Academic literature on the topic 'Elements de transition'

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Journal articles on the topic "Elements de transition"

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Yamamoto, A. "Middle transition elements." Polyhedron 7, no. 21 (January 1988): 2245–46. http://dx.doi.org/10.1016/s0277-5387(00)81818-5.

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Calderazzo, F. "Late transition elements." Polyhedron 7, no. 21 (January 1988): 2246. http://dx.doi.org/10.1016/s0277-5387(00)81819-7.

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Manu, C. "Quadratic isoparametric elements as transition elements." Engineering Fracture Mechanics 24, no. 4 (January 1986): 509–12. http://dx.doi.org/10.1016/0013-7944(86)90224-9.

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Calderazzo, Fausto, Alberto Juris, Rinaldo Poli, and Fausto Ungari. "Reactivity of molecules containing element-element bonds. 2. Transition elements." Inorganic Chemistry 30, no. 6 (March 1991): 1274–79. http://dx.doi.org/10.1021/ic00006a022.

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Gopalakrishnan, R., S. Vijayakar, and H. Busby. "An iterative algorithm for adaptive element splitting using transition elements." Computers & Structures 37, no. 3 (January 1990): 283–94. http://dx.doi.org/10.1016/0045-7949(90)90320-2.

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Roesky, Herbert W., Sanjay Singh, K. K. M. Yusuff, John A. Maguire, and Narayan S. Hosmane. "Organometallic Hydroxides of Transition Elements." Chemical Reviews 106, no. 9 (September 2006): 3813–43. http://dx.doi.org/10.1021/cr050203b.

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Ullman, R. "Ferrum and the transition elements." British Homoeopathic journal 86, no. 2 (April 1997): 104. http://dx.doi.org/10.1016/s0007-0785(97)80138-x.

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Lim, I. L., I. W. Johnston, and S. K. Choi. "The use of transition elements." Engineering Fracture Mechanics 40, no. 6 (January 1991): 975–83. http://dx.doi.org/10.1016/0013-7944(91)90163-u.

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Hamer, D. "Transition elements in transcription factors." Journal of Inorganic Biochemistry 43, no. 2-3 (August 1991): 503. http://dx.doi.org/10.1016/0162-0134(91)84480-w.

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Horváth, Ágnes. "General forming of transition elements." Communications in Numerical Methods in Engineering 10, no. 3 (March 1994): 267–73. http://dx.doi.org/10.1002/cnm.1640100310.

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Dissertations / Theses on the topic "Elements de transition"

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Alshehri, Abdulmohsen. "Methanol oxidation on transition elements oxides." Thesis, Cardiff University, 2013. http://orca.cf.ac.uk/47041/.

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Methanol oxidation to formaldehyde is one of the most important industries in our lives; the reaction occurs on catalyst surface in heterogeneous catalysis. Iron molybdate is the current selective catalyst. However, molybdenum volatilises during methanol oxidation and leaving the catalyst with a low molybdenum ratio, which deactivates the catalyst, a 2.2 Mo: 1Fe iron molybdate catalyst was used instead the stoichiometric catalyst, while yield of formaldehyde cannot be 100%. The goal of this study is to find more selective and more productive catalyst than iron molybdate catalyst, the first step is to find another transition element as selective as molybdenum, because molybdenum is the selective part, and iron is the active part, the resulting iron molybdate catalyst is a selective catalyst to formaldehyde near molybdenum and active near iron. Experimentally, catalysts were prepared using co-precipitation method, however, some doped catalysts were papered by incipient wetness impregnation, also sol-immobilization was used to prepare nano-gold particles on the surfaces of few supports. Catalysts characterizations were carried out within several techniques for the surface analysis (XPS) and bulk analysis (XRD), also the surface area was measured by BET equipment. Raman too was used in this study, while micro-reactor was the reactor to determine selectivity and activity of each catalyst. When molybdenum replaced by vanadium, the catalyst yielded 100% formaldehyde at 200 oC; moreover, tungsten was selective. Likewise, iron was replaced by other active metals such as manganese, copper and bismuth, which are active. Nano-gold improved activity when doped on molybdenum oxide and iron molybdate supports.
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Semeniuk, Jaroslaw Ivan. "Ultra violet Fourier transform spectroscopy of transition elements." Thesis, Imperial College London, 1996. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.321659.

