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Dissertations / Theses on the topic 'Electrolytes for electrochemical machining'

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Published: 4 June 2025

Last updated: 1 August 2025

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1

Mahat, Abu Bakar. "An experimental study of parameters affecting ECM gap profile." Thesis, University of Manchester, 1987. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.302003.

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2

Jui, Sumit Kumar Narendrakumar. "Study of Micro-Electrochemical Discharge Machining (ECDM) Using Low Electrolyte Concentration." University of Cincinnati / OhioLINK, 2013. http://rave.ohiolink.edu/etdc/view?acc_num=ucin1384870046.

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3

Msakni, Malouche Mariem. "Usinage par Pulse ElectroChemical Machining (PECM) de superalliages base nickel employés pour des pièces aéronautiques fortement sollicitées thermomécaniquement : compréhension des phénomènes physicochimiques et optimisation du procédé." Electronic Thesis or Diss., Université de Lorraine, 2019. http://www.theses.fr/2019LORR0267.

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L’usinage électrochimique impulsionnel (Pulse Electro Chemical Machining PECM) est un procédé d’usinage non conventionnel (sans outils coupants) de pièces métalliques à géométrie complexe et nécessitant des précisions élevées. Cette technique repose sur l’oxydation anodique du métal et se distingue par l’imposition d’un fort courant impulsionnel. Le courant est synchronisé à un mouvement de translation rectiligne et oscillant de la cathode. L’électrolyte est continuellement renouvelé permettant l’évacuation des résidus du métal usiné. Le PECM permet de travailler avec des distances inter-élect

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4

Clarke, M. D. "Electrochemical studies on polymeric electrolytes." Thesis, University of Newcastle Upon Tyne, 1986. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.373076.

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5

Ismail, Iqbal M. I. "Electrochemical studies of polymer electrolytes." Thesis, University of Southampton, 1996. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.242319.

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6

Srinivas, Sundarram Sriharsha. "Development of Electrochemical Micro Machining." Texas A&M University, 2008. http://hdl.handle.net/1969.1/86045.

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The machining of materials on micrometer and sub-micrometer scale is considered the technology of the future. The current techniques for micro manufacturing mostly are silicon based. These manufacturing techniques are not suitable for use in demanding applications like aerospace and biomedical industries. Micro electrochemical machining (μECM) removes material while holding micron tolerances and μECM can machine hard metals and alloys. This study aims at developing a novel μECM utilizing high frequency voltage pulses and closed loop control. Stainless steel SS-316L and copper alloy CA-173 were

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7

Mitchell-Smith, Jonathon. "Advancing electrochemical jet machining techniques." Thesis, University of Nottingham, 2018. http://eprints.nottingham.ac.uk/54833/.

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Electrochemical Jet Processing (EJP) techniques have been traditionally limited in application by the inherent geometric inflexibility and limited process precision in comparison to alternative processes. It has been stated that process resultant geometries are defined by the Gaussian in-jet energy distribution and the hydrodynamic stagnation region formed under a jet on an impinging surface. This thesis reports upon investigations and innovations designed to challenge these assumptions. EJP is an emergent manufacturing process with a unique capability of subtraction and deposition of metals w

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8

Clifton, David. "Process characterisation for electrochemical machining." Thesis, University of Edinburgh, 2001. http://hdl.handle.net/1842/13433.

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Electrochemical machining is a process that has the potential to machine complex full-form shapes at high production rates. The economic utilisation of this process, however, has been impeded by the iterative trial and error approach that is often required to generate process specifications for any one machining set-up. This approach arises due to the incompleteness of models used to describe the complex physical, chemical and hydrodynamic parameter interdependencies. Such interdependence results in non-ideal effects that distort the transfer geometry between the tool shape and the required wo

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9

Muir, Rachel N. "The parameterisation of electrochemical machining." Thesis, University of Edinburgh, 2006. http://hdl.handle.net/1842/15455.

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Electrochemical Machining (ECM) is a non-conventional, non-contact technique, popular in the aerospace and automotive industries, used to machine ultra hard metal alloys. This work details a novel system, using ultrasound to dynamically measure the interelectrode gap. For greater accuracy, thermocouples have also been incorporated into the system to allow for the often significant temperature variation due to resistive heating. This gives time-resolved data for the discussion valency and overpotential during ECM. The time averaged dissolution valencies found using this technique are the same,

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10

Howarth, Paul. "The electrochemistry of electrochemical machining." Thesis, University of Edinburgh, 2003. http://hdl.handle.net/1842/10966.

