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Relevant bibliographies by topics / Electrochemical equilibrium

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Academic literature on the topic 'Electrochemical equilibrium'

Author: Grafiati

Published: 4 June 2021

Last updated: 1 February 2022

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Journal articles on the topic "Electrochemical equilibrium"

1

Roh, Heui-Seol. "Statistical Thermodynamic Theory for Non-Equilibrium, Quasi-Equilibrium, and Equilibrium Electrochemical Reactions." Journal of The Electrochemical Society 160, no. 8 (2013): H420—H429. http://dx.doi.org/10.1149/2.030308jes.

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Laviron, E. "Electrochemical reactions with protonations at equilibrium." Journal of Electroanalytical Chemistry and Interfacial Electrochemistry 208, no. 2 (1986): 357–72. http://dx.doi.org/10.1016/0022-0728(86)80543-5.

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Laviron, E., and R. Meunier-Prest. "Electrochemical reactions with protonations at equilibrium." Journal of Electroanalytical Chemistry 324, no. 1-2 (1992): 1–18. http://dx.doi.org/10.1016/0022-0728(92)80032-y.

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Meunier-Prest, R., and E. Laviron. "Electrochemical reactions with protonations at equilibrium." Journal of Electroanalytical Chemistry 328, no. 1-2 (1992): 33–46. http://dx.doi.org/10.1016/0022-0728(92)80168-4.

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Maier, J. "Control parameters for electrochemically relevant materials: the significance of size and complexity." Faraday Discuss. 176 (2014): 17–29. http://dx.doi.org/10.1039/c4fd00135d.

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This contribution is concerned with the control parameters for arriving at defined, electrochemically relevant materials. The treatment is precise as far as the equilibrium situation of simple crystals is concerned, but becomes more and more qualitative if the distance from equilibrium or the (structural or compositional) complexity increases. It proves useful to distinguish between in situ parameters and ex situ parameters, the number ratio of which decreases with increasing distance from equilibrium. A particularly complex situation is met if not only size, shape and phase distribution are i

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Han Guang, Sun Cheng, Wu Di, and Chen Wei-Rong. "Electrochemical potential equilibrium criterion of Invar alloy." Acta Physica Sinica 63, no. 6 (2014): 068101. http://dx.doi.org/10.7498/aps.63.068101.

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Markin, V. S., and V. S. Sokolov. "A new concept of electrochemical membrane equilibrium." Journal of Electroanalytical Chemistry and Interfacial Electrochemistry 298, no. 1 (1990): 1–16. http://dx.doi.org/10.1016/0022-0728(90)87445-p.

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Markin, V. S., and V. S. Sokolov. "A new concept of electrochemical membrane equilibrium." Bioelectrochemistry and Bioenergetics 23, no. 1 (1990): 1–16. http://dx.doi.org/10.1016/0302-4598(90)80001-y.

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Grafov, Boris M. "Gibbs fluctuation theory in the context of electrochemical equilibrium noise." Pure and Applied Chemistry 83, no. 2 (2010): 253–57. http://dx.doi.org/10.1351/pac-con-10-07-10.

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The electrochemical noise verification of the Gibbs fluctuation theory shows that the Gibbs ergodic idea works perfectly with respect to the pair correlations of the electrode charge thermal fluctuations. At the same time, the Gibbs formulae for the triple- and higher-order correlations of the electrode charge thermal fluctuations are outside of the ergodic hypothesis. This failure of the Gibbs ergodic idea suggests that the noise version of the electrochemical charge-transfer theory should be developed. In the context of nano-electrochemistry, the second- and higher-order correlations of the

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Guo, Xiao Fei, and Ai Ling Du. "Thermodynamic Equilibrium Diagram of Oxygen-Chlorine-Titanium System." Advanced Materials Research 233-235 (May 2011): 2068–71. http://dx.doi.org/10.4028/www.scientific.net/amr.233-235.2068.

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The chemical and electrochemical equilibrium of oxygen-chlorine-titanium system in the presence of gaseous phase were investigated. Many species, which consisted of oxygen, chlorine and titanium, were considered. Various thermodynamic equilibriums were calculated in the different pressures and temperatures. Calculation results were shown as E-T diagram. This diagram will be used as important tools for corrosion study and titanium production, and it is also used to thermodynamically determine the existence areas of various species and so on.

