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Dissertations / Theses on the topic 'Electrochemical’ interaction'

Author: Grafiati

Published: 28 May 2022

Last updated: 31 July 2025

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1

Damian, Alexis. "An electrochemical study of NAD+ interaction with a polycrystalline gold surface /." Thesis, McGill University, 2006. http://digitool.Library.McGill.CA:80/R/?func=dbin-jump-full&object_id=99405.

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The interaction of an oxidized form of nicotinamide adenine dinucleotide, NAD+, with a polycrystalline gold electrode surface was investigated using a range of electrochemical and spectroscopic techniques. It was shown that the reduction of NAD+ on gold is irreversible and occurs at cathodic overpotentials larger than -0.2 V. The NAD+ reduction reaction was found to be mass-transport controlled, and of first order with respect to NAD+. A set of kinetic parameters was calculated and verified independently using various experimental techniques: the apparent transfer and diffusion coefficients, t

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2

Khani, Meynaq Mohammad Yaser. "Electrochemical investigations on lipid cubic phases." Doctoral thesis, Umeå universitet, Kemiska institutionen, 2017. http://urn.kb.se/resolve?urn=urn:nbn:se:umu:diva-130174.

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Electrochemical Impedance Spectroscopy (EIS) was used to develop a novel methodology for studying ionic interaction with lipids arranged in a lipid cubic phase (LCP). Studying different types of ions, both cations and anions, validated the method. A free-standing LCP membrane was formed between two cell compartments and impedance experiments were carried out in a 2-electrode setup to estimate dielectric properties of the membrane, exposed to the following electrolyte solutions at different concentrations: KCl, CsBr, CaCl2, MgCl2, CsCl, NaCl, NaOAc and NaTryptophan. Two different LCP were used

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3

Oliinyk, O. V., V. A. Tatarenko, Y. B. Park, and P. O. Selyshchev. "Influence of Fluctuations of the Point-Defects’ Generation Rate and Inhomogeneity of Irradiated F.C.C. Crystal on the Temperature Dependence of the Dissipative-Structure Period in a Spatial Distribution of Radiation Vacancies." Thesis, Sumy State University, 2012. http://essuir.sumdu.edu.ua/handle/123456789/35438.

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A kinetic model for the influence of external noise, such as fluctuations of the point-defects’ production rate and inhomogeneity of irradiated f.c.c. crystal, on the formation of modulated defect-distribution structure is considered. Defect-production rate and density of sinks for point defects are simulated as independent uniform and stationary stochastic fields with certain parameters. The interaction between vacancies is taken into account. Such stochastic fields can induce a spatial point-defects’ distribution, which is a stationary uniform stochastic field. Its mean value and correl

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4

Dole, Holly. "Connecting Metal-Support Interaction and Electrochemical Promotion Phenomena for Nano-structured Catalysts." Thesis, Université d'Ottawa / University of Ottawa, 2016. http://hdl.handle.net/10393/34610.

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Air pollutants can cause poor air quality; however, the use of heterogeneous catalytic oxidation has been shown to be an efficient and cost-effective removal method. Some examples of commercial application of such catalysts include catalytic convertors in automobiles and industrial process exhausts. Research with regards to improving these technologies has included using less-expensive catalyst materials, increasing catalytic performance, and achieving higher efficiency. The concept of metal-support interaction (MSI) is one method of altering catalytic performance through changing the proper

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5

Wong, Rick P. C. "Electrochemical behaviour of quaternary pyridinium compounds and their interaction with electrode surfaces." Thesis, National Library of Canada = Bibliothèque nationale du Canada, 1998. http://www.collectionscanada.ca/obj/s4/f2/dsk2/ftp01/MQ35008.pdf.

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6

Pouliwe, Antibe. "Electrochemical Studies of The Interaction Between DNA and a Compound Having Anticancer Properties." Digital Commons @ East Tennessee State University, 2011. https://dc.etsu.edu/etd/1352.

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Electrochemical method has been used to study the interaction between DNA and the compound N-(3',6'-dihydroxy-3-oxospiro[isobenzofuran-1(3H),9'-[9H]xanthen]-5-yl)-N'-(2-imidazoyl)urea having anticancer properties. A DNA modified nanometer-sized gold electrode was prepared by surface modification of a bare gold electrode using cysteamine. These electrodes have been characterized using electrochemical techniques and were used to study the interaction between DNA and the compound. Our results showed an increase in the adsorption peak current and a negative shift of E1/2 in the oxidation of ferroc

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7

Hajar, Yasmine. "Effect of Electrochemical Promotion and Metal-Support Interaction on Catalytic Performance of Nano-catalysts." Thesis, Université d'Ottawa / University of Ottawa, 2019. http://hdl.handle.net/10393/39701.

