Academic literature on the topic 'DSC and kinetics of thermal decomposition'

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Journal articles on the topic "DSC and kinetics of thermal decomposition"

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Tsai, Lung Chang, Jian Ming Wei, Yung Chuan Chu, et al. "RDX Kinetic Model Evaluation by Nth Order Kinetic Algorithms and Model Simulations." Advanced Materials Research 189-193 (February 2011): 1413–16. http://dx.doi.org/10.4028/www.scientific.net/amr.189-193.1413.

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A kinetic model based on the thermal decomposition of 1,3,5-trinitro-1,3,5-triazmane (RDX) was constructed via differential scanning calorimetry (DSC), well-known kinetic equations, curve-fitting analysis, and simulations of thermal analysis. Our objective was to analyze thermokinetic parameters derived from heating rates used in DSC and compare simulations of thermal decomposition under various kinetic models. Experimental results were strongly dependent on the validity of the kinetic model, which was based on an appropriate mathematical model and a proper method for the evaluation of kinetic
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Nowak, Mariusz, Barbara Cichy, and Ewa Kużdżał. "Kinetics of melamine phosphate thermal decomposition in DSC studies." Journal of Thermal Analysis and Calorimetry 126, no. 1 (2016): 277–85. http://dx.doi.org/10.1007/s10973-016-5705-2.

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Gu, Jiangshan, Lu Liu, Huanhuan Chen, Wanghua Chen, Zichao Guo, and Liping Chen. "Study on the thermal decomposition kinetics of DNTF." E3S Web of Conferences 245 (2021): 01027. http://dx.doi.org/10.1051/e3sconf/202124501027.

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3,4-Dinitrofurazanylfuroxan (DNTF) is a representative of the third-generation energetic materials with complex thermal decomposition behavior. Understanding thermal decomposition process of DNTF is of great significance for the safety of its production, storage and use. In this paper, the dynamic differential scanning calorimetry (DSC) test is carried out to study its thermal decomposition characteristics. The quench and reheat experiments and isothermal tests were performed to determine the types of decomposition reactions. A four-step consecutive reaction model, A→B→C→D→E, where each step i
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Li, Yuehua, Yu Liu, Liping Chen, Wenqian Wu, Xiaoqiao Zhao, and Wanghua Chen. "Research on the thermal hazard of N-Nitrodihydroxyethyl dinitrate (DINA) under the action of diethanolamine." E3S Web of Conferences 245 (2021): 03026. http://dx.doi.org/10.1051/e3sconf/202124503026.

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N-Nitrodihydroxyethyl dinitrate (DINA) is a commonly used energetic material. In this work, the effect of diethanolamine (DEA) on the thermal stability of DINA was studied. Firstly, the decomposition kinetics of DINA under the influence of DEA was analyzed by applying dynamic differential scanning calorimeter (DSC) experiments. Then, isothermal DSC tests with the “Interruption and re-scanning” method determined that the decomposition reactions of DINA containing 29% DEA consists of four continuous steps: the first step is a n-order reaction, and the last three steps are autocatalytic reactions
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Liu, Rui, Tonglai Zhang, Li Yang, Zunning Zhou, and Xiaochun Hu. "Research on thermal decomposition of trinitrophloroglucinol salts by DSC, TG and DVST." Open Chemistry 11, no. 5 (2013): 774–81. http://dx.doi.org/10.2478/s11532-013-0205-8.

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AbstractThe thermal decomposition of the four nitrogen-rich salts of ammonia (NH4), aminoguanidine (AG), carbohydrazide (CHZ) and 5-aminotetrazo (ATZ) based on trinitrophloroglucinol (H3TNPG) was investigated using the differential scanning calorimetry (DSC), thermogravity (TG), and dynamic vacuum stability test (DVST). DSC and TG methods research the complete decomposition, while DVST method researches the very early reaction stage. The peak temperatures of DSC curves are consistent with the temperatures of maximum mass loss rates of TG curves. The apparent activation energies of these H3TNPG
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Perrenot, B., and G. Widmann. "TG and DSC kinetics of thermal decomposition and crystallization processes." Journal of Thermal Analysis 37, no. 8 (1991): 1785–92. http://dx.doi.org/10.1007/bf01912209.

