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Journal articles on the topic 'Electroactive Molecules'

Author: Grafiati

Published: 1 February 2025

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1

Gorman, Christopher B. "Encapsulated electroactive molecules." Advanced Materials 9, no. 14 (1997): 1117–19. http://dx.doi.org/10.1002/adma.19970091412.

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2

Dai, Yunlong, and Xianwen Kan. "From non-electroactive to electroactive species: highly selective and sensitive detection based on a dual-template molecularly imprinted polymer electrochemical sensor." Chem. Commun. 53, no. 86 (2017): 11755–58. http://dx.doi.org/10.1039/c7cc06329f.

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A selective and sensitive detection of non-electroactive and electroactive molecules has been achieved on a dual-template imprinted electrochemical sensor. And the proposed dual-signal strategy can be used for highly sensitive detection of electroactive analytes.

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3

Coronado, E., J. R. Galán-Mascarós, and C. J. Gómez-García. "Hybrid molecular magnets incorporating organic donors and other electroactive molecules." Synthetic Metals 102, no. 1-3 (1999): 1459–60. http://dx.doi.org/10.1016/s0379-6779(98)00518-9.

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4

Tirado, Jorge D., David Acevedo, Richard L. Bretz, and Hector D. Abruna. "Adsorption Dynamics of Electroactive Self-Assembling Molecules." Langmuir 10, no. 6 (1994): 1971–79. http://dx.doi.org/10.1021/la00018a057.

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5

Yamamoto, Yohei. "Electroactive Nanotubes from π-Conjugated Discotic Molecules". Bulletin of the Chemical Society of Japan 84, № 1 (2011): 17–25. http://dx.doi.org/10.1246/bcsj.20100272.

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6

Clair, Sean, and Michael R. Norris. "Strategy for functionalization of electrodes with discrete, unmodified small molecules exhibiting aqueous stability." Journal of Materials Chemistry A 8, no. 31 (2020): 15681–86. http://dx.doi.org/10.1039/d0ta03785k.

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7

Rybakiewicz, Renata, Łukasz Skórka, and Roman Gańczarczyk. "Dithienopyrrole-based Organic Electroactive Materials and Their Photovoltaic Aspects." Current Organic Chemistry 24, no. 23 (2020): 2695–736. http://dx.doi.org/10.2174/1385272824999201014154321.

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4H-dithieno[3,2-b:2',3'-d]pyrrole has recently become a useful building block in the synthesis of donor-acceptor molecules with practical application in various organic technologies. The DTP molecule itself consists of a pyrrole ring with two fused thiophenes providing an alternative for the related dithieno[3,2-b:2′,3′-d]thiophene. Most notably, the significance of DTP-based low- and high-molecular weight species has increased in recent years since, upon proper processing, they allow to improve the performance of many fields of organic electronics. This review is a trial of a brief report on

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8

Vela, Sonia, José Augusto Berrocal, Carmen Atienza, E. W. Meijer, and Nazario Martín. "Mesoscopic helical architectures via self-assembly of porphyrin-based discotic systems." Chemical Communications 53, no. 29 (2017): 4084–87. http://dx.doi.org/10.1039/c7cc01670k.

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9

Breitwieser, R., M. Marsault, V. Repain, et al. "Long-range ordered nanodomains of grafted electroactive molecules." Journal of Chemical Physics 139, no. 20 (2013): 204703. http://dx.doi.org/10.1063/1.4830402.

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10

Pshenichnyuk, S. A., A. V. Kukhto, I. N. Kukhto, and N. L. Asfandiarov. "Resonance capture of electrons by electroactive organic molecules." Russian Journal of Physical Chemistry B 4, no. 6 (2010): 1014–27. http://dx.doi.org/10.1134/s1990793110060205.

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11

Mecheri, B., G. Gabrielli, L. Piras, L. Ciotti, M. Cocco, and G. Caminati. "Immobilization of electroactive molecules in organized thin films." Materials Science and Engineering: C 22, no. 2 (2002): 307–12. http://dx.doi.org/10.1016/s0928-4931(02)00216-3.

