Academic literature on the topic 'Electrophilic substitutions'

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Journal articles on the topic "Electrophilic substitutions"

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Kolodiazhnyi, Oleg I. "Stereochemistry of electrophilic and nucleophilic substitutions at phosphorus." Pure and Applied Chemistry 91, no. 1 (2019): 43–57. http://dx.doi.org/10.1515/pac-2018-0807.

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Abstract Nucleophilic and electrophilic substitutions are the most often applied reactions in organophosphorus chemistry. They are closely interrelated, because in a reacting pair always one reagent is an electrophile, and another nucleophile. The reactions of electrophilic and nucleophilic substitutions at the phosphorus center proceed via the formation of a pentacoordinated intermediate. The mechanism of nucleophilic substitution involves the exchange of ligands in the pentacoordinate phosphorane intermediate, leading to the more stable stereomer under the thermodynamic control. Electrophili
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Szántay, Csaba, Álmos Gorka-Kereskényi, Lajos Szabó, et al. "Aromatic Electrophilic Substitutions on Vindoline." HETEROCYCLES 71, no. 7 (2007): 1553. http://dx.doi.org/10.3987/com-07-11049.

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Puciová, Monika, Eva Solčániová, and Štefan Toma. "Electrophilic substitutions on some ferrocenylheteroarenes." Tetrahedron 50, no. 19 (1994): 5765–74. http://dx.doi.org/10.1016/s0040-4020(01)85644-1.

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COOMBES, R. G. "ChemInform Abstract: Electrophilic Aromatic Substitutions." ChemInform 28, no. 30 (2010): no. http://dx.doi.org/10.1002/chin.199730259.

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Christoffers, Jens, and Mathias S. Wickleder. "Synthesis of Aromatic and Aliphatic Di-, Tri-, and Tetrasulfonic Acids." Synlett 31, no. 10 (2020): 945–52. http://dx.doi.org/10.1055/s-0039-1691745.

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Oligosulfonic acids are promising linker compounds for coordination polymers and metal-organic frameworks, however, compared to their carboxylic acid congeners, often not readily accessible by established synthetic routes. This Account highlights the synthesis of recently developed aromatic and aliphatic di-, tri- and tetrasulfonic acids. While multiple electrophilic sulfonations of aromatic substrates are rather limited, the nucleophilic aromatic substitution including an intramolecular variant, the Newman–Kwart rearrangement, allows the flexible introduction of up to four sulfur-containing m
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Uchida, Yuzuru, and Shigeru Oae. "Electrophilic Substitutions on Tris(Pyridyl)Phosphine." Phosphorus, Sulfur, and Silicon and the Related Elements 109, no. 1-4 (1996): 605–8. http://dx.doi.org/10.1080/10426509608545226.

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Gracza, Tibor, Zdeněk Arnold, and Jaroslav Kováč. "Electrophilic ipso substitutions of furan vinamidinium salts." Collection of Czechoslovak Chemical Communications 53, no. 5 (1988): 1053–59. http://dx.doi.org/10.1135/cccc19881053.

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5-(N,N-Dialkylamino)-2-furfurylidene-N,N-dialkylimminium salts I (the vinamidinium salts of furan) react with arenediazonium salts to give products of ipso substitution in position 2 of the furan ring, i.e. 5-(N,N-dialkylamino)-2-azoarenefuran salts II. The structure of these products was evidenced by 1H NMR and UV spectral data.
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Keumi, Takashi, Naoto Tomioka, Kozo Hamanaka, et al. "Positional reactivity of dibenzofuran in electrophilic substitutions." Journal of Organic Chemistry 56, no. 15 (1991): 4671–77. http://dx.doi.org/10.1021/jo00015a020.

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KNIPE, A. C. "ChemInform Abstract: Carbanions and Electrophilic Aliphatic Substitutions." ChemInform 28, no. 30 (2010): no. http://dx.doi.org/10.1002/chin.199730256.

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PUCIOVA, M., E. SOLCANIOVA, and S. TOMA. "ChemInform Abstract: Electrophilic Substitutions on Some Ferrocenylheteroarenes." ChemInform 25, no. 39 (2010): no. http://dx.doi.org/10.1002/chin.199439228.

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Dissertations / Theses on the topic "Electrophilic substitutions"

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Westermaier, Martin. "Electrophilic Substitutions of Indoles and Pyrroles:." Diss., lmu, 2007. http://nbn-resolving.de/urn:nbn:de:bvb:19-77431.