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Hu, Shichao. "Transition metal oxofluorides comprising lone pair elements : Synthesis and Characterization." Doctoral thesis, Stockholms universitet, Institutionen för material- och miljökemi (MMK), 2014. http://urn.kb.se/resolve?urn=urn:nbn:se:su:diva-103051.

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Within the family of transition metal oxochlorides/bromides containing lone pair elements, the transition metal cations often adopt a low-dimensional arrangement such as 2D layers, 1D chains or 0D clusters. The reduced dimensionality is attributed to the presence of stereochemically active lone pairs which are positioned in the non-bonding orbital and will not participate in bond formation and instead act as structural spacers that help to separate coordination polyhedra around transition metal cations from forming three dimensional networks. On the other hand, the chlorine and bromine ions also play an important role to open up the crystal structure because of their low coordination number. However, fluorine has been rarely used in this concept due to the difficulties in synthesis. This thesis is focused on finding new compounds in the M-L-O-F system (M = transition metal cation, L= p-block lone pair elements such as Te4+, Se4+, or Sb3+) in order to study the structural character of fluorine. Hydrothermal reactions have been adopted instead of conventional chemical transport reactions that are commonly used for synthesizing compounds in the M-L-O-(Cl, Br) family. A total of 8 new transition metal oxofluorides containing lone pair elements have been synthesized and their structures have been determined via single crystal X-ray diffraction. Bond valence sum calculations are used to distinguish in between fluorine and oxygen due to their very similar X-ray scattering factors.

At the time of the doctoral defense, the following papers were unpublished and had a status as follows: Paper 4: Manuscript. Paper 5: Manuscript.

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Manikas, Mary. "The stabilisation of high oxidation states in transition and main group elements /." Title page, contents and abstract only, 1993. http://web4.library.adelaide.edu.au/theses/09PH/09phm278.pdf.

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Wan, Ka-ho, and 溫家豪. "Transition finite elements for mesh refinement in plane and plate bending analyses." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 2004. http://hub.hku.hk/bib/B29478546.

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Matthies, Olga. "Topological analysis of the cd → β-Sn phase transition of group 14 elements." Doctoral thesis, Saechsische Landesbibliothek- Staats- und Universitaetsbibliothek Dresden, 2018. http://nbn-resolving.de/urn:nbn:de:bsz:14-qucosa-232747.

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To understand the mechanism of a pressure-induced structural phase transition, it is important to know which bonding changes lead to the stabilization of the new structure. A useful approach in this regard is the quantum chemical topology, which provides a large variety of indicators for the characterization of interatomic interactions. In this work, a number of topological indicators are used to analyze the bonding changes during the pressure-induced phase transition from the cubic diamond (cd) to the β-Sn-type structure of the elements of the 14th group of the periodic table. The ability of these indicators to reflect the presence of the cd → β-Sn transition in experiment for Si, Ge and Sn and its absence for carbon is investigated. Furthermore, the effect of pressure on the interatomic interactions in the cd- and β-Sn-type structures is examined. It is observed that the energy change along the cd → β-Sn transformation pathway correlates with the evolution of certain parameters of the electron density and the electron localizability indicator (ELI-D). Accordingly, criteria of structural stability were formulated based on characteristics of interatomic interactions. These results can serve as guidelines for the investigation of other solid-state phase transformations by the topological methods.
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Coombs, Natalie D. "Synthesis of low-coordinate transition metal complexes of the heavier group 13 elements." Thesis, Cardiff University, 2008. http://orca.cf.ac.uk/54759/.

