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Journal articles on the topic 'Eley-Rideal mechanism'

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Published: 4 June 2021
Last updated: 17 February 2022

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1

Prins, R. "Eley–Rideal, the Other Mechanism." Topics in Catalysis 61, no. 9-11 (April 11, 2018): 714–21. http://dx.doi.org/10.1007/s11244-018-0948-8.

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2

Ma, Dongwei, Qinggao Wang, Tingxian Li, Zhenjie Tang, Gui Yang, Chaozheng He, and Zhansheng Lu. "CO catalytic oxidation on Al-doped graphene-like ZnO monolayer sheets: a first-principles study." Journal of Materials Chemistry C 3, no. 38 (2015): 9964–72. http://dx.doi.org/10.1039/c5tc02071a.

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3

Zeinalipour-Yazdi, Constantinos D. "On the possibility of an Eley–Rideal mechanism for ammonia synthesis on Mn6N5+x (x = 1)-(111) surfaces." Physical Chemistry Chemical Physics 20, no. 27 (2018): 18729–36. http://dx.doi.org/10.1039/c8cp02381f.

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4

Xiang, Jinyao, Xuesen Du, Yuyi Wan, Yanrong Chen, Jingyu Ran, and Li Zhang. "Alkali-driven active site shift of fast SCR with NH3 on V2O5–WO3/TiO2 catalyst via a novel Eley–Rideal mechanism." Catalysis Science & Technology 9, no. 21 (2019): 6085–91. http://dx.doi.org/10.1039/c9cy01565e.

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The heterogeneous SCR reaction obeys the well-known Eley–Rideal mechanism or Langmuir–Hinshelwood mechanism, while fast SCR over alkali-doping catalysts follows the another “E–R” mechanism with adsorbed NO2.
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5

Yu, Yanke, Jiali Zhang, Changwei Chen, Mudi Ma, Chi He, Jifa Miao, Huirong Li, and Jinsheng Chen. "Selective catalytic reduction of NOx with NH3 over TiO2 supported metal sulfate catalysts prepared via a sol–gel protocol." New Journal of Chemistry 44, no. 32 (2020): 13598–605. http://dx.doi.org/10.1039/d0nj02647f.

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Metal sulfate catalysts exhibited high SO2 tolerance in the NH3-SCR reaction. The NH3-SCR reaction mechanism on metal sulfate catalysts should follow the Eley–Rideal mechanism.
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6

Lin, Ken-Huang, Shin-Pon Ju, Jia-Yun Li, and Hsin-Tsung Chen. "The CO oxidation mechanism on the W(111) surface and the W helical nanowire investigated by the density functional theory calculation." Physical Chemistry Chemical Physics 18, no. 4 (2016): 3322–30. http://dx.doi.org/10.1039/c5cp05681k.

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7

Lu, Zhansheng, Peng Lv, Zongxian Yang, Shuo Li, Dongwei Ma, and Ruqian Wu. "A promising single atom catalyst for CO oxidation: Ag on boron vacancies of h-BN sheets." Physical Chemistry Chemical Physics 19, no. 25 (2017): 16795–805. http://dx.doi.org/10.1039/c7cp02430d.

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8

Czelej, Kamil, Karol Cwieka, Juan C. Colmenares, and Krzysztof J. Kurzydlowski. "Atomistic insight into the electrode reaction mechanism of the cathode in molten carbonate fuel cells." Journal of Materials Chemistry A 5, no. 26 (2017): 13763–68. http://dx.doi.org/10.1039/c7ta02011b.

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The O-terminated octopolar NiO(111) is predicted to facilitate cathodic transformation of CO2 to CO32− through sequential Mars-van Krevelen and Eley-Rideal mechanisms.
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9

Li, Houqian, Junming Sun, Gengnan Li, Di Wu, and Yong Wang. "Real-time monitoring of surface acetone enolization and aldolization." Catalysis Science & Technology 10, no. 4 (2020): 935–39. http://dx.doi.org/10.1039/c9cy02339a.

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10

Rai, Sandhya, Masahiro Ehara, and U. Deva Priyakumar. "Nucleobases tagged to gold nanoclusters cause a mechanistic crossover in the oxidation of CO." Physical Chemistry Chemical Physics 17, no. 37 (2015): 24275–81. http://dx.doi.org/10.1039/c5cp04273a.