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Hartley, Joseph P. "Indium catalysed electrophilic aromatic substitution." Thesis, University of Bath, 2002. https://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.760785.

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McMurdo, J. "Electrophilic aromatic substitution using methoxyacetyl chloride." Thesis, University of East Anglia, 1988. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.302997.

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Rodriguez, Medina Inmaculada Concepcion. "Studies on oxidative aromatic substitution." Thesis, University of Sussex, 2001. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.390923.

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Roberts, S. D. "Regioselective electrophilic aromatic substitution reactions of naphthalene over solids." Thesis, Swansea University, 2000. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.638685.

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Chapter 1 highlights the many advantages of heterogeneous inorganic solids as catalysts, and summarises the various microporous and mesoporous solids that have been employed as catalysts. The synthesis and characterisation of the mesoporous materials that were used in the study are described. Chapter 2 focuses on the nitration of naphthalene. An introduction to nitration is given, and the results of nitration over a range of solids are presented. Unusual dinitronaphthalene product ratios were achieved over Al-MCM-41. Reactions catalysed by heteropoly acid immobilised within the pores of mesopo
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Duffy, Anne Merete. "Students' ways of understanding aromaticity and electrophilic aromatic substitution reactions." Connect to a 24 p. preview or request complete full text in PDF format. Access restricted to UC campuses, 2006. http://wwwlib.umi.com/cr/ucsd/fullcit?p3210647.

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Thesis (Ph. D.)--University of California, San Diego and San Diego State University, 2006.<br>Title from first page of PDF file (viewed June 7, 2006). Available via ProQuest Digital Dissertations. Vita. Includes bibliographical references (p. 280-290).
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Earle, Martyn John. "New approaches to aromatic substitution reactions with carbon electrophiles." Thesis, Loughborough University, 1992. https://dspace.lboro.ac.uk/2134/33242.

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The thesis gives an account of work directed towards developing new reagent systems and methodology, with particular reference to the Friedel–Crafts and Vilsmeier–Haack reactions of aromatic and heteroaromatlc compounds. Ways of improving regioselectivity and developing a stereoselective Friedel–Crafts reaction have been investigated for a range of hetero-atom stabilised carbocations. This work is divided into two main areas: (1) the synthesis and use of pyrophosphoryl chloride in the Vilsmeier–Haack reaction, the results of this has shed new light on the mechanism of this classical reaction;
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Nguyen, Quang. "Reinventing Aromatic Substitution: A Novel Look." TopSCHOLAR®, 2013. http://digitalcommons.wku.edu/theses/1292.

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Electrophilic aromatic substitution (EAS) and directed ortho-metalation (DoM) involve the direct substitution of an arene hydrogen. A major drawback involving EAS is the necessity for harsh forcing conditions for the reaction to proceed. Catalysts such as Lewis acids FeBr3 and AICI3 for the introduction of halogens and acyl groups, respectively, are each highly toxic and corrosive. Textbook preparations of aryl iodides classicaly involved the use of iodine and nitric acid. This approach affords only modest yields and does not provide regiospecific substitution of most substituted aromatics bec
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Koumaglo, Mensah-Dzraku Kossi. "Vinylsilanes and allysilanes in electrophilic substitution reactions : stereocontrolled synthesis of insect sex pheromones." Thesis, McGill University, 1985. http://digitool.Library.McGill.CA:80/R/?func=dbin-jump-full&object_id=72769.

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Shah, Parin Ajay. "Synthesis of terpenoids using a tandem cationic cascade cyclization-electrophilic aromatic substitution reaction." Diss., University of Iowa, 2018. https://ir.uiowa.edu/etd/6639.

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The terpene and terpenoid family of compounds is considered to be the largest group of natural products. These compounds not only display great diversity in their structural features but are also known to have a multitude of biological activities including but not limited to anti-bacterial, anti-cancer, anti-inflammatory, and anti-HIV properties. Remarkably, all the terpenoids formed in nature come from two molecules viz. isopentenyl pyrophosphate and its isomer, dimethylallyl pyrophosphate both consisting of just five carbons but assembled in many ways. Nature utilizes highly efficient, enzym
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Books on the topic "Electrophilic substitutions"

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Taylor, R. Electrophilic aromatic substitution. J. Wiley, 1990.

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McMurdo, J. Electrophilic aromatic substitution using methoxyacetyl chlorine. University of East Anglia, 1988.

