To see the other types of publications on this topic, follow the link: Electrochemical interface.

Journal articles on the topic 'Electrochemical interface'

Create a spot-on reference in APA, MLA, Chicago, Harvard, and other styles

Select a source type:

Consult the top 50 journal articles for your research on the topic 'Electrochemical interface.'

Next to every source in the list of references, there is an 'Add to bibliography' button. Press on it, and we will generate automatically the bibliographic reference to the chosen work in the citation style you need: APA, MLA, Harvard, Chicago, Vancouver, etc.

You can also download the full text of the academic publication as pdf and read online its abstract whenever available in the metadata.

Browse journal articles on a wide variety of disciplines and organise your bibliography correctly.

1

Bond, AlanM. "Electrochemical Interfaces: Modern Techniques for In-Situ Interface Characterization." Analytica Chimica Acta 258, no. 2 (March 1992): 349–50. http://dx.doi.org/10.1016/0003-2670(92)85118-p.

Full text
APA, Harvard, Vancouver, ISO, and other styles
2

Holze, Rudolf. "Electrochemical Interfaces: Modern Techniques for In-Situ Interface Characterisation." Electrochimica Acta 37, no. 8 (June 1992): 1461. http://dx.doi.org/10.1016/0013-4686(92)87023-s.

Full text
APA, Harvard, Vancouver, ISO, and other styles
3

Vitt, Joseph E. "Books: Studying the Electrochemical Interface." Analytical Chemistry 68, no. 9 (May 1996): 320A—321A. http://dx.doi.org/10.1021/ac961919x.

Full text
APA, Harvard, Vancouver, ISO, and other styles
4

Chung, Taek Dong, Seok Hee Han, Joohee Jeon, Sung Il Kim, Min-Ah Oh, Wonkyung Cho, Sun-heui Yoon, Ji Yong Kim, and Chang Il Shin. "Electrochemical Neural Interface and Iontronics." ECS Meeting Abstracts MA2020-02, no. 44 (November 23, 2020): 2792. http://dx.doi.org/10.1149/ma2020-02442792mtgabs.

Full text
APA, Harvard, Vancouver, ISO, and other styles
5

Avila, Edith Ariza, and L. A. Rocha. "Evaluation of Corrosion Resistance of Multi-Layered Ti/Glass-Ceramic Interfaces by Electrochemical Impedance Spectroscopy." Materials Science Forum 492-493 (August 2005): 189–94. http://dx.doi.org/10.4028/www.scientific.net/msf.492-493.189.

Full text
Abstract:
Practical applications of metal/ceramic joints can be found in the biomedical field regarding the encapsulation of implantable telemetric devices, the fabrication of crowns and bridges for dental restoration, or in the production of drug delivery systems, biomedical sensors and electrodes. Most of metal/ceramic joints are produced by the active metal brazing technique, which originates a multi-layered interface which should be able of accommodating the abrupt electronic, crystallographic, chemical, mechanical and thermo-mechanical discontinuity that characterize these systems. Additionally, when considering biomedical applications, corrosion resistance becomes of prime importance. In this work, the corrosion resistance of Ti/glass-ceramic interfaces obtained by active metal brazing was evaluated by electrochemical impedance spectroscopy (EIS) tests. The electrochemical behaviour of the interface was monitored, as a function of time, in a simulated physiological solution at room temperature. In order to evaluate the contribution of each layer and galvanic interactions between them, to the degradation mechanism of the interface, individual samples, representative of reaction layers present at the interface, were fabricated and electrochemically tested. Results show that the corrosion behaviour, of the whole interface was strongly influenced by the chemical composition of its constitutive layers. Thus, layers containing high contents of both titanium and silver showed a polarisation resistance increase with the immersion time, as a result of the formation of a thermodynamically stable passive film. On the other hand, the copper rich layer, appears to be the main responsible for the interface degradation. In fact, for high immersion times, an instable passive film is formed and, as a consequence, large amounts of copper are released. Galvanic interactions between the copper and the silver rich layers where also identified.
APA, Harvard, Vancouver, ISO, and other styles
6

Bagger, Alexander, Logi Arnarson, Martin H. Hansen, Eckhard Spohr, and Jan Rossmeisl. "Electrochemical CO Reduction: A Property of the Electrochemical Interface." Journal of the American Chemical Society 141, no. 4 (January 8, 2019): 1506–14. http://dx.doi.org/10.1021/jacs.8b08839.