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Electrochemical machining is a process that has the potential to machine complex shapes at high production rates. However, the expansion of ECM in industry has been impeded by the iterative trial and error approach that is often required to generate process parameters for any one machining set-up. This arises due to the incompleteness of models used to describe the complex physical, chemical and hydrodynamic parameter interdependencies. Such interdependence results in non-ideal effects that distort the transfer geometry between the tool shape and the required workpiece shape. The aim of this t

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11

De, Sliva A. K. "Process developments in electrochemical arc machining." Thesis, University of Edinburgh, 1988. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.383017.

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12

Darling, Gordon. "Mathematical modelling of electrochemical machining processes." Thesis, University of Edinburgh, 2001. http://hdl.handle.net/1842/13565.

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13

Pajak, Przemyslaw T. "Investigation of laser assisted electrochemical machining." Thesis, Glasgow Caledonian University, 2006. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.426411.

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14

Leese, Rebecca Jane. "Electrochemical machining : new machining targets and adaptations with suitability for micromanufacturing." Thesis, Brunel University, 2016. http://bura.brunel.ac.uk/handle/2438/12978.

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Electrochemical machining (ECM) is a non-conventional machining technique capable of machining any conductive substrate, regardless of its physical properties e.g. hardness. ECM became an attractive method due to its ability to machine substrates without creating a defective surface layer. ECM utilises electrolysis; a small gap is maintained between two electrodes whilst a favourable potential is applied between them to remove material from the workpiece. The parameters are adjusted to obtain the desired machining results i.e. surface finish, machining resolution and machining rate. Much work

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15

Cservenyak, Iidiko. "Electrochemical reduction of pyrite in acidic aqueous electrolytes." Thesis, Imperial College London, 1994. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.326666.

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16

Sivapalan, Nagalingam. "Electrical and electrochemical studies of some solid electrolytes." Thesis, University of Cambridge, 1987. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.236018.

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In Chapter 1 solid electrolytes are reviewed. The historical development, mechanism of ionic conduction in solids and the properties and applications of important solid electrolytes are given. Chapter 2 discusses impedance methods as applied to electrochemistry and the equivalent circuit representation of the solid electrolyte/electrode interface. The application of a computer program that gives theoretical impedance and/or admittance plots is also described. The application of four-electrode conductivity measurements to solid electrolytes is described in Chapter 3. Since this is the first tim

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17

Inoguchi, Shota. "Studies on Electrochemical Reactions Using Concentrated Aqueous Electrolytes." Doctoral thesis, Kyoto University, 2021. http://hdl.handle.net/2433/263660.

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18

Gamage, Janaka Ranganath. "Assessment of environmental performance of electrochemical machining and electrodischarge machining unit proceses." Thesis, Glasgow Caledonian University, 2017. https://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.726787.

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19

El-Hofy, H. A. G. "Fundamental studies of electrochemical arc wire machining." Thesis, University of Aberdeen, 1985. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.377368.

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20

Pattavanitch, Jitti. "Numerical and experimental investigations into electrochemical machining." Thesis, University of Manchester, 2011. https://www.research.manchester.ac.uk/portal/en/theses/numerical-and-experimental-investigations-into-electrochemical-machining(dc33039b-cbad-4a65-8660-3a0abc72f465).html.

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This thesis presents numerical and experimental investigations into Electrochemical Machining (ECM). The aim is to develop a computer program to predict the shape of a workpiece machined by the ECM process. The program is able to simulate various applications of EC machining which are drilling, milling, turning and shaped tube electrochemical drilling (STED). The program has been developed in a MATLAB environment. In this present work, EC-drilling, EC-milling and EC-turning are analysed as three-dimensional problems whereas STED is simulated in two-dimensions. Experiments have been carried out

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21

Pell, Wendy. "Zinc/bromine battery electrolytes: Electrochemical, physicochemical and spectroscopic studies." Thesis, University of Ottawa (Canada), 1995. http://hdl.handle.net/10393/9521.

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The zinc/bromine battery is a flowing electrolyte battery operating at ambient temperatures, and having both stationary and mobile applications. It is characterized by a flat voltage discharge profile, can be deeply discharged without adverse effects, and is made from low cost materials which can be recycled at the end of the battery's life. The electrochemically active materials are stored externally to the electrode assembly in two reservoirs, and are pumped to the electrodes during operation. The electrolyte typically includes aqueous zinc bromide and quaternary ammonium salts, such as meth

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22

Sheldon, M. H. "Structural, electrochemical and thermal studies of divalent polymer electrolytes." Thesis, De Montfort University, 1989. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.233834.