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In heterogeneous catalysis, promoting the activity of the catalytic metals is long known as an important method to make a process more efficient and viable. Noble metals have been promoted classically by a chemical coverage of an ionic solution on the surface of the catalyst or using inert support, e.g., silica or alumina, allowing an increase of the dispersion of the catalyst. Therefore, new methods of promotion needed to be better explored to improve the efficiency of metal and metal oxide catalysts. One way of enhancing the catalyst’s activity is to disperse the noble metal at the nanoscale

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8

Ghoreishi, Sayed Mehdi. "Electrochemical studies associated with the interaction between ionic surfactants and a number of different macromolecules." Thesis, University of Salford, 1998. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.265530.

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9

Chen, Peng. "Single cell assays of exocytosis /." free to MU campus, to others for purchase, 2002. http://wwwlib.umi.com/cr/mo/fullcit?p3074384.

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10

Panaritis, Christopher. "Metal-Support Interaction and Electrochemical Promotion of Nano-Structured Catalysts for the Reverse Water Gas Shift Reaction." Thesis, Université d'Ottawa / University of Ottawa, 2021. http://hdl.handle.net/10393/41963.

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The continued release of fossil-fuel derived carbon dioxide (CO₂) emissions into our atmosphere led humanity into a climate and ecological crisis. Converting CO₂ into valuable chemicals and fuels will replace and diminish the need for fossil fuel-derived products. Through the use of a catalyst, CO₂ can be transformed into a commodity chemical by the reverse water gas shift (RWGS) reaction, where CO₂ reacts with renewable hydrogen (H₂) to form carbon monoxide (CO). CO then acts as the source molecule in the Fischer-Tropsch (FT) synthesis to form a range of hydrocarbons to manufacture chemicals

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11

Kamasah, Alexander. "Using Electrochemical Method to Study the Interaction Between DNA and a compound Known to Have Anticancer Property." Digital Commons @ East Tennessee State University, 2011. https://dc.etsu.edu/etd/1379.

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The interaction of 4-(1'-[8'-(1''-pyrenyl)naphthyl])-2,6-diaminopyridine bis-glycamide bishydrocholride known to have anticancer properties with deoxyribonucleic acid (DNA) had been studied on a modified gold electrode by self-assembled monolayer using cyclic voltammetry. K4Fe (CN)6 was used as a probe to obtain electrochemical information on the electrode surface. A bare gold (Au) electrode was modified with cysteamine and our results showed no change in the limiting steady state current as compared to the bare Au electrode. There was a reduction in the steady state current after the modifica

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12

Desroches, Marie-Josée. "Electrochemical and PM-IRRAS studies of the interaction of plasma protein fibrinogen with a biomedical-grade 316LVM stainless steel surface." Thesis, McGill University, 2007. http://digitool.Library.McGill.CA:80/R/?func=dbin-jump-full&object_id=99757.

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It is widely accepted that the initial event that significantly influences biocompatibility is the nearly instantaneous adsorption of proteins from biological fluids onto the biomaterial surface. For blood-contacting devices, the complex layer of adsorbed plasma proteins is generally unfavourable and leads to major complications, including thrombus formation, inflammatory tissue responses, and microbial infections. Furthermore, protein interaction with passive films on metallic biomaterial surfaces may contribute to enhanced in vivo corrosion. To gain a better understanding of this phenomenon,

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13

Bolivar, Vina José. "Experimental study of the behavior of colonies of environmentally-assisted short cracks by digital image correlation, acoustic emission and electrochemical noise." Thesis, Lyon, 2017. http://www.theses.fr/2017LYSEI059/document.

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Ce travail s’inscrit dans le contexte d’une meilleure prédiction de la durée de vie de structures soumises au risque d’amorçage et de propagation de fissures multiples de corrosion sous contrainte (CSC). Ainsi, en développant une méthodologie expérimentale originale basée sur des mesures conjointes de corrélation d’images numériques (DIC), d’émission acoustique (EA) et de bruit électrochimique (EN), et leur analyse, ce travail vise à contribuer à l’amélioration de la compréhension des mécanismes impliqués dans le développement de colonies de fissures courtes de CSC qui interagissent entre elle

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14

Herraiz, Michael. "Graphène et fluorographène par exfoliation de graphite fluoré : applications électrochimiques et propriétés de surface." Thesis, Université Clermont Auvergne‎ (2017-2020), 2018. http://www.theses.fr/2018CLFAC094/document.