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12

Ruiz, Constanza, Ángeles Monge, Enrique Gutiérrez-Puebla, et al. "Saddle-Shaped Cyclic Indole Tetramers: 3D Electroactive Molecules." Chemistry - A European Journal 22, no. 30 (2016): 10651–60. http://dx.doi.org/10.1002/chem.201600932.

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13

Sarmet, Julien, Fabrice Leroux, Christine Taviot-Gueho, et al. "Interleaved Electroactive Molecules into LDH Working on Both Electrodes of an Aqueous Battery-Type Device." Molecules 28, no. 3 (2023): 1006. http://dx.doi.org/10.3390/molecules28031006.

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By selecting two electroactive species immobilized in a layered double hydroxide backbone (LDH) host, one able to act as a positive electrode material and the other as a negative one, it was possible to match their capacity to design an innovative energy storage device. Each electrode material is based on electroactive species, riboflavin phosphate (RF) on one side and ferrocene carboxylate (FCm) on the other, both interleaved into a layered double hydroxide (LDH) host structure to avoid any possible molecule migration and instability. The intercalation of the electroactive guest molecules is

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14

Vecherskii, Sergei Ivanovich, Maksim Alekseevich Konopel'ko, and Nikolai Nikolaevich Batalov. "The equilibrate concentration of the electro-active species in (Li0.62K0.38)2CO3 melt and reaction mechanisms of the oxygen reduction on the gold electrode." Electrochemical Energetics 11, no. 3 (2011): 120–27. http://dx.doi.org/10.18500/1608-4039-2011-11-3-120-127.

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The concentrations of the main components of the (Li0.62K0.38)2CO3 melt have been evaluated by the thermodynamic modeling technique, and the Warburg coefficients of electroactive particles as a function of temperature and CO2/O2 gas mixture composition have been calculated. The same dependences of Warburg coefficient and charge transfer resistance were studied on Au cathode using coulostatic technique. It is shown that O2 ions and O2 molecules are the main electroactive species in the melt. Their relative concentration determines which reaction mechanism dominates.

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15

Phan Thanh, Hai, Le Tran Thi Ngoc, Mai Truong Thi Cam, Thanh Huynh Thi Minh, and Trung Huynh Thi Mien. "Dibenzyl viologgen adlayer functionalzed graphitic surraces using electrochemical approach." Vietnam Journal of Catalysis and Adsorption 10, no. 1S (2021): 14–17. http://dx.doi.org/10.51316/jca.2021.083.

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In this contribution, the electrochemciacl deposition method is used to synthesize uncharged dibenzyl viologen (DBV0) firm on HOPG surface. Electrochemical property and surface structure of the molecular adlayer are characterized by employing a combination of cyclic voltammetry (CV) and scanning electron microscope (SEM). Consequently, the DBV0 molecules generated from the reduction of the corresponding DBV2+ molecules at the solid/liqid interface by applying suitable electrochemical potentials are able to physisorb and form a physisorbed adlayer on HOPG. The existence of the DBV0 adlayer on H

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16

Mas-Torrent, M., C. Rovira, and J. Veciana. "Surface-Confined Electroactive Molecules for Multistate Charge Storage Information." Advanced Materials 25, no. 3 (2012): 462–68. http://dx.doi.org/10.1002/adma.201201510.

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17

Yamamoto, Yohei. "ChemInform Abstract: Electroactive Nanotubes from π-Conjugated Discotic Molecules". ChemInform 42, № 17 (2011): no. http://dx.doi.org/10.1002/chin.201117224.

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18

Souto, Manuel, Joaquín Calbo, Samuel Mañas-Valero, Aron Walsh, and Guillermo Mínguez Espallargas. "Charge-transfer interactions between fullerenes and a mesoporous tetrathiafulvalene-based metal–organic framework." Beilstein Journal of Nanotechnology 10 (September 18, 2019): 1883–93. http://dx.doi.org/10.3762/bjnano.10.183.