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This thesis describes the synthesis, structural and reaction chemistry of a number of novel gallium and indium containing species, including metal complexes featuring previously unreported gallium and indium ligand systems. The synthesis, spectroscopic and structural characterisation of the asymmetric haloindyl (n5-C5R5)Fe(CO)2In(Mes*)Br (R = H, Me) and halogallyl Cp*Fe(CO)2Ga(Mes)I complexes are reported herein, with Cp*Fe(CO)2ln(Mes*)Br representing the first example of structurally characterised asymmetric bromoindyl complex. Cp*Fe(CO)2In(Mes*)Br is a versatile substrate for the synthesis of asymmetric indyl complexes via substitution chemistry, thereby allowing the synthesis and characterisation of Cp*Fe(CO)2In(Mes*)ERn (ERn = OC6H4/Bu-4, SPh). The synthesis, spectroscopic and structural characterisation of the dihalogallyl complex Cp*Fe(dppe)Gal2 is also reported this synthesis was accomplished via photolytic displacement of the carbonyl ligands in Cp*Fe(CO)2Gal2 2 by dppe 1,2-bis(diphenylphosphino)ethane. Cp*Fe(dppe)Gal2 has proven to be versatile reagent in the generation of the asymmetric halogallyl species via substitution chemistry with retention of the iron-gallium bond, thereby allowing the synthesis and characterisation of Cp*Fe(dppe)Ga(Mes)I. The diiodogallyl complex has also been implicated in the synthesis of the first structurally characterised base-free cationic gallylene complex Cp*Fe(CO)2Gal + BAr/4 bearing a terminally bound Gal ligand which is valence isoelectronic with CO and N2. Investigations into the synthesis of molybdenum- and ruthenium-phosphine containing systems are also reported herein. Insertion of 'Gal' into metal-halogen bonds has proved to a viable synthetic route, for example in the 7 7 formation of (n-C7H7)Mo(CO)2Gal2 2. Further reaction of (n-C7H7)Mo(CO)2Gal2 2 with dppe, however, has been shown to yield (r - C7H7)Mo(CO)2Gai2 2(u-dppe). Investigation of 'Gal' insertion reactions involving ruthenium-halogen bonds have shown to yield the tetraiodogallate species CpRu(PPh3)2(u-I)Gal3 and CpRu(dppe) Gal4. The synthesis, spectroscopic and structural characterisation of the bridging halo-indanediyl complexes Cp*Fe(CO)2 2lnX (X = Br, I) are reported. The bromo-substituted species has proven to be a useful precursor in the synthesis of the cationic trimetallic system {Cp*Fe(CO)2}2(-In) + BA/4, the formation of which has been shown to be strongly dependant on the nature of abstracting agent and on the identity of the halide. Reactivity studies of {Cp*Fe(CO)2}2( i-E) + (E = Ga, In) involving the addition of nucleophiles has allowed the synthesis and characterisation of the three-coordinate cationic complexes {Cp*Fe(CO)2}2(u-E L) + BAr4 (E = Ga, In L = thf, 4-picoline, PPh3). The syntheses and metallation of sterically bulky carbazol-9-yl ligands derived from 1,8-diaryl-3,6-dimethylcarbazole are described herein. Furthermore, the synthesis and structural characterisation of the amidogally l complexes (1,8-diphenyl-3,6-dimethylcarbazol-9-yl)gallium dichloride and (1,8-dimesity 1-3,6-dimethylcarbazol-9-yl)gallium dichloride are reported by salt metathesis reactions involving gallium trichloride. Investigations of subsequent reduction chemistry using potassium metal yielded the potassium salt 1,8-diphenyl-3,6-dimethylcarbazol-9-yl-potassium. Quantum chemical investigations using Density Functional Theory have been explored to probe the electronic structure in the novel bond types. In particular, studies targeted factors affecting the degree of 7c back-bonding (and hence multiple bond character) within the TM-ER bond.
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Boizot, Bruno. "Cristallochimie des elements de transition fer, chrome et manganese dans les alumines techniques." Paris 6, 1996. http://www.theses.fr/1996PA066483.