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Sa conductivité électronique ou encore sa transparence optique sont autant de propriétés physico-chimiques singulières du graphène qui expliquent le nombre accru de méthodes d’exfoliation de précurseurs graphitiques développées pour l’obtention de ce matériau. Pour palier à l’utilisation d’un oxyde de graphite/graphène caractérisé par une chimie de surface mal maitrisée, des graphites fluorés, de cristallinité mais aussi de concentration en fluor variables, ont été préparés par fluoration de graphite sous fluor moléculaire pur après optimisation des paramètres. Les précurseurs, que ce soit par

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15

Dahbi, Mouad. "Etude d'électrolytes organiques pour la réalisation de supercondensateurs lithium-ion." Thesis, Tours, 2013. http://www.theses.fr/2013TOUR4031.

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Le travail réalisé dans cette thèse concerne l'optimisation d’électrolytes organiques pour supercondensateur lithium-ion. Plusieurs solvants ont été sélectionnés pour la formulation de mélanges binaires ou ternaires additionnés de sel de lithium. Les propriétés physicochimiques et électrochimiques de ces électrolytes contenant LiTFSI ou LiPF6 (EC/DMC ; dinitrile/DMC ; EC/Ester/3DMC, EC/MiPC/3DMC) ont été caractérisées en vue de leur utilisation dans des dispositifs hybrides, l’objectif étant de satisfaire à la fois aux exigences des matériaux graphite et carbone activé. Les interactions solvan

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16

Schneider, Wolfgang Benedikt. "Quantenchemie in elektrochemischen Prozessen." Doctoral thesis, Universitätsbibliothek Chemnitz, 2015. http://nbn-resolving.de/urn:nbn:de:bsz:ch1-qucosa-169966.

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Kern der vorliegenden Arbeit ist die Anwendung quantenchemischer Methoden auf Probleme der elektrochemischen Katalyse vor dem Hintergrund der Sauerstoffreduktion, wie sie an kohlenstoffgeträgerten Platinkatalysatoren abläuft. In diesem Zusammenhang werden die Stabilität des Katalysatorsystems und der Mechanismus der Sauerstoffreduktion untersucht, sowie ein Algorithmus zur Berechnung von Molekülen unter einem gegebenen Potential vorgestellt. Zuerst werden die Wechselwirkungen von Platinnanopartikeln mit polyzyklischen Aromaten als Modellverbindungen des Katalysatormaterials untersucht. Weiterh

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17

Rukšnaitė, Justina. "Paviršiaus plazmonų rezonanso ir elektrocheminiai imuniniai jutikliai žmogaus augimo hormono ir antikūnų prieš žmogaus augimo hormoną nustatymui." Doctoral thesis, Lithuanian Academic Libraries Network (LABT), 2014. http://vddb.library.lt/obj/LT-eLABa-0001:E.02~2014~D_20140929_100412-46854.

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Šioje daktaro disertacijoje buvo nagrinėjami paviršiaus plazmonų rezonanso (PPR) ir elektrocheminiai imuniniai jutikliai žmogaus augimo hormonui (ŽAH) ir antikūnams prieš žmogaus augimo hormoną (anti-ŽAH) nustatyti bei pritaikyti juos realių mėginių analizei. Šiame darbe buvo nagrinėjami nekryptingas ir kryptingas antikūnų imobilizavimo būdai PPR jutiklio lusto paviršiuje ir tirtas antikūno-antigeno komplekso formavimasis. Buvo nustatyta, kad tinkamiausias iš tirtų anti-ŽAH imobilizavimo PPR jutiklio lusto paviršiuje būdų yra kryptingas anti-ŽAH fragmentų gautų redukuojant anti-ŽAH 2-merkatoet

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18

Silwal, Achut Prasad. "Raman Spectroscopic Imaging Analysis of Signaling Proteins and Protein Cofactors in Living Cells." Bowling Green State University / OhioLINK, 2018. http://rave.ohiolink.edu/etdc/view?acc_num=bgsu1528721394633565.

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19

Ambari, Abdelhak. "Application des méthodes électrochimiques à l'étude de l'interaction entre l'hydrodynamique et la dynamique des polymères en écoulement élongationnel : interaction entre particules solides en régime de Stokes." Paris 6, 1986. http://www.theses.fr/1986PA066006.

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Dynamique des polymères linéaires et flexibles en écoulement élongationnel. Mise en évidence du changement brutal de la forme pelote à la forme étirée. Deux méthodes de mesure différentes : l'une basée sur la mesure directe de la dissipation viscoélastique, l'autre basée sur les effets de cette transition sur le transfert massique et sur l'hydrodynamique.

