak Chemical Communications 72, no. 12 (2007): 1717–24. http://dx.doi.org/10.1135/cccc20071717.

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An efficient general synthetic approach giving a facile, rapid and inexpensive access to a wide range of novel 1,2,3-triazoles bearing closo-dodecaborate fragment has been developed. The method is based on the nucleophilic cleavage of oxonium dodecaborate with NaN3 or tertiary propargylamine and subsequent Huisgen 1,3-dipolar cycloaddition ("click" methodology) of the cleavage products and organic acetylenes or azides.

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14

Saleh, Mahmoud, Douglas R. Powell, and Rudolf J. Wehmschulte. "Chlorination of 1-Carba-closo-dodecaborate and 1-Ammonio-closo-dodecaborate Anions." Inorganic Chemistry 55, no. 20 (2016): 10617–27. http://dx.doi.org/10.1021/acs.inorgchem.6b01867.

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15

Marx, Thiemo, Benno Ronig, Herbert Schulze, Ingo Pantenburg, and Lars Wesemann. "Alkylderivatives of Stanna-closo-dodecaborate." Journal of Organometallic Chemistry 664, no. 1-2 (2002): 116–22. http://dx.doi.org/10.1016/s0022-328x(02)01971-x.

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16

Gädt, Torben, Falko M. Schappacher, Rainer Pöttgen, and Lars Wesemann. "Iodination of Stanna-closo-dodecaborate." Inorganic Chemistry 46, no. 7 (2007): 2864–69. http://dx.doi.org/10.1021/ic0622858.

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17

King, Benjamin T., Zbyněk Janoušek, Bohumír Grüner, Matthew Trammell, Bruce C. Noll, and Josef Michl. "Dodecamethylcarba-closo-dodecaborate(−) Anion, CB11Me12-." Journal of the American Chemical Society 118, no. 13 (1996): 3313–14. http://dx.doi.org/10.1021/ja9541443.

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18

Novopashina, Darya S., Mariya A. Vorobyeva, Alexander A. Lomzov, Vladimir N. Silnikov, and Alya G. Venyaminova. "Terminal Mono- and Bis-Conjugates of Oligonucleotides with Closo-Dodecaborate: Synthesis and Physico-Chemical Properties." International Journal of Molecular Sciences 22, no. 1 (2020): 182. http://dx.doi.org/10.3390/ijms22010182.

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Oligonucleotide conjugates with boron clusters have found applications in different fields of molecular biology, biotechnology, and biomedicine as potential agents for boron neutron capture therapy, siRNA components, and antisense agents. Particularly, the closo-dodecaborate anion represents a high-boron-containing residue with remarkable chemical stability and low toxicity, and is suitable for the engineering of different constructs for biomedicine and molecular biology. In the present work, we synthesized novel oligonucleotide conjugates of closo-dodecaborate attached to the 5′-, 3′-, or bot

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19

Wixtrom, Alex I., Zeeshan A. Parvez, Miles D. Savage, et al. "Tuning the electrochemical potential of perfunctionalized dodecaborate clusters through vertex differentiation." Chemical Communications 54, no. 46 (2018): 5867–70. http://dx.doi.org/10.1039/c8cc03477j.

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20

Joshi, Meenakshi, and Tapan K. Ghanty. "Lanthanide and actinide doped B12H122− and Al12H122− clusters: new magnetic superatoms with f-block elements." Physical Chemistry Chemical Physics 21, no. 42 (2019): 23720–32. http://dx.doi.org/10.1039/c9cp04333k.

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21

Jiang, Yanrong, Qinqin Yuan, Wenjin Cao та ін. "Gaseous cyclodextrin-closo-dodecaborate complexes χCD·B12X122− (χ = α, β, and γ; X = F, Cl, Br, and I): electronic structures and intramolecular interactions". Physical Chemistry Chemical Physics 23, № 24 (2021): 13447–57. http://dx.doi.org/10.1039/d1cp01131f.

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22

Shen, Yunjun, Yani Pan, Kang Zhang, et al. "B–H functionalization of the monocarba-closo-dodecaborate anion by rhodium and iridium catalysis." Dalton Transactions 46, no. 10 (2017): 3135–40. http://dx.doi.org/10.1039/c7dt00269f.