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Chu, I. Tien, Shu Yao Tsai, Wan Tran Huang, Jo Ming Tseng, Jin Shuh Li, and Chun Ping Lin. "Modelling Method for Preventing Thermal Runaway Reaction Accident of Thermal Reactive Material." Advanced Materials Research 936 (June 2014): 2030–34. http://dx.doi.org/10.4028/www.scientific.net/amr.936.2030.

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Thermally reactive materials have caused many serious accidents involving storage and transportation, due to being thermally reactive. The safe storage and management of these materials still is a critical problem in many countries. We studied the thermal hazard of thermal reactive materials, such as a propellant, by employing differential scanning calorimetry (DSC) non-isothermal tests and isothermal tests, and then comparing the kinetic parameters by isothermal and non-isothermal of kinetics, avoiding the mistaken results of the single thermal analysis model. The chosen approach was to obtai
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Svoboda, Roman, Zuzana Olmrová Zmrhalová, Dušan Galusek, Daniela Brandová, and Jozef Chovanec. "Thermal decomposition of mixed calcium oxalate hydrates – kinetic deconvolution of complex heterogeneous processes." Physical Chemistry Chemical Physics 22, no. 16 (2020): 8889–901. http://dx.doi.org/10.1039/c9cp06867h.

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Kiselev, Vitaly G., Nikita V. Muravyev, Konstantin A. Monogarov, et al. "Toward reliable characterization of energetic materials: interplay of theory and thermal analysis in the study of the thermal stability of tetranitroacetimidic acid (TNAA)." Physical Chemistry Chemical Physics 20, no. 46 (2018): 29285–98. http://dx.doi.org/10.1039/c8cp05619f.

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Kinetics and mechanism of thermal decomposition of tetranitroacetimidic acid, a novel green energetic material, were studied using complementary thermoanalytical methods (DSC and TGA) and quantum chemistry (CCSD(T)-F12).
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Pan, Feng, Zai Yuan Li, and Chun Ji Li. "Study on Thermal Decomposition Kinetics of Nano-Cr(OH)3 Powder." Applied Mechanics and Materials 692 (November 2014): 377–80. http://dx.doi.org/10.4028/www.scientific.net/amm.692.377.

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Abstract. This paper studies on the thermal decomposition analysis kinetics of nanometer powders. The DTA-TG-DTG curves obtain by SDT 2960 Simultaneous DSC-TGA analysis apparatus. Under the condition of N2atmosphere operation and rise temperature velocity was 10°C·min-1. The mechanism function dα/dt=κ(1-α)nis used to calculate the kinetics factors. Reaction progressionnwas obtained by calculation of the kissinger peak shape factor method. The results showed that the apparent activation energy of nano-Ni(OH)2was 254.027 KJ·mol-1, the pre-exponential factor was 3.062×1036, the reaction progressi
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Dissertations / Theses on the topic "DSC and kinetics of thermal decomposition"

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Neres, Renata Aparecida. "Caracterização térmica de amostras de esponja sintética dupla face e palha de aço." Universidade de São Paulo, 2014. http://www.teses.usp.br/teses/disponiveis/46/46136/tde-23012015-100142/.

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Este trabalho tem por objetivo a caracterização comparativa do comportamento de degradação e/ou decomposição térmica da esponja sintética dupla face, base poliuretana (parte amarela e parte verde), e da palha de aço, a partir das técnicas termoanalíticas. As esponjas sintéticas para limpeza doméstica, em substituição à palha de aço, apesar da vantagem econômica, podem apresentar restrições de descartes para o meio ambiente ou expor o usuário a riscos de contaminação. Amostras de esponja sintética dupla face (verde e amarela) e de palha de aço foram caracterizadas por análise térmica (TG/DTG, D
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Koreeda, Tamy. "Caracterização termoanalítica e estudo de cura de compósito de resina epóxi e mica com propriedades elétricas isolantes aplicado em máquinas hidrogeradoras." Universidade de São Paulo, 2011. http://www.teses.usp.br/teses/disponiveis/46/46133/tde-25042011-112216/.

