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Dissertations / Theses on the topic 'Electrochemistry'

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1

Brookes, Benjamin A. "Computational electrochemistry." Thesis, University of Oxford, 2002. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.270000.

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2

Fisher, Adrian Charles. "Mechanistic electrochemistry." Thesis, University of Oxford, 1991. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.293419.

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3

Klymenko, O. V. "Computational electrochemistry." Thesis, University of Oxford, 2004. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.409030.

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4

Hunt, Nicholas Imber. "Biological electrochemistry." Thesis, University of Oxford, 1994. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.386592.

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5

Lane, R. L. "Semiconductor electrochemistry." Thesis, University of Oxford, 1985. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.370280.

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6

Melville, James. "Computational electrochemistry." Thesis, University of Oxford, 2002. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.249179.

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7

Thompson, Mary. "Computational electrochemistry." Thesis, University of Oxford, 2006. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.432256.

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8

Chevallier, François Gregory. "Computational electrochemistry." Thesis, University of Oxford, 2006. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.433380.

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9

Alden, John. "Computational electrochemistry." Thesis, University of Oxford, 1998. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.297935.

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10

Du, G. "Computational electrochemistry." Thesis, University of Cambridge, 2010. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.598660.

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This thesis describes the development and application of the lattice Boltzmann method for the investigation of electrolysis mechanisms. Hydrodynamic, mass transport and potential distributions models have been implemented by this method and used to simulate the different electrochemical problems. Chapter 2 introduces a Lattice Bhatnagar-Gross-Krook (LBGK) model, the simplest and most popular lattice Boltzmann method. The theory and implementation of the LBGK for hydrodynamic and mass transport were demonstrated. Chapter 3 describes the development of two and three-dimensional lattice Boltzmann
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11

Henley, Iain. "Computational electrochemistry." Thesis, University of Bath, 2004. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.410800.

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12

Gooch, Kerry A. "Numerical electrochemistry." Thesis, University of Bath, 2003. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.425881.

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13

Zhou, Yan. "Molecular electrochemistry." Thesis, University of Hull, 2012. http://hydra.hull.ac.uk/resources/hull:7072.

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14

Belding, Stephen Richard. "Computational electrochemistry." Thesis, University of Oxford, 2012. http://ora.ox.ac.uk/objects/uuid:e997642f-fbaa-469c-98a3-f359b0996f03.

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Electrochemistry is the science of electron transfer. The subject is of great importance and appeal because detailed information can be obtained using relatively simple experimental techniques. In general, the raw data is sufficiently complicated to preclude direct interpretation, yet is readily rationalised using numerical procedures. Computational analysis is therefore central to electrochemistry and is the main topic of this thesis. Chapters 1 and 2 provide an introductory account to electrochemistry and numerical analysis respectively. Chapter 1 explains the origin of the potential differe
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15

Menshykau, Dzianis. "Computational electrochemistry." Thesis, University of Oxford, 2012. http://ora.ox.ac.uk/objects/uuid:64e553c7-1bd2-429d-a5de-aeb4a29fc067.

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This thesis addresses simulation of electrochemical experiments, with an emphasis on processes of diffusional mass transport to electrode surface. Following system has been studied: • Applying theoretical modeling and experimentation is shown that even significant surface roughness produced by deliberate polishing or scratching is not sufficient to be distinguished in cyclic voltammetry experiments conducted under the usual conditions. In stripping voltammetry experiment the shape of the voltammograms strongly depends on the model of the electron transfer but is not always sensitive to th
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16

Williams, Nia Ann. "Mechanistic electrochemistry." Thesis, University of Bath, 2000. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.341638.

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17

Taylor, Alasdair W. "Electrochemistry In Vacuo." Thesis, University of Nottingham, 2010. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.523505.

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18

Oliver, B. Nigel. "Electrochemistry of metalloproteins." Thesis, University of Oxford, 1985. http://ora.ox.ac.uk/objects/uuid:0fddb16d-0dd1-42ab-a3b5-f1dc73bc922b.

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The direct (unmediated) electrochemistry of a variety of redox proteins has been studied at a range of electrode materials. Electrochemical studies using cytochromes, iron-sulphur proteins and copper proteins show a marked enhancement of the heterogeneous electron-transfer rate at the "edge" plane of pyrolytic graphite. Parallel ESCA studies have shown that mechanical polishing of edge graphite provides an electrode with a high surface coverage of oxidised functional groups. These results indicate the importance of oxidised functional groups in facilitating productive interactions with the pro
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19

Saidi, Mohammed-Yazid. "Electrochemistry of intercalation." Thesis, Heriot-Watt University, 1991. http://hdl.handle.net/10399/845.

