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Relevant bibliographies by topics / Electrophilic aldehydes

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Journal articles
Dissertations / Theses
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Academic literature on the topic 'Electrophilic aldehydes'

Author: Grafiati

Published: 11 December 2022

Last updated: 31 July 2025

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Journal articles on the topic "Electrophilic aldehydes"

1

Tola, Adesola J., Amal Jaballi, Hugo Germain, and Tagnon D. Missihoun. "Recent Development on Plant Aldehyde Dehydrogenase Enzymes and Their Functions in Plant Development and Stress Signaling." Genes 12, no. 1 (2020): 51. http://dx.doi.org/10.3390/genes12010051.

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Abiotic and biotic stresses induce the formation of reactive oxygen species (ROS), which subsequently causes the excessive accumulation of aldehydes in cells. Stress-derived aldehydes are commonly designated as reactive electrophile species (RES) as a result of the presence of an electrophilic α, β-unsaturated carbonyl group. Aldehyde dehydrogenases (ALDHs) are NAD(P)+-dependent enzymes that metabolize a wide range of endogenous and exogenous aliphatic and aromatic aldehyde molecules by oxidizing them to their corresponding carboxylic acids. The ALDH enzymes are found in nearly all organisms,

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2

Kočovský, Pavel, and Andrei V. Malkov. "Asymmetric synthesis: From transition metals to organocatalysis." Pure and Applied Chemistry 80, no. 5 (2008): 953–66. http://dx.doi.org/10.1351/pac200880050953.

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Umpolung in the allylation reaction is discussed with examples drawn from transition-metal-catalyzed allylic substitution (with the allylic unit acting as an electrophile) and Lewis base-catalyzed allylation of aldehydes with allyltrichlorosilane (with the allyl acting as a nucleophile). Iridium-catalyzed electrophilic allylation of O-nucleophiles has been employed in our new approach to C-nucleoside analogs, where the C-O bond (rather than C-C) was constructed stereospecifically. Variation of the absolute configuration in the starting segments allowed the synthesis of all four combinations of

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3

Li, Bin-Jie, Claudia EI-Nachef, and André M. Beauchemin. "Organocatalysis using aldehydes: the development and improvement of catalytic hydroaminations, hydrations and hydrolyses." Chemical Communications 53, no. 99 (2017): 13192–204. http://dx.doi.org/10.1039/c7cc07352f.

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4

Liang, Xin, Ruyi Qian, Dan Wang, Lijuan Liu, Chengliang Sun, and Xianyong Lin. "Lipid-Derived Aldehydes: New Key Mediators of Plant Growth and Stress Responses." Biology 11, no. 11 (2022): 1590. http://dx.doi.org/10.3390/biology11111590.

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Aldehydes, derivatives of lipids, are ubiquitously produced through non-enzymatic and enzymatic pathways in higher plants and participate in many physiological and biological processes. Increasing evidence demonstrates that aldehydes are involved in plants response to many abiotic stresses, such as light, drought, heat and nutrient deficiency. In plant cells, endogenously triggered or exogenously applied high concentrations of aldehydes can damage proteins and nucleic acid, disturb redox homeostasis, and consequently inhibit plant growth; therefore, they are considered cytotoxins. Aldehyde lev

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5

Senthil Kumar Raju, Archana Settu, Archana Thiyagarajan, Divya Rama, Praveen Sekar, and Shridharshini Kumar. "Synthetic approaches of medicinally important Schiff bases: An updated Review." World Journal of Advanced Research and Reviews 16, no. 3 (2022): 838–52. http://dx.doi.org/10.30574/wjarr.2022.16.3.1394.