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Dans les alumines, les proprietes physiques peuvent etre modifiees par le dopage de ce materiau avec des elements de transition. La comprehension de l'influence des dopants sur la structure reelle de ces materiaux est donc un enjeu fondamental pour mieux controler leurs proprietes physiques. Deux facteurs conditionnent fortement l'influence du dopage. Le premier est l'interaction entre le dopant et le reseau cristallographique au sein des grains de corindon. Le second facteur concerne la localisation et la repartition des dopants dans les ceramiques alumines. L'objectif de ce travail etait d'analyser quantitativement l'influence du dopage par les ions de transition fer, chrome et manganese sur la structure reelle des ceramiques d'alumine. L'analyse de l'environnement local autour des ions de transitions et de la microstructure des alumines dopees a necessite l'utilisation combinee de techniques cristallographiques et spectroscopiques telles que la diffraction de rayons x (drx), la resonance paramagnetique electronique (rpe) et la spectroscopie optique en reflectance diffuse (drs). L'analyse quantitative rpe a ete effectuee grace au developpement d'un code de simulation des spectres rpe de poudre. Ce traitement a permis d'affiner les parametres de l'hamiltonien de spin pour des ions en champ cristallin intermediaire et de determiner l'environnement local des ions fe#3#+, cr#3#+ et mn#2#+ substitues a al#3#+ dans le corindon. L'affinement rietveld des diffractogrammes de rayons x et l'analyse des spectres de drs d'alumines dopees nous ont permis de mieux quantifier l'influence de procedes de synthese sur la localisation des dopants chrome et manganese au sein des ceramiques: le chrome est majoritairement insere dans le grain de corindon alors que le manganese est precipite sous la forme d'une phase spinelle aux joints de grain des ceramiques. Nous avons montre egalement dans cette etude la presence de contraintes interne residuelles dans les ceramiques quelles que soient les conditions de synthese
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MARTINS, EVELY. "Estudos espectroscopicos de fluoperovskitas dopadas com ions de metais de transicao." reponame:Repositório Institucional do IPEN, 1994. http://repositorio.ipen.br:8080/xmlui/handle/123456789/10389.

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Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)
Tese (Doutoramento)
IPEN/T
Instituto de Pesquisas Energeticas e Nucleares - IPEN/CNEN-SP
FAPESP:93/03991-2
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Stavros, Katsas. "The role of solute and transition elements in the superplastic behaviour of aluminium alloys." Thesis, Imperial College London, 2007. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.486326.

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This project fOllows on from work carried out at Imperial College London to develop aluminium alloys with enhanced superplastic properties for automotive applications. In this prior work it was found that AI-Mg-Zralloys exhibited superior superplastic properties to other 5xxx alloys including the widely used superplastic variant of5083. The aim of the current work was to fully characterise the AI-Mg-:Zr alloys at each stage of the production route in order to optimise the processing conditions and exploit alternative production routes. It is generally accepted that there are two main requirements for superplasticity in ..J aluminium alloys. The first is the addition of a solute element to reduce the high stacking fault energy associated with pure aluminium energy and hence favour recrystallisation over recovery during thermomechanical processing. The second is a homogeneous dispersion of fine, thermally stable second phase particles to control grain growth via Zener pinning. For this reason the characterisation of the AI-Mg-Zr alloys focussed on the individual roles of the solute (magnesium) and transition element (zirconium) additions. In order to' better understand the role of zirconium a binary AI-Zr alloy was also prepared and investigated. Furthermore, some preliminary casting trials' where zirconium was either partially or totally replaced by vanadium were conducted. The purpose of these experiments was to' produce a more economical and practical grain control methodology. The implication of the work presented in this thesis is that although it is well recognised that solute elements together with high amounts of stored energy (as a result of complex thermomechanical processing) are both necessary to achieve superplasticitY in aluminium alloys, under certain circumstances the presence of either may be sufficient Furthermore, useful conclusions about the pinning capability of the second phase particles were also drawn. The findings described in this thesis can have a significant impact on the design not of)ly of the processing route of the AIMg- Zr alloys but also of other established superplastic aluminium alloys.
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Books on the topic "Elements de transition"

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The transition elements: The 38 transition metals. New York: Rosen Central, 2010.