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A mechanistic crossover is observed upon using nucleobase tagged gold clusters as catalysts favoring the Eley–Rideal mechanism, over the conventional Langmuir–Hinshelwood pathway followed using pristine gold clusters during CO oxidation.
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11

Kong, Song Il, Anca Borcea, Diana Cursaru, and Dragos Ciuparu. "Kinetics of Gas Phase Synthesis of Ethyl-tert-butyl Ether (ETBE) on H3PW12O40/MCM-41 Catalyst." Revista de Chimie 69, no. 11 (December 15, 2018): 3042–47. http://dx.doi.org/10.37358/rc.18.11.6678.

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The mechanism and kinetics of gas phase synthesis of ethyl-tert-butyl ether (ETBE) in the reaction between tert-butyl alcohol (TBA) and ethanol (EtOH) were investigated performing the reaction in a continuous flow quartz reactor at different temperatures and atmospheric pressure, using a heteropoliacid catalyst with 30wt% loading, dispersed on MCM-41. The Eley-Rideal reaction mechanism was previously proposed based on experimental observations that showed the rate of ETBE increased when partial pressure of tert-butyl alcohol increased, and the partial pressure of ethanol decreased, without significant effects on product selectivity. The kinetic model based on the Eley-Rideal mechanism was proposed and successfully employed to model accurately the experimental data at three different temperatures. The apparent activation energy and the frequency factor of the etherification reaction were 39.42 kJ/mol and 1.69 x 108 mol/kg . h . bar, respectively.
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12

Camu, Esteban, Cesar Pazo, Daniel Becerra, Yoan Hidalgo-Rosa, Dayan Paez-Hernandez, Ximena Zarate, Eduardo Schott, and Nestor Escalona. "A new approach to the mechanism for the acetalization of benzaldehyde over MOF catalysts." New Journal of Chemistry 44, no. 35 (2020): 14865–71. http://dx.doi.org/10.1039/d0nj02416c.

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The benzaldehyde acetalization catalyzed by UiO-66 and UiO-66F, was carried out in a batch-type reactor at room temperature and atmospheric pressure, and the full kinetic study was performed using the Langmuir–Hinshelwood and Eley–Rideal models.
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13

Jiang, Quanguo, Jianfeng Zhang, Huajie Huang, Yuping Wu, and Zhimin Ao. "A novel single-atom catalyst for CO oxidation in humid environmental conditions: Ni-embedded divacancy graphene." Journal of Materials Chemistry A 8, no. 1 (2020): 287–95. http://dx.doi.org/10.1039/c9ta08525d.

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A termolecular Eley–Rideal (TER) mechanism is preferred for CO oxidation on Ni-DG in humid environments, and the energy barrier for the rate limiting step (2CO + O2 → OCOOCO) is only 0.34 eV.
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14

Shi, Huancong, Min Huang, Yuandong Huang, Lifeng Cui, Linna Zheng, Mingqi Cui, Linhua Jiang, Hussameldin Ibrahim, and Paitoon Tontiwachwuthikul. "Eley–Rideal model of heterogeneous catalytic carbamate formation based on CO 2 –MEA absorptions with CaCO 3 , MgCO 3 and BaCO 3." Royal Society Open Science 6, no. 5 (May 2019): 190311. http://dx.doi.org/10.1098/rsos.190311.

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The mechanism was proposed of heterogeneous catalytic CO 2 absorptions with primary/secondary amines involving ‘catalytic carbamate formation’. Compared with the non-catalytic ‘Zwitterion mechanism’, this Eley–Rideal model was proposed for CO 2 + RR′NH with MCO 3 (M = Ca, Mg, and Ba) with four elementary reaction steps: (B1) amine adsorption, (B2) Zwitterion formation, (B3) carbamate formation, and (B4) carbamate desorption. The rate law if determining step of each elementary step was generated based on ‘steady-state approximation’. Furthermore, the solid chemicals were characterized by SEM and BET, and this rate model was verified with 39 sets of experimental datasets of catalytic CO 2 –MEA absorptions with the existence of 0–25 g CaCO 3 , MgCO 3 and BaCO 3 . The results indicated that the rate-determining step was B1 as amine adsorption onto solid surface, which was pseudo-first-order for MEA. This was the first time that the Eley–Rideal model had been adopted onto the reactions of CO 2 + primary/secondary amines over alkaline earth metal carbonate (MCO 3 ).
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15