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Atualmente, a participação da energia elétrica na matriz energética mundial é um assunto em evidência. O estudo do compósito isolante da barra estatórica, um dos componentes principais da máquina hidrogeradora, permite a obtenção de informações físico-químicas relevantes ao aperfeiçoamento do sistema, e também de estudos de comportamento térmico quando este é exposto à alta temperatura, por diferentes intervalos de tempo submetidos a estresses mecânicos, elétricos e/ou químicos. O sistema em estudo é o MICALASTIC®, desenvolvido pela empresa Siemens em 1960. Neste trabalho, as propriedades térm
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Gundogar, Sati Asli. "Thermal Characterization And Kinetics Of Crude Oils By Tga And Dsc Methods." Master's thesis, METU, 2010. http://etd.lib.metu.edu.tr/upload/12611502/index.pdf.

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In recent years, the application of thermal analysis to study the combustion and pyrolysis behavior of fossil fuels has gained a wide acceptance because of its significance for industry and economy. In this thesis, the thermal and kinetic analysis of different origin crude oil samples are performed by two well-known thermal analysis techniques: Differential Scanning Calorimetry (DSC) and Thermogravimetry (TG/DTG). The investigation of combustion and pyrolysis behaviors, kinetic analysis of oil samples and the determination of heating rate effect are the main objectives of this study. Six diffe
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Brien, Kimberly A. "Bismuth aryloxide reactivity kinetics of thermal decomposition and resulting organic oxidation products /." [Fort Worth, Tex.] : Texas Christian University, 2010. http://etd.tcu.edu/etdfiles/available/etd-07232010-131742/unrestricted/Brien.pdf.

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Chai, Ming. "Thermal Decomposition of Methyl Esters in Biodiesel Fuel: Kinetics, Mechanisms and Products." University of Cincinnati / OhioLINK, 2012. http://rave.ohiolink.edu/etdc/view?acc_num=ucin1342544227.

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Topa, Ece Hatice. "Thermal Characterization And Kinetics Of Diesel, Methanol Route Biodiesel, Canola Oil And Diesel-biodiesel Blends At Different Blending Rates By Tga And Dsc." Master's thesis, METU, 2010. http://etd.lib.metu.edu.tr/upload/12612460/index.pdf.

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Application of thermogravimetric analysis to the renewable energy sources is a novel study and it has been becoming attractive by the researchers in recent years. In this thesis, thermal and kinetic properties of biodiesel as new energy source, diesel and canola oil have been analyzed by using very popular thermogravimetric analysis methods which are<br>Differential Scanning Calorimetry (DSC) and Thermogravimetry (TGA/DTG). The main aim of the study is to observe the combustion and pyrolysis behaviour of methanol route biodiesel and diesel blends at different blending rates. Additionally, comb
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Haligva, Cef. "Natural gas recovery from hydrates in a silica sand matrix." Thesis, University of British Columbia, 2008. http://hdl.handle.net/2429/2791.

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This thesis studies methane hydrate crystal formation and decomposition at 1.0, 4.0 and 7.0°C in a new apparatus. Hydrate was formed in the interstitial space of a variable volume bed of silica sand particles with an average diameter equal to 329μm (150 to 630μm range). The initial pressure inside the reactor was 8.0MPa for all the formation experiments. Three bed sizes were employed in order to observe the effects of the silica sand bed size on the rate of methane consumption (formation) and release (decomposition). The temperature at various locations inside the silica sand bed was measured
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Al-Sousi, Ghareeb N. "Studies on the thermal decomposition behaviour, kinetics and electrical conductivity of the non-isothermal decomposition of pyridine mono carboxylic acids and some of their transition metal complexes." Thesis, Aston University, 2000. http://publications.aston.ac.uk/9623/.

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The thesis is divided into four chapters. They are: introduction, experimental, results and discussion about the free ligands and results and discussion about the complexes. The First Chapter, the introductory chapter, is a general introduction to the study of solid state reactions. The Second Chapter is devoted to the materials and experimental methods that have been used for carrying out the experiments. The Third Chapter is concerned with the characterisations of free ligands (Picolinic acid, nicotinic acid, and isonicotinic acid) by using elemental analysis, IR spectra, X-ray diffraction,
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McSwiney, Michael L. "The thermal decomposition of calcium copper acetate hexahydrate : a study of the overall pathway and the kinetics and mechanism of the dehydration /." The Ohio State University, 1997. http://rave.ohiolink.edu/etdc/view?acc_num=osu1487948440825499.