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Dissertations / Theses on the topic "Electrochemical equilibrium"

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Möller, Friederike Maria [Verfasser], and Dieter [Akademischer Betreuer] Braun. "Biomolecule transport in electrochemical non-equilibrium systems / Friederike Maria Möller ; Betreuer: Dieter Braun." München : Universitätsbibliothek der Ludwig-Maximilians-Universität, 2016. http://d-nb.info/1117474089/34.

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Gong, Yukun. "Electrochemical Atomic Layer Etching of Copper and Ruthenium." Case Western Reserve University School of Graduate Studies / OhioLINK, 2021. http://rave.ohiolink.edu/etdc/view?acc_num=case1625783128128316.

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Bechtel, Tom B. "Electrochemical partitioning of actinides and rare earths in molten salt and cadmium solvents : activity coefficients and equilibrium simulation /." free to MU campus, to others for purchase, 1997. http://wwwlib.umi.com/cr/mo/fullcit?p9841263.

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Zheng, Zhi. "Electrokinetic flow in micro- and nano-fluidic components." Columbus, Ohio : Ohio State University, 2003. http://rave.ohiolink.edu/etdc/view?acc%5Fnum=osu1068243983.

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Thesis (Ph. D.)--Ohio State University, 2003.<br>Title from first page of PDF file. Document formatted into pages; contains xxix, 269 p.; also includes graphics (some col.). Includes abstract and vita. Advisor: A. Terry Conlisk, Biomedical Engineering Center. Includes bibliographical references (leaves 261-269).

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Sasaki, Kazunari. "Phase equilibria, electrical conductivity, and electrochemical properties of ZrO₂-In₂O₃ /." Zürich, 1993. http://e-collection.ethbib.ethz.ch/show?type=diss&nr=10331.

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Kim, Jae Jin Ph D. "Defect equilibria and electrode kinetics in Prx̳Ce1̳-̳x̳O2̳-̳[̳d̳e̳l̳t̳a̳]̳ mixed conducting thin films : an in-situ optical and electrochemical investigation." Thesis, Massachusetts Institute of Technology, 2015. http://hdl.handle.net/1721.1/98737.

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Thesis: Ph. D., Massachusetts Institute of Technology, Department of Materials Science and Engineering, 2015.<br>In title on title-page, double underscored characters appear as subscript (Prx̳Ce1̳-̳x̳O2̳-̳[̳d̳e̳l̳t̳a̳]̳) Cataloged from PDF version of thesis.<br>Includes bibliographical references (pages 129-134).<br>An improved fundamental understanding of oxygen defect equilibria and transport kinetics in oxides is essential for achieving enhanced performance and longevity in many oxide-based practical applications. The ability to diagnose a material's behavior in a thin film structure under

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Chang, Keke [Verfasser]. "Phase equilibria, thermodynamic and electrochemical properties of cathodes in lithium ion batteries based on the Li–(Co, Ni)–O system / Keke Chang." Aachen : Hochschulbibliothek der Rheinisch-Westfälischen Technischen Hochschule Aachen, 2013. http://d-nb.info/1044748702/34.

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Martí, Calatayud Manuel César. "STUDY OF THE TRANSPORT OF HEAVY METAL IONS THROUGH CATION-EXCHANGE MEMBRANES APPLIED TO THE TREATMENT OF INDUSTRIAL EFFLUENTS." Doctoral thesis, Universitat Politècnica de València, 2015. http://hdl.handle.net/10251/46004.

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La presente Tesis Doctoral consiste en la determinación de las propiedades de transporte de diferentes especies catiónicas a través de membranas de intercambio catiónico. Las membranas de intercambio iónico son un componente clave de los reactores electroquímicos y de los sistemas de electrodiálisis, puesto que determinan el consumo energético y la eficiencia del proceso. La utilización de este tipo de membranas para el tratamiento de efluentes industriales no es muy extendida debido a los requisitos de elevada resistencia química y durabilidad que deben cumplir las membranas. Otro asunto impo

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Sadeghi, H. S. Saman. "Design of an electrochemical cognitive system: A study and application of emergent spatio-temporal patterns in far from equilibrium nonlinear systems /." 2008. http://proquest.umi.com/pqdlink?did=1659840471&sid=3&Fmt=2&clientId=12520&RQT=309&VName=PQD.