Kuipers, E. W., A. Vardi, A. Danon, and A. Amirav. "Surface-molecule proton transfer: A demonstration of the Eley-Rideal mechanism." Physical Review Letters 66, no. 1 (January 7, 1991): 116–19. http://dx.doi.org/10.1103/physrevlett.66.116.

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16

Gillespie, Ralph D., Robert L. Burwell, and Tobin J. Marks. "Isotopic exchange between H2 and D2 by the Rideal-Eley mechanism." Catalysis Letters 9, no. 5-6 (September 1991): 363–68. http://dx.doi.org/10.1007/bf00764827.

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17

Jackson, Bret, Mats Persson, and Bruce D. Kay. "Quantum mechanical study of H(g)+Cl–Au(111): Eley–Rideal mechanism." Journal of Chemical Physics 100, no. 10 (May 15, 1994): 7687–95. http://dx.doi.org/10.1063/1.466862.

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18

Koleske, D. D., S. M. Gates, and B. Jackson. "Atomic H abstraction of surface H on Si: An Eley–Rideal mechanism?" Journal of Chemical Physics 101, no. 4 (August 15, 1994): 3301–9. http://dx.doi.org/10.1063/1.467577.

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19

Galván Muciño, Gabriel E., Rubi Romero, Armando Ramírez, María Jesús Ramos, Ramiro Baeza-Jiménez, and Reyna Natividad. "Kinetics of Transesterification of Safflower Oil to Obtain Biodiesel Using Heterogeneous Catalysis." International Journal of Chemical Reactor Engineering 14, no. 4 (August 1, 2016): 929–38. http://dx.doi.org/10.1515/ijcre-2015-0108.

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Abstract The kinetics of the transesterification of safflower oil and methanol catalyzed by K2O/NaX was studied and modeled. The influence of the oil-methanol initial molar ratio and amount of catalyst were investigated to achieve a maximum triglycerides conversion (99 %) and a final methyl esters content of 94 % ±1. A kinetic model based on an Eley–Rideal mechanism was found to best fit the experimental data when assuming methanol adsorption as determining step. Other models derived from Langmuir – Hinshelwood – Hougen –Watson (LHHW) mechanisms were rejected based on statistical analysis, mechanistic considerations and physicochemical interpretation of the estimated parameters.
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20

Kocemba, Ireneusz, Sławomir Szafran, Jacek Rynkowski, and Tadeusz Paryjczak. "Relationship between the Catalytic and Detection Properties of SnO2 and Pt/SnO2 Systems." Adsorption Science & Technology 20, no. 9 (November 2002): 897–905. http://dx.doi.org/10.1260/02636170260555804.

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Semiconductor gas sensors based on metal oxides have been widely accepted as an important tool for the detection of different gases in air. An understanding of all the mechanisms related to such detection is essential in order to improve the sensitivity and selectivity of these gas detectors. This paper considers the mechanism of detection by semiconductor oxide gas sensors in terms of catalytic reactions described by Rideal–Eley and Langmuir–Hinshelwood mechanisms. Some relationships were discussed between the catalytic and detection properties of SnO2 and Pt/SnO2 systems used on the one hand as catalysts of low-temperature CO oxidation and on the other hand as sensors of CO in air.
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21

Farebrother, Adam J., Anthony J. H. M. Meijer, David C. Clary, and Andrew J. Fisher. "Formation of molecular hydrogen on a graphite surface via an Eley–Rideal mechanism." Chemical Physics Letters 319, no. 3-4 (March 2000): 303–8. http://dx.doi.org/10.1016/s0009-2614(00)00128-7.

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22

Rutigliano, M., M. Cacciatore, and G. D. Billing. "Hydrogen atom recombination on graphite at 10 K via the Eley–Rideal mechanism." Chemical Physics Letters 340, no. 1-2 (May 2001): 13–20. http://dx.doi.org/10.1016/s0009-2614(01)00366-9.

