Academic literature on the topic 'Electrophilic Additions'

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Journal articles on the topic "Electrophilic Additions"

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Bertolini, Thomas M., and Phuc D. Tran. "Electrophilic Additions to Alkenes." Journal of Chemical Education 83, no. 4 (2006): 590. http://dx.doi.org/10.1021/ed083p590.

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Herges, Rainer, and Helfried Neumann. "Electrophilic additions to tetradehydrodianthracene." Liebigs Annalen 1995, no. 7 (1995): 1283–89. http://dx.doi.org/10.1002/jlac.1995199507170.

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Klop, W., P. A. A. Klusener, and L. Brandsma. "Electrophilic additions to (dimethylamino)allene." Recueil des Travaux Chimiques des Pays-Bas 103, no. 1 (2010): 27–29. http://dx.doi.org/10.1002/recl.19841030105.

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Pasquato, Lucia, Riccardo Destro, Vittorio Lucchini, and Giorgio Modena. "Sulfur Electrophiles as Mechanistic Probe. New Insight in the Electrophilic Additions." Phosphorus, Sulfur, and Silicon and the Related Elements 153, no. 1 (1999): 235–45. http://dx.doi.org/10.1080/10426509908546437.

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Lavilla, Rodolfo, Oscar Coll, Rakesh Kumar, and Joan Bosch. "Electrophilic Oxidative Additions upon 1,4-Dihydropyridines." Journal of Organic Chemistry 63, no. 8 (1998): 2728–30. http://dx.doi.org/10.1021/jo971947v.

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HERGES, R., and H. NEUMANN. "ChemInform Abstract: Electrophilic Additions to Tetradehydrodianthracene." ChemInform 26, no. 42 (2010): no. http://dx.doi.org/10.1002/chin.199542118.

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Deng, Danfeng, Dayun Huang, Xiangyu Sun, and Biwen Gao. "Recent Advances in the Tandem Difunctionalization of Alkynes: Mechanism-Based Classification." Synthesis 53, no. 19 (2021): 3522–34. http://dx.doi.org/10.1055/a-1486-2158.

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AbstractRecent advances on the tandem difunctionalization of alkynes in the last decade (2010–2020) are summarized into five categories based on the type of mechanism: (1) radical addition and coupling for the synthesis of polysubstituted ketones and alkenes, (2) electrophilic addition of alkynes, (3) reactions mediated by haloalkynes or copper acetylides, (4) the preparation of cyclic compounds via radical processes, palladium-catalyzed reactions or conjugate additions, and (5) cyclic compounds as intermediates in ring openings. Herein, radical, electrophilic and nucleophilic reactions are di
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Mayr, Herbert, and Karl-Heinz Müller. "Determination of the Nucleophilicity of Tricarbonyliron Coordinated Cyclohepta-1,3,5-triene." Collection of Czechoslovak Chemical Communications 64, no. 11 (1999): 1770–79. http://dx.doi.org/10.1135/cccc19991770.

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The kinetics of the electrophilic additions of four diarylcarbenium ions (4a-4d) to tricarbonyl(η4-cyclohepta-1,3,5-triene)iron (1) have been studied photometrically. The second-order rate constants match the linear Gibbs energy relationship log k20 °C = s(E + N) and yield the nucleophilicity parameter N(1) = 3.69. It is concluded that electrophiles with E ≥ -9 will react with complex 1 at ambient temperature.
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Meneses, L., A. Araya, F. Pilaquinga, R. Contreras, and P. Fuentealba. "Local hardness: An application to electrophilic additions." Chemical Physics Letters 446, no. 1-3 (2007): 170–75. http://dx.doi.org/10.1016/j.cplett.2007.07.092.

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KOCOVSKY, P. "ChemInform Abstract: Electrophilic Additions to Double Bonds." ChemInform 29, no. 13 (2010): no. http://dx.doi.org/10.1002/chin.199813283.

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Dissertations / Theses on the topic "Electrophilic Additions"

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Bruzco, de Milano D. L. "Electrophilic additions to steroidal alkenes." Thesis, University of Southampton, 1985. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.303720.

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Creeke, Paul Ivan. "Electrophilic additions to functionalised alkenes : the chemistry and synthesis of heterocyclic compounds." Thesis, University of Southampton, 1990. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.255650.

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Ma, Jihai. "Mono(trimethylsilyl) bisketenes, cycloaddition and electrophilic addition reactions." Thesis, National Library of Canada = Bibliothèque nationale du Canada, 1997. http://www.collectionscanada.ca/obj/s4/f2/dsk2/tape16/PQDD_0016/NQ28003.pdf.

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Zhang, Yafen. "Fundamental Studies of Reactions between NO3 Radicals and Organic Surfaces." Thesis, Virginia Tech, 2012. http://hdl.handle.net/10919/42372.