Full text
APA, Harvard, Vancouver, ISO, and other styles
7

You, Hoydoo, and Zoltán Nagy. "Applications of Synchrotron Surface X-Ray Scattering Studies of Electrochemical Interfaces." MRS Bulletin 24, no. 1 (January 1999): 36–40. http://dx.doi.org/10.1557/s088376940005171x.

Full text
Abstract:
Aqueous-solution/solid interfaces are ubiquitous in modern manufacturing environments as well as in our living environment, and studies of such interfaces are an active area of science and engineering research. An important area is the study of liquid/solid interfaces under active electrochemical control, which has many immediate technological implications, for example, corrosion/passivation of metals and energy storage in batteries and ultracapacitors. The central phenomenon of electrochemistry is the charge transfer at the interface, and the region of interest is usually wider than a single atomic layer, ranging from a monolayer to thousands of angstroms, extending into both phases.Despite the technological and environmental importance of liquid/solid interfaces, the atomic level understanding of such interfaces had been very much hampered by the absence of nondestructive, in situ experimental techniques. The situation has changed somewhat in recent decades with the development of the largely ex situ ultrahigh vacuum (UHV) surface science, modern spectroscopic techniques, and modern surface microscopy.However in situ experiments of electrochemical interfaces are difficult, stemming from the special nature of these interfaces. These are so-called buried interfaces in which the solid electrode surface is covered by a relatively thick liquid layer. For this reason, the probe we use in the structural investigation must satisfy simultaneously two conditions: (1) the technique must be surface/interface sensitive, and (2) absorption of the probe in the liquid phase must be sufficiently small for penetration to and from the interface of interest without significant intensity loss.
APA, Harvard, Vancouver, ISO, and other styles
8

Power, Aoife C., Brian Gorey, Shaneel Chandra, and James Chapman. "Carbon nanomaterials and their application to electrochemical sensors: a review." Nanotechnology Reviews 7, no. 1 (February 23, 2018): 19–41. http://dx.doi.org/10.1515/ntrev-2017-0160.

Full text
Abstract:
AbstractCarbon has long been applied as an electrochemical sensing interface owing to its unique electrochemical properties. Moreover, recent advances in material design and synthesis, particularly nanomaterials, has produced robust electrochemical sensing systems that display superior analytical performance. Carbon nanotubes (CNTs) are one of the most extensively studied nanostructures because of their unique properties. In terms of electroanalysis, the ability of CNTs to augment the electrochemical reactivity of important biomolecules and promote electron transfer reactions of proteins is of particular interest. The remarkable sensitivity of CNTs to changes in surface conductivity due to the presence of adsorbates permits their application as highly sensitive nanoscale sensors. CNT-modified electrodes have also demonstrated their utility as anchors for biomolecules such as nucleic acids, and their ability to diminish surface fouling effects. Consequently, CNTs are highly attractive to researchers as a basis for many electrochemical sensors. Similarly, synthetic diamonds electrochemical properties, such as superior chemical inertness and biocompatibility, make it desirable both for (bio) chemical sensing and as the electrochemical interface for biological systems. This is highlighted by the recent development of multiple electrochemical diamond-based biosensors and bio interfaces.
APA, Harvard, Vancouver, ISO, and other styles
9

Yang, Fan, PeiLin Deng, Qingyong Wang, Jiexin Zhu, Ya Yan, Liang Zhou, Kai Qi, Hongfang Liu, Ho Seok Park, and Bao Yu Xia. "Metal–organic framework-derived cupric oxide polycrystalline nanowires for selective carbon dioxide electroreduction to C2 valuables." Journal of Materials Chemistry A 8, no. 25 (2020): 12418–23. http://dx.doi.org/10.1039/d0ta03565c.