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The design of metal–organic frameworks (MOFs) incorporating electroactive guest molecules in the pores has become a subject of great interest in order to obtain additional electrical functionalities within the framework while maintaining porosity. Understanding the charge-transfer (CT) process between the framework and the guest molecules is a crucial step towards the design of new electroactive MOFs. Herein, we present the encapsulation of fullerenes (C60) in a mesoporous tetrathiafulvalene (TTF)-based MOF. The CT process between the electron-acceptor C60 guest and the electron-donor TTF liga

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19

Fujisaki, Masahiro, Ryoya Naito, Takashi Shirahata, Yoshitaka Kawasugi, Naoya Tajima, and Yohji Misaki. "Molecular Conductors Based on Dimethylcyclohexene-Fused Tetrathiafulvalene." Chemistry 6, no. 6 (2024): 1509–22. http://dx.doi.org/10.3390/chemistry6060091.

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Chiral electroactive materials have attracted attention for the effects of electrical magnetochiral anisotropy (eMChA) and chirality-induced spin selectivity (CISS). The combination of tetrathiafulvalene (TTF) with chiral moieties is one way to access chiral electroactive materials. In this paper, we have focused on the fused 2,3-dimethylcyclohexene (DMCh) ring as a substituent with chiral carbon atoms and without heteroatoms, which has not been used in the field of molecular conductors, and we synthesized a new TTF derivative (rac-DMCh-EDT-TTF). We have developed novel molecular conductors (r

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20

Krukiewicz, Katarzyna, and Jean-Christophe Lacroix. "Preface: Electroactive conjugated molecules and macromolecules in bioelectrochemistry and biosensing." Synthetic Metals 296 (July 2023): 117382. http://dx.doi.org/10.1016/j.synthmet.2023.117382.

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21

Weese-Myers, Moriah E., and Ashley E. Ross. "Characterization of Electroactive Amino Acids with Fast-Scan Cyclic Voltammetry." Journal of The Electrochemical Society 168, no. 12 (2021): 126524. http://dx.doi.org/10.1149/1945-7111/ac4187.

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Small molecules and signaling peptides are extensively involved in controlling basic brain function. While classical neurotransmitters can be detected with a variety of techniques, methods for measurement of rapidly-released neuropeptides remain underdeveloped. Fast-scan cyclic voltammetry (FSCV) is an electrochemical technique often used for subsecond detection of small molecule neurotransmitters, in vivo. A few peptides have been detected with FSCV; however, a detailed analysis of the electrochemical signature of all electroactive amino acids with FSCV has not been fully investigated. Becaus

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22

Mecheri, B., L. Piras, L. Ciotti, and G. Caminati. "Electrode Coating With Ultrathin Films Containing Electroactive Molecules for Biosensor Applications." IEEE Sensors Journal 4, no. 2 (2004): 171–79. http://dx.doi.org/10.1109/jsen.2004.823675.

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23

Lee, W. R., Y. Kim, J. Y. Kim, T. H. Kim, K. D. Ahn, and E. Kim. "Electro-fluorescence Switching of Bis-imidazolium onic Liquids." Journal of Nanoscience and Nanotechnology 8, no. 9 (2008): 4630–34. http://dx.doi.org/10.1166/jnn.2008.ic50.

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Room-temperature ionic liquids (RTILs) containing bis-imidazolium salts were explored to control their optical properties of them in an organic device. The neat bis-imidazolium salts showed ionic conductivity of 3.5 × 10−4 S/cm at room-temperature and the electrochemical window was exhibited within ±2.5 V in a two electrode cell. The bis-imidazolium salts were transparent yellow and showed fluorescence upon excitation with light in the range of 360 to 500 nm. A two electrode organic ionic liquid cell was fabricated using a mixture of PEO200BIm-TFSI and electroactive molecules to control the em

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24

Echeverry, Carlos A., Alexis Tigreros, Alejandro Ortiz, Braulio Insuasty, and Nazario Martín. "Free-base tetraarylporphyrin covalently linked to [60]fullerene through ethynylfluorene spacer." Journal of Porphyrins and Phthalocyanines 15, no. 11n12 (2011): 1231–38. http://dx.doi.org/10.1142/s1088424611004257.