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Ashworth, Charlotte. "Electrochemical speciation and quantitative chromatography for modelling of indium bioleaching solutions." Doctoral thesis, 2018. https://tubaf.qucosa.de/id/qucosa%3A32002.

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In order to meet increasing indium demands, (bio)hydrometallurgical winning of low-grade sources will likely be required. The goal of this work in the scope of the Biohydrometallurgical Centre Freiberg, was to use geochemical modelling to improve indium leaching and extraction efficiency. Indium stability constants and chemical conditions of process relevant solutions were required. Electrochemical methods were used to determine the stability constants of indium complexes with nitrate, chloride, sulfate, and hydroxide ions, as well as with electrowinning additives. High pressure liquid chromat

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Books on the topic "Electrochemical equilibrium"

1

Soustelle, Michel. Ionic and Electrochemical Equilibria. John Wiley & Sons, Inc., 2016. http://dx.doi.org/10.1002/9781119178606.

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Pourbaix, Marcel. Atlas of chemical and electrochemical equilibria in the presence of gaseous phase. Cebelcor, 1996.

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D, Abruña Héctor, ed. Electrochemical interfaces: Modern techniques for in-situ interface characterization. VCH Pub., 1991.

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Soustelle, Michel. Ionic and Electrochemical Equilibria. Wiley & Sons, Incorporated, John, 2016.

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Kimura, T., and Y. Otani. Magnetization switching due to nonlocal spin injection. Oxford University Press, 2017. http://dx.doi.org/10.1093/oso/9780198787075.003.0021.

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This chapter discusses and presents a schematic illustration of nonlocal spin injection. In this case, the spin-polarized electrons are injected from the ferromagnet and are extracted from the left-hand side of the nonmagnet. This results in the accumulation of nonequilibrium spins in the vicinity of the F/N junctions. Since the electrochemical potential on the left-hand side is lower than that underneath the F/N junction, the electron flows by the electric field. On the right-hand side, although there is no electric field, the diffusion process from the nonequilibrium into the equilibrium sta

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Marcel, Pourbaix, Zhang Heming, Yang XiZhen, and Pourbaix Antoine, eds. Atlas of chemical and electrochemical equilibria in the presence of a gaseous phase. CEBELCOR, 1996.

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Atlas of Chemical and Electrochemical Equilibria in the Presence of a Gaseous Phase. Natl Assn of Corrosion, 1998.

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Book chapters on the topic "Electrochemical equilibrium"

1

Andriiko, Aleksandr A., Yuriy O. Andriyko, and Gerhard E. Nauer. "Dynamics of a Non-equilibrium Electrochemical System." In Monographs in Electrochemistry. Springer Berlin Heidelberg, 2013. http://dx.doi.org/10.1007/978-3-642-35770-1_5.

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Giorno, Lidietta, Heiner Strathmann, and Enrico Drioli. "Chemical and Electrochemical Equilibrium in Membrane Systems." In Encyclopedia of Membranes. Springer Berlin Heidelberg, 2016. http://dx.doi.org/10.1007/978-3-662-44324-8_2219.

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Giorno, Lidietta, Heiner Strathmann, and E. Drioli. "Chemical and Electrochemical Equilibrium in Membrane Systems." In Encyclopedia of Membranes. Springer Berlin Heidelberg, 2015. http://dx.doi.org/10.1007/978-3-642-40872-4_2219-1.

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Guth, Ulrich. "Solid Electrolytes Cells, Electrochemical Cells with Solid Electrolytes in Equilibrium." In Encyclopedia of Applied Electrochemistry. Springer New York, 2014. http://dx.doi.org/10.1007/978-1-4419-6996-5_520.

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Burgot, Jean-Louis. "Redox Reactions and Electrochemical Cells." In Ionic Equilibria in Analytical Chemistry. Springer New York, 2012. http://dx.doi.org/10.1007/978-1-4419-8382-4_13.