Full text
Abstract:
Enriching the interface: metal–organic framework-derived copper oxide nanowires with abundant crystalline interfaces contribute to the efficient electrochemical CO2 reduction towards fast hydrocarbon generation.
APA, Harvard, Vancouver, ISO, and other styles
10

Ouyang, Yixin, Yehui Zhang, Peter S. Rice, Li Shi, Jinlan Wang, and P. Hu. "Electrochemical CO2 reduction: water/catalyst interface versus polymer/catalyst interface." Journal of Materials Chemistry A 9, no. 32 (2021): 17474–80. http://dx.doi.org/10.1039/d1ta04867h.

Full text
Abstract:
Alkaline polymer electrolyte electrolytic cells (APEECs) have the potential to replace aqueous-phase CO2 electrolyzer. Full reaction kinetics at polymer/copper interface is obtained to present a fundamental understanding of the superiority of APEECs.
APA, Harvard, Vancouver, ISO, and other styles
11

Nunomura, Norio, and Satoshi Sunada. "Iron-Water Interface under Electrochemical Condition." Materials Science Forum 879 (November 2016): 1399–403. http://dx.doi.org/10.4028/www.scientific.net/msf.879.1399.

Full text
Abstract:
Spin polarized density functional theory calculations have been performed to characterize the structure of water molecules on iron surface under applied charges. It is found that water molecules of the contact layer take H-down configuration under the negative charge, on the other hand, under the positive charge, they adsorbed on a top site of iron atom, as the applied charge increases, the dissociation of water molecules proceed. In addition, we found that the energy shift of the Fermi level varies linearly in the range from-e to +e, while beyond this range it tends to saturate.
APA, Harvard, Vancouver, ISO, and other styles
12

Lucas, C. A. "Atomic structure at the electrochemical interface." Journal of Physics D: Applied Physics 32, no. 10A (January 1, 1999): A198—A201. http://dx.doi.org/10.1088/0022-3727/32/10a/338.

Full text
APA, Harvard, Vancouver, ISO, and other styles
13

Gordon, J. G., O. R. Melroy, G. L. Borges, D. L. Reisner, H. D. Abruña, P. Chandrasekhar, and L. Blum. "Surface exafs of an electrochemical interface." Journal of Electroanalytical Chemistry and Interfacial Electrochemistry 210, no. 2 (October 1986): 311–14. http://dx.doi.org/10.1016/0022-0728(86)80584-8.

Full text
APA, Harvard, Vancouver, ISO, and other styles
14

Aurongzeb, Deeder. "Interface evolution during electrochemical oxidation-dissolution." Applied Surface Science 252, no. 4 (November 2005): 872–77. http://dx.doi.org/10.1016/j.apsusc.2005.01.032.

Full text
APA, Harvard, Vancouver, ISO, and other styles
15

Li, Min, Min Lv, Lihua Wang, Chunhai Fan, and Xiaolei Zuo. "Engineering electrochemical interface for biomolecular sensing." Current Opinion in Electrochemistry 14 (April 2019): 71–80. http://dx.doi.org/10.1016/j.coelec.2019.01.001.

Full text
APA, Harvard, Vancouver, ISO, and other styles
16

Iwasita, T., F. C. Nart, A. Rodes, E. Pastor, and M. Weber. "Vibrational spectroscopy at the electrochemical interface." Electrochimica Acta 40, no. 1 (January 1995): 53–59. http://dx.doi.org/10.1016/0013-4686(94)00239-w.

Full text
APA, Harvard, Vancouver, ISO, and other styles
17

Kornyshev, A. A., and I. Vilfan. "Phase transitions at the electrochemical interface." Electrochimica Acta 40, no. 1 (January 1995): 109–27. http://dx.doi.org/10.1016/0013-4686(94)00264-2.

Full text
APA, Harvard, Vancouver, ISO, and other styles
18

Brodsky, A. "Mesoscopic description of an electrochemical interface." Electrochimica Acta 41, no. 14 (July 1996): 2071–78. http://dx.doi.org/10.1016/0013-4686(96)00038-2.