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The synthesis, structural and electronic characterization of novel electroactive systems based on porphyrin-fullerene in which the chromophores are linked by an ethynylfluorene spacer unit is reported. Sonogashira couplings have been used in short and efficient sequences to give access to these new molecules on a practical scale. The absorption studies, voltamperometric measurements and theoretical calculations at DFT level reveal the push-pull behavior for these systems.

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25

Hong, Daewha, Kyungtae Kang, Seok-Pyo Hong, et al. "Electrochemical Release of Amine Molecules from Carbamate-Based, Electroactive Self-Assembled Monolayers." Langmuir 28, no. 1 (2011): 17–21. http://dx.doi.org/10.1021/la203420h.

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26

Yamamoto, Yohei. "Programmed self-assembly of largeπ-conjugated molecules into electroactive one-dimensional nanostructures". Science and Technology of Advanced Materials 13, № 3 (2012): 033001. http://dx.doi.org/10.1088/1468-6996/13/3/033001.

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27

Pineda Flores, Sergio D., Geoffrey C. Martin-Noble, Richard L. Phillips, and Joshua Schrier. "Bio-Inspired Electroactive Organic Molecules for Aqueous Redox Flow Batteries. 1. Thiophenoquinones." Journal of Physical Chemistry C 119, no. 38 (2015): 21800–21809. http://dx.doi.org/10.1021/acs.jpcc.5b05346.

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28

Gorman, Christopher B., Brandon L. Parkhurst, Wendy Y. Su, and Kang-Yi Chen. "Encapsulated Electroactive Molecules Based upon an Inorganic Cluster Surrounded by Dendron Ligands." Journal of the American Chemical Society 119, no. 5 (1997): 1141–42. http://dx.doi.org/10.1021/ja963541q.

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29

Zhang, Jie, He Liu, Yan Zhang, et al. "Enhanced CO2 Reduction by Electron Shuttle Molecules via Coupling Different Electron Transport Processes in Microbial Electrosynthesis." Fermentation 9, no. 7 (2023): 679. http://dx.doi.org/10.3390/fermentation9070679.

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Electron shuttling molecules (ESMs) have been proven to accelerate the electron transfer from the electrode to the electroactive microorganism in microbial electrosynthesis (MES) for higher CO2 reduction or chemical production rate. However, the microbial electron acceptors of electroactive microorganisms and their responses to different electron shuttling molecules in MES were still unknown. In this study, three kinds of ESMs, e.g., riboflavin (B2), methyl viologen (MV) and neutral red (NR) were applied in the MES for acetate production to explore the mechanism of different ESMs on microbial

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30

Kitamura, An, and Christian Malapit. "Enabling Two-Electron Redox Systems for Energy-Dense Organic-Based Flow Batteries." ECS Meeting Abstracts MA2024-02, no. 9 (2024): 1266. https://doi.org/10.1149/ma2024-0291266mtgabs.

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Redox flow batteries (RFBs) have emerged as a promising grid-scale energy storage technology to meet increasing energy demands. In RFBs, the electroactive materials are in solution stored in external tanks. This separation of the electrode from the electroactive material allows them to be scalable for large-scale operation. Current RFBs use Vanadium as the active material (VRFB). Despite its ability to provide long-duration cycling, VRFBs are limited by the high cost of vanadium and low energy density. To address this issue, organic-based redox flow batteries (ORFB) have gained attention to re

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31

Kim, Pankyu, Hyeongkwon Moon, and Jun Hui Park. "Electrochemical Detection of Surfactant-Encapsulated Aqueous Nanodroplets in Organic Solution." Chemosensors 11, no. 2 (2023): 112. http://dx.doi.org/10.3390/chemosensors11020112.