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23

Quan, Jiamei, Fahdzi Muttaqien, Takahiro Kondo, Taijun Kozarashi, Tomoyasu Mogi, Takumi Imabayashi, Yuji Hamamoto, et al. "Vibration-driven reaction of CO2 on Cu surfaces via Eley–Rideal-type mechanism." Nature Chemistry 11, no. 8 (June 24, 2019): 722–29. http://dx.doi.org/10.1038/s41557-019-0282-1.

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24

Jackson, Bret, and Mats Persson. "Vibrational excitation in recombinative desorption of hydrogen on metal surfaces: Eley-Rideal mechanism." Surface Science 269-270 (May 1992): 195–200. http://dx.doi.org/10.1016/0039-6028(92)91249-b.

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25

Dai, Guoliang, Lei Chen, and Xin Zhao. "Tungsten-Embedded Graphene: Theoretical Study on a Potential High-Activity Catalyst toward CO Oxidation." Materials 11, no. 10 (September 28, 2018): 1848. http://dx.doi.org/10.3390/ma11101848.

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The oxidation mechanism of CO on W-embedded graphene was investigated by M06-2X density functional theory. Two models of tungsten atom embedded in single and double vacancy (W-SV and W-DV) graphene sheets were considered. It was found that over W-SV-graphene and W-DV-graphene, the oxidation of CO prefers to Langmuir-Hinshelwood (LH) and Eley-Rideal (ER) mechanism, respectively. The two surfaces exhibit different catalytic activity during different reaction stages. The present results imply that W-embedded graphene is a promising catalyst for CO oxidation, which provides a useful reference for the design of a high-efficiency catalyst in detecting and removing of toxic gases.
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26

KHALID, M., A. U. QAISRANI, and M. K. KHAN. "CO–NO CATALYTIC SURFACE REACTION ON BODY-CENTERED CUBIC STRUCTURE: MONTE CARLO STUDY." International Journal of Modern Physics C 16, no. 08 (August 2005): 1279–91. http://dx.doi.org/10.1142/s012918310500790x.

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A Monte Carlo Simulation study of the monomer dimer ( CO–NO ) heterogeneous catalytic reaction on body-centered cubic structure (BCC) is presented. The effect of Eley–Rideal (ER), diffusion of nitrogen and carbon monoxide on the phase diagram is investigated. The steady reactive state is observed while using Langmuir–Hinsehelwood (LH) mechanism. Whenever the ER mechanism is included in our simulation, the production of CO 2 starts as soon as y CO departs from zero, which is consistent with the experimental results. The ER mechanism does not affect the production of N 2. The effect of diffusion of CO and N are found very little on the steady state reactive region where the concentration of CO is very high.
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27

Williams, E. R., G. C. Jones, L. Fang, R. N. Zare, B. J. Garrison, and D. W. Brenner. "Ion pickup of large, surface-adsorbed molecules: a demonstration of the Eley-Rideal mechanism." Journal of the American Chemical Society 114, no. 9 (April 1992): 3207–10. http://dx.doi.org/10.1021/ja00035a006.

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28

Ahmad, Waqar. "NO—CO—O 2 Reaction on a Metal Catalytic Surface using Eley—Rideal Mechanism." Chinese Physics Letters 25, no. 10 (October 2008): 3728–31. http://dx.doi.org/10.1088/0256-307x/25/10/057.

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29

Chaudhari, Ajay, Ching-Cher Sanders Yan, and Shyi-Long Lee. "2A + B2 →2AB catalytic reaction over rough surface: the effect of Eley-Rideal mechanism." Catalysis Today 97, no. 1 (October 2004): 89–92. http://dx.doi.org/10.1016/j.cattod.2004.06.139.

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30

Du, Wen, Li Bao Yin, Yu Qun Zhuo, Qi Sheng Xu, Liang Zhang, and Chang He Chen. "Factors Affecting Mercury Oxidation by SCR Catalysts." Advanced Materials Research 986-987 (July 2014): 755–60. http://dx.doi.org/10.4028/www.scientific.net/amr.986-987.755.