Full text
APA, Harvard, Vancouver, ISO, and other styles
19

Jiao, Yan-Ni, and Wan-Guo Hou. "Some Interface Electrochemical Properties of Kaolinite." Chinese Journal of Chemistry 25, no. 6 (June 2007): 756–64. http://dx.doi.org/10.1002/cjoc.200790140.

Full text
APA, Harvard, Vancouver, ISO, and other styles
20

Landers, Alan T., David M. Koshy, Soo Hong Lee, Walter S. Drisdell, Ryan C. Davis, Christopher Hahn, Apurva Mehta, and Thomas F. Jaramillo. "A refraction correction for buried interfaces applied to in situ grazing-incidence X-ray diffraction studies on Pd electrodes." Journal of Synchrotron Radiation 28, no. 3 (March 15, 2021): 919–23. http://dx.doi.org/10.1107/s1600577521001557.

Full text
Abstract:
In situ characterization of electrochemical systems can provide deep insights into the structure of electrodes under applied potential. Grazing-incidence X-ray diffraction (GIXRD) is a particularly valuable tool owing to its ability to characterize the near-surface structure of electrodes through a layer of electrolyte, which is of paramount importance in surface-mediated processes such as catalysis and adsorption. Corrections for the refraction that occurs as an X-ray passes through an interface have been derived for a vacuum–material interface. In this work, a more general form of the refraction correction was developed which can be applied to buried interfaces, including liquid–solid interfaces. The correction is largest at incidence angles near the critical angle for the interface and decreases at angles larger and smaller than the critical angle. Effective optical constants are also introduced which can be used to calculate the critical angle for total external reflection at the interface. This correction is applied to GIXRD measurements of an aqueous electrolyte–Pd interface, demonstrating that the correction allows for the comparison of GIXRD measurements at multiple incidence angles. This work improves quantitative analysis of d-spacing values from GIXRD measurements of liquid–solid systems, facilitating the connection between electrochemical behavior and structure under in situ conditions.
APA, Harvard, Vancouver, ISO, and other styles
21

Lück, Jessica, and Arnulf Latz. "Modeling of the electrochemical double layer and its impact on intercalation reactions." Physical Chemistry Chemical Physics 20, no. 44 (2018): 27804–21. http://dx.doi.org/10.1039/c8cp05113e.

Full text
APA, Harvard, Vancouver, ISO, and other styles
22

Dong, Xiao Dong, Jun Hua Liu, and Yong Xia. "Electrochemical Fabrication and Characterization of Iron Quantum Wire." Advanced Materials Research 548 (July 2012): 147–50. http://dx.doi.org/10.4028/www.scientific.net/amr.548.147.

Full text
Abstract:
Stable iron quantum wire with atomic-scale was successfully fabricated and electrically characterized with an electrochemical method in solution by a home-made electrochemically controlled system. By careful controlling the etching/deposition process, stepwise conductance behavior could be clearly observed. The I-V curve of the formed iron quantum wire showed the ohmic behavior with low bias voltage. The work is of great significance for molecular electronics, interface electrochemistry and sensing.
APA, Harvard, Vancouver, ISO, and other styles
23

Maouche, Naima, and Belkacem Nessark. "Cyclic Voltammetry and Impedance Spectroscopy Behavior Studies of Polyterthiophene Modified Electrode." International Journal of Electrochemistry 2011 (2011): 1–5. http://dx.doi.org/10.4061/2011/670513.

Full text
Abstract:
We present in this work a study of the electrochemical behaviour of terthiophene and its corresponding polymer, which is obtained electrochemically as a film by cyclic voltammetry (CV) on platinum electrode. The analysis focuses essentially on the effect of two solvents acetonitrile and dichloromethane on the electrochemical behaviour of the obtained polymer. The electrochemical behavior of this material was investigated by cyclic voltammetry and electrochemical impedance spectroscopy (EIS). The voltammograms show that the film of polyterthiophene can oxide and reduce in two solutions; in acetonitrile, the oxidation current intensity is more important than in dichloromethane. The impedance plots show the semicircle which is characteristic of charge-transfer resistance at the electrode/polymer interface at high frequency and the diffusion process at low frequency.
APA, Harvard, Vancouver, ISO, and other styles
24

Lewandowski, Zbigniew, Wayne Dickinson, and Whonchee Lee. "Electrochemical interactions of biofilms with metal surfaces." Water Science and Technology 36, no. 1 (July 1, 1997): 295–302. http://dx.doi.org/10.2166/wst.1997.0067.