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We report enhanced electrochemical detection of single water-in-oil emulsion droplets using the nano-impact method. To detect the emulsion droplets, the water molecules in the droplets were directly oxidized (i.e., water splitting) without additional electroactive species when the droplets collided with the ultramicroelectrode. The water molecules in the emulsion droplet cannot be directly electrolyzed in an organic solvent because the emulsifier does not require a hydrophobic electrolyte. To enhance the signal intensity, the electrochemistry of sub-microscale single droplets was investigated

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32

Jiao, Jieying, Miao Yu, Dewey Holten, Jonathan S. Lindsey, and David F. Bocian. "Characterization of Hydroporphyrins Covalently Attached to Si(100)." Journal of Porphyrins and Phthalocyanines 21, no. 07n08 (2017): 453–64. http://dx.doi.org/10.1142/s1088424617500547.

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Attachment of synthetic analogs of natural tetrapyrroles to electroactive surfaces enables physicochemical interrogation and may provide material for use in catalysis, diagnostics, and energy conversion. Six synthetic zinc chlorins and one free base bacteriochlorin, tailored analogs of chlorophyll and bacteriochlorophyll, respectively, have been attached to Si(100) via a high-temperature (400°C) baking method. The hydroporphyrins bear diverse functional groups that enable surface attachment (vinyl, acetyl, triisopropylsilylethynyl, pentafluorophenyl, and hydroxymethylphenyl) and a geminal dime

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33

Konev, Dmitry V., Olga I. Istakova, and Mikhail A. Vorotyntsev. "Electrochemical Measurement of Interfacial Distribution and Diffusion Coefficients of Electroactive Species for Ion-Exchange Membranes: Application to Br2/Br− Redox Couple." Membranes 12, no. 11 (2022): 1041. http://dx.doi.org/10.3390/membranes12111041.

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A novel method has been proposed for rapid determination of principal transmembrane transport parameters for solute electroactive co-ions/molecules, in relation to the crossover problem in power sources. It is based on direct measurements of current for the electrode, separated from solution by an ion-exchange membrane, under voltammetric and chronoamperometric regimes. An electroactive reagent is initially distributed within the membrane/solution space under equilibrium. Then, potential change induces its transformation into the product at the electrode under the diffusion-limited regime. For

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34

Magaldi, Diego, Maria Ulfa, Sébastien Péralta, Fabrice Goubard, Thierry Pauporté, and Thanh-Tuân Bui. "Carbazole Electroactive Amorphous Molecular Material: Molecular Design, Synthesis, Characterization and Application in Perovskite Solar Cells." Energies 13, no. 11 (2020): 2897. http://dx.doi.org/10.3390/en13112897.

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In perovskite photovoltaics (PSCs), the role of the hole transporting material (HTM) is highly important as it significantly influents to the global device’s performance and stability. Hole transporter ensures the extraction of hole at the perovskite/HTM interface and transport it towards the cathode. Thus, accurate molecular design affording to efficient and cost-effective HTM is of major interest. Small molecules having glass forming property is an attractive class as it can form morphologically stable thin film. Herein, a carbazole molecular glass bearing a polymerizable function was design

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35

Deng, Dehua, Yong Chang, Wenjing Liu, Mingwei Ren, Ning Xia, and Yuanqiang Hao. "Advancements in Biosensors Based on the Assembles of Small Organic Molecules and Peptides." Biosensors 13, no. 8 (2023): 773. http://dx.doi.org/10.3390/bios13080773.

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Over the past few decades, molecular self-assembly has witnessed tremendous progress in a variety of biosensing and biomedical applications. In particular, self-assembled nanostructures of small organic molecules and peptides with intriguing characteristics (e.g., structure tailoring, facile processability, and excellent biocompatibility) have shown outstanding potential in the development of various biosensors. In this review, we introduced the unique properties of self-assembled nanostructures with small organic molecules and peptides for biosensing applications. We first discussed the appli

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36

Mejías, Sara H., Javier López-Andarias, Tsuneaki Sakurai, et al. "Repeat protein scaffolds: ordering photo- and electroactive molecules in solution and solid state." Chemical Science 7, no. 8 (2016): 4842–47. http://dx.doi.org/10.1039/c6sc01306f.

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An innovative approach is investigated in which a protein building block is designed to organize porphyrin molecules. The strategy is based on a modular protein unit with tunable properties including stability, function and self-assembly.