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23

Liang, Zhuowang. "Electrochemical behaviour of cuprous sulphide (Cu2S) in alkaline electrolytes." Thesis, Imperial College London, 1989. http://hdl.handle.net/10044/1/47539.

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24

Temur, Roberto. "Tool-electrodes design and construction for electrochemical machining." Thesis, Bucks New University, 2002. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.251330.

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25

Chmielowiec, Brian John. "Electrochemical engineering considerations for gas evolution in molten sulfide electrolytes." Thesis, Massachusetts Institute of Technology, 2019. https://hdl.handle.net/1721.1/122158.

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Thesis: Sc. D., Massachusetts Institute of Technology, Department of Materials Science and Engineering, 2019<br>Cataloged from PDF version of thesis.<br>Includes bibliographical references.<br>The current interrupt and galvanostatic electrochemical impedance spectroscopy techniques were utilized to characterize the ohmic, charge transfer, and mass transfer over-potential behavior of gas evolving electrodes in aqueous, molten chloride, and molten sulfide electrolyte solutions under steady-state natural convective flow conditions as a means to gain access to thermodynamic, physicochemical, and h

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26

Propst, Eric Keith. "The electrochemical oxidation and dissolution of silcon in an acetonitrile-HF electrolyte." Diss., Georgia Institute of Technology, 1993. http://hdl.handle.net/1853/11123.

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27

Gomez, Gallegos Ares Argelia. "Electrochemical machining : towards 3D simulation and application on SS316." Thesis, University of Edinburgh, 2016. http://hdl.handle.net/1842/16190.

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Electrochemical machining (ECM) is a non-conventional manufacturing process, which uses electrochemical dissolution to shape any conductive metal regardless of its mechanical properties and without leaving behind residual stresses or tool wear. Therefore, ECM can be an alternative for machining difficult-to-cut materials, complex geometries, and materials with improved characteristics, such as strength, heat-resistance or corrosion-resistance. Notwithstanding its great potential as a shaping tool, the ECM process is still not fully characterised and its research is an on-going process. Various

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28

Tsukamoto, Hisashi. "Synthesis and electrochemical studies of lithium transition metal oxides for lithium-ion batteries." Thesis, University of Aberdeen, 1999. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.327428.

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29

Kashyap, Aditya Jagannath. "Conducting Polymer Based Gel Electrolytes for pH Sensitivity." Scholar Commons, 2019. https://scholarcommons.usf.edu/etd/7824.

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The evaluation of concentration of ions and molecules with the help of biosensors have been regarded as an emerging technology. Bio and chemical sensors have a variety of applications in the field of medicine, military, environmental and food industries alike. With an estimated investment growth of over 4.31% in the development of pH sensors in the next five year, the objective of a developing a robust measurement system is all the more required. The scope of this research is to evaluate the ability of conducting polymer-based gel electrolytes for pH sensitivity, as a function of the transisto

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30

Copcutt, Robert Charles. "Investigations of gaseous electrochemical reactions on zirconia electrolytes using amperometric sensors." Thesis, Middlesex University, 1993. http://eprints.mdx.ac.uk/6685/.

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Sensors incorporating zirconia electrolytes have been widely used for monitoring oxygen concentration and the air-to-fuel ratio of combustion systems. The aim of this work was to investigate the extension of this technology to other gases and to gas mixtures. Initial work was done on single zirconia. discs with porous metal electrodes on each face. Platinum, silver and gold electrodes were tested in controlled Atmospheres at temperatures between 300*C and 850*C. It was shown, as expected, that in 02/N2 mixtures electrode activity/conductance decreased as oxygen concentration and temperature we

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31

Bachman, John Christopher. "Organic electrodes and solid-state electrolytes for lithium electrochemical energy storage." Thesis, Massachusetts Institute of Technology, 2017. http://hdl.handle.net/1721.1/111719.