Full text
Abstract:
Two mechanisms of microbially influenced corrosion (MIC) are discussed and compared: corrosion modified by the presence of (1) sulfate-reducing bacteria (SRB) and (2) manganese-oxidizing bacteria (MOB). It is demonstrated that the nature of MIC in both cases depends on the nature of inorganic materials precipitated at the metal surface, iron sulfides and manganese oxides. Those materials are electrochemically active and, therefore, modify the electrochemical processes naturally occurring at the metal-solution interface. Some of these modifications may lead to accelerated corrosion.
APA, Harvard, Vancouver, ISO, and other styles
25

Dey, Ramendra Sundar, Susmita Gupta, Rupankar Paira, and C. Retna Raj. "Electrochemically Derived Redox Molecular Architecture: A Novel Electrochemical Interface for Voltammetric Sensing." ACS Applied Materials & Interfaces 2, no. 5 (April 28, 2010): 1355–60. http://dx.doi.org/10.1021/am1000213.

Full text
APA, Harvard, Vancouver, ISO, and other styles
26

Guymon, Rowley, Harb, and Wheeler. "Simulating an electrochemical interface using charge dynamics." Condensed Matter Physics 8, no. 2 (2005): 335. http://dx.doi.org/10.5488/cmp.8.2.335.

Full text
APA, Harvard, Vancouver, ISO, and other styles
27

Cao, C. "On electrochemical techniques for interface inhibitor research." Corrosion Science 38, no. 12 (December 1996): 2073–82. http://dx.doi.org/10.1016/s0010-938x(96)00034-0.

Full text
APA, Harvard, Vancouver, ISO, and other styles
28

Schwarz, Kathleen, and Ravishankar Sundararaman. "The electrochemical interface in first-principles calculations." Surface Science Reports 75, no. 2 (May 2020): 100492. http://dx.doi.org/10.1016/j.surfrep.2020.100492.

Full text
APA, Harvard, Vancouver, ISO, and other styles
29

Aggour, M., U. Störkel, C. Murrell, S. A. Campbell, H. Jungblut, P. Hoffmann, R. Mikalo, D. Schmeißer, and H. J. Lewerenz. "Electrochemical interface modification of CuInS2 thin films." Thin Solid Films 403-404 (February 2002): 57–61. http://dx.doi.org/10.1016/s0040-6090(01)01532-2.

Full text
APA, Harvard, Vancouver, ISO, and other styles
30

Chazalviel, J. N., V. M. Dubin, K. C. Mandal, and F. Ozanam. "Modulated Infrared Spectroscopy at the Electrochemical Interface." Applied Spectroscopy 47, no. 9 (September 1993): 1411–16. http://dx.doi.org/10.1366/0003702934067658.

Full text
Abstract:
Performing infrared spectroscopy of chemical species at the electrochemical interface represents a difficult challenge in terms of sensitivity (1 monolayer ∼1015 species/cm2) and selectivity (presence of the electrolyte). These problems are efficiently addressed by using modulation coupled with lock-in detection of the optical signal. The electrode potential, which governs the interface behavior, is the most straightforward physical quantity that can be modulated. Such a modulation technique may be combined with Fourier transform spectroscopy by using an interferometer with a very slow scanning speed of the movable mirror (∼1–10 μm/s). This approach allows one to reach high sensitivity (typical minimum detectable signal Δ I/I ∼ 10−6 in a single-reflection arrangement). In some special cases, other modulations may be of interest, for example, modulation of the light at a semiconducting photoelectrode. A common benefit of these modulation techniques is that the resulting response can be analyzed as a function of the modulation frequency or by consideration of the phase of the signal at a given frequency. As can be shown for several examples, this analysis allows one to distinguish between the various physical and electrochemical processes taking place at the interface: change of free-carrier concentration beneath the electrode surface or of ion populations in the ionic double layer, adsorptiondesorption effects, and Faradaic processes, for which useful information on the reaction mechanisms may be obtained.
APA, Harvard, Vancouver, ISO, and other styles
31