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Ultrahigh vacuum (UHV) surface science experiments were designed to study reaction kinetics and mechanisms of gas-phase NO3 radicals with well-organized, highly characterized, organic thin films. The surface reactions were monitored in situ with reflection-absorption infrared spectroscopy (RAIRS). The oxidation states of surface-bound molecules were identified with X-ray photoelectron spectroscopy (XPS). Consumption of vinyl groups was observed concurrently with formation of organic nitrates in RAIRS. XPS spectra showed little oxidation of sulfur head groups. The observed rate constant was det
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Tani, Yosuke. "Catalytic Addition of Functionalities across Carbon-Carbon Multiple Bonds with Carbon Dioxide and Related Electrophiles." 京都大学 (Kyoto University), 2015. http://hdl.handle.net/2433/199321.

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Bierwisch, Michael. "Synthese und Charakterisierung neuer potentieller M 3 -selektiver Anticholinergika mit Diphenylessigsäurestruktur zur Therapie der Harninkontinenz." Doctoral thesis, Humboldt-Universität zu Berlin, Mathematisch-Naturwissenschaftliche Fakultät I, 2003. http://dx.doi.org/10.18452/14835.

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Zusammenfassung: Im Hinblick auf eine medikamentöse Behandlung der Harninkontinenz ist die Entwicklung neuartiger, selektiv und damit nebenwirkungsreduzierter, am Muscarin-M3-Rezeptor wirkender Therapeutika ein wichtiges Ziel der Pharmaforschung. An verschiedenen stickstoffhaltigen und stickstofffreien Esterderivaten der 2,2-Diphenylessigsäure (Alkyl-, Cycloalkyl, Aminoalkyl- und Piperidinylester) wurden über die Generierung von Enolatstrukturen mit Hilfe metallorganischer Verbindungen systematisch elektrophile Additionsreaktionen mit einer breiten Palette von Alkyl- und Acylhalogeniden, A
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Le, Cornec-Macé Aurélie. "Synthèse et étude de la réactivité de nouveaux allylboronates alpha-hétérosubstitués." Thesis, Rennes 1, 2014. http://www.theses.fr/2014REN1S176/document.

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Au cours de ces trente dernières années, les allylboranes, une classe particulière de composés organoborés, ont pris une place particulièrement importante en synthèse organique, principalement dans la synthèse stéréocontrôlée d'alcools homoallyliques par addition sur un aldéhyde. C'est dans ce contexte que s'inscrit mon travail de thèse qui a pour objectif la mise au point de voies d'accès originales à deux familles d'allylboronates alpha-hétérosubstitués et à l'étude de leur réactivité. Pour cela, nous nous sommes intéressés dans un premier temps au comportement de gamma-borylallylsilanes vis
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Michel, Boris. "Rhodium catalysed asymmetric conjugate addition to alkenylheteroarenes/continuous flow synthesis of 2-trimethylsilyl arylperfluorosulfonates/copper catalysed electrophilic trifluoromethylation of activated and unactivated alkyl halides." Thesis, University of Manchester, 2016. https://www.research.manchester.ac.uk/portal/en/theses/rhodium-catalysed-asymmetric-conjugate-addition-to-alkenylheteroarenes--continuous-flow-synthesis-of-2trimethylsilyl-arylperfluorosulfonates--copper-catalysed-electrophilic-trifluoromethylation-of-activated-and-unactivated-alkyl-halides(d74fba64-aa9a-45fe-9c8e-563df0ed0253).html.

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The first chapter of this thesis describes an investigation as a continuation of work published in 2010 on the asymmetric catalytic conjugate addition of aryl boronic acids onto alkenylazaarenes. The work described herein shows an attempt at facilitating asymmetric catalytic addition of alkenyl boronic acids to the same class of substrates. A number of novel chiral diene ligands were synthesised and investigated as well as a broad substrate scope subjected to the optimised reaction conditions. The second chapter contains the development of a flow chemistry process that enables the synthesis of
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Barth, Francis. "Synthese de squelettes mono et sesquiterpeniques au depart de cyclopropenes et cyclobutenes electrophiles." Université Louis Pasteur (Strasbourg) (1971-2008), 1988. http://www.theses.fr/1988STR13167.

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Preparation des structures du titre grace a des reactions de cycloaddition. Une nouvelle synthese non photochimique de systemes bicyclo (2. 2. 0) hexaniques a partir de cyclobutenes et d'enamines est ainsi effectuee. La reaction de diels alder de cyclopropenes electrophiles avec des dienes heterosubstitues permet l'obtention de systemes careniques. Enfin, une synthese de la dihydro-2,3 illudine m est realisee
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MICHAUD, DAVID. "Synthese organique sans solvant activee par les micro-ondes focalisees : addition de michael du nitromethane sur des alcenes et alcynes electrophiles." Rennes 1, 1998. http://www.theses.fr/1998REN10044.

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Ce travail s'insere dans le cadre des recherches entreprises au laboratoire sur les reactions sans solvant activees par les micro-ondes. Apres un chapitre introductif sur le phenomene micro-onde et son application en synthese organique, nous decrivons la preparation de cyclohexenes fonctionnalises obtenus a partir du nitromethane et des alcenes electrophiles diactives par des groupements ester et nitrile. Le mecanisme implique est de type mimirc : la double addition est diastereoselective (seulement deux isomeres sont formes ; ils ne different que par la configuration du carbone c#3 apres anal
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Books on the topic "Electrophilic Additions"

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Ma, Jihai. Mono(trimethylsilyl) bisketenes: Cycloaddition and electrophilic addition reactions. National Library of Canada = Bibliothèque nationale du Canada, 1997.