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Earle, Martyn John. New approaches to aromatic substitution reactions with carbon electrophiles. 1992.

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Advances in Heterocyclic Chemistry: Electrophilic Substitution of Heterocycles : Quantitative Aspects (Advances in Heterocyclic Chemistry, 47). Academic Press, 1990.

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Book chapters on the topic "Electrophilic substitutions"

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Vančik, Hrvoj. "Electrophilic Substitutions." In Basic Organic Chemistry for the Life Sciences. Springer International Publishing, 2014. http://dx.doi.org/10.1007/978-3-319-07605-8_9.

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Vančik, Hrvoj. "Electrophilic Substitutions." In Basic Organic Chemistry for the Life Sciences. Springer International Publishing, 2022. http://dx.doi.org/10.1007/978-3-030-92438-6_9.

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Bandini, Marco. "Catalytic Enantioselective Electrophilic Aromatic Substitutions." In Arene Chemistry. John Wiley & Sons, Inc, 2015. http://dx.doi.org/10.1002/9781118754887.ch5.

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Balaji, B. S. "Aromatic Electrophilic and Nucleophilic Substitutions." In A Foundation Course for College Organic Chemistry. CRC Press, 2024. http://dx.doi.org/10.1201/9781032631165-9.

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Brouwer, D. M., and H. Hogeveen. "Electrophilic Substitutions at Alkanes and in Alkylcarbonium Ions." In Progress in Physical Organic Chemistry. John Wiley & Sons, Inc., 2007. http://dx.doi.org/10.1002/9780470171882.ch4.

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Coombes, R. G. "Electrophilic Aromatic Substitution." In Organic Reaction Mechanisms Series. John Wiley & Sons, Ltd, 2011. http://dx.doi.org/10.1002/9780470975800.ch6.

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Norman, Richard, and James M. Coxon. "Electrophilic aromatic substitution." In Principles of Organic Synthesis. Springer Netherlands, 1993. http://dx.doi.org/10.1007/978-94-011-2166-8_11.

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Coombes, R. G. "Electrophilic Aromatic Substitution." In Organic Reaction Mechanisms · 2008. John Wiley & Sons, Ltd, 2011. http://dx.doi.org/10.1002/9780470979525.ch6.

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Coombes, R. G. "Electrophilic Aromatic Substitution." In Organic Reaction Mechanisms Series. John Wiley & Sons, Ltd, 2011. http://dx.doi.org/10.1002/9781119972471.ch6.

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Crampton, M. R. "Electrophilic Aromatic Substitution." In Organic Reaction Mechanisms Series. John Wiley & Sons, Ltd, 2014. http://dx.doi.org/10.1002/9781118560273.ch6.

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Conference papers on the topic "Electrophilic substitutions"

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Kashman, Yoel, Avi Koller, Amira Rudi, and Marta Gravalos. "Synthesis And Electrophilic Substitution of Pyrido[2,3,4-kl]acridines." In The 4th International Electronic Conference on Synthetic Organic Chemistry. MDPI, 2000. http://dx.doi.org/10.3390/ecsoc-4-01809.

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Plotnikova, K. A., M. G. Pervova, and T. I. Gorbunova. "Electrophilic substitution in row of the poly-chlorinated bi-phenyls. Peculiarities of mass-spectra of the derivatives." In VI Information school of a young scientist. Central Scientific Library of the Urals Branch of the Russian Academy of Sciences, 2018. http://dx.doi.org/10.32460/ishmu-2018-6-0020.

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Kinaci, Emre, Giuseppe Palmese, Joseph Stanzione, and Sarah Salazar. "Evaluation of hybridized bio-based building blocks as coating materials." In 2022 AOCS Annual Meeting & Expo. American Oil Chemists' Society (AOCS), 2022. http://dx.doi.org/10.21748/oyjf3899.

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Commercial epoxy resins are often the oligomeric reaction products of bisphenol A (BPA) with epichlorohydrin. BPA is a toxic petrochemical and a well-known endocrine disruptor which can mimic the body’s own hormones and may lead to several negative health effects. The most common curing agents are also the derivatives of toxic amines such as aniline, ethylene di-amine, and ammonia etc. which are under strict regulations and restrictions by TSCA and (REACH) agencies. Therefore; there is a growing demand to develop epoxy and amine systems from non- or less- toxic and annually renewable precurs
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