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20

Amar, Khodja Ahcène. "Interactions entre molecules hydrophobes et micelles mixtes ioniques formees par des melanges binaires de surfactifs : influence des caracteristiques physico-chimiques des melanges." Paris 6, 1987. http://www.theses.fr/1987PA066235.

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Etude de la solubilisation du pentanol-1 dans des micelles mixtes d'agents de surface anioniques, cationiques, non ioniques, hydrogenes et perfluores, et de la perturbation de la condensation ionique a la surface micellaire

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21

Schneider, Wolfgang Benedikt. "Quantenchemie in elektrochemischen Prozessen: Untersuchungen zu Stabilität, Reaktivität undLadungsübertragung bei der platinkatalysiertenSauerstoffreduktion." Doctoral thesis, Max-Planck-Institut für Chemische Energiekonversion, 2014. https://monarch.qucosa.de/id/qucosa%3A20252.

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Kern der vorliegenden Arbeit ist die Anwendung quantenchemischer Methoden auf Probleme der elektrochemischen Katalyse vor dem Hintergrund der Sauerstoffreduktion, wie sie an kohlenstoffgeträgerten Platinkatalysatoren abläuft. In diesem Zusammenhang werden die Stabilität des Katalysatorsystems und der Mechanismus der Sauerstoffreduktion untersucht, sowie ein Algorithmus zur Berechnung von Molekülen unter einem gegebenen Potential vorgestellt. Zuerst werden die Wechselwirkungen von Platinnanopartikeln mit polyzyklischen Aromaten als Modellverbindungen des Katalysatormaterials untersucht. Weiterh

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22

Limson, Janice Leigh. "Electrochemical studies of metal-ligand interactions and of metal binding proteins." Thesis, Rhodes University, 1999. http://hdl.handle.net/10962/d1018239.

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Electrochemical methods were researched for the analysis of metals, proteins and the identification of metal binding proteins. Adsorptive cathodic stripping voltamrnetry for metal analysis combines the inherent sensitivity of electrochemical techniques with the specificity of ligands for the nonfaradaic preconcentration of analytes at the electrode. The utility of catechol, resorcinol, 4-methylcatechol and 4-t-butylcatechol as ligands was explored for the sensitive analysis of copper, bismuth, cadmium and lead on a mercury film glassy carbon electrode. Metal complexes of lead, copper and bismu

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23

Onofri, Manuele <1983&gt. "Electrochemical sensing strategies for the detection of interactions between biological macromolecules." Doctoral thesis, Alma Mater Studiorum - Università di Bologna, 2013. http://amsdottorato.unibo.it/5552/1/Onofri_Manuele_tesi.pdf.

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Electrochemical biosensors provide an attractive means to analyze the content of a biological sample due to the direct conversion of a biological event to an electronic signal, enabling the development of cheap, small, portable and simple devices, that allow multiplex and real-time detection. At the same time nanobiotechnology is drastically revolutionizing the biosensors development and different transduction strategies exploit concepts developed in these field to simplify the analysis operations for operators and end users, offering higher specificity, higher sensitivity, higher operational

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24

Onofri, Manuele <1983&gt. "Electrochemical sensing strategies for the detection of interactions between biological macromolecules." Doctoral thesis, Alma Mater Studiorum - Università di Bologna, 2013. http://amsdottorato.unibo.it/5552/.

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Electrochemical biosensors provide an attractive means to analyze the content of a biological sample due to the direct conversion of a biological event to an electronic signal, enabling the development of cheap, small, portable and simple devices, that allow multiplex and real-time detection. At the same time nanobiotechnology is drastically revolutionizing the biosensors development and different transduction strategies exploit concepts developed in these field to simplify the analysis operations for operators and end users, offering higher specificity, higher sensitivity, higher operational

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25

Tanco, Margot Anabell Llosa. "Thermodynamic and electrochemical aspects of lithium-macrocycle interactions in dipolar aprotic media." Thesis, University of Surrey, 1996. http://epubs.surrey.ac.uk/844404/.

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In the introduction of this thesis thermodynamic and electrochemical studies on macrocyclic ligands related to those ligands investigated in this thesis are reviewed. A brief account on the progress made and the problems encountered in lithium battery technology are also presented. Thermodynamic parameters of complexation (Gibbs energies, DeltacG°, enthalpies, DeltacH°, and entropies, DeltacS° of lithium (hexafluoroarsenate, tetrafluoroborate and trifluoromethanesulfonate) and crown ethers (1-aza-12-crown-4 and 15-crown-5) in acetonitrile and propylene carbonate and (4'-aminobenzo-

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26

Ciocchetti, Fabiana. "Synthesis and electrochemical investigation of modified viologens capable of radical-radical interactions." Electronic Thesis or Diss., Strasbourg, 2025. http://www.theses.fr/2025STRAF010.

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Cette thèse de doctorat explore les interactions radical–radical dans des systèmes à base de viologènes non conventionnels, afin d’éclairer leur comportement électrochimique et leurs mécanismes rédox au sein d’architectures supramoléculaires hôte–invité. Une synthèse améliorée du cyclobis(paraquat-p-phénylène) fonctionnalisé par un alcyne est présentée. Cette plateforme a permis la création de dérivés multitopiques, répondant à une lacune où seule la composante axiale des (pseudo)rotaxanes était modifiée. Ces systèmes ont révélé une homodimérisation spontanée inédite, affectant la complexation

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27

Musgrove, Amanda. "Electrochemically controlled interaction of liposomes with a solid-supported octadecanol bilayer." Thesis, University of British Columbia, 2013. http://hdl.handle.net/2429/45323.

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28

Watson, Charles Martin. "Surface Interactions of Mercury on Gold Foil Electrodes in Electrodeposition and Stripping and ; An Investigation of Free Thiolate Ions from Metal-Thiolate Chalcogenides." Fogler Library, University of Maine, 2003. http://www.library.umaine.edu/theses/pdf/WatsonCM2003.pdf.

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29

Bonnet, Nicéphore. "A multiscale study of atomic interactions in the electrochemical double layer applied to electrocatalysis." Thesis, Massachusetts Institute of Technology, 2011. http://hdl.handle.net/1721.1/76914.

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Thesis (Ph. D.)--Massachusetts Institute of Technology, Dept. of Nuclear Science and Engineering, 2011.<br>Cataloged from PDF version of thesis.<br>Includes bibliographical references (p. 171-182).<br>This work is an integrated study of chemical and electrostatic interactions in the electrochemical double layer, and their significance for accurate prediction of reaction kinetics in electrocatalysis. First, a kinetic model of the oxygen reduction reaction (ORR) on platinum, in connexion with first-principles techniques, is developed to illustrate that a self-consistent description of kinetics a

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30

Wilson, Lindsay. "Electrochemical immunosensor based on cyclodextrin supramolecular interactions for the detection of human chorionic gonadotropin." Thesis, University of the Western Cape, 2012. http://hdl.handle.net/11394/3995.

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>Magister Scientiae - MSc<br>Glucose oxidase (GOx) and horseradish peroxidase (HRP) are important enzymes for the development of amperometric enzyme linked immunosensors. The selectivity of each enzyme towards its analyte deepens its importance in determining the sensitivity of the resultant immunosensor. In designing immunosensors that have customized transducer surfaces, the incorporation with FAD and iron based enzymes ensures that electron kinetics remains optimal for electrochemical measurement. Various different immobilization strategies are used to produce response signals directly prop

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31

Minton, Geraint Philip. "Modelling the static and dynamic behaviour of electrolytes : a modified Poisson-Nernst-Planck approach." Thesis, University of Manchester, 2014. https://www.research.manchester.ac.uk/portal/en/theses/modelling-the-static-and-dynamic-behaviour-of-electrolytes-a-modified-poissonnernstplanck-approach(de9671fd-feb5-4870-b0a9-ad6a28ff953d).html.

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In this thesis a method is presented for the modelling the effects of the excluded volume (ion-ion) and ion excess polarisability (ion-solvent) interactions in an electrolyte at a smooth planar electrode. The impact of these interactions is studied in terms of the equilibrium state of single and mixed electrolytes, the dynamic response of single electrolytes to a time-dependent applied potential, and their effect on the reaction rate, for both steady and time-dependent applied potentials. For reacting systems, the reaction rate is modelled using a modified form of the Frumkin-Butler-Volmer equ

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32

Ali, Irshad. "Electrochemical investigations of the interactive behavior of Nicotinamide Adenine Dinucleotide (NAD+/NADH) with electrode surfaces: towards direct electrochemical regeneration of enzymatically-active NADH." Thesis, McGill University, 2013. http://digitool.Library.McGill.CA:80/R/?func=dbin-jump-full&object_id=117104.

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Nicotinamide adenine dinucleotide NAD(H) is a co-enzyme which participates in a large number of biochemical processes in which it acts as a hydrogen and electron carrier. Hence, NAD(H) is found in two redox forms: oxidized, NAD+, and reduced, 1,4-NADH. Despite its high potential industrial use, due to its very high cost (especially that of 1,4-NADH) and the need to be added in a biochemical reactor in stoichiometric quantities, its current use is very limited. Hence, there is a need to develop in-situ 1,4-NADH regeneration methods. Electrochemical methods are of particular interest because of

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33

Kanbertay, Elif. "Synthesis Of Dopamine Functionalized Silver Nanoparticles Together With Possible Interactions Between Silver And Dopamine Having Different Oxidation Forms." Master's thesis, METU, 2013. http://etd.lib.metu.edu.tr/upload/12615658/index.pdf.