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Thesis: Ph. D., Massachusetts Institute of Technology, Department of Mechanical Engineering, 2017.<br>Cataloged from PDF version of thesis.<br>Includes bibliographical references.<br>Viable electrical energy storage is essential for the development of sustainable energy technologies, such as renewable power and electric vehicles. Electrochemical energy storage devices are promising candidates for these applications, and lithium-ion batteries are the leading available technology. However, the current cost and performance of these devices limit their widespread adoption. In this thesis, we devel

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32

Meera, P. "Nafion based hybrid polymer electrolytes and nanocomposites: design and electrochemical investigations." Thesis(Ph.D.), CSIR-National Chemical Laboratory, Pune, 2009. http://dspace.ncl.res.in:8080/xmlui/handle/20.500.12252/2726.

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33

Flint, Sara Dianne. "Experimental investigations of doped barium cerate and zirconate ceramic electrolytes." Thesis, University of Exeter, 1995. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.262596.

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34

Lu, Jinming [Verfasser]. "Cathode shape design for steady-state electrochemical machining / Jinming Lu." München : Verlag Dr. Hut, 2015. http://d-nb.info/1070124494/34.

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35

Yahyavi, Zanjani Matin, Mattias Hackert‐Oschätzchen, André Martin, and Andreas Schubert. "Experimental Study on Jet Electrochemical Machining of Intersecting Single Grooves." Universitätsbibliothek Chemnitz, 2018. http://nbn-resolving.de/urn:nbn:de:bsz:ch1-qucosa-231636.

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Due to unique advantages of Jet Electrochemical Machining (Jet‐ECM) such as the absence of mechanical and thermal effects, there is an increasing demand for the implementation of the technology in industrial sectors. However, meeting the stringent quality requirements of the current technological level is a challenge in Jet‐ECM especially for complicated microstructures. Hence, the implementation of an adequate metrology system is necessary to minimise deviations and to enhance the process towards zero‐defect‐manufacturing. The metrology system should be capable of measuring the workpiece befo

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36

Altena, Harmen S. J. "Precision ECM by process characteristic modelling." Thesis, Glasgow Caledonian University, 2000. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.322280.

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37

Mathew, Ronnie A. M. S. "Study of the Pulsed Electrochemical Micromachining of Ultra High Aspect Ratio Micro Tools." University of Cincinnati / OhioLINK, 2011. http://rave.ohiolink.edu/etdc/view?acc_num=ucin1299012683.

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38

Wagner, Thomas. "High rate electrochemical dissolution of ironbased alloys in NaCl and NaNO3 electrolytes /." [S.l. : s.n.], 2002. http://www.bsz-bw.de/cgi-bin/xvms.cgi?SWB10317253.

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39

Maeshima, Hiroyuki. "Theoretical Study of Electrochemical Stability and Ionic Conductivity of Organic Liquid Electrolytes." 京都大学 (Kyoto University), 2014. http://hdl.handle.net/2433/188591.

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40

YANG, HUAN. "Functional Electrolytes for Advanced Electrochemical Performance in Sodium and Potassium Secondary Batteries." Kyoto University, 2020. http://hdl.handle.net/2433/259756.

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41

Dubouis, Nicolas. "Understanding the role of electrolytes solvation structure for electrochemical energy storage applications." Electronic Thesis or Diss., Sorbonne université, 2021. http://www.theses.fr/2021SORUS089.

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Cette thèse s’intéresse au rôle de l’électrolyte et la structure de solvatation des espèces qui le composent pour des dispositifs de stockage électrochimique de l’énergie. Plus particulièrement, le début de ce manuscrit décrit les récentes avancées dans la compréhension du rôle de la molécule l’eau pour la génération d’hydrogène dans des électrolyseurs. Nous proposons ensuite une stratégie basée sur le confinement de l’eau au sein d’une matrice organique inerte afin de mieux comprendre comment les interactions non-covalentes modifient la cinétique de la réaction de réduction de l’eau. Des simu

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42

Yahyavi, Zanjani Matin, Matthias Hackert-Oschätzchen, André Martin, and Andreas Schubert. "Evaluation of On-Machine Gap Measurement Strategies in Jet-Electrochemical Machining." Universitätsbibliothek Chemnitz, 2018. http://nbn-resolving.de/urn:nbn:de:bsz:ch1-qucosa-231608.

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Jet Electrochemical Machining (Jet-ECM) is a manufacturing technique that applies a free electrolyte jet to generate the desired shapes [1]. Since the principle of the technique is the same as other techniques of Electrochemical Machining where the material removal takes place based on the anodic dissolution of workpiece, the working distance, which is the distance between nozzle’s front surface and the workpiece surface, is one important parameter of the process. The working distance affects the current density and consequently the geometry removal. The control of the working distance can be

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43

Petzold, Tom, Matthias Hackert-Oschätzchen, André Martin, and Andreas Schubert. "Deburring and Edge Shaping by Electrochemical Machining with Differentially Switched Currents." Universität des Saarlandes, 2019. https://monarch.qucosa.de/id/qucosa%3A72519.