Hai, Nguyen T. M., Shuhei Furukawa, Tom Vosch, Steven De Feyter, Peter Broekmann, and Klaus Wandelt. "Electrochemical reactions at a porphyrin–copper interface." Physical Chemistry Chemical Physics 11, no. 26 (2009): 5422. http://dx.doi.org/10.1039/b807075j.

Full text
APA, Harvard, Vancouver, ISO, and other styles
32

Preiss, U., E. Borukhovich, N. Alemayehu, I. Steinbach, and F. LaMantia. "A permeation model for the electrochemical interface." Modelling and Simulation in Materials Science and Engineering 21, no. 7 (October 1, 2013): 074006. http://dx.doi.org/10.1088/0965-0393/21/7/074006.

Full text
APA, Harvard, Vancouver, ISO, and other styles
33

Oldham, Trey, Moshan Chen, Stephen Sharkey, Kimberly M. Parker, and Elijah Thimsen. "Electrochemical characterization of the plasma-water interface." Journal of Physics D: Applied Physics 53, no. 16 (February 18, 2020): 165202. http://dx.doi.org/10.1088/1361-6463/ab6e9c.

Full text
APA, Harvard, Vancouver, ISO, and other styles
34

Pang, J., and S. Chander. "Electrochemical characterization of the chalcopyrite/solution interface." Mining, Metallurgy & Exploration 9, no. 3 (August 1992): 131–36. http://dx.doi.org/10.1007/bf03402984.

Full text
APA, Harvard, Vancouver, ISO, and other styles
35

Moisel, M., M. A. F. L. de Mele, and W. D. Müller. "Biomaterial Interface Investigated by Electrochemical Impedance Spectroscopy." Advanced Engineering Materials 10, no. 10 (October 2008): B33—B46. http://dx.doi.org/10.1002/adem.200800184.

Full text
APA, Harvard, Vancouver, ISO, and other styles
36

Gründer, Yvonne, and Christopher A. Lucas. "Probing the charge distribution at the electrochemical interface." Physical Chemistry Chemical Physics 19, no. 12 (2017): 8416–22. http://dx.doi.org/10.1039/c7cp00244k.

Full text
APA, Harvard, Vancouver, ISO, and other styles
37

Sa, Young Jin, Chan Woo Lee, Si Young Lee, Jonggeol Na, Ung Lee, and Yun Jeong Hwang. "Catalyst–electrolyte interface chemistry for electrochemical CO2 reduction." Chemical Society Reviews 49, no. 18 (2020): 6632–65. http://dx.doi.org/10.1039/d0cs00030b.

Full text
APA, Harvard, Vancouver, ISO, and other styles
38

Mai, Sebastian, Janine Wessel, Anna Dimitrova, Michael Stich, Svetlozar Ivanov, Stefan Krischok, and Andreas Bund. "Nanoscale Morphological Changes at Lithium Interface, Triggered by the Electrolyte Composition and Electrochemical Cycling." Journal of Chemistry 2019 (February 3, 2019): 1–13. http://dx.doi.org/10.1155/2019/4102382.

Full text
Abstract:
Understanding the electrochemical and morphological properties of the Li-electrolyte interface plays a central role in the implementation of metallic Li in safe and efficient electrochemical energy storage. The current study explores the influence of soluble polysulfides (PS) and lithium nitrate (LiNO3) on the characteristics of the solid electrolyte interphase (SEI) layer, formed spontaneously on the Li surface, prior to electrochemical cycling. Special attention is paid to the evolution of the electrochemical impedance and nanoscale morphology of the interface, influenced by the contact time and electrolyte composition. The basic tools applied in this investigation are electrochemical impedance spectroscopy (EIS), atomic force microscopy (AFM) performed at the nanoscale, and X-ray photoelectron spectroscopy (XPS). The individual addition of polysulfides and LiNO3 increases the interface resistance, while the simultaneous application of these components is beneficial, reducing the SEI resistive behavior. The electrochemical cycling of Li in nonmodified 1,2-dimethoxy ethane (DME) and tetraethylene glycol dimethyl ether (TEGDME) based electrolytes leads to slight morphological changes, compared to the pristine Li pattern. In contrast, we found that in the presence of PS and LiNO3, the interface displays a rough and inhomogeneous morphology.
APA, Harvard, Vancouver, ISO, and other styles
39