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Pruchnik, Florian P., and Stan A. Duraj. Organometallic Chemistry of the Transition Elements. Boston, MA: Springer US, 1990. http://dx.doi.org/10.1007/978-1-4899-2076-8.

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Organometallic chemistry of the transition elements. New York: Plenum Press, 1990.

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Forest, David Henry. High resolution laser spectroscopy of transition elements. Birmingham: University of Birmingham, 1999.

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Center, Lewis Research, ed. A novel approach in formulation of special transition elements: Mesh interface elements : status report. Columbus, Ohio: The Ohio State University Research Foundation, 1989.

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Saunders, N. The transition metals 2: Gold, iron and other elements. Oxford [England]: Heinemann Library, 2003.

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François, Mathey. Molecular chemistry of the transition elements: An introductory course. Chichester: John Wiley, 1996.

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-L, Bobet J., Chevalier B, and Fruchart D, eds. Solid compounds of transition elements: Selected, peer reviewed papers from the 17th International Conference on Solid Compounds of Transition Elements, (SCTE2010), September 5-10, 2010, Annecy, France. Durnten-Zurich, Switzerland: Trans Tech Publications, 2011.

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Burzo, E. Magnetic Properties of Non-Metallic Inorganic Compounds Based on Transition Elements. Edited by H. P. J. Wijn. Berlin, Heidelberg: Springer Berlin Heidelberg, 2017. http://dx.doi.org/10.1007/978-3-662-49337-3.

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Itzak, Levit, Stanley Gary Mitchel, and United States. National Aeronautics and Space Administration., eds. Evaluation of discretization procedures for transition elements in adaptive mesh refinement. Boulder, Colo: Center for Space Structures and Controls, College of Engineering, University of Colorado, 1991.

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Book chapters on the topic "Elements de transition"

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Canil, Dante. "Transition Elements." In Encyclopedia of Earth Sciences Series, 1–4. Cham: Springer International Publishing, 2016. http://dx.doi.org/10.1007/978-3-319-39193-9_230-1.

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Canil, Dante. "Transition Elements." In Encyclopedia of Earth Sciences Series, 1452–55. Cham: Springer International Publishing, 2018. http://dx.doi.org/10.1007/978-3-319-39312-4_230.

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Poll, D. I. A. "The Effect of Isolated Roughness Elements on Transition in Attachment-Line Flows." In Laminar-Turbulent Transition, 657–67. Berlin, Heidelberg: Springer Berlin Heidelberg, 1990. http://dx.doi.org/10.1007/978-3-642-84103-3_61.

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Wedig, Ulrich, Michael Dolg, Hermann Stoll, and Heinzwerner Preuss. "Energy-Adjusted Pseudopotentials for Transition-Metal Elements." In Quantum Chemistry: The Challenge of Transition Metals and Coordination Chemistry, 79–89. Dordrecht: Springer Netherlands, 1986. http://dx.doi.org/10.1007/978-94-009-4656-9_6.

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Choi, Chang-Koon, and Yong-Myung Park. "Transition Plate Bending Elements with Variable Nodes." In Numerical Techniques for Engineering Analysis and Design, 271–78. Dordrecht: Springer Netherlands, 1987. http://dx.doi.org/10.1007/978-94-009-3653-9_31.

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Pruchnik, Florian P., and Stan A. Duraj. "Introduction to Organometallic Chemistry." In Organometallic Chemistry of the Transition Elements, 1–21. Boston, MA: Springer US, 1990. http://dx.doi.org/10.1007/978-1-4899-2076-8_1.

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Pruchnik, Florian P., and Stan A. Duraj. "Complexes Containing Six-Electron π-Ligands." In Organometallic Chemistry of the Transition Elements, 575–601. Boston, MA: Springer US, 1990. http://dx.doi.org/10.1007/978-1-4899-2076-8_10.