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The Schiff base defined by an imine or azomethine (-CH= N-) group, is mostly synthesized by the condensation reaction of carbonyl compounds (Aldehyde or Ketone) with compounds consisting of amine moiety. Schiff bases are among the most chiefly used organic compounds, revealing a wide range of applications, such as electroluminescent effects, fluorescence properties, nonlinear optical and chemosensory properties. The typical Schiff bases are crystalline solids that are basic, although at least some of them combine with strong acids to generate insoluble salt. Schiff bases are widely used in the

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6

O'Brien, Nicholas S., and Adam McCluskey. "A Facile Microwave and SnCl2 Synthesis of 2,3-Dihydroquinazolin-4(1H)-ones." Australian Journal of Chemistry 73, no. 12 (2020): 1176. http://dx.doi.org/10.1071/ch20101.

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An elegantly simple, facile, and robust approach to a scaffold of biological importance, 2,3-dihydroquinazolin-4(1H)-ones, is reported. A catalytic 1% SnCl2/microwave-mediated approach afforded access to pure material, collected by cooling and filtration after 20-min microwave irradiation at 120°C. A total of 41 analogues were prepared in isolated yields of 17–99%. This process was highly tolerant of aliphatic, aromatic, heterocyclic, and acyclic aldehydes, but furan, pyrrole, and thiophene aldehyde reactivity correlated with propensity towards electrophilic addition and/or Diels–Alder additio

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7

Kripli, Balázs, Miklós Szávuly, Flóra Viktória Csendes та József Kaizer. "Functional models of nonheme diiron enzymes: reactivity of the μ-oxo-μ-1,2-peroxo-diiron(iii) intermediate in electrophilic and nucleophilic reactions". Dalton Transactions 49, № 6 (2020): 1742–46. http://dx.doi.org/10.1039/c9dt04551a.

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8

Senthil, Kumar Raju, Settu Archana, Thiyagarajan Archana, Rama Divya, Sekar Praveen, and Kumar Shridharshini. "Synthetic approaches of medicinally important Schiff bases: An updated Review." World Journal of Advanced Research and Reviews 16, no. 3 (2022): 838–52. https://doi.org/10.5281/zenodo.7903785.

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The Schiff base defined by an imine or azomethine (-CH= N-) group, is mostly synthesized by the condensation reaction of carbonyl compounds (Aldehyde or Ketone) with compounds consisting of amine moiety. Schiff bases are among the most chiefly used organic compounds, revealing a wide range of applications, such as electroluminescent effects, fluorescence properties, nonlinear optical and chemosensory properties. The typical Schiff bases are crystalline solids that are basic, although at least some of them combine with strong acids to generate insoluble salt. Schiff bases are widely used in the

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9

Vera, Silvia, Aitor Landa, Antonia Mielgo, Iñaki Ganboa, Mikel Oiarbide та Vadim Soloshonok. "Catalytic Asymmetric α-Functionalization of α-Branched Aldehydes". Molecules 28, № 6 (2023): 2694. http://dx.doi.org/10.3390/molecules28062694.

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Aldehydes constitute a main class of organic compounds widely applied in synthesis. As such, catalyst-controlled enantioselective α-functionalization of aldehydes has attracted great interest over the years. In this context, α-branched aldehydes are especially challenging substrates because of reactivity and selectivity issues. Firstly, the transient trisubstituted enamines and enolates resulting upon treatment with an aminocatalyst or a base, respectively, would exhibit attenuated reactivity; secondly, mixtures of E- and Z-configured enamines/enolates may be formed; and third, effective face-

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Murugan, Rajendran, and Boreddy S. R. Reddy. "A New Protocol to Synthesize Di(indolyl)pyrazolyl Methanes Using H2PtCl6 as a Catalyst in Ionic Liquid: Synthesis of Novel 3-[1H-indol-3-yl(3-phenyl-1H-pyrazol-4-yl)methyl]-1H-indoles." Australian Journal of Chemistry 59, no. 4 (2006): 273. http://dx.doi.org/10.1071/ch05208.

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Biologically important di(indolyl)pyrazolyl methanes and their derivatives were synthesized in excellent yields by the electrophilic substitution of indole with pyrazolyl aldehydes catalyzed by H2PtCl6 in ionic liquid.