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The application of selective catalytic reduction (SCR) system may affect mercury speciation in coal-combustion flue gas. The factors affecting mercury oxidation efficiency by SCR catalysts have been evaluated in this research. The influencing factors investigated included hydrogen chloride (HCl), sulfur dioxide (SO2), ammonia (NH3) injection rate and space velocity. HCl had been found to promote mercury oxidation significantly. The Eley-Rideal mechanism was proven to be suitable to explain the reaction of Hg0 and HCl. NH3 injection had a strong negative effect to mercury oxidation. The deactivation of aged SCR catalysts was mainly due to loss of active sites.
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31

Gao, Ying, Wei Chen, Jun Li, Hong Qi Liu, and Zhen Huo. "Study on Identification Method of Chemical Reaction Kinetic Parameters in Heavy Duty Diesel's SCR Catalytic Converter." Advanced Materials Research 864-867 (December 2013): 271–77. http://dx.doi.org/10.4028/www.scientific.net/amr.864-867.271.

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Chemical reaction kinetic parameters are key factors to influence the NOx conversion in heavy duty diesel's SCR catalytic converter. Therefore the identification method of SCR chemical reaction kinetic parameters is studied in this paper. Based on the software AVL BOOST , SCR catalytic reaction model and its transient rate equations are established according to Eley-rideal mechanism. The identification method of kinetic parameters is studied applying AVL Design Explorer. The simulation model shows good agreement with experiment after identification. The result shows that the identification method is reasonable and feasible to ensure the reliability of catalytic converter model.
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32

Brandt, M., F. Kuhlmann, T. Greber, N. Böwering, and U. Heinzmann. "Interaction of gas-phase oriented N2O with lithium metal: evidence for an Eley–Rideal mechanism." Surface Science 439, no. 1-3 (September 1999): 49–58. http://dx.doi.org/10.1016/s0039-6028(99)00692-5.

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33

Khan, K. M., and W. Ahmad. "NO-CO catalytic reaction on a square lattice: the effect of the Eley-Rideal mechanism." Journal of Physics A: Mathematical and General 35, no. 12 (March 15, 2002): 2713–23. http://dx.doi.org/10.1088/0305-4470/35/12/302.

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34

Mai, J., and W. von Niessen. "The influence of physisorption and the Eley-Rideal mechanism on a surface reaction: CO + O2." Chemical Physics 156, no. 1 (September 1991): 63–69. http://dx.doi.org/10.1016/0301-0104(91)87037-v.

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35

Chairuddin, Z. B., M. S. Perdani, D. N. Putri, T. S. Utami, and H. Hermansyah. "Kinetic Model Based on Eley-Rideal and Irreversible Mechanism for Multilevel Reaction of Biodiesel Synthesis." IOP Conference Series: Earth and Environmental Science 673, no. 1 (February 1, 2021): 012006. http://dx.doi.org/10.1088/1755-1315/673/1/012006.

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36

Saeed, Muhammad, Muhammad Amjed, Attaul Haq, Muhammad Usman, and Shahid Adeel. "Synthesis and characterization of nickel oxide and evaluation of its catalytic activities for degradation of methyl orange in aqueous medium." Applied Chemical Engineering 3, no. 2 (November 4, 2020): 47. http://dx.doi.org/10.24294/ace.v3i2.737.

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This study focuses on synthesis of nickel oxide catalyst and exploration of its catalytic activities for degradation of methyl orange in aqueous medium. Nickel oxide was prepared sole-gel method using nickel nitrate haxahydrate and citric acid as precursor materials. X-ray diffractometry and scanning electron microscopy were used for characterization of prepared nickel oxide particles. The prepared particles were used as the catalysts for the degradation of Methyl Orange in aqueous medium. The effects of different parameters on degradation of methyl orange were investigated. The degradation of methyl orange followed the Eley-Rideal (E-R) mechanism. The apparent activation energies for degradation of methyl orange determined was found as 36.4 kJ/mol.
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37

Zhang, Xilin, Zhansheng Lu, Guoliang Xu, Tianxing Wang, Dongwei Ma, Zongxian Yang, and Lin Yang. "Single Pt atom stabilized on nitrogen doped graphene: CO oxidation readily occurs via the tri-molecular Eley–Rideal mechanism." Physical Chemistry Chemical Physics 17, no. 30 (2015): 20006–13. http://dx.doi.org/10.1039/c5cp01922b.