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Li, Fan. "Development of Techniques to Produce Nickel Coated Composite Materials as well as Hollow Nickel Fibres and Kinetic Study of the Process Involved." Doctoral thesis, Stockholm : Materialvetenskap, Kungliga Tekniska högskolan, 2007. http://urn.kb.se/resolve?urn=urn:nbn:se:kth:diva-4478.

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Books on the topic "DSC and kinetics of thermal decomposition"

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service), SpringerLink (Online, ed. Thermal Decomposition of Solids and Melts: New Thermochemical Approach to the Mechanism, Kinetics and Methodology. Springer, 2007.

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Gao neng xiao an zha yao de re fen jie: Thermal decomposition of nitamine high explosives. Guo fang gong ye chu ban she, 2010.

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B, Manelis G., ed. Thermal decomposition and combustion of explosives and propellants. Taylor & Francis, 2003.

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I, Popović, ed. The Thermal degradation of poly (2-mono-, 2,2-di-, and 2,2,2-trichloroethyl methacrylate): Kinetics and mechanisms. Forschungszentrum Jülich, 1991.

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Thermal Decomposition Of Solids And Melts New Thermochemical Approach To The Mechanism Kinetics And Methodology. Springer, 2010.

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Book chapters on the topic "DSC and kinetics of thermal decomposition"

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Czarnecki, J., and J. Šesták. "The Physical Kinetics of Reversible Thermal Decomposition." In Hot Topics in Thermal Analysis and Calorimetry. Springer International Publishing, 2017. http://dx.doi.org/10.1007/978-3-319-45899-1_17.

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Zhang, Hai Jun, En Xia Xiu, Xiu Juan Wang, Quan Li Jia, Hong Wei Sun, and Xiao Lin Jia. "Thermal Decomposition Kinetics of Ammonium Aluminum Carbonate Hydroxide." In High-Performance Ceramics V. Trans Tech Publications Ltd., 2008. http://dx.doi.org/10.4028/0-87849-473-1.1577.

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Poletto, Matheus, Heitor L. Ornaghi Júnior, and Ademir J. Zattera. "Thermal Decomposition of Natural Fibers: Kinetics and Degradation Mechanisms." In Reactions and Mechanisms in Thermal Analysis of Advanced Materials. John Wiley & Sons, Inc., 2015. http://dx.doi.org/10.1002/9781119117711.ch21.

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Eser, Anil, Cem Kahruman, and Ibrahim Yusufoglu. "Thermal Decomposition Reaction Mechanisms and Kinetics of Ammonium Paratungstate Tetrahydrate." In Characterization of Minerals, Metals, and Materials 2014. John Wiley & Sons, Inc., 2014. http://dx.doi.org/10.1002/9781118888056.ch76.

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Cavus, Hande, Cem Kahruman, and Ibrahim Yusufoglu. "Thermal Decomposition Kinetics of the Thermal Decomposition Products of Ammonium Heptamolybdate Tetrahydrate in Air and Inert Gas Atmospheres." In T.T. Chen Honorary Symposium on Hydrometallurgy, Electrometallurgy and Materials Characterization. John Wiley & Sons, Inc., 2012. http://dx.doi.org/10.1002/9781118364833.ch74.

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Kartik, S., Hemant K. Balsora, Abhishek Sharma, et al. "Distributed Activation Energy Model for Thermal Decomposition of Polypropylene Waste." In Springer Proceedings in Energy. Springer International Publishing, 2021. http://dx.doi.org/10.1007/978-3-030-63916-7_23.

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AbstractThermal decomposition kinetics of Polypropylene (PP) waste is extremely important with respect to valorisation of waste plastics and production of utilizable components viz. chemicals, fuel oil &amp; gas. The present research study focuses on pyrolysis kinetics of PP waste, which is present as a fraction of municipal plastic waste through distributed activation energy model (DAEM). The decomposition kinetics for PP follows a Gaussian distribution, where the normal distribution curves were centred corresponding to activation energy of 224 kJ/mol. The standard deviation of the distribution for the PP sample was found to be 22 kJ/mol indicating its wider distribution of decomposition range. The data validation has been carried out by comparing the rate parameter and extent of conversion values calculated through DAEM model with the Thermogravimetric analysis (TGA) experiments carried out for PP at various heating rates of 5, 10, 20 and 40 °C/min.
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Catoire, B., V. Verney, and A. Michel. "Thermal Decomposition Kinetics of Polypropylene Peroxides in the Polymer Matrix by ESR." In Electron Spin Resonance (ESR) Applications in Organic and Bioorganic Materials. Springer Berlin Heidelberg, 1992. http://dx.doi.org/10.1007/978-3-642-77214-6_8.