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20

Kang, Minkyung. "Single nanoparticle electrochemistry." Thesis, University of Warwick, 2017. http://wrap.warwick.ac.uk/99424/.

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This thesis presents various pipette-based techniques for resolving the electrochemical activities of single nanoentities (e.g., nanoparticles, NPs) in time and/or space. In particular, the work provides a framework for understanding the (electro)chemistry of single NPs and the development of tools to resolve them temporally and/or spatially. Through the use of the state-of-the-art instrumentation developed by the Warwick Electrochemistry & Interfaces Group (WEIG), electrochemical measurements with a “static” probe (i.e., micro-droplet electrochemical cell) have revealed detailed (temporally-r
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21

Su, Wen-Ta. "Electrochemistry in supercritical fluids." Thesis, University of Nottingham, 2010. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.537675.

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22

Fitzgerald, A. M. "Electrochemistry in ionic liquids." Thesis, Queen's University Belfast, 2005. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.419511.

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23

Brooks, C. B. "Electrochemistry in ionic liquids." Thesis, Queen's University Belfast, 2004. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.401797.

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24

Latto, Matthew Neil. "The electrochemistry of diamond." Thesis, University of Bristol, 2001. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.247232.

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25

Dabo, Ismaila. "Towards first-principles electrochemistry." Thesis, Massachusetts Institute of Technology, 2008. http://hdl.handle.net/1721.1/44320.

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Thesis (Ph. D.)--Massachusetts Institute of Technology, Dept. of Materials Science and Engineering, 2008.<br>Includes bibliographical references (p. 143-151).<br>This doctoral dissertation presents a comprehensive computational approach to describe quantum mechanical systems embedded in complex ionic media, primarily focusing on the first-principles representation of catalytic electrodes under electrochemical conditions. The accurate electrostatic description of electrified metal-solution interfaces represents a persistent challenge for ab-initio simulations and an essential requisite for pred
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26

Jiao, Xue. "Electrochemistry of platinum nanoparticles." Thesis, University of Oxford, 2018. http://ora.ox.ac.uk/objects/uuid:5652b2fa-92cd-4ea6-829c-03c6f4b230dd.

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This thesis reports experimental work with two main aims: the first is the investigation of single nanoparticles with an emphasis on their porosity, and the second is to develop a more comprehensive understanding of their electrocatalytic behavior. The fundamental principles and techniques of electrochemistry are introduced in Chapter 1. Chapters 2 and 3 respectively summarize nanomaterials and their characterization methods. In particular, the technique of single particle electrochemical impacts, so-called "nanoimpacts", is used to study redox reactions at individual nanoparticles. Chapters 4
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27

Li, Xiuting. "Electrochemistry of single nanoparticles." Thesis, University of Oxford, 2017. https://ora.ox.ac.uk/objects/uuid:1ea3a662-242d-4734-a4da-25765fad4427.

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This thesis presents experimental work with two main aims: one is the detection and characterization of single electrocatalytic nanoparticles with an emphasis on metal nanoparticle decorated carbon nanotubes, and the other is to develop a more comprehensive understanding of nanoscale electrocatalysis by exploring the differences in the electrocatalytic behaviour of single nanotubes as compared to their ensembles. The first chapter introduces the basic principles and techniques of electrochemistry and the second chapter gives a brief introduction to the nanomaterials and electrochemical methods
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28

Toh, Her Shuang. "Electrochemistry of silver nanoparticles." Thesis, University of Oxford, 2015. https://ora.ox.ac.uk/objects/uuid:7b9c8a2f-6599-446e-a0b3-cb33ca39e476.

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This thesis presents findings realising two main objectives. The first aim is to investigate the electrochemical detection of nanomaterials with an emphasis on silver nanoparticles. The second goal is to employ silver nanoparticles in electroanalysis to aid in the detection of other analytes. First, the detection of silver nanoparticles was demostrated through two different electrochemical methods, stripping voltammetry and 'nano-impacts'. For stripping voltammetry, the potential of metallic nanoparticles oxidation was quantified by various new analytical expressions for peak potential. For th
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29

Xiao, Shaorong. "The electrochemistry of phenothiazine derivatives." Thesis, University of Central Lancashire, 2000. http://clok.uclan.ac.uk/20876/.