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23

Assaf, Khaleel I., Detlef Gabel, Wolfgang Zimmermann, and Werner M. Nau. "High-affinity host–guest chemistry of large-ring cyclodextrins." Organic & Biomolecular Chemistry 14, no. 32 (2016): 7702–6. http://dx.doi.org/10.1039/c6ob01161f.

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24

Qi, Bin, Xin Li, Liang Sun, et al. "In situsynthesis of ultrafine metal clusters triggered by dodecaborate supramolecular organic frameworks." Nanoscale 10, no. 42 (2018): 19846–53. http://dx.doi.org/10.1039/c8nr06917d.

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25

Wang, Wenjing, Xiaoqiang Wang, Jin Cao, et al. "The chaotropic effect as an orthogonal assembly motif for multi-responsive dodecaborate-cucurbituril supramolecular networks." Chemical Communications 54, no. 17 (2018): 2098–101. http://dx.doi.org/10.1039/c7cc08078f.

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26

Ishii, Satomu, Shinichi Sato, Hiroya Asami, Tomoko Hasegawa, Jun-Ya Kohno, and Hiroyuki Nakamura. "Design of S–S bond containing maleimide-conjugated closo-dodecaborate (SSMID): identification of unique modification sites on albumin and investigation of intracellular uptake." Organic & Biomolecular Chemistry 17, no. 22 (2019): 5496–99. http://dx.doi.org/10.1039/c9ob00584f.

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27

Assaf, Khaleel I., Andreas Hennig, Shu Peng, Dong-Sheng Guo, Detlef Gabel, and Werner M. Nau. "Hierarchical host–guest assemblies formed on dodecaborate-coated gold nanoparticles." Chemical Communications 53, no. 33 (2017): 4616–19. http://dx.doi.org/10.1039/c7cc01507k.

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28

Marx, Thiemo, and Lars Wesemann. "Platinum complexes of stanna-closo-dodecaborate." Journal of Organometallic Chemistry 614-615 (December 2000): 137–43. http://dx.doi.org/10.1016/s0022-328x(00)00468-x.

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29

Himmelspach, Alexander, Guido J. Reiss, and Maik Finze. "2-Azaniumylcarba-closo-dodecaborate ethanol monosolvate." Acta Crystallographica Section E Structure Reports Online 67, no. 3 (2011): o704. http://dx.doi.org/10.1107/s1600536811006222.

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30

Doch, M., A. Lindemann, A. Hammerschmidt, and B. Krebs. "The novel octathallium-selenoborato-closo-dodecaborate." Acta Crystallographica Section A Foundations of Crystallography 58, s1 (2002): c315. http://dx.doi.org/10.1107/s0108767302097593.

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31

Peymann, Toralf, Carolyn B. Knobler, Saeed I. Khan, and M. Frederick Hawthorne. "ChemInform Abstract: Dodecahydroxy-closo-dodecaborate(2-)." ChemInform 32, no. 26 (2010): no. http://dx.doi.org/10.1002/chin.200126022.

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32

Zhang, Kang, Yunjun Shen, Jiyong Liu, Bernhard Spingler, and Simon Duttwyler. "Crystal structure of a carborane endo/exo-dianion and its use in the synthesis of ditopic ligands for supramolecular frameworks." Chemical Communications 54, no. 14 (2018): 1698–701. http://dx.doi.org/10.1039/c7cc07724f.

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33

Tachikawa, Shoji, Tatsuro Miyoshi, Hayato Koganei, et al. "Spermidinium closo-dodecaborate-encapsulating liposomes as efficient boron delivery vehicles for neutron capture therapy." Chem. Commun. 50, no. 82 (2014): 12325–28. http://dx.doi.org/10.1039/c4cc04344h.

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34

Meschaninova, Mariya I., Darya S. Novopashina, Olga A. Semikolenova, Vladimir N. Silnikov, and Alya G. Venyaminova. "Novel Convenient Approach to the Solid-Phase Synthesis of Oligonucleotide Conjugates." Molecules 24, no. 23 (2019): 4266. http://dx.doi.org/10.3390/molecules24234266.

