Academic literature on the topic 'Dodecane cracking'

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Journal articles on the topic "Dodecane cracking"

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Ishihara, Atsushi, Kouki Mori, Kazuya Mori, Tadanori Hashimoto, and Hiroyuki Nasu. "Preparation of hierarchical catalysts with the simultaneous generation of microporous zeolite using a template and large mesoporous silica by gel skeletal reinforcement and their reactivity in the catalytic cracking of n-dodecane." Catalysis Science & Technology 9, no. 14 (2019): 3614–18. http://dx.doi.org/10.1039/c9cy00693a.

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Chen, Zhiqiang, Suyao Liu, Huaike Zhang, et al. "Selective regulation of n-dodecane isomerization and cracking performance in Pt/beta catalysts via orientation control of Brønsted acid site distribution." Catalysis Science & Technology 11, no. 6 (2021): 2094–102. http://dx.doi.org/10.1039/d0cy02088e.

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Wang, Ya, Xiaochao Xian, Xu Hou, Xiangwen Zhang, Li Wang, and Guozhu Liu. "Catalytic cracking of binary hydrocarbons of n-dodecane and iso-dodecane under supercritical conditions." Journal of Analytical and Applied Pyrolysis 113 (May 2015): 133–36. http://dx.doi.org/10.1016/j.jaap.2014.11.015.

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Zhao, Jie, Wei Guo, Guozhu Liu, Xiangwen Zhang, and Li Wang. "Cracking of n-dodecane during supercritical state on HZSM-5 membranes." Fuel Processing Technology 91, no. 9 (2010): 1090–97. http://dx.doi.org/10.1016/j.fuproc.2010.03.019.

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Song, Kyoung Ho, Soon Kwan Jeong, Ki Tae Park, Kwan-Young Lee, and Hak Joo Kim. "Supercritical catalytic cracking of n-dodecane over air-oxidized activated charcoal." Fuel 276 (September 2020): 118010. http://dx.doi.org/10.1016/j.fuel.2020.118010.

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Chen, Wenkai, Xiaoyuan Fang, Cheng Zhu, Xinqi Qiao, and Dehao Ju. "Development of a skeletal oxidation mechanism for Fischer–Tropsch diesel surrogate based on decoupling method and particle swarm optimization." Proceedings of the Institution of Mechanical Engineers, Part A: Journal of Power and Energy 234, no. 8 (2020): 1147–60. http://dx.doi.org/10.1177/0957650919897474.

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As an alternative liquid fuel, Fischer–Tropsch (FT) diesel has received significant attentions due to its characteristics of high efficiency and low emission. In this study, a surrogate fuel containing iso-hexadecane and n-dodecane with a mole ratio of 0.16:0.84 is formulated for real FT diesel by mimicking its combustion-related physicochemical properties. Mechanisms of these two components are developed based on decoupling methodology: skeletal sub-mechanisms describing iso-hexadecane and n-dodecane cracking process are constructed and combined with a reduced C0–C4 core mechanism, and then the Arrhenius parameters of certain reactions are tuned by particle swarm optimization algorithm to improve prediction accuracy. The optimized mechanisms are validated against experimental results of ignition delays, species concentrations and laminar flame speeds for iso-hexadecane and n-dodecane, respectively. Finally, by merging all the sub-mechanisms mentioned above, a skeletal oxidation model for FT diesel surrogate including 73 species and 324 reactions is obtained and employed in 3D CFD simulations to validate the ignition behavior of FT diesel sprays in a constant-volume combustion vessel; the simulation results show good agreement with experimental data.
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Zhang, Dingrui, Lingyun Hou, Mingyu Gao, and Xiaoxiong Zhang. "Experiment and Modeling on Thermal Cracking of n-Dodecane at Supercritical Pressure." Energy & Fuels 32, no. 12 (2018): 12426–34. http://dx.doi.org/10.1021/acs.energyfuels.8b03386.

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Hao, Jiangge, Ying Wang, Guozhu Liu, Jingwen Zhang, Guozhu Li, and Xuesong Ma. "Synthesis of ITQ-2 Zeolites and Catalytic Performance in n-Dodecane Cracking." Chinese Journal of Chemical Engineering 22, no. 8 (2014): 869–74. http://dx.doi.org/10.1016/j.cjche.2014.06.008.

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Diao, Zhenheng, Lushi Cheng, Xu Hou, et al. "Fabrication of the Hierarchical HZSM-5 Membrane with Tunable Mesoporosity for Catalytic Cracking of n-Dodecane." Catalysts 9, no. 2 (2019): 155. http://dx.doi.org/10.3390/catal9020155.