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Weppner, Werner. "Solid State Electrochemical Methods for the Characterization of the Kinetics, Thermodynamics and Phase Equilibria of Lithium Battery Materials." In Materials for Lithium-Ion Batteries. Springer Netherlands, 2000. http://dx.doi.org/10.1007/978-94-011-4333-2_23.

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"Equilibrium Electrode Potential." In Fundamentals of Electrochemical Deposition. John Wiley & Sons, Inc., 2005. http://dx.doi.org/10.1002/0470009403.ch5.

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"Electrochemical Thermodynamics: The Gibbs Function, Electrochemical Reactions, and Equilibrium Potentials." In Fundamentals of Electrochemical Corrosion. ASM International, 2000. http://dx.doi.org/10.31399/asm.tb.fec.t65940023.

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"Electrochemical Experiments in Systems Far from Equilibrium." In Thermodynamics and Fluctuations far from Equilibrium. Springer Berlin Heidelberg, 2008. http://dx.doi.org/10.1007/978-3-540-74555-6_10.

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Fawcett, W. Ronald. "Non-Equilibrium Phenomena in Liquids and Solutions." In Liquids, Solutions, and Interfaces. Oxford University Press, 2004. http://dx.doi.org/10.1093/oso/9780195094329.003.0010.

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The topics considered up to this point have involved liquids and solutions at equilibrium. Attention is now turned to systems which are not at equilibrium, and the processes which occur spontaneously in such systems. The physical phenomena involved can be quite complex, so that the task faced in early experiments was to separate the various processes and understand the physical properties of the system which govern them. Consider what happens when a beaker of pure isothermal water is placed on a hot plate. The water near the bottom rises in temperature and a temperature gradient is set up. As a result heat flows from the bottom of the beaker, producing a gradual increase in temperature in the water at a given height above the bottom. In addition, the temperature varies with distance, being highest at the bottom and lowest at the top. Eventually, the temperature of the water in the beaker is uniform and equal to that of the hot plate, assuming that the water does not boil. However, the flow of heat is not the only process resulting from the heat source. The density of the hot water is less than that of the cold water, so that a convection process is set up in order to achieve uniform density. Convection results in cold water moving down into the hot region so that the flow of water molecules assists the flow of heat. The changes which occur in this system cannot be understood without considering both processes. A system undergoing an irreversible change involving an electrolyte is electrolysis in an electrochemical cell. When current flows between two copper electrodes in an aqueous solution of CuSO4 the charge in solution is carried by migration of Cu2+ ions moving in one direction and SO42− ions moving in the opposite. At the cathode, the incoming Cu2+ ions are reduced to metallic copper, thereby lowering the concentration of these ions in the electrode’s vicinity. At the anode, Cu metal is oxidized to produce Cu2+ ions in the solution, so that the local concentration of cations is increased.

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Conference papers on the topic "Electrochemical equilibrium"

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Zhu, Zengwei, Dengyong Wang, Jun Bao, and Di Zhu. "Process Simulation of Electrochemical Machining of Convexity Structure on Revolving Workpiece." In ASME 2015 International Manufacturing Science and Engineering Conference. American Society of Mechanical Engineers, 2015. http://dx.doi.org/10.1115/msec2015-9275.

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A special electrochemical machining (ECM) process using a revolving cathode tool with hollow windows is presented. Unlike conventional sinking ECM, this presented ECM process fabricates the convexity structures on a revolving part by the relative rotation of anode workpiece and cathode tool. In this paper, a mathematical model is established to describe the evolution of the machining process, the finite element simulations of the new forming fashion are focused for the workpiece’s revolving surface and the convexity’s side profile. The simulation results show that both the cathode feed rate an

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Li, Guanchen, and Michael R. von Spakovsky. "Study of the Transient Behavior and Microstructure Degradation of a SOFC Cathode Using an Oxygen Reduction Model Based on Steepest-Entropy-Ascent Quantum Thermodynamics." In ASME 2015 International Mechanical Engineering Congress and Exposition. American Society of Mechanical Engineers, 2015. http://dx.doi.org/10.1115/imece2015-53726.