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Guan, Lukui, Ting-an Zhang, Zhi-he Dou, and Daxue Fu. "Thermal Decomposition Kinetics of Dolomite in Pre-prepared Pellets for Magnesium Production." In The Minerals, Metals & Materials Series. Springer International Publishing, 2017. http://dx.doi.org/10.1007/978-3-319-52392-7_33.

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Wang, Lin, Yan-hong Li, Jin-lin Lu, Wei Xu, and Hui-long Lin. "Thermal Decomposition Kinetics of Manganese Carbonate In the Process of MnZn Ferrite Preparation." In TMS 2016: 145thAnnual Meeting & Exhibition: Supplemental Proceedings. John Wiley & Sons, Inc., 2016. http://dx.doi.org/10.1002/9781119274896.ch40.

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Várhegyi, Gábor, Piroska Szabó, and Michael Jerry Antal. "Reaction Kinetics of the Thermal Decomposition of Cellulose and Hemicellulose in Biomass Materials." In Advances in Thermochemical Biomass Conversion. Springer Netherlands, 1993. http://dx.doi.org/10.1007/978-94-011-1336-6_59.

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Conference papers on the topic "DSC and kinetics of thermal decomposition"

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Missoum, Azzedine, Ashwani K. Gupta, and Jianrong Chen. "Global Kinetics of the Thermal Decomposition of Materials." In ASME 1997 Design Engineering Technical Conferences. American Society of Mechanical Engineers, 1997. http://dx.doi.org/10.1115/detc97/cie-4433.

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Abstract Results on the thermal destruction behavior during the decomposition of cellulose under controlled conditions are presented. Thermogravimetric (TGA) and Differential Scanning Calorimetry (DSC) tests have been carried out on the celluose samples under conditions of various heating rate and surrounding gas environment. Pyrolysis times were also measured for different size particles having different moisture contents in a controlled mixing history reactor (CMHR). The global decomposition kinetics were investigated and it was found that the decomposition process is shifts to higher temper
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Brundage, Aaron L., Kenneth L. Erickson, and Kevin J. Dowding. "Thermal Decomposition Modeling and Thermophysical Property Measurement of a Highly Crosslinked Polymer Composite." In ASME 2009 International Mechanical Engineering Congress and Exposition. ASMEDC, 2009. http://dx.doi.org/10.1115/imece2009-12473.

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Thermophysical properties including density, specific heat, and thermal diffusivity of a poly (diallyl phthalate) inert filler composite material were characterized over a wide temperature range from room temperature to 800 °C. Over this temperature range, the material decomposition was approximated by a one-step process with first-order kinetics. Thermal kinetics data were obtained by thermal gravimetric analysis with Fourier transform infrared spectroscopy (TGA-FTIR) and thermophysical properties were obtained from differential scanning calorimetry (DSC) and laser flash diffusivity experimen
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Fopah Lele, Armand, Fréderic Kuznik, Holger Urs Rammelberg, Thomas Schmidt, and Wolfgang K. L. Ruck. "Modeling Approach of Thermal Decomposition of Salt-Hydrates for Heat Storage Systems." In ASME 2013 Heat Transfer Summer Conference collocated with the ASME 2013 7th International Conference on Energy Sustainability and the ASME 2013 11th International Conference on Fuel Cell Science, Engineering and Technology. American Society of Mechanical Engineers, 2013. http://dx.doi.org/10.1115/ht2013-17022.

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Heat storage systems using reversible chemical solid-fluid reactions to store and release thermal energy operates in charging and discharging phases. During last three decades, discussions on thermal decomposition of several salt-hydrates were done (experimentally and numerically) [1,2]. A mathematical model of heat and mass transfer in fixed bed reactor for heat storage is proposed based on a set of partial differential equations (PDEs). Beside the physical phenomena, the chemical reaction is considered via the balances or conservations of mass, extent conversion and energy in the reactor. Th
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Illera Perozo, Danny, Humberto Gómez Vega, and Julian Yepes Martínez. "Synthesis and Characterization of Conjugated-Polymer/Graphene/Nanodiamond Nanocomposite for Electrochemical Energy Storage." In ASME 2015 International Mechanical Engineering Congress and Exposition. American Society of Mechanical Engineers, 2015. http://dx.doi.org/10.1115/imece2015-51982.