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Manufacturing of components with complex internal features, e.g. for medical applications, aeronautics or automobile industry, is challenging. Those components are often machined in temporarily and locally separated production stages. As results of these separated stages form deviations and positioning errors increase, which lead to additional efforts for the quality assurance. The technology aimed within the project SwitchECM is expected to allow the machining of different complex features of one workpiece in one single production stage and shall simultaneously allow a high precision. For th

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44

Lilly, Blaine W. "An investigation of pulsed electrochemical machining of H-13 tool steel /." The Ohio State University, 1998. http://rave.ohiolink.edu/etdc/view?acc_num=osu1487949150072426.

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45

Chang, Hao-wei, and 張皓瑋. "The Analysis and Research of Machining P-type Silicon in different Electrolytes by Electrochemical Machining." Thesis, 2013. http://ndltd.ncl.edu.tw/handle/06291101986569266022.

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碩士<br>國立中央大學<br>機械工程學系<br>101<br>In numerous non-traditional machinings, the electrochemical machining (ECM) has the advantage of quick processing speed, good convergence in surface stress, and nice smoothness on the workpiece surface with enormous potentialities and highly added value. 　　Single-crystal p-Si is machined by ECM. Tungsten carbide cylinders with diameter of 50 and 100 micro-meter are selected as the electrode tools. In this research, four kinds of solution, namely ammonium fluoride, hydrofluoric acid, ammonium fluoride added with hydrogen chloride and ammonium fluoride added with

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46

Chao, Guan-Wei, and 趙冠瑋. "The Investigation of Electrochemical Machining Characteristics for Common Metallic Materials in NaNO3 and NaCl Electrolytes." Thesis, 2016. http://ndltd.ncl.edu.tw/handle/zxzk2b.

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碩士<br>國立中央大學<br>機械工程學系<br>104<br>Electrochemical machining (ECM) is one of the non-traditional manufacturing process which works on the low voltage and high current to dissolve materials rapidly in ion states. It has advantages such as inexpensive machining equipment, little or no tool wear, no residual stress on the work piece surface, and competence for machining complex geometries. In previous studies, it had not enough information about electrochemical characteristics of materials, so the aim of thesis is to establish the electrochemical characteristics for common metallic materials. It ca

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47

Song, Shang-Lin, and 宋尚霖. "The effect of electrolyte mixed SiC on Wire Electrochemical Discharge Machining." Thesis, 2002. http://ndltd.ncl.edu.tw/handle/78863863797120403600.

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48

He, Jia-Jhe, and 何嘉哲. "The effect of electrolyte powder-mixed on Wire Electrochemical Discharge Machining." Thesis, 2013. http://ndltd.ncl.edu.tw/handle/82344320796346244619.

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碩士<br>國立中央大學<br>機械工程學系<br>101<br>In this experiment, the process is added with a new effect of the electrolytic solution by letting the electrolytic solution to coat on a quartz glass in the shape of a droplet while dripping down, in order to avoid the bubbles released during the electrolysis accumulating at the inlet and outlet of the processing area and affecting the gas film stability and developing slit expansion phenomenon, therefore, to increase the process efficiency. Although the process has pretty good features, however, the surface of the slit is less refined after the process. There

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49

Kuo, Kuan-yuan, and 郭寬淵. "Study of Wire Electrochemical Discharge Machining (WECDM) of Quartz Glass with Titrated Electrolyte Flow." Thesis, 2015. http://ndltd.ncl.edu.tw/handle/91357165184471106269.

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博士<br>國立中央大學<br>機械工程學系<br>103<br>Quartz has excellent properties, but its brittleness property results in the difficulty of balance between efficiency and precision for traditional machining method. ECDM aids in machining with high temperature fusion and etching, and is very appropriate for quartz material. In WECDM machining system, uneasy control of insulation gas film structure and difficult electrolyte circulation in machining zone. Therefore, thesis topic is to explore WECDM machining mechanisms, development new methods and improve the micro slit surface quality. First, investigate the fl

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50

Maurer, Joseph J. "Ultrashort pulse electrochemical machining /." 2008. http://wwwlib.umi.com/dissertations/fullcit/3329761.

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