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A novel and convenient approach for the solid-phase 5′-functionalization of oligonucleotides is proposed in this article. The approach is based on the activation of free 5′-hydroxyl of polymer support-bound protected oligonucleotides by N,N′-disuccinimidyl carbonate followed by interaction with amino-containing ligands. Novel amino-containing derivatives of closo-dodecaborate, estrone, cholesterol, and α-tocopherol were specially prepared. A wide range of oligonucleotide conjugates bearing closo-dodecaborate, short peptide, pyrene, lipophilic residues (cholesterol, α-tocopherol, folate, estron

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35

Fan, Ping, Stefan Stolte, and Detlef Gabel. "Interaction of organic compounds and boron clusters with new silica matrices containing the phosphatidylcholine headgroup." Anal. Methods 6, no. 9 (2014): 3045–55. http://dx.doi.org/10.1039/c4ay00119b.

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36

Zhu, Tian-Cheng, Yang-Yang Xing, Yuji Sun, Simon Duttwyler, and Xin Hong. "Directed B–H functionalization of the closo-dodecaborate cluster via concerted iodination–deprotonation: reaction mechanism and origins of regioselectivity." Organic Chemistry Frontiers 7, no. 22 (2020): 3648–55. http://dx.doi.org/10.1039/d0qo01019g.

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37

Shen, Yunjun, Yani Pan, Jiyong Liu, Tosaporn Sattasathuchana, Kim K. Baldridge, and Simon Duttwyler. "Synthesis and full characterization of an iridium B–H activation intermediate of the monocarba-closo-dodecaborate anion." Chemical Communications 53, no. 1 (2017): 176–79. http://dx.doi.org/10.1039/c6cc08121e.

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38

Jiang, Tao, Kang Zhang, Yunjun Shen, et al. "The 12-ethynylmonocarba-closo-dodecaborate anion as a versatile ligand for Cu(i) alkyne and heterobimetallic Cu(i)/M(ii) (M = Pd, Pt) alkynide complexes." Dalton Transactions 48, no. 46 (2019): 17192–99. http://dx.doi.org/10.1039/c9dt03272j.

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39

Jung, Dahee, Fernando Raffan-Montoya, Roshini Ramachandran, et al. "Cross-linked porous polyurethane materials featuring dodecaborate clusters as inorganic polyol equivalents." Chemical Communications 55, no. 60 (2019): 8852–55. http://dx.doi.org/10.1039/c9cc03350e.

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A perhydroxylated dodecaborate cluster acts as an inorganic polyol to produce cross-linked polyurethanes, which confers a porous structure and enhanced thermal stability compared to analogous polymers produced from carbon-based polyols.

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40

Justus, Eugen, Dana T. Izteleuova, Alexander V. Kasantsev, Mendel M. Axartov, Enno Lork, and Detlef Gabel. "Preparation of Carboranyl and Dodecaborate Derivatives of Coumarin." Collection of Czechoslovak Chemical Communications 72, no. 12 (2007): 1740–54. http://dx.doi.org/10.1135/cccc20071740.

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A series of derivatives of coumarin (2H-chromen-2-one) and 6,7-benzocoumarin (3H-benzo-[f]chromen-3-one) carrying the o-carborane, m-carborane, and dodecaborate clusters, has been obtained. X-ray structure analysis has been carried out for three of the products. The addition of o-carborane occurs in the 4-position of the coumarin ring, in a stereoselective way, independent of whether the cluster was reacted as the lithium or magnesium salt. m-Carborane gives two products, one being the result of 1,2-addition to an exocyclic ester bond and 1,4-addition to the coumarin system, the other resultin

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41

Watanabe, Mamoru, Junichiro Kanazawa, Tomofumi Hamamura, et al. "Boron-vertex modification of carba-closo-dodecaborate for high-performance magnesium-ion battery electrolyte." Materials Advances 2, no. 3 (2021): 937–41. http://dx.doi.org/10.1039/d0ma00925c.