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Methylene blue derivatives (MBDs) such as methylene blue (MB -), 1-methyl methylene blue (1MMB) and 1,9-dimethyl-methylene blue (DMMB) have potential use as drugs within photodynamic therapy (PDT). Knowing the redox properties of MBDs will help in understanding the way in which MBDs interact with a range of biological systems. In this work, the electrochemical behaviour of MBDs at various solution pHs have been studied for the first time on gold microdisc electrodes using steady state and non-steady state cyclic voltammetric methods. Steady-state studies The reduction of MBDs is an ECE(CC) pro
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30

Noël, James J. "The electrochemistry of titanium corrosion." Thesis, National Library of Canada = Bibliothèque nationale du Canada, 2000. http://www.collectionscanada.ca/obj/s4/f2/dsk1/tape2/PQDD_0028/NQ51663.pdf.

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31

Basura, Vesna Ivana. "Electrochemistry of proton exchange membranes." Thesis, National Library of Canada = Bibliothèque nationale du Canada, 2000. http://www.collectionscanada.ca/obj/s4/f2/dsk1/tape2/PQDD_0011/NQ61625.pdf.

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32

Wain, Andrew John. "Electron spin resonance in electrochemistry." Thesis, University of Oxford, 2006. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.432259.

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33

Dickinson, Edmund John Farrer. "Charge transport dynamics in electrochemistry." Thesis, University of Oxford, 2011. http://ora.ox.ac.uk/objects/uuid:e4acac56-7265-49ec-9a36-49b3ae6729ed.

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Electrolytic solutions contain mobile ions that can pass current, and are essential components of any solution-phase electrochemical system. The Nernst–Planck–Poisson equations describe the electrodynamics and transport dynamics of electrolytic solutions. This thesis applies modern numerical and mathematical techniques in order to solve these equations, and hence determine the behaviour of electrochemical systems involving charge transport. The following systems are studied: a liquid junction where a concentration gradient causes charge transport; an ideally polarisable electrode where an appl
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34

Whitaker, Richard George. "The electrochemistry of redox enzymes." Thesis, University of Warwick, 1989. http://wrap.warwick.ac.uk/4235/.

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The work presented in this thesis is of two types. Firstly methods for the electrochemical immobilisation of redox enzymes in organic polymers are described. The electrochemical monitoring of the immobilised enzyme reaction by detection of one of the enzyme's products is discussed, and the results obtained for such a system under a variety of experimental conditions are presented. A good understanding of the way in which such a system operates' was obtained by using a specially developed kinetic model., This model is explained fully in the theory chapter of this thesis. A variety of organic po
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35

Stevens, Nicholas P. C. "Finite element simulations in electrochemistry." Thesis, University of Bath, 1998. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.285310.

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36

McCormack, Sean Patrick. "Electrochemistry in the gas phase." Thesis, University College London (University of London), 2004. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.415192.

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37

Silva-Martinez, Susana. "Applications of ultrasound in electrochemistry." Thesis, University of Southampton, 1997. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.242670.

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38

Kloppers, Marius Jacques 1962. "Electrochemistry of iron-chromium alloys." Thesis, Massachusetts Institute of Technology, 1991. http://hdl.handle.net/1721.1/106706.

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Thesis (Ph. D.)--Massachusetts Institute of Technology, Dept. of Materials Science and Engineering, 1991.<br>Vita.<br>Includes bibliographical references (leaves 307-314).<br>by Marius Jacques Kloppers.<br>Ph.D.
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39

Dydek, EthelMae Victoria. "Electrochemistry and Electrokinetics in Microchannels." Thesis, Massachusetts Institute of Technology, 2012. http://hdl.handle.net/1721.1/70401.

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Thesis (Ph. D.)--Massachusetts Institute of Technology, Dept. of Chemical Engineering, 2012.<br>Cataloged from PDF version of thesis.<br>Includes bibliographical references (p. 119-123).<br>The main body of this work considers the design and development of a microfluidic, continuous electrochemical sensor capable of measuring accurate potential differences. The key challenge in creating such a device is the implementation of a miniaturized reference electrode and salt bridge. The purpose of a salt bridge is to allow ionic conduction between the reference and working electrodes while maintainin
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40

Dann, Thomas. "Pioneering investigations into organometallic electrochemistry." Thesis, University of East Anglia, 2014. https://ueaeprints.uea.ac.uk/49707/.

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Recently there has been a large effort to take advantage of electrochemistry to develop and understand novel chemical processes and reactivity. This thesis contains investigations into the synthesis and electrochemical properties of three diverse organometallic systems. In chapter 2, the first experimental determination of a an unsupported AuII-AuII bond is reported. The electrochemical characterisation of gold(III) hydride, hydroxide and chloride pincer complexes based on a backbone of a doubly cyclometalated 2,6-bis(4’-tert-butylphenyl) pyridine ligand was performed, in which it was determin
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41

Sheng, Tian. "Heterogeneous catalytic reactions in electrochemistry." Thesis, Queen's University Belfast, 2014. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.675473.