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Dopamine is a neurotransmitter found in central nerve system which has a vital role for human health. Dopamine oxidation in body is an important issue since it may form reactive metabolites which can be toxic to the cell. Surface-enhanced Raman scattering (SERS) is currently recognized as one of the most sensitive spectroscopic tools, which can be exploited for ultrasensitive chemical and biological detection, addition to providing structural information on the systems of interest. SERS of dopamine displays three strong bands at 1269, 1331 and 1479 cm-1. These bands are the signature of dopami

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34

Karlsson, Christoffer. "Conducting Redox Polymers for Electrical Energy Storage : Backbone - Substituent Interactions in Quinone Polypyrrole Model Systems." Doctoral thesis, Uppsala universitet, Nanoteknologi och funktionella material, 2014. http://urn.kb.se/resolve?urn=urn:nbn:se:uu:diva-230647.

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Organic electrical energy storage (EES) is a growing field of research that is expected to play an important role in the future, as the need for sustainable EES increases. Conducting redox polymers (CRPs), i.e. conducting polymers with incorporated redox active moieties e.g. as pendant groups (PGs), are proposed as a promising class of compounds for this purpose. Redox cycling of the PGs can be utilized for high charge storage capacity, while the conducting polymer backbone provides fast charge transport through the material. Some of the major challenges with small-molecule systems for EES cou

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35

Pardo, Maria Teresa Garrido. "Neutral macrocycles and their interactions with amino acids and amines : thermodynamic, electrochemical and structural studies in non-aqueous media." Thesis, University of Surrey, 1993. http://epubs.surrey.ac.uk/843851/.

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The first part of this work deals with the interactions of amino acids and neutral macrocyclic ligands (18-crown-6 and cryptand 222). Solubilities and Gibbs energies of solution of several amino acids and their complexes with 18-crown-6 in acetonitrile, as well as of some amino acid ester salts in chloroform have been determined at 298.15 K. An increase in the solubility data for the amino acid complexes relative to the free amino acids has been found, as a result of the interactions of the guest molecules with the macrocyclic ligands. Stability constants, Gibbs energies, enthalpies and entrop

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36

Ehrensberger, Mark T. "The in-vitro biological and electrochemical interactions of electrically polarized commercially pure titanium used for orthopedic and dental applications." Related electronic resource: Current Research at SU : database of SU dissertations, recent titles available, full text:, 2008. http://wwwlib.umi.com/cr/syr/main.

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37

Protsailo, Lesia V. "Characterization of the electrode/SAM/electrolyte interface and intermolecular interactions in solutions using electrochemical impedance spectroscopy and ATR-FTIR spectroscopy /." For electronic version search Digital dissertations database. Restricted to UC campuses. Access is free to UC campus dissertations, 2002. http://uclibs.org/PID/11984.

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Taranovskyy, Andriy [Verfasser]. "Study of dynamic processes at the electrochemical interface by in situ high speed STM: surface diffusion and adsorbate interactions / Andriy Taranovskyy." Kiel : Universitätsbibliothek Kiel, 2012. http://d-nb.info/1029083754/34.

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39

Kaabi, Walid. "Etude des interactions cadmium-or par microbalance électrochimique à cristal de quartz et rétrodiffusion de Rutherford." Châtenay-Malabry, Ecole centrale de Paris, 2007. http://www.theses.fr/2007ECAP1046.

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L'électrodépôt de cadmium sur or et sur platine a été étudié par microbalance électrochimique à cristal de quartz (EQCM) et spectrométrie de rétrodiffusion de Rutherford (RBS). Les résultats ont montré que pour les deux systèmes le processus de dépôt était amorcé en région UPD (Under Potential Deposition), mais différents processus se déroulaient lors du dépôt OPD (Over Potential Deposition) et la redissolution. Pour le système cadmium-or, une étape de formation d'alliage Cd-Au était observée en fin de région UPD et continuait à progresser en région OPD. Ainsi, le processus de redissolution s'

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40

Heresanu, Vasile. "Electrodéposition sous champ magnétique de zinc et de fer : propriétés magnétiques des arborescences de fer." Université Joseph Fourier (Grenoble), 2003. https://tel.archives-ouvertes.fr/tel-00004123.