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Pruchnik, Florian P., and Stan A. Duraj. "Complexes Containing Seven- and Eight-Electron π-Ligands." In Organometallic Chemistry of the Transition Elements, 603–16. Boston, MA: Springer US, 1990. http://dx.doi.org/10.1007/978-1-4899-2076-8_11.

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Pruchnik, Florian P., and Stan A. Duraj. "Isocyanide Complexes." In Organometallic Chemistry of the Transition Elements, 617–45. Boston, MA: Springer US, 1990. http://dx.doi.org/10.1007/978-1-4899-2076-8_12.

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Pruchnik, Florian P., and Stan A. Duraj. "Application of Organometallic Compounds in Homogeneous Catalysis." In Organometallic Chemistry of the Transition Elements, 647–743. Boston, MA: Springer US, 1990. http://dx.doi.org/10.1007/978-1-4899-2076-8_13.

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Conference papers on the topic "Elements de transition"

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Stręk, W., W. Ryba-Romanowski, J. Legendziewicz, and B. Jeżowska-Trzebiatowska. "Excited States of Transition Elements." In 2nd International School on Excited States of Transition Elements. WORLD SCIENTIFIC, 1992. http://dx.doi.org/10.1142/9789814536639.

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ODABAS, ONUR, and NESRIN SARIGUL-KLIJN. "TRANSITION ELEMENTS BASED ON TRANSFINITE INTERPOLATION." In 34th Structures, Structural Dynamics and Materials Conference. Reston, Virigina: American Institute of Aeronautics and Astronautics, 1993. http://dx.doi.org/10.2514/6.1993-1326.

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Wu, Zhifu, Liyun Hu, and Qinglin Han. "On Family Tree of Transition Elements." In 8th International Conference on Social Network, Communication and Education (SNCE 2018). Paris, France: Atlantis Press, 2018. http://dx.doi.org/10.2991/snce-18.2018.3.

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Rath, P. K., Osvaldo Civitarese, Ivan Stekl, and Jouni Suhonen. "Uncertainties in nuclear transition matrix elements for neutrinoless ββ decay." In WORKSHOP ON CALCULATION OF DOUBLE-BETA-DECAY MATRIX ELEMENTS (MEDEX '11). AIP, 2011. http://dx.doi.org/10.1063/1.3671043.

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Sun, Tao-Heng, M. K. Kim, and E. L. Hahn. "Rotary echo measurement of dipole transition matrix elements." In Conference on Lasers and Electro-Optics. Washington, D.C.: OSA, 1985. http://dx.doi.org/10.1364/cleo.1985.wn5.

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Harmon, Natalie, Alicia Cruz-Uribe, and Jesse Walters. "Distribution of First Row Transition Elements in Eclogites." In Goldschmidt2020. Geochemical Society, 2020. http://dx.doi.org/10.46427/gold2020.956.

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Flynn, G., and R. Jones. "Attachment line transition with 3D isolated roughness elements." In 37th Aerospace Sciences Meeting and Exhibit. Reston, Virigina: American Institute of Aeronautics and Astronautics, 1999. http://dx.doi.org/10.2514/6.1999-1018.

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Zimmermann, P. "Innershell photo-ionization of the 3d transition elements." In IV Workshop on Atomic and Molecular Physics, edited by Jozef Heldt. SPIE, 2003. http://dx.doi.org/10.1117/12.544338.

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KRÜCKEN, R., C. HUTTER, J. R. COOPER, C. J. BARTON, M. SHAWCROSS, A. APRAHAMIAN, C. W. BEAUSANG, et al. "TRANSITION MATRIX ELEMENTS IN NEUTRON-RICH FISSION FRAGMENTS." In Proceedings of the Eleventh International Symposium. WORLD SCIENTIFIC, 2003. http://dx.doi.org/10.1142/9789812795151_0016.

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Meepung, Tippawan, Panita Wannapiroon, and Prachyanun Nilsook. "Transition Elements, Enterprise Architecture for Digital Entrepreneurial University." In 2021 Research, Invention, and Innovation Congress: Innovation Electricals and Electronics (RI2C). IEEE, 2021. http://dx.doi.org/10.1109/ri2c51727.2021.9559833.