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37

Schmidt, Izabela, Jieying Jiao, David F. Bocian, and Jonathan S. Lindsey. "A Bipodal-Tethered Porphyrin for Attachment to Silicon Surfaces in Studies of Molecular Information Storage." Journal of Nanoscience and Nanotechnology 8, no. 9 (2008): 4813–17. http://dx.doi.org/10.1166/jnn.2008.ic85.

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An approach for molecular information storage entails use of redox-active molecules attached to an electroactive surface. Understanding the structural features that give rise to robust molecular monolayers with high charge density is an essential objective. Toward this goal, a zinc-porphyrin bearing an all-carbon bipodal tether, 5-(1,6-heptadien-4-yl)-15-phenyl-10,20-di-p-tolylporphinatozinc(II), has been synthesized by the reaction of a dipyrromethane and a dipyrromethane-1,9-dicarbinol. The porphyrin was attached to Si(100) via a high temperature procedure. The resulting molecular monolayers

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38

Messmore, Benjamin W., James F. Hulvat, Eli D. Sone, and Samuel I. Stupp. "Synthesis, Self-Assembly, and Characterization of Supramolecular Polymers from Electroactive Dendron Rodcoil Molecules." Journal of the American Chemical Society 126, no. 44 (2004): 14452–58. http://dx.doi.org/10.1021/ja049325w.

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39

Sharma, Jadab, and Kunjukrishna P. Vijayamohanan. "Organic dye molecules as reducing agent for the synthesis of electroactive gold nanoplates." Journal of Colloid and Interface Science 298, no. 2 (2006): 679–84. http://dx.doi.org/10.1016/j.jcis.2005.12.048.

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40

Tendero, María José L., Angel Benito, Juan Cano, et al. "Host molecules containing electroactive cavities obtained by the molecular assembly of redox-active ligands and metal ions." J. Chem. Soc., Chem. Commun., no. 16 (1995): 1643–44. http://dx.doi.org/10.1039/c39950001643.

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41

Boubezari, Imane, Ali Zazoua, Abdelhamid Errachid, and Nicole Jaffrezic-Renault. "Sensitive Electrochemical Detection of Bioactive Molecules (Hydrogen Peroxide, Glucose, Dopamine) with Perovskites-Based Sensors." Chemosensors 9, no. 10 (2021): 289. http://dx.doi.org/10.3390/chemosensors9100289.

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Perovskite-modified electrodes have received increasing attention in the last decade, due to their electrocatalytic properties to undergo the sensitive and selective detection of bioactive molecules, such as hydrogen peroxide, glucose, and dopamine. In this review paper, different types of perovskites involved for their electrocatalytic properties are described, and the proposed mechanism of detection is presented. The analytical performances obtained for different electroactive molecules are listed and compared with those in terms of the type of perovskite used, its nanostructuration, and its

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42

Sun, Yanmei, Li Li, and Keying Shi. "Analog and Digital Bipolar Resistive Switching in Co–Al-Layered Double Hydroxide Memristor." Nanomaterials 10, no. 11 (2020): 2095. http://dx.doi.org/10.3390/nano10112095.

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We demonstrate a nonvolatile memristor based on Co–Al-layered double hydroxide (Co–Al LDH). We also introduce a memristor that has a hexazinone-adsorbing Co–Al LDH composite active layer. Memristor characteristics could be modulated by adsorbing hexazinone with Co–Al LDHs in the active layer. While different, Co–Al LDH-based memory devices show gradual current changes, and the memory device with small molecules of adsorbed hexazinone undergo abrupt changes. Both devices demonstrate programmable memory peculiarities. In particular, both memristors show rewritable resistive switching with electr

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43

Sikukuu Nambafu, Gabriel. "Organic molecules as bifunctional electroactive materials for symmetric redox flow batteries: A mini review." Electrochemistry Communications 127 (June 2021): 107052. http://dx.doi.org/10.1016/j.elecom.2021.107052.