Yu, Lei, Zhongyu Qian, Nannan Shi, Qi Liu, Jun Wang, and Xiaoyan Jing. "Interface chemistry engineering in electrode systems for electrochemical energy storage." RSC Adv. 4, no. 71 (2014): 37491–502. http://dx.doi.org/10.1039/c4ra03616f.

Full text
Abstract:
In this review, we introduce two powerful strategies for well-controlled interface. Interface chemistry engineering in electrode systems for electrochemical energy storage needs to integrate individual materials components to interface design and optimization.
APA, Harvard, Vancouver, ISO, and other styles
40

Samec, Zdenĕk, Jan Langmaier, and Takashi Kakiuchi. "Charge-transfer processes at the interface between hydrophobic ionic liquid and water." Pure and Applied Chemistry 81, no. 8 (July 31, 2009): 1473–88. http://dx.doi.org/10.1351/pac-con-08-08-36.

Full text
Abstract:
This article provides a brief review of theoretical and methodological concepts in the area of the charge-transfer processes at the interface between a hydrophobic ionic liquid (IL) and an electrolyte solution in water (W). Electrochemical methods of study of the W|IL interfaces are described, current experimental problems are indicated, and the most important experimental results are summarized. The relevance of electrochemistry at the W|IL interfaces to the extraction behavior of ILs is outlined.
APA, Harvard, Vancouver, ISO, and other styles
41

Zhou, Qiong, Xiao Mei Su, Hong Zhang, and Yong Ji Weng. "Characterization of Electrochemically Synthesized Pani on Graphite Electrode Use EIS." Advanced Materials Research 295-297 (July 2011): 1124–28. http://dx.doi.org/10.4028/www.scientific.net/amr.295-297.1124.

Full text
Abstract:
Polyaniline (Pani) on graphite electrode was synthesized electrochemically under galvanostatic condition at current density of 2.0 mA/cm2 from aqueous solution of 1.0 mol/L HCl and 0.25 mol/L aniline monomer. The Electrochemical Impedance Spectroscopy investigation of Pani was carried out at different stages of polymers oxidation. In the potential range 0.2V~0.7 V vs SCE, with the increase of test potential the membrane resistance decreased rapidly, and Faraday process at the polymer/solution interface weakened. When the test potential in range of -0.8V~0.2V or 0.7V~0.8V, the film has a higher membrane resistance, and lower ionic charge transfer resistance, which indicated that the ion exchange for the charge compensation at the polymer/electrolyte interface is much easier. And anticorrosion properties of Pani coating of different oxidations was investigated by salt spray test. The final visual observations of the tested coatings are in agree with the results of electrochemical impedance spectroscopy.
APA, Harvard, Vancouver, ISO, and other styles
42

Serva, Alessandra, Mathieu Salanne, Martina Havenith, and Simone Pezzotti. "Size dependence of hydrophobic hydration at electrified gold/water interfaces." Proceedings of the National Academy of Sciences 118, no. 15 (April 5, 2021): e2023867118. http://dx.doi.org/10.1073/pnas.2023867118.