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42

Cutress, Ian James. "Algorithm development in computational electrochemistry." Thesis, University of Oxford, 2011. http://ora.ox.ac.uk/objects/uuid:a1cfb510-3656-4396-84b3-8e67b88d3d2f.

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This thesis presents algorithm development in computational chemistry, and applies new computer science concepts to voltammetric simulation. To begin, this thesis discusses why algorithm development is necessary, and inherent problems found in commercial simulation solvers. As a result of this discussion, this thesis describes the need for simulators to keep abreast of recent computational developments. Algorithm development in this thesis is taken through stages. Chapter 3 applies known theory relating to the stripping voltammetry at a macroelectrode to the diffusional model of a microdisk, u
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43

Zhou, Xiaofei. "The electrochemistry of organic nanoparticles." Thesis, University of Oxford, 2016. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.728824.

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44

Lin, Shioujenq Andrew. "The electrochemistry of carbon monoxide." Case Western Reserve University School of Graduate Studies / OhioLINK, 2003. http://rave.ohiolink.edu/etdc/view?acc_num=case1055944045.

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45

Howarth, Paul. "The electrochemistry of electrochemical machining." Thesis, University of Edinburgh, 2003. http://hdl.handle.net/1842/10966.

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Electrochemical machining is a process that has the potential to machine complex shapes at high production rates. However, the expansion of ECM in industry has been impeded by the iterative trial and error approach that is often required to generate process parameters for any one machining set-up. This arises due to the incompleteness of models used to describe the complex physical, chemical and hydrodynamic parameter interdependencies. Such interdependence results in non-ideal effects that distort the transfer geometry between the tool shape and the required workpiece shape. The aim of this t
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46

Udit, Andrew K. Barton Jacqueline K. "P450 BM3 electrochemistry and electrocatalysis /." Diss., Pasadena, Calif. : California Institute of Technology, 2005. http://resolver.caltech.edu/CaltechETD:etd-05112005-100825.

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47

Sebantu, Lambert. "Electrochemistry of polyaniline-DNA system." [Johnson City, Tenn. : East Tennessee State University], 2004. https://dc.etsu.edu/etd/895.

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Thesis (M.S.)--East Tennessee State University, 2004.<br>Title from electronic submission form. ETSU ETD database URN: etd-0331104-130134. Includes bibliographical references. Also available via Internet at the UMI web site.
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48

Arnaboldi, S. "CHIRAL ELECTROCHEMISTRY IN IONIC LIQUIDS." Doctoral thesis, Università degli Studi di Milano, 2014. http://hdl.handle.net/2434/244316.

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This thesis has been initially conceived as a study of molecular electrochemistry and electrocatalysis in ionic liquids, emerging media for safe and environmentally friendly chemical and electrochemical processes, particularly focusing on the combined effects of the ionic liquid molecular structure and the nature of the electrode surface, and considering two model processes: • the electroreductive cleavage of the carbon-halogen bond in organic halides, of high interest in the synthetic, analytical and environmental fields; • the electrooxidative coupling of thiophene-based monomers, resultin
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49

Lázaro-Báez, María Isabel. "Electrochemistry of the leaching of chalcopyrite." Murdoch University, 2001. http://wwwlib.murdoch.edu.au/adt/browse/view/adt-MU20060817.125248.

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The potential region in which chalcopyrite dissolves during the oxidative leaching of the mineral in ferric sulphate solutions has been established. These results have been modelled using an extended mixed-potential description of the system. The initial stages of the dissolution process have been studied using a chalcopyrite disk and a platinum ring electrode held at appropriate potentials for the detection of ferrous and cupric ions. These experiments have shown that the initial stages of oxidation of the mineral involve the formation of soluble sulphur species in addition to elemental sulph
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50

Odenthal, Katherine Jane Chemistry Faculty of Science UNSW. "Novel redox molecules for surface electrochemistry." Publisher:University of New South Wales. Chemistry, 2009. http://handle.unsw.edu.au/1959.4/43661.

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The research presented herein reports the development of two novel redox molecules for biosensing applications. Frequently electrochemical biosensors necessitate the use of strictly controlled conditions including the pH of the surrounding solution. Electrochemical biosensors that only operate under such conditions are not viable as portable sensors for in-field analysis. Consequently, a method for measuring the pH in conjunction with electrochemical biosensors would provide an opening for such sensors in in-field analysis. A novel redox molecule, JUGSH, has been prepared for this purpose.
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