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Oxygen reduction in a solid oxide fuel cell (SOFC) cathode involves a non-equilibrium process of coupled mass and heat diffusion and electrochemical and chemical reactions. These phenomena occur at multiple temporal and spatial scales, from the mesoscopic to the atomistic level, making the modeling, especially in the transient regime, very difficult. Nonetheless, multi-scale models are needed to improve an understanding of oxygen reduction and guide fuel cell cathode design. Existing methods are typically phenomenological or empirical in nature so their application is limited to the continuum

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Hemmes, Kas, and Michel Cassir. "A Theoretical Study of the Carbon/Carbonate/Hydroxide (Electro-) Chemical System in a Direct Carbon Fuel Cell." In ASME 2004 2nd International Conference on Fuel Cell Science, Engineering and Technology. ASMEDC, 2004. http://dx.doi.org/10.1115/fuelcell2004-2497.

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Both the hydroxide and the carbonate melt are proposed and tested by researchers trying to develop a DCFC (Direct Carbon Fuel Cell). It is well known that the hydroxide melt is not stable due to the carbon dioxide formed in the fuel cell reaction. The hydroxide ion OH− reacts with CO2 to form carbonate ions and water. From this reaction it is clear that in either approach the melt is a mixture of carbonate and hydroxide depending on the partial pressures of water and CO2 above the melt. Therefore a good insight in the equilibria present in the melts is essential for understanding and optimizin

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Magar, Yogesh N., and Raj M. Manglik. "Thermal and Hydrodynamic Modeling of Fully-Developed Convection in Anode-Supported Planar Solid Oxide Fuel Cells." In ASME 2005 International Mechanical Engineering Congress and Exposition. ASMEDC, 2005. http://dx.doi.org/10.1115/imece2005-79986.

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Uniform supply of volatile species to an active surface along with the oxidant flow to sustain the surface electrochemical reaction, and its effective cooling in an anode supported solid oxide fuel cell (SOFC) is modeled. Three-dimensional nonlinear partial differential governing equations for the conservation of mass, momentum, energy, species, and electrochemical kinetics for both the anode and cathode ducts for steady laminar, incompressible flow are solved computationally. A planar, tri-layer SOFC module, which consists of porous anode and cathode layers, solid electrolyte and rectangular

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Hwang, J. J. "Heat Transfer in a Porous Cathode of Fuel Cells." In ASME 2005 Summer Heat Transfer Conference collocated with the ASME 2005 Pacific Rim Technical Conference and Exhibition on Integration and Packaging of MEMS, NEMS, and Electronic Systems. ASMEDC, 2005. http://dx.doi.org/10.1115/ht2005-72731.

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This paper has provided an innovative aspect in the heat transfer of fuel-cell related studies. A heat/mass coupled modeling approach is presented to predict the transport phenomena inside the porous electrode of a fuel cell. The energy equations based on the local thermal non-equilibrium (LTNE) is derived to resolve the temperature difference between the solid and fluid phases inside the porous electrode. The surface heat transfer is coupled with the species transports via a macroscopic electrochemical model on the reaction boundary. A general criterion for the local thermal non-equilibrium i

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Mendoza, Sergio, and Hosam K. Fathy. "Entropy Coefficient and Thermal Time Constant Estimation From Dynamic Thermal Cycling of a Cylindrical LiFePO4 Battery Cell." In ASME 2014 Dynamic Systems and Control Conference. American Society of Mechanical Engineers, 2014. http://dx.doi.org/10.1115/dscc2014-6176.

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This paper presents a method for estimating (i) the reciprocal of the thermal time constant of a lithium-ion battery cell and (ii) the cell’s entropy coefficients for different states of charge. The method utilizes dynamic battery temperature cycling for parameter estimation. The paper demonstrates this method specifically for a cylindrical lithium iron phosphate (LiFePO4) cell. Identifying battery thermal parameters is important for accurate thermo-electrochemical modeling and model-based battery management. Entropy coefficients have been identified in previous research for various battery ch

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Li, Pei-Wen, Laura Schaefer, and Minking K. Chyu. "Interdigitated Heat/Mass Transfer and Chemical/Electrochemical Reactions in a Planar Type Solid Oxide Fuel Cell." In ASME 2003 Heat Transfer Summer Conference. ASMEDC, 2003. http://dx.doi.org/10.1115/ht2003-47436.