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Hierarchical HZSM-5 membranes were prepared on the inner wall of stainless steel tubes, using amphiphilic organosilane (TPOAC) and mesitylene (TMB) as a meso-porogen and a swelling agent, respectively. The mesoporosity of the HZSM-5 membranes were tailored via formulating the TPOAC/Tetraethylorthosilicate (TPOAC/TEOS) ratio and TMB/TPOAC ratio, in synthesis gel, and the prepared membranes were systematically characterized by X-ray diffraction (XRD), scanning electron microscope (SEM), N2 adsorption–desorption, N2 permeation, inductively coupled plasma (ICP), in situ fourier transform infrared (FT-IR), ammonia temperature-programmed desorption (NH3-TPD), etc. It was found that the increase of the TPOAC/TEOS ratio promoted a specific surface area and diffusivity of the HZSM-5 membranes, as well as decreased acidity; the increase of the TMB/TPOAC ratios led to an enlargement of the mesopore size and diffusivity of the membranes, but with constant acid properties. The catalytic performance of the prepared HZSM-5 membranes was tested using the catalytic cracking of supercritical n-dodecane (500 °C, 4 MPa) as a model reaction. The hierarchical membrane with the TPOAC/TEOS ratio of 0.1 and TMB/TPOAC ratio of 2, exhibited superior catalytic performances with the highest activity of up to 13% improvement and the lowest deactivation rate (nearly a half), compared with the microporous HZSM-5 membrane, due to the benefits of suitable acidity, together with enhanced diffusivity of n-dodecane and cracking products.
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Ji, Yajun, Bofang Shi, Honghui Yang, and Wei Yan. "Synthesis of isomorphous MFI nanosheet zeolites for supercritical catalytic cracking of n-dodecane." Applied Catalysis A: General 533 (March 2017): 90–98. http://dx.doi.org/10.1016/j.apcata.2017.01.005.

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Dissertations / Theses on the topic "Dodecane cracking"

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Guerra, Patricia. "Effect of supercritical water on coke formed during dodecane cracking with ZSM-5." Digital WPI, 2018. https://digitalcommons.wpi.edu/etd-theses/1301.

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The objective of this work was to study the effect of supercritical water on coke formed on ZSM-5 during its use as a dodecane cracking catalyst. ZSM-5 coking was quantified at different reaction times, finding that the presence of supercritical water reduced coke formation by an order of magnitude or more. Coked samples were analyzed using several methods, including temperature programmed oxidation (TPO), attenuated total reflectance infrared (ATR-IR) spectroscopy, carbon-13 nuclear magnetic resonance (13C NMR), diffuse reflectance ultraviolet-visible spectroscopy (DR-UV-vis) and UV-Raman. Coked produced in the absence of SCW was formed by polycyclic aromatic hydrocarbons (PAHs) with more than 4 aromatic rings containing alkyl side chains. Coke produced in the presence of SCW was formed by aromatics with 1 to 3 aromatic rings. The characteristics of coke formed in the absence of water on ZSM-5 that had been pretreated in SCW were intermediate to those of coke formed on fresh ZSM-5 in the presence and absence of water, suggesting that the presence of water influences coke properties. It was also verified that SCW can decrease coke formation due to its effect on Bronsted acidity of the catalyst and ability to promote coke gasification. The effect of coke deposits produced in the presence and absence of SCW on the rate of ethanol dehydration, a model reaction studied under diffusion-controlled conditions, indicated that SCD/SWC coke deactivated less the catalyst than SCD coke.
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Bruening, Christopher. "Decalin Dehydrogenation for In-Situ Hydrogen Production to Increase Catalytic Cracking Rate of n-Dodecane." University of Dayton / OhioLINK, 2018. http://rave.ohiolink.edu/etdc/view?acc_num=dayton1525100991525704.

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Zaker, Azadeh. "Supercritical Water Assisted Zeolite Catalyzed Upgrading of Hydrocarbons." Digital WPI, 2019. https://digitalcommons.wpi.edu/etd-dissertations/579.