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The synthesis and characterization of Polyaniline/Graphene/ Nanodiamond Nanocomposite is reported. The resulting materials were synthetized following a polymerization in situ scheme and characterized by Fourier Transform Infrared Spectroscopy (FTIR), Thermogravimetry (TGA), Differential Scanning Calorimetry (DSC), Scanning Electron Microscopy (SEM) and Cyclic Voltammetry (CV). The effect of different loads of graphene and nanodiamond on the resulting nanocomposite was studied. Despite the presence of the host materials, the formation of Polyaniline polymer is successfully accomplished for all
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Wang, Di, Guang-Lei Tan, Zhen Zhao, and Qi Wang. "Calcite: Kinetics of Two-step Thermal Decomposition." In 2nd Annual International Conference on Advanced Material Engineering (AME 2016). Atlantis Press, 2016. http://dx.doi.org/10.2991/ame-16.2016.148.

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Nefedov, Roman, Nikolay Posternak, and Yuriy Ferapontov. "Kinetics of lithium peroxide monohydrate thermal decomposition." In PROSPECTS OF FUNDAMENTAL SCIENCES DEVELOPMENT (PFSD-2017): Proceedings of the XIV International Conference of Students and Young Scientists. Author(s), 2017. http://dx.doi.org/10.1063/1.5009838.

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Xie, Wancui, Chao Yin, Xihong Yang, et al. "Thermal Decomposition Kinetics Analysis of Citronellol- -D-glucopyranoside." In 2016 5th International Conference on Sustainable Energy and Environment Engineering (ICSEEE 2016). Atlantis Press, 2016. http://dx.doi.org/10.2991/icseee-16.2016.147.

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Tang, Z. J., P. Fang, J. H. Huang, Z. X. Tang, and C. P. Cen. "Investigation on thermodynamics characteristics of biomass thermal decomposition using TG/DSC method." In 5th International Conference on Advanced Design and Manufacturing Engineering. Atlantis Press, 2015. http://dx.doi.org/10.2991/icadme-15.2015.177.

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Xue, Tian, Yong-he Han, Qi-zhi Zhao, and Ning Lyu. "Thermal Decomposition of CS by TG/DSC-FITR and PY-GC/MS." In 2015 International Conference on Mechatronics, Electronic, Industrial and Control Engineering. Atlantis Press, 2015. http://dx.doi.org/10.2991/meic-15.2015.208.

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Lee, Hobin, Leif Thompson, and Andy Konst. "Preliminary Investigation of SPLA/RD-1333 Lead Azide Thermal Decomposition Kinetics." In 48th AIAA Aerospace Sciences Meeting Including the New Horizons Forum and Aerospace Exposition. American Institute of Aeronautics and Astronautics, 2010. http://dx.doi.org/10.2514/6.2010-335.

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Reports on the topic "DSC and kinetics of thermal decomposition"

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Burnham, A., and R. Weese. Thermal Decomposition Kinetics of HMX. Office of Scientific and Technical Information (OSTI), 2004. http://dx.doi.org/10.2172/15009839.

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Burnham, A., and R. Weese. Thermal Decomposition Kinetics of HMX. Office of Scientific and Technical Information (OSTI), 2004. http://dx.doi.org/10.2172/877784.

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Ismail, Ismail M., and Tom W. Hawkins. Kinetics of Thermal Decomposition of Aluminum Hydride in Argon. Defense Technical Information Center, 2005. http://dx.doi.org/10.21236/ada440306.

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Cordaro, Joseph, Alan Kruizenga, and April Nissen. Thermal characterization and model free kinetics of aged epoxies and foams using TGA and DSC methods. Office of Scientific and Technical Information (OSTI), 2013. http://dx.doi.org/10.2172/1104770.

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Burnham, A. Kinetics of TATB and LX-17 Decomposition by Thermal Analysis. Office of Scientific and Technical Information (OSTI), 2020. http://dx.doi.org/10.2172/1657677.

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Kinetics studies, thermal decomposition and carbonation. Final report. Office of Scientific and Technical Information (OSTI), 1993. http://dx.doi.org/10.2172/10153551.

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