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Dissertations / Theses on the topic "Electrophilic aldehydes"

1

Appel, Roland. "Phosphorus Ylides, Sulfur Ylides, and Related Carbanions as Reference Nucleophiles for the Quantification of the Electrophilic Reactivities of Aldehydes, Imines, and Enones." Diss., lmu, 2011. http://nbn-resolving.de/urn:nbn:de:bvb:19-129816.

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2

Hall, Sally Elizabeth. "Towards non-surgical sterilisation of feral horses: biomarkers of folliculogenesis and covalent modification of proteins using electrophilic aldehydes." Thesis, 2017. http://hdl.handle.net/1959.13/1347466.

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Research Doctorate - Doctor of Philosophy (PhD)<br>Feral horses currently require immediate population control in certain areas of Australia, and are a pest species across many regions of the world. Fertility control is considered the most suitable management strategy for control; however, agents currently available are largely non-sustainable for free-ranging feral horses. This is due to the difficulties associated with application of a fertility control agent, the ability to then identify animals which have been treated, and finally, the timely readministration of boosters. Consequently, the

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Appel, Roland [Verfasser]. "Phosphorus ylides, sulfur ylides, and related carbanions as reference nucleophiles for the quantification of the electrophilic reactivities of aldehydes, imines, and enones / Roland Joachilm Appel." 2011. http://d-nb.info/1011344777/34.

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Book chapters on the topic "Electrophilic aldehydes"

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Olpp, T. "Electrophilic Substitution in Phosphoranylideneacetaldehyde." In Aldehydes. Georg Thieme Verlag KG, 2007. http://dx.doi.org/10.1055/sos-sd-025-00301.

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Oestreich, M. "Electrophilic Aromatic Substitution of Unprotected Arenecarbaldehydes." In Aldehydes. Georg Thieme Verlag KG, 2007. http://dx.doi.org/10.1055/sos-sd-025-00471.

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Oestreich, M. "Classic Suzuki–Miyaura Coupling Reactions Using Electrophilic Arenecarbaldehydes." In Aldehydes. Georg Thieme Verlag KG, 2007. http://dx.doi.org/10.1055/sos-sd-025-00480.

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Oestreich, M. "Stille-Type Cross-Coupling Reactions Using Electrophilic Arenecarbaldehydes." In Aldehydes. Georg Thieme Verlag KG, 2007. http://dx.doi.org/10.1055/sos-sd-025-00484.

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Oestreich, M. "Negishi-Type Cross-Coupling Reactions Using Electrophilic Arenecarbaldehydes." In Aldehydes. Georg Thieme Verlag KG, 2007. http://dx.doi.org/10.1055/sos-sd-025-00486.

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Oestreich, M. "Hiyama-Type Cross-Coupling Reactions Using Electrophilic Arenecarbaldehydes." In Aldehydes. Georg Thieme Verlag KG, 2007. http://dx.doi.org/10.1055/sos-sd-025-00487.

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Berkenbusch, T. "Synthesis by Electrophilic Aromatic Substitution: Hydrogen–Heteroatom Exchange." In Aldehydes. Georg Thieme Verlag KG, 2007. http://dx.doi.org/10.1055/sos-sd-025-00492.

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8

Oestreich, M. "sp–sp Cross-Coupling Reactions of Electrophilic Arenecarbaldehydes (Sonogashira Coupling)." In Aldehydes. Georg Thieme Verlag KG, 2007. http://dx.doi.org/10.1055/sos-sd-025-00478.

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Oestreich, M. "sp–sp Cross-Coupling Reactions of Electrophilic or Nucleophilic Arenecarbaldehydes." In Aldehydes. Georg Thieme Verlag KG, 2007. http://dx.doi.org/10.1055/sos-sd-025-00479.

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10

Oestreich, M. "Palladium-Catalyzed Arylation of Alkenes Using Electrophilic Arenecarbaldehydes (Heck Reaction)." In Aldehydes. Georg Thieme Verlag KG, 2007. http://dx.doi.org/10.1055/sos-sd-025-00488.

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