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38

Buntin, Steven A. "H atom abstraction of D adsorbed on Si(100): dynamical evidence for an Eley-Rideal mechanism." Chemical Physics Letters 278, no. 1-3 (October 1997): 71–76. http://dx.doi.org/10.1016/s0009-2614(97)01030-0.

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39

Xu, Guoliang, Ran Wang, Feng Yang, Dongwei Ma, Zongxian Yang, and Zhansheng Lu. "CO oxidation on single Pd atom embedded defect-graphene via a new termolecular Eley-Rideal mechanism." Carbon 118 (July 2017): 35–42. http://dx.doi.org/10.1016/j.carbon.2017.03.034.

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40

Fu, Guangying, Junwen Chen, Yuqian Liang, Rui Li, Xiaobo Yang, and Jiuxing Jiang. "Cu-IM-5 as the Catalyst for Selective Catalytic Reduction of NOx with NH3: Role of Cu Species and Reaction Mechanism." Catalysts 11, no. 2 (February 7, 2021): 221. http://dx.doi.org/10.3390/catal11020221.

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The role of Cu species in Cu ion-exchanged IM-5 zeolite (Cu-IM-5) regarding the performance in selective catalytic reduction (SCR) of NOx with NH3 (NH3-SCR) and the reaction mechanism was studied. Based on H2 temperature-programmed reduction (H2-TPR) and electron paramagnetic resonance (EPR) results, Cu–O–Cu and isolated Cu species are suggested as main Cu species existing in Cu-IM-5 and are active for SCR reaction. Cu–O–Cu species show a good NH3-SCR activity at temperatures below 250 °C, whereas their NH3 oxidation activity at higher temperatures hinders the SCR performance. At low temperatures, NH4NO3 and NH4NO2 are key reaction intermediates. In situ diffuse reflectance infrared Fourier transform spectroscopy (DRIFTS) suggests a mixed Eley–Rideal (E–R) and Langmuir–Hinshelwood (L–H) mechanism over Cu-IM-5 at low temperatures.
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41

Shen, Bo Xiong, Ning Zhao, Ting Liu, Feng Peng Wu, and Chen Zuo. "Modeling and Simulation of Selective Catalytic Reduction for Flue Gas Denitration in Power Plants." Advanced Materials Research 383-390 (November 2011): 6580–86. http://dx.doi.org/10.4028/www.scientific.net/amr.383-390.6580.

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Based on Eley-Rideal kinetic mechanism, one dimensional mathematical model for selective catalytic reduction reaction was established, in order to simulate the SCR process in the catalyst channel. The thermal effect on the reaction and the side effect of ammonia oxidation in the channel were considered simultaneously in the modeling. The model was testified to be reliable by compared with the experimental data. By the model, the concentration and temperature distributions in the channel were simulated. The effects of catalyst structure parameters, such as the pitch, the shape of catalyst channel and the monolithic catalyst type, on de-NOX efficiency were studied emphatically. The simulation results would be as an important reference for the design of SCR catalyst in the practical application.
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42

Meijer, Anthony J. H. M., Adam J. Farebrother, and David C. Clary. "Isotope Effects in the Formation of Molecular Hydrogen on a Graphite Surface via an Eley−Rideal Mechanism." Journal of Physical Chemistry A 106, no. 39 (October 2002): 8996–9008. http://dx.doi.org/10.1021/jp020983h.

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43

Xiao, You Hong, Wei Zheng, Yu Shan Jin, and Xin Na Tian. "Investigation on the Simulation of Control Strategy for a SCR System." Advanced Materials Research 860-863 (December 2013): 770–73. http://dx.doi.org/10.4028/www.scientific.net/amr.860-863.770.