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Ce travail concerne les effets de champ magnétique sur les arborescences de zinc et de fer obtenues par électrodéposition en cellule fine et les propriétés magnétiques des arborescences de fer. Pour le zinc et sous champ magnétique normal, les changements de morphologie macroscopiques variés sont expliqués par l'action mécanique sur l'agrégat en croissance de convections fluides induites par la force de Lorentz. Un faible effet est observé à l'échelle microscopique mais pas sur la structure cristalline. Un champ plan n'influence que faiblement la croissance. Pour le fer, un champ magnétique no

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Bodea, Simona. "Arborescences magnétiques de fer et de cobalt élaborées par électrodéposition." Phd thesis, Université Joseph Fourier (Grenoble), 2000. http://tel.archives-ouvertes.fr/tel-00005942.

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Ce travail concerne la croissance d'arborescences magnétiques de fer et de cobalt par électrodéposition en cellule mince. Seules deux morphologies sont obtenues, une dense avec de nombreuses branches à faible concentration et une ramifiée avec moins de branches à forte concentration. L'effet d'un champ magnétique sur la croissance est étudié. En champ vertical, contrairement aux métaux non magnétiques, la morphologie des dépôts de fer et de cobalt ne spirale pas. Un changement de morphologie est toutefois observé, plus prononcé à forte concentration. En champ horizontal, à forte concentration,

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Crozier, Paul S. "Slab-Geometry Molecular Dynamics Simulations: Development and Application to Calculation of Activity Coefficients, Interfacial Electrochemistry, and Ion Channel Transport." BYU ScholarsArchive, 2002. https://scholarsarchive.byu.edu/etd/2.

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Methods of slab-geometry molecular dynamics computer simulation were tested, compared, and applied to the prediction of activity coefficients, interfacial electrochemistry characterization, and ion transport through a model biological channel-membrane structure. The charged-sheets, 2-D Ewald, corrected 3-D Ewald, and corrected particle-particle-particle-mesh (P3M) methods were compared for efficiency and applicability to slab-geometry electrolyte systems with discrete water molecules. The P3M method was preferred for long-range force calculation in the problems of interest and was used through

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Creazzo, Fabrizio. "Oxygen evolution reaction at cobalt oxides/water interfaces : heterogeneous electrocatalysis by DFT-MD simulations & metadynamics Ab initio molecular dynamics study of an aqueous NaCl solution under an electric field Ionic diffusion and proton transfer in aqueous solutions of alkali metal salts Ionic Diffusion and Proton Transfer in Aqueous Solutions under an Electric Field: State-of-The-Art Ionic diffusion and proton transfer of MgCl2 and CaCl2 aqueous solutions: an ab initio study under electric field DFT-MD of the (110)-Co 3 O 4 cobalt oxide semiconductor in contact with liquid water, preliminary chemical and physical insights into the electrochemical environment Enhanced conductivity of water at the electrified air–water interface: a DFT-MD characterization Ions tune interfacial water structure and modulate hydrophobic interactions at silica surfaces." Thesis, université Paris-Saclay, 2020. http://www.theses.fr/2020UPASE012.

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Dans cette thèse, des simulations DFT-MD couplées à des techniques inno-vantes de métadynamique, sont appliquées pour acquérir une compréhensionglobale des interfaces aqueuses d'oxyde de cobalt Co3O4 et CoO(OH) dansla catalyse de la réaction d'évolution de l'oxygène (OER), et ainsi éventuellement aider à la conception de nouveaux catalyseurs basés sur des matériaux non précieux, un domaine clé de la recherche scientifique et technologique, particulièrement important pour l'économie de l'hydrogène, pour les technologies vertes dans une période de temps avec une demande toujours plus croissantee

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Huang, Guozhi. "Modelling of sulphide minerals: grinding media electrochemical interaction during grinding." 2005. http://arrow.unisa.edu.au:8081/1959.8/28362.

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In this study the unique Magotteaux Mill® system was used to control the grinding chemical conditions, which may be adjusted by varying grinding media, purging gas and pH, during grinding. An electrochemical apparatus was used to investigate oxidation-reduction behaviour of grinding media and sulphide mineral electrodes, as well as their galvanic interaction in-situ of the Magotteaux Mill®. Galvanic interaction between the grinding media (mild steel, 15% chromium, 21% chromium and 30% chromium media) and the sulphide minerals (bornite, arsenopyrite and pyrite) was initially quantified in-situ

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Lin, Jing-Hong, and 林敬浤. "Electrochemical and spectral studies of intermolecular interaction between porphyrin rings and aromatic amines." Thesis, 2010. http://ndltd.ncl.edu.tw/handle/53621530663204809727.