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A new family of Mg salts of carba-closo-dodecaborate was developed for Mg ion battery applications. Modification at the boron vertices drastically improves the solubility without compromising the chemical and redox stability.

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42

Šembera, Filip, Alexander Higelin, Ivana Císařová, and Josef Michl. "12-(N-Methylnitrilium)monocarba-closo-dodecaborate Ylide." Croatica Chemica Acta 87, no. 4 (2014): 357–61. http://dx.doi.org/10.5562/cca2475.

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43

Semioshkin, Andrey, Julia Laskova, Błażej Wojtczak, et al. "Synthesis of closo-dodecaborate based nucleoside conjugates." Journal of Organometallic Chemistry 694, no. 9-10 (2009): 1375–79. http://dx.doi.org/10.1016/j.jorganchem.2008.12.024.

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44

Juhasz, Marcus A., Douglas H. Juers, Gregory E. Dwulet, and Aaron J. Rosenbaum. "Tetraethylammonium 7,12-dicyano-1-carba-closo-dodecaborate." Acta Crystallographica Section E Structure Reports Online 70, no. 4 (2014): o411—o412. http://dx.doi.org/10.1107/s1600536814004759.

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In the title compound, C8H20N+·C3H10B11N2−, the carborane anion cage displays nearly-perfectCssymmetry, with the two CN groups lying on a noncrystallographic mirror plane that bisects the cage. In the crystal, the anions form extended chains along thea-axis direction, with C—H...N hydrogen bonds linking consecutive anions. The C[triple-bond]N bond lengths (and B—C[triple-bond]N angles) in the nitrile moities are 1.1201 (19) Å, 178.60 (15)° and 1.1433 (17) Å, 179.45 (15)°, similar to those observed in organic nitriles. A hydrogen bond between a methylene H atom of the cation and the N atom in o

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45

Saldin, V. I., M. A. Karpenko, L. N. Ignat’eva, Yu M. Nikolenko, V. M. Buznik, and Yu M. Mikhailov. "Hexamethylenetetrammonium dodecahydro-closo-dodecaborate: Synthesis and study." Russian Journal of Inorganic Chemistry 54, no. 1 (2009): 13–16. http://dx.doi.org/10.1134/s0036023609010033.

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46

Saldin, V. I., L. N. Ignat’eva, Yu M. Nikolenko, V. M. Buznik, and Yu M. Mikhailov. "Thermal conversions of chitosanium dodecahydro-closo-dodecaborate." Russian Journal of Inorganic Chemistry 55, no. 8 (2010): 1221–27. http://dx.doi.org/10.1134/s0036023610080115.

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47

Tanaka, Naoki, Yoshiaki Shoji, and Takanori Fukushima. "Convenient Route to Monocarba-closo-dodecaborate Anions." Organometallics 35, no. 11 (2016): 2022–25. http://dx.doi.org/10.1021/acs.organomet.6b00309.

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48

Kirchmann, Marius, Torben Gädt, Klaus Eichele, and Lars Wesemann. "Nickel Coordination Compounds of Stanna-closo-dodecaborate." European Journal of Inorganic Chemistry 2008, no. 14 (2008): 2261–65. http://dx.doi.org/10.1002/ejic.200800142.

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49

Kirchmann, Marius, Sebastian Fleischhauer, and Lars Wesemann. "Iridium Coordination Compounds of Stanna-closo-dodecaborate." Organometallics 27, no. 12 (2008): 2803–8. http://dx.doi.org/10.1021/om8001679.

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50

Gädt, Torben, Jörg-Alexander Dimmer, Sebastian Fleischhauer, et al. "Oxidation of germa- and stanna-closo-dodecaborate." Dalton Transactions 44, no. 10 (2015): 4726–31. http://dx.doi.org/10.1039/c5dt00099h.

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Oxidation of group 14 heteroborates [GeB<sub>11</sub>H<sub>11</sub>]<sup>2−</sup> and [SnB<sub>11</sub>H<sub>11</sub>]<sup>2−</sup> yields a symmetrical dimer exhibiting a Ge–Ge bond or an unsymmetrical dimer bearing an Sn–B bond.

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