Full text
Abstract:
Hydrophobic hydration at metal/water interfaces actively contributes to the energetics of electrochemical reactions, e.g. CO2 and N2 reduction, where small hydrophobic molecules are involved. In this work, constant applied potential molecular dynamics is employed to study hydrophobic hydration at a gold/water interface. We propose an adaptation of the Lum–Chandler–Weeks (LCW) theory to describe the free energy of hydrophobic hydration at the interface as a function of solute size and applied voltage. Based on this model we are able to predict the free energy cost of cavity formation at the interface directly from the free energy cost in the bulk plus an interface-dependent correction term. The interfacial water network contributes significantly to the free energy, yielding a preference for outer-sphere adsorption at the gold surface for ideal hydrophobes. We predict an accumulation of small hydrophobic solutes of sizes comparable to CO or N2, while the free energy cost to hydrate larger hydrophobes, above 2.5-Å radius, is shown to be greater at the interface than in the bulk. Interestingly, the transition from the volume dominated to the surface dominated regimes predicted by the LCW theory in the bulk is also found to take place for hydrophobes at the Au/water interface but occurs at smaller cavity radii. By applying the adapted LCW theory to a simple model addition reaction, we illustrate some implications of our findings for electrochemical reactions.
APA, Harvard, Vancouver, ISO, and other styles
43

Varatharajan, S., Sheela Berchmans, and V. Yegnaraman. "Tailoring self-assembled monolayers at the electrochemical interface." Journal of Chemical Sciences 121, no. 5 (September 2009): 665–74. http://dx.doi.org/10.1007/s12039-009-0080-1.

Full text
APA, Harvard, Vancouver, ISO, and other styles
44

Peng, Xianghong, Yi Liu, William E. Bentley, and Gregory F. Payne. "Electrochemical Fabrication of Functional Gelatin-Based Bioelectronic Interface." Biomacromolecules 17, no. 2 (January 21, 2016): 558–63. http://dx.doi.org/10.1021/acs.biomac.5b01491.

Full text
APA, Harvard, Vancouver, ISO, and other styles
45

Foresti, M. L., G. Pezzatini, and M. Innocenti. "Electrochemical behaviour of the Cu(110)|water interface." Journal of Electroanalytical Chemistry 434, no. 1-2 (August 1997): 191–200. http://dx.doi.org/10.1016/s0022-0728(97)00177-0.

Full text
APA, Harvard, Vancouver, ISO, and other styles
46

Frommhold, A., and E. Tarte. "Electrochemical Interface Modification Through Large Area Surface Nanostructuring." Sensor Letters 8, no. 3 (June 1, 2010): 470–75. http://dx.doi.org/10.1166/sl.2010.1296.

Full text
APA, Harvard, Vancouver, ISO, and other styles
47

Barker, Anna L., Marylou Gonsalves, Julie V. Macpherson, Christopher J. Slevin, and Patrick R. Unwin. "Scanning electrochemical microscopy: beyond the solid/liquid interface." Analytica Chimica Acta 385, no. 1-3 (April 1999): 223–40. http://dx.doi.org/10.1016/s0003-2670(98)00588-1.

Full text
APA, Harvard, Vancouver, ISO, and other styles
48

Ma, Ye, Cristian Zagar, Daniel J. Klemme, Debabrata Sikdar, Leonora Velleman, Yunuen Montelongo, Sang-Hyun Oh, Anthony R. Kucernak, Joshua B. Edel, and Alexei A. Kornyshev. "A Tunable Nanoplasmonic Mirror at an Electrochemical Interface." ACS Photonics 5, no. 11 (October 25, 2018): 4604–16. http://dx.doi.org/10.1021/acsphotonics.8b01105.

Full text
APA, Harvard, Vancouver, ISO, and other styles
49

Anthony Smith, J., Mira Josowicz, and Jiří Janata. "Gold–polyaniline composite : Part I. Moving electrochemical interface." Physical Chemistry Chemical Physics 7, no. 20 (2005): 3614. http://dx.doi.org/10.1039/b507038d.

Full text
APA, Harvard, Vancouver, ISO, and other styles
50

Martinez Moreno, Elias, and Marinus Kunst. "Microwave Electrochemical Characterization of the Si/Isolator Interface." ECS Transactions 35, no. 8 (December 16, 2019): 185–200. http://dx.doi.org/10.1149/1.3567750.

Full text
APA, Harvard, Vancouver, ISO, and other styles
We offer discounts on all premium plans for authors whose works are included in thematic literature selections. Contact us to get a unique promo code!

To the bibliography