Academic literature on the topic 'Elimination reactions'

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Journal articles on the topic "Elimination reactions"

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WESTWELL, A. D., and J. M. J. WILLIAMS. "ChemInform Abstract: Elimination and Addition-Elimination Reactions." ChemInform 28, no. 29 (2010): no. http://dx.doi.org/10.1002/chin.199729292.

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Knipe, A. C. "ChemInform Abstract: Elimination Reactions." ChemInform 31, no. 16 (2010): no. http://dx.doi.org/10.1002/chin.200016305.

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Graulich, Nicole, Henning Hopf, and Peter R. Schreiner. "Heuristic Chemistry-Elimination Reactions." Chemistry - An Asian Journal 6, no. 12 (2011): 3180–88. http://dx.doi.org/10.1002/asia.201100110.

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Knipe, A. C. "ChemInform Abstract: Elimination Reactions." ChemInform 33, no. 50 (2010): no. http://dx.doi.org/10.1002/chin.200250263.

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KNIPE, A. C. "ChemInform Abstract: Elimination Reactions." ChemInform 28, no. 30 (2010): no. http://dx.doi.org/10.1002/chin.199730255.

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THIBBLIN, A. "ChemInform Abstract: Elimination Reactions." ChemInform 24, no. 2 (2010): no. http://dx.doi.org/10.1002/chin.199302307.

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O'FERRALL, R. A. M. "ChemInform Abstract: Elimination Reactions." ChemInform 22, no. 33 (2010): no. http://dx.doi.org/10.1002/chin.199133306.

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Meng, Qingshui, and Alf Thibblin. "Mechanisms of solvolytic elimination reactions of tertiary substrates: stereospecific 1,2-elimination reactions." Journal of the Chemical Society, Perkin Transactions 2, no. 7 (1999): 1397–404. http://dx.doi.org/10.1039/a901296f.

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Viola, Luis, and Rita H. de Rossi. "Effect of cyclodextrin on elimination reactions." Canadian Journal of Chemistry 77, no. 5-6 (1999): 860–67. http://dx.doi.org/10.1139/v99-085.

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The reaction of 1-bromo-2-X-2-(Y-phenyl) ethane derivatives (1: X = Y = H; 2: X = Ph, Y = H; 3: X = H, Y = 4-Ac; 4: X = H, Y = 3-NO2; 5: X = H, Y = 4-NO2; 6: X = H, Y = 3-Me; 7: X = H, Y = 4-Me) in basic solution was studied, and in most cases, only the elimination product is formed. Only (2-bromo-1-phenylethyl)benzene, 2, yielded significant substitution product, and this yield decreased with the concentration of HO-. Addition of cyclodextrin (β-CD) diminished (about half for 0.02 M cