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Journal articles on the topic 'Electrochemiluminescent (ECL) iridium(III) complexes'

Author: Grafiati
Published: 10 December 2022
Last updated: 31 July 2025

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1

Zhou, Yuyang, Kai Xie, Ruimei Leng, et al. "Highly efficient electrochemiluminescence labels comprising iridium(iii) complexes." Dalton Transactions 46, no. 2 (2017): 355–63. http://dx.doi.org/10.1039/c6dt04038a.

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Highly efficient iridium ECL labels exhibiting various emission colors have been developed. Importantly, BSA labeled with the novel iridium labels displays much more intense ECL than the same amount labeled by a traditional ruthenium label in ProCell buffer solution.
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2

Zhou, Yuyang, Wanfei Li, Linpo Yu, Yang Liu, Xiaomei Wang, and Ming Zhou. "Highly efficient electrochemiluminescence from iridium(iii) complexes with 2-phenylquinoline ligand." Dalton Transactions 44, no. 4 (2015): 1858–65. http://dx.doi.org/10.1039/c4dt02809k.

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3

Huang, Yueyue, Egan H. Doeven, Lifen Chen, et al. "Facial Preparation of Cyclometalated Iridium (III) Nanowires as Highly Efficient Electrochemiluminescence Luminophores for Biosensing." Biosensors 13, no. 4 (2023): 459. http://dx.doi.org/10.3390/bios13040459.

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In this study, highly efficient ECL luminophores composed of iridium complex-based nanowires (Ir–NCDs) were synthesized via covalently linking bis(2-phenylpyridine)-(4-carboxypropyl-2,2′-bipyridyl) iridium(III) hexafluorophosphate with nitrogen-doped carbon quantum dots (NCDs). The ECL intensity of the nanowires showed a five-fold increase in ECL intensity compared with the iridium complex monomer under the same experimental conditions. A label-free ECL biosensing platform based on Ir–NCDs was established for Salmonella enteritidis (SE) detection. The ECL signal was quenched linearly in the ra
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4

Polo, Federico, Beatrice Polido, Mattia Reato, Giulia Moro, Neso Sojic, and Matteo Mauro. "(Invited) Heterobimetallic IrIII-MI (MI = Au, Cu) Complexes: A Novel and Bright Alternative As Electrochemiluminescence Probes for Sensing and Imaging." ECS Meeting Abstracts MA2025-01, no. 60 (2025): 2903. https://doi.org/10.1149/ma2025-01602903mtgabs.

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Bimetallic complexes are rapidly emerging as a valid and attractive class of emitters. In this presentation, we will describe a recent work concerning the yet unexplored electrochemiluminescence (ECL) properties of a series of heterobimetallic complexes of general structure IrIII-MI belonging to the class of ionic transition metal complexes (iTMCs). In the IrIII-MI series, the formally neutral cyclometalated iridium complex provides efficient photo- and electro-active properties to the molecular emitters. Whereas bulky MI(gold or copper) metalloligand increases structural rigidity and chemical
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5

Park, Joonho, Taemin Kim, Hoon Jun Kim, and Jong-In Hong. "Iridium(iii) complex-based electrochemiluminescent probe for H2S." Dalton Transactions 48, no. 14 (2019): 4565–73. http://dx.doi.org/10.1039/c8dt04901g.

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6

Li, Chunxiang, Juan Lin, Xiaoyan Yang, and Jun Wan. "Efficient electrochemiluminescent cyclometalated iridium(III) complexes: Synthesis, photophysical and electrochemiluminescent properties." Journal of Organometallic Chemistry 696, no. 11-12 (2011): 2445–50. http://dx.doi.org/10.1016/j.jorganchem.2011.03.015.

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7

Bandini, Marco, Michele Bianchi, Giovanni Valenti, et al. "Electrochemiluminescent Functionalizable Cyclometalated Thiophene-Based Iridium(III) Complexes." Inorganic Chemistry 49, no. 4 (2010): 1439–48. http://dx.doi.org/10.1021/ic901660m.

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8

Quan, Linh M., Bradley D. Stringer, Mohammad A. Haghighatbin, et al. "Tuning the electrochemiluminescent properties of iridium complexes of N-heterocyclic carbene ligands." Dalton Transactions 48, no. 2 (2019): 653–63. http://dx.doi.org/10.1039/c8dt04433c.

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9

Karmis, Rebecca E., Serena Carrara, Amy A. Baxter, Conor F. Hogan, Mark D. Hulett, and Peter J. Barnard. "Luminescent iridium(iii) complexes of N-heterocyclic carbene ligands prepared using the ‘click reaction’." Dalton Transactions 48, no. 27 (2019): 9998–10010. http://dx.doi.org/10.1039/c9dt01362h.