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44

Ackov, Renal B., Laurent Binet, Jean-Marc Fabre, Deborah J. Jones, and Jacques Roziere. "Intercalation and Post-synthesis Oxidation of Basic Electroactive TTF-type Molecules in Zirconium Phosphate." Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals 311, no. 1 (1998): 239–44. http://dx.doi.org/10.1080/10587259808042392.

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45

Shi, Gaoquan. "Matrix chain-length dependence of the electrochemistry of electroactive molecules in amorphous polymeric solvents." Journal of Physical Chemistry 96, no. 11 (1992): 4677–79. http://dx.doi.org/10.1021/j100190a097.

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46

Sandín, Pilar, Angeles Martínez-Grau, Luis Sánchez, et al. "The First Spiroconjugated TTF- and TCNQ-Type Molecules: A New Class of Electroactive Systems?" Organic Letters 7, no. 2 (2005): 295–98. http://dx.doi.org/10.1021/ol047681d.

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47

Chang, Yong, Jiaxin Lou, Luyao Yang, Miaomiao Liu, Ning Xia, and Lin Liu. "Design and Application of Electrochemical Sensors with Metal–Organic Frameworks as the Electrode Materials or Signal Tags." Nanomaterials 12, no. 18 (2022): 3248. http://dx.doi.org/10.3390/nano12183248.

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Metal–organic frameworks (MOFs) with fascinating chemical and physical properties have attracted immense interest from researchers regarding the construction of electrochemical sensors. In this work, we review the most recent advancements of MOF−based electrochemical sensors for the detection of electroactive small molecules and biological macromolecules (e.g., DNA, proteins, and enzymes). The types and functions of MOF−based nanomaterials in terms of the design of electrochemical sensors are also discussed. Furthermore, the limitations and challenges of MOF−based electrochemical sensing devic

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48

Shanta, Aysha S., Khandakar A. Al Mamun, Syed K. Islam, Nicole McFarlane, and Dale K. Hensley. "Carbon Nanotubes, Nanofibers and Nanospikes for Electrochemical Sensing: A Review." International Journal of High Speed Electronics and Systems 26, no. 03 (2017): 1740008. http://dx.doi.org/10.1142/s0129156417400080.

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The structural and material properties of carbon based sensors have spurred their use in biosensing applications. Carbon electrodes are advantageous for electrochemical sensors due to their increased electroactive surface areas, enhanced electron transfer, and increased adsorption of target molecules. The bonding properties of carbon allows it to form a variety of crystal structures. This paper performs a comparative review of carbon nanostructures for electrochemical sensing applications. The review specifically compares carbon nanotubes (CNT), carbon nanofibers (CNF), and carbon nanospikes (

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Yu, Zhang-Yu, De-Sheng Kong, Shu-Xin Wu, Lei Wang, and Hanf-Qing Wang. "Electrocatalysis of a SiC particle-modified glassy carbon electrode for the oxidation of adrenaline in a KRPB physiological solution." Journal of the Serbian Chemical Society 70, no. 5 (2005): 745–52. http://dx.doi.org/10.2298/jsc0505745y.

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Abstract:

The electrocatalytic properties of a SiC particle-modified glassy carbon electrode (MGC) for adrenaline oxidation were studied by cyclic voltammetry, double-potential step chronoculometry and electrochemical impedance spectroscopy in a pH 7.4 physiological Kres?Ringer phosphate buffer (KRPB) solution. It was shown that modification of the electrode with SiC particles has a marked electrocatalytic effect on the electrochemical reaction of adrenaline, i.e., the activity and the reversibility of the MGC electrode were significantly improved compared to an unmodified electrode. This was attributed

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Guo, Bingshu, Zhongai Hu, Yufeng An, et al. "Nitrogen-doped heterostructure carbon functionalized by electroactive organic molecules for asymmetric supercapacitors with high energy density." RSC Advances 6, no. 46 (2016): 40602–14. http://dx.doi.org/10.1039/c6ra07923g.

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Abstract:

The organic molecules (TCBQ, AQ) with multi-electron redox center are selected to modify nitrogen-doped heterostructure carbon (NHC) by noncovalent interaction and the electrode materials show good performances and potential self-matching behaviors.

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