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The details of the heat/mass transfer in a planar type solid oxide fuel cell that controls the energy conversion performance are studied by employing a three-dimensional numerical computation for the fields of velocity, gas mass fractions and temperature. The SOFC under investigation is a unit working in a SOFC stack. It has the tri-layer of anode-electrolyte-cathode and interconnects having multiple channels for fuel and air. Two designs of the tri-layer, anode-supported and electrolyte-supported, are studied. Pre-reformed fuel gas with components of H2, H2O, CO, CO2 and CH4 is arranged in cr

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Venkata, P. P., M. A. Jog, and R. M. Manglik. "Computational Modeling of Planar SOFC: Effects of Volatile Species/Oxidant Mass Flow Rate and Electrochemical Reaction Rate on Convective Heat Transfer." In ASME 2008 International Mechanical Engineering Congress and Exposition. ASMEDC, 2008. http://dx.doi.org/10.1115/imece2008-69249.

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A three-dimensional computational simulation of an intermediate temperature planar, tri-layered solid oxide fuel cell is considered for steady incompressible fully developed laminar flow in the interconnect ducts of rectangular cross section, with uniform supply of volatile species (80% H2 + 20% H2O vapor) and oxidant (20% O2 + 80% N2) at the electrolyte surface. The governing equations of mass, momentum and energy conservation coupled with that for electrochemical species are solved computationally. The Darcy-Forchheimer model described the fuel and oxidant transport through the porous electr

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Najm, Habib N., Bert J. Debusschere, Omar M. Knio, Roger R. Ghanem, Alain Matta, and Olivier P. Le Maiˆtre. "Uncertainty Quantification in Models of Microfluid Systems." In ASME 2003 International Mechanical Engineering Congress and Exposition. ASMEDC, 2003. http://dx.doi.org/10.1115/imece2003-43240.

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Uncertainty quantification (UQ) in models of physical systems is a necessary tool for both model validation and engineering design optimization. We have applied UQ tools using stochastic spectral polynomial chaos techniques to the modeling of fluid flow in an electrokinetically driven microchannel, allowing for detailed buffer electrochemistry and finite rate analyte reactions. The model includes full coupling of wall electric double layer potential with variations in PH and local electric field. Allowing for uncertainties in species mobilities, buffer equilibrium constants, and wall propertie

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Ettefagh, Ali Hemmasian, Hao Wen, Fengyuan Lu, and Shengmin Guo. "Phase Evolution and Corrosion Performance of Laser Processed Oxide Dispersion Strengthened Ferritic Alloys." In ASME 2018 International Mechanical Engineering Congress and Exposition. American Society of Mechanical Engineers, 2018. http://dx.doi.org/10.1115/imece2018-86736.

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The application of laser processing as a surface treatment method on oxide dispersion strengthened (ODS) Fe-14Cr ferritic alloys, Fe-14Cr-3W-0.3Ti-xY2O3 (x = 0.3, 0.6, 0.9) (wt%), was examined in this paper. The ODS ferritic alloys with different amount of Y2O3 particles were prepared by mechanical milling and subsequently consolidated by spark plasma sintering (SPS). The effect of surface laser processing on the corrosion behavior was investigated for these ODS alloys with different oxide contents. The corrosion behaviors of SPS consolidated ODS samples with subsequent laser melting/solidific

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Reports on the topic "Electrochemical equilibrium"

1

Lussem, Bjorn. Finding the Equilibrium of Organic Electrochemical Transistors. Kent State University, 2020. http://dx.doi.org/10.21038/blus.2020.0101.

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Hu, Hongqiang, Claire Xiong, Mike Hurley, and Ju Li. Establishing New Capability of High Temperature Electrochemical Impedance Spectroscopy Techniques for Equilibrium and Kinetic Experiments. Office of Scientific and Technical Information (OSTI), 2017. http://dx.doi.org/10.2172/1468632.

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