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P. B. D. De La Mare and R. Bolton. Electrophilic Additions to Unsaturated Systems. Elsevier Science & Technology Books, 2013.

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Book chapters on the topic "Electrophilic Additions"

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Carey, Francis A., and Richard J. Sundberg. "Electrophilic Additions to Carbon-Carbon Multiple Bonds." In Advanced Organic Chemistry. Springer US, 1990. http://dx.doi.org/10.1007/978-1-4613-9797-7_4.

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Carey, Francis A., and Richard J. Sundberg. "Electrophilic Additions to Carbon-Carbon Multiple Bonds." In Part B: Reactions and Synthesis. Springer Berlin Heidelberg, 2001. http://dx.doi.org/10.1007/978-3-662-39510-3_4.

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Fahey, Robert C. "The Stereochemistry of Electrophilic Additions to Olefins and Acetylenes." In Topics in Stereochemistry. John Wiley & Sons, Inc., 2007. http://dx.doi.org/10.1002/9780470147122.ch4.

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Went, Charles. "Electrophilic Addition Reactions of Alkenes and Alkynes." In Ionic Organic Mechanisms. Macmillan Education UK, 1986. http://dx.doi.org/10.1007/978-1-349-07964-3_9.

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Saavedra, Joseph E., Tambra M. Dunams, Judith L. Flippen-Anderson, and Larry K. Keefer. "Electrophilic Addition to "AminoNONOate" (R1R2NN(O)NO-) Ions." In Nitrosamines and RelatedN-Nitroso Compounds. American Chemical Society, 1994. http://dx.doi.org/10.1021/bk-1994-0553.ch024.

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Heppert, J. A., and M. L. Milligan. "Formation of η5 -Cyclohexadienide Complexes via Electrophilic Addition to Metal Arene Complexes." In Inorganic Reactions and Methods. John Wiley & Sons, Inc., 2007. http://dx.doi.org/10.1002/9780470145272.ch29.

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Aschwanden, Patrick, and Erick M. Carreira. "Addition of Terminal Acetylides to CO and CN Electrophiles." In Acetylene Chemistry. Wiley-VCH Verlag GmbH & Co. KGaA, 2005. http://dx.doi.org/10.1002/3527605487.ch3.

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Gilchrist, T. L. "By Electrophilic Additions to Nitriles." In Four Carbon-Heteroatom Bonds. Georg Thieme Verlag KG, 2005. http://dx.doi.org/10.1055/sos-sd-018-01163.

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"H8 Electrophilic additions to alkynes." In BIOS Instant Notes in Organic Chemistry. Taylor & Francis, 2004. http://dx.doi.org/10.4324/9780203427613-41.

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Block, E. "Electrophilic Additions to Thiophene 1,1-Dioxides." In Ene-X Compounds (X=S, Se, Te, N, P). Georg Thieme Verlag KG, 2007. http://dx.doi.org/10.1055/sos-sd-033-00252.

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Conference papers on the topic "Electrophilic Additions"

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Kinaci, Emre, Giuseppe Palmese, Joseph Stanzione, and Sarah Salazar. "Evaluation of hybridized bio-based building blocks as coating materials." In 2022 AOCS Annual Meeting & Expo. American Oil Chemists' Society (AOCS), 2022. http://dx.doi.org/10.21748/oyjf3899.

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Commercial epoxy resins are often the oligomeric reaction products of bisphenol A (BPA) with epichlorohydrin. BPA is a toxic petrochemical and a well-known endocrine disruptor which can mimic the body’s own hormones and may lead to several negative health effects. The most common curing agents are also the derivatives of toxic amines such as aniline, ethylene di-amine, and ammonia etc. which are under strict regulations and restrictions by TSCA and (REACH) agencies. Therefore; there is a growing demand to develop epoxy and amine systems from non- or less- toxic and annually renewable precurs
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Xinglei, Hu. "Experiment and Mechanism Study on the Effect of Coal Ash on the Capture of Alkali Metals in Zhundong Coal." In ASME 2017 Power Conference Joint With ICOPE-17 collocated with the ASME 2017 11th International Conference on Energy Sustainability, the ASME 2017 15th International Conference on Fuel Cell Science, Engineering and Technology, and the ASME 2017 Nuclear Forum. American Society of Mechanical Engineers, 2017. http://dx.doi.org/10.1115/power-icope2017-3570.

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A large number of Xinjiang Zhundong coal was found in China. Its high content of alkali metals can cause serious fouling/slagging problems which may lead to economic losses. It is significant to control the release of alkali metals from Zhundong coal during the combustion. Si-Al additives are used to capture Na released from the Zhundong coal. In this work, a combination of experimental research and quantum chemical calculation was used to study the effect of coal ash on the capture of alkali metal in Zhundong high alkali Coal and the related mineral evolution mechanism during melting processe
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