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Reports on the topic "Elements de transition"

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Selle, J. E. Calculation of binary phase diagrams between the actinide elements, rare earth elements, and transition metal elements. Office of Scientific and Technical Information (OSTI), June 1992. http://dx.doi.org/10.2172/7203729.

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Sadan, Mandy, Dan Smyer Yü, Dan Seng Lawn, David Brown, and Ronghui Zhou. Rare Earth Elements, Global Inequalities, and the ‘Just Transition’. The British Academy, June 2022. http://dx.doi.org/10.5871/just-transitions-s-i/m-s.

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Watts, R. J. Cyclometallated and cyclometalsilylated complexes of transition elements as photoredox sensitizers. Office of Scientific and Technical Information (OSTI), January 1992. http://dx.doi.org/10.2172/6923703.

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Watts, R. J. Cyclometallated and cyclometalsilylated complexes of transition elements as photoredox sensitizers. Office of Scientific and Technical Information (OSTI), January 1992. http://dx.doi.org/10.2172/5396788.

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5

Wills, J. W., and O. Eriksson. Bulk and surface electronic structure of actinide, rare earth, and transition metal elements and compounds. Office of Scientific and Technical Information (OSTI), July 1996. http://dx.doi.org/10.2172/258186.

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Watts, R. J. Cyclometallated and cyclometalsilylated complexes of transition elements as photoredox sensitizers. Progress report, October 1, 1991--November 31, 1992. Office of Scientific and Technical Information (OSTI), May 1992. http://dx.doi.org/10.2172/10138113.

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Watts, R. J. Cyclometallated and cyclometalsilylated complexes of transition elements as photoredox sensitizers. Final report, January 1, 1988--September 30, 1996. Office of Scientific and Technical Information (OSTI), December 1996. http://dx.doi.org/10.2172/656625.

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8

Decolvenaere, Elizabeth, and Ann Elisabet Wills. DENSITY FUNCTIONAL THEORY APPLIED TO TRANSITION METAL ELEMENTS AND BINARIES: DEVELOPMENT APPLICATION AND RESULTS OF THE V-DM/16 TEST SET. Office of Scientific and Technical Information (OSTI), October 2016. http://dx.doi.org/10.2172/1562832.

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Watts, R. J. Cyclometallated and cyclometalsilylated complexes of transition elements as photoredox sensitizers. Progress report for the period December 1, 1991--September 30, 1992. Office of Scientific and Technical Information (OSTI), December 1992. http://dx.doi.org/10.2172/10116518.

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Finkelstein-Shapiro, Alan, and Victoria Nuguer. Climate Policies, Labor Markets, and Macroeconomic Outcomes in Emerging Economies. Inter-American Development Bank, April 2023. http://dx.doi.org/10.18235/0004844.

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Abstract:
We study the labor market and macroeconomic effects of introducing a carbon tax in the energy sector in emerging economies (EMEs) by building a framework with equilibrium unemployment and firm entry that incorporates key elements of the distinct employment and firm structure of EMEs. Our model endogenizes the adoption of green energy-production technologies--a core element of policy discussions regarding the transition to a low-carbon economy. Calibrating the model to EME data, we show that a carbon tax fosters greater green technology adoption and increases the share of green energy produced. However, the tax leads to higher energy prices, which reduce salaried firm creation and formal employment and increase self-employment, labor participation, and unemployment. As a result, the tax generates output and welfare losses. Green technology adoption plays a key role in limiting the quantitative magnitude of these losses, while the response of self-employment is crucial to explaining the adverse labor market and macroeconomic effects of the policy. Given this finding, we show that a carbon tax coupled with a plausible reduction in the cost of becoming a formal firm can offset the adverse effects of the tax and generate a transition to a lower-carbon economy with minimal economic costs. Finally, we show that lowering green-technology adoption costs or the cost of green-energy production inputs--two alternative climate policies--reduces emissions while limiting the output and welfare costs compared to a carbon tax.
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