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Luminescent and electrochemiluminescent N-heterocyclic carbene-combined 1,2,3-triazole and 1,2,3-triazolylidene Ir(iii) complexes have been prepared and their potential as luminescent probes in cell imaging has been evaluated.
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10

Castor, Katherine J., Kimberly L. Metera, Ushula M. Tefashe, Christopher J. Serpell, Janine Mauzeroll, and Hanadi F. Sleiman. "Cyclometalated Iridium(III) Imidazole Phenanthroline Complexes as Luminescent and Electrochemiluminescent G-Quadruplex DNA Binders." Inorganic Chemistry 54, no. 14 (2015): 6958–67. http://dx.doi.org/10.1021/acs.inorgchem.5b00921.

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11

Zhu, Shengnan, Qijun Song, Songlin Zhang, and Yuqiang Ding. "Effects of the frontier orbitals on the electrochemical and electrochemiluminescent properties of the bis-cyclometalated iridium(III) complexes with different ligands." Journal of Molecular Structure 1035 (March 2013): 224–30. http://dx.doi.org/10.1016/j.molstruc.2012.11.015.

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12

Qu, Weiyu, Xinrui Yang, Xiaojin Huang, Weiliang Guo, and Zhihui Dai. "Electrochemiluminescence of Iridium(III)/Ruthenium(II) Complexes with Naphthyl Tags in Solutions and in Host-Guest Thin Films." Dalton Transactions, 2024. http://dx.doi.org/10.1039/d3dt03922f.

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Herein we report the electrochemiluminescence (ECL) generation from three new iridium(III)/ruthenium(II) (Ir(III)/Ru(II)) complexes with naphthyl (nap) tags in solutions and in host-guest thin films. In comparison with its parent structure,...
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13

Manimaran, Kesha Sriee, Shelby K. Semjanov, Keith F. White, et al. "Exploiting a New Strategy to Prepare Water‐Soluble Heteroleptic Iridium(III) Complexes to Control Electrochemiluminescence Reaction Pathways in Aqueous Solution." Chemistry – A European Journal, April 10, 2025. https://doi.org/10.1002/chem.202500701.

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The direct derivatisation of heteroleptic iridium(III) complexes with sulfonate groups removes the limitations of prior strategies for the preparation of water‐soluble analogues, in which complexes were prepared from a narrow range of ligands with suitably polar or charged functional groups. Phenylpyridine, phenylpyrazole and phenylbenzothiazole ligands were selectively sulfonated opposite to their cyclometalated carbon within iridium(III) complexes containing bipyridine or N‐heterocyclic carbene ancillary ligands. Altering reaction conditions enabled additional sulfonation of the benzothiazol
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14

Liu, Bingqing, Xin Yang, Mohammed A. Jabed, Svetlana Kilina, Zhengchun Yang, and Wenfang Sun. "Water-soluble Dinuclear Iridium(III) and Ruthenium(II) Bis-terdentate Complexes: Photophysics and Electrochemiluminescence." Dalton Transactions, 2022. http://dx.doi.org/10.1039/d2dt02104h.

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The synthesis, photophysics, and electrochemiluminescence (ECL) of four water-soluble dinuclear Ir(III) and Ru(II) complexes (1−4) terminally-capped by 4′-phenyl-2,2′:6′,2′′-terpyridine (tpy) or 1,3-di(pyrid-2-yl)-4,6-dimethylbenzene (N^C^N) ligands and linked by a 2,7-bis(2,2′:6′,2′′-terpyridyl)fluorene with oligoether...
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15

Reato, Mattia, Beatrice Polido, Anna Bonfiglio, et al. "Bright and Stable Electrochemiluminescence by Heterobimetallic IrIII‐MI (MI = CuI, AuI) Complexes." Advanced Optical Materials, April 2025. https://doi.org/10.1002/adom.202403430.

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AbstractIonic transition metal complexes (iTMCs) often suffer from low photoluminescence quantum yield, especially in the red to near‐infrared spectral region. Rational molecular design strategies unlock recovering the emission features efficiently. A potential solution is offered by bimetallic complexes, which are rapidly emerging as a valid and attractive class of emitters. In this work, the yet unexplored electrochemiluminescence (ECL) properties of a series of heterobimetallic complexes of general structure IrIII‐MI are investigated, where the formally neutral cyclometalated iridium comple
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16

Ramkissoon, Pria, Georgina Armendariz-Vidales, Laena D’Alton, et al. "Iridium(III) Complexes of Bifunctional 2-(2-Pyridyl)imidazole Ligands: Electrochemiluminescent Emitters in Aqueous Media." Inorganic Chemistry, November 19, 2024. http://dx.doi.org/10.1021/acs.inorgchem.4c03121.

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17

Zhao, Yibo, Ziwang Mao, Junli Jia, Chenji Dai, Liangzhi Li, and Yuyang Zhou. "Novel Electrochemiluminescent Biosensor to Ultrasensitively Detect U94 Gene in Human Herpesvirus 6 Using Metal–Organic Framework-Based Nanoemitters Comprising Iridium(III) Complexes via One-Pot Coordination Reaction Strategy." Analytical Chemistry, November 9, 2023. http://dx.doi.org/10.1021/acs.analchem.3c04268.

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