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碩士<br>國立暨南國際大學<br>應用化學系<br>98<br>The electrochemical and spectral properties of different free base porphyrin with p-phenylenediamine (PD) have been studied. The oxidation potentials of porphyrin and p-phenylenediamine were obtained by cyclic voltammetry (CV). The oxidation potential and wave changed by titration between porphyrin and p-phenylenediamine. The spectral change was investigated by using optically transparent thin-layer electrode (OTTLE). The interaction between different oxidation states of porphyrins and p-phenylenediamine are discussed. When the PD is oxidized, it interacts with

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Aphane, Germinah Polina. "Electrochemical studies on the interaction of mineralogy and ferric oxidants on sulphuric acid leaching of sphalerite." 2013. http://encore.tut.ac.za/iii/cpro/DigitalItemViewPage.external?sp=1000989.

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M. Tech. Metallurgical Engineering.<br>Investigate the dissolution behaviour of sphalerite minerals in sulphuric acid using ferric ions as oxidants. The specific objectives are to study the following: 1. the mineralogical characteristics of sphalerite ores ; 2. mineralogical effects on dissolution kinetics in sulphuric acid and 3. Effect of ferric ion concentration on the dissolution kinetics of sphalerite ores in sulphuric acid. Mineralogy is a critical area in mineral processing and has to be considered during process design stage, and during each processing stage. The type and concentration

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Sun, Sin-Cih, and 孫心慈. "Interaction between Ferric/Ferrous Cytochrome c and Cardiolipin: An Electrochemical and Quartz Crystal Microbalance with Dissipation Study." Thesis, 2015. http://ndltd.ncl.edu.tw/handle/56486163318642135298.

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碩士<br>東海大學<br>化學系<br>103<br>Cytochrome c (cyt c), a protein inherent with a redox-centered heme in ferric/ferrous states, locates in the mitochondrial intermembrane space in eukaryotic cells. The oxidation state of heme regulates structure of cyt c and its affinity to electron transport complexes, in which the ferric cyt c tends to bind to complex III and the ferrous cyt c associates with complex IV. Approximate 15 % of the positively charged cyt c associates with the mitochondrial cardiolipin (CL) in homeostatic conditions and function as a peroxidase to promote CL oxidation which is referred

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Tu, Yi-Jung, and 杜宜容. "(1) Theoretical Study of the Effect of Porphyrin-meso-Phenyl Interaction on Oxidation Potential(2) CV Simulation of Hydrogen-Bonding Effect on the Electrochemical Behavior of Phenylenediamines." Thesis, 2010. http://ndltd.ncl.edu.tw/handle/71450559661200366422.

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碩士<br>國立暨南國際大學<br>應用化學系<br>98<br>The thesis involves three topics. In the first part, the various values of the difference between the first and second oxidation potentials (ΔEox) for non-metalated meso-tetraphenylporphyrins (H2TPP) are determined by positions of the substituents on the meso-phenyl group. If a substituent is present only at the para position of the meso-phenyl group, ΔEox is generally significantly smaller than those of the H2TPPs with bulky o,o’-substituents on the phenyl group. The second part is concerned with unusual spectral and electrochemical properties of azobenzene-su

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Machini, Wesley Bruno da Silva. "Mecanismos de Interação de Fármacos e Proteínas com DNA Detetados In Situ com o Biossensor Eletroquímico Modificado com Nanoestruturas de DNA." Doctoral thesis, 2019. http://hdl.handle.net/10316/88806.

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Tese no âmbito do Doutoramento em Química, ramo de Eletroquímica e apresentada ao Departamento de Química da Faculdade de Ciências e Tecnologias da Universidade de Coimbra<br>O biossensor eletroquímico de DNA consiste num dispositivo em que o DNA é imobilizado na superfície de um transdutor eletroquímico, para detetar processos específicos de ligação com diferentes moléculas, monitorar as mudanças na estrutura conformacional do DNA após a interação com essas moléculas, e o aparecimento de resíduos das bases do DNA e dos seus produtos de oxidação, os biomarcadores do dano oxidativo do DNA. A in

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Roumi, Farshid. "Shape Changing Transformations: Interactions with Plasticity and Electrochemical Processes." Thesis, 2010. https://thesis.library.caltech.edu/5883/2/Payan_1.pdf.

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<p>Solids undergo phase transformations where the crystal structure changes with temperature, chemical potential, stress, applied electric fields, or other external parameters. These occur by either long-range diffusion of atoms (diffusional phase transformation) or by some form of cooperative, homogeneous movement of many atoms that results in changes in crystal structure (displacive phase transformation). In the latter case, these movements are usually less than the interatomic distances, and the atoms maintain their coordination. The most common example of displacive phase transformations i

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