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Previous studies have successfully used near and supercritical water (SCW) for cracking and desulfurization of heavy crude oil and bio-oil, suppressing coke formation as a low-value by-product. Some of these studies benefited from using zeolite catalysts to increase the activity and selectivity toward targeted products; however, in depth studies are required to identify the role of water on zeolite catalysis under supercritical condition. Using three common zeolites, ZSM-5, HY, and β for supercritical water cracking of dodecane at 400°C, 24±2 MPa (in a 100 ml batch reactor), we showed that ZSM-5 is the only catalyst that partially retains its crystalline structure and activity under hydrothermal conditions. Further characterization of the ZSM-5 (used under 50/50 wt% SCW/dodecane feed) revealed 95% decrease in Brønsted acid site (BAS) density and 80% decrease in microporous area after 2 h reaction time. However, compared to the runs where SCW was absent, the apparent dodecane cracking rate constant in SCW decreased only by a factor of 2.6. Examining catalytic activity of ZSM-5 degradation products and re-using ZSM-5 showed that the unexpected activity cannot be ascribed to ZSM-5 degradation products. Using a group-type model, we showed that SCW accelerated gas and suppressed coke formations. Additionally a coke gasification pathway was suggested to account for formation of CO and CO2 in the presence of SCW. Additional experiments with two different ZSM-5 particle sizes suggested that dodecane cracking reaction is diffusion-limited in the absence of SCW and reaction-limited in its presence. Zero length chromatography of calcined and hydrothermally treated ZSM-5 showed 10 times greater apparent diffusivity for un-treated catalyst. This, according to Weisz-Prater analysis, suggested a 250 times greater dodecane surface concentration in the absence of SCW. We successfully optimized the water content of feed (5-15 wt%) to decrease the destructive effects of SCW on the structure, increase the selectivity toward BTEX products and eliminate coke formation.
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Smith, Bradley Joseph. "Steam-Assisted Catalysis of n-Dodecane as a Jet Fuel Analogue in a Flow Reactor System for Hypersonic Thermal Management." University of Dayton / OhioLINK, 2019. http://rave.ohiolink.edu/etdc/view?acc_num=dayton1577978953025703.

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Book chapters on the topic "Dodecane cracking"

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Sicard, M., M. Grill, B. Raepsaet, F. Ser, C. Potvin, and G. Djéga-Mariadassou. "n-dodecane thermal and catalytic cracking under supercritical conditions." In Zeolites and related materials: Trends, targets and challenges, Proceedings of the 4th International FEZA Conference. Elsevier, 2008. http://dx.doi.org/10.1016/s0167-2991(08)80078-x.

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Al-Baghli, N., and S. Al-Khattaf. "Catalytic cracking of a mixture of dodecane and 1,3,5 triisopropyl-benzene over USY and ZSM-5 zeolites based catalysts." In Molecular Sieves: From Basic Research to Industrial Applications, Proceedings of the 3rd International Zeolite Symposium (3rd FEZA). Elsevier, 2005. http://dx.doi.org/10.1016/s0167-2991(05)80523-3.

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Conference papers on the topic "Dodecane cracking"

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Liu, Guozhu, Yongjin Han, Wei Guo, Xiangwen Zhang, Li Wang, and Zhentao Mi. "Supercritical Initiative Cracking of Endothermic Fuel Model Compound n-Dodecane with 1-Nitroprapane." In 44th AIAA/ASME/SAE/ASEE Joint Propulsion Conference & Exhibit. American Institute of Aeronautics and Astronautics, 2008. http://dx.doi.org/10.2514/6.2008-5127.

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Guo, Wei, Xiangwen Zhang, Guozhu Liu, Guimei Chen, and Zhentao Mi. "Coke and Its Precursor Formation During n-Dodecane and Toluene Supercritical Catalytic Cracking." In 44th AIAA/ASME/SAE/ASEE Joint Propulsion Conference & Exhibit. American Institute of Aeronautics and Astronautics, 2008. http://dx.doi.org/10.2514/6.2008-5128.

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Plekhova, K. S., A. S. Yurtaeva, T. I. Gulyaeva, O. V. Potapenko, T. P. Sorokina, and V. P. Doronin. "Joint transformations of H-dodecane and 2-methylthiophene on bizeolite cracking catalysts containing phosphorus-modified zeolite ZSM-5." In INTERNATIONAL CONFERENCE ON PHYSICS AND CHEMISTRY OF COMBUSTION AND PROCESSES IN EXTREME ENVIRONMENTS (COMPHYSCHEM’20-21) and VI INTERNATIONAL SUMMER SCHOOL “MODERN QUANTUM CHEMISTRY METHODS IN APPLICATIONS”. AIP Publishing, 2020. http://dx.doi.org/10.1063/5.0032913.

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