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In this paper, the model of SCR after-treatment system is established by the software MATLAB and the control strategy for the system is studied also. Based on Eley-rideal mechanism, four major chemical reactions including the adsorption of ammonia, desorption of ammonia, selective catalytic reduction and oxidation of adsorbed ammonia are selected to study the SCR control strategy. Based on the energy conservation law, the equation calculating the temperature of the layered model is derived. Combined with the equations of chemical reaction process, a mathematical model of SCR catalytic converter is established. To achieve a high NOXreduction efficiency of SCR system, the reasonable and efficacious control strategies for the micro-element models of SCR catalytic is simulated, which including the feedback control strategy based on the feed-forward controller and the PID control strategy.
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44

Zavrazhnov, Sergey, Anton Esipovich, Sergey Zlobin, Artem Belousov, and Andrey Vorotyntsev. "Mechanism Analysis and Kinetic Modelling of Cu NPs Catalysed Glycerol Conversion into Lactic Acid." Catalysts 9, no. 3 (March 2, 2019): 231. http://dx.doi.org/10.3390/catal9030231.

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Mechanism analysis and kinetic modeling of glycerol conversion into lactic acid in the alkaline media with and without heterogeneous catalyst Cu NPs are reported. The reaction pathways were determined in agreement with the experimental results and comprise several types of reactions, namely dehydrogenation, hydrogenolysis, dehydration and C–C cleavage. Experimental concentration-time profiles were obtained in a slurry batch reactor at different glycerol, NaOH and Cu NPs concentrations in a temperature range of 483–518 K. Power law, Langmuir–Hinshelwood (LH) and Eley–Rideal (ER) models were chosen to fit the experimental data. The proposed reaction pathways and obtained kinetic model adequately describe the experimental data. The reaction over Cu NPs catalyst in the presence of NaOH proceeds with a significantly lower activation barrier (Ea = 81.4 kJ∙mol−1) compared with the only homogeneous catalytic conversion (Ea = 104.0 kJ∙mol−1). The activation energy for glycerol hydrogenolysis into 1,2-propanediol on the catalyst surface without adding hydrogen is estimated of 102.0 kJ∙mol−1. The model parameters obtained in this study would be used to scale an industrial unit in a reactor modeling.
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45

Meijer, Anthony J. H. M., Andrew J. Fisher, and David C. Clary. "Surface Coverage Effects on the Formation of Molecular Hydrogen on a Graphite Surface via an Eley−Rideal Mechanism." Journal of Physical Chemistry A 107, no. 50 (December 2003): 10862–71. http://dx.doi.org/10.1021/jp035809n.

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46

Xi, Ming. "Evidence for an Eley–Rideal mechanism in the addition of hydrogen atoms to unsaturated hydrocarbons on Cu(111)." Journal of Vacuum Science & Technology B: Microelectronics and Nanometer Structures 10, no. 6 (November 1992): 2440. http://dx.doi.org/10.1116/1.586037.

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Cheng, Cheng, Xilin Zhang, Mingyang Wang, Shiyan Wang, and Zongxian Yang. "Single Pd atomic catalyst on Mo2CO2 monolayer (MXene): unusual activity for CO oxidation by trimolecular Eley–Rideal mechanism." Physical Chemistry Chemical Physics 20, no. 5 (2018): 3504–13. http://dx.doi.org/10.1039/c7cp07161b.

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Kessels, W. M. M., A. H. M. Smets, and M. C. M. van de Sanden. "The a-Si:H growth mechanism and the role of H abstraction from the surface by SiH3 radicals via an Eley–Rideal mechanism." Journal of Non-Crystalline Solids 338-340 (June 2004): 27–31. http://dx.doi.org/10.1016/j.jnoncrysol.2004.02.015.

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Urchaga, Patrick, Stève Baranton, Christophe Coutanceau, and Gregory Jerkiewicz. "Evidence of an Eley–Rideal Mechanism in the Stripping of a Saturation Layer of Chemisorbed CO on Platinum Nanoparticles." Langmuir 28, no. 36 (August 29, 2012): 13094–104. http://dx.doi.org/10.1021/la302388p.

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Juaristi, J. I., E. Díaz, G. A. Bocan, R. Díez Muiño, M. Alducin, and M. Blanco-Rey. "Angular distributions and rovibrational excitation of N2 molecules recombined on N-covered Ag(111) by the Eley–Rideal mechanism." Catalysis Today 244 (April 2015): 115–21. http://dx.doi.org/10.1016/j.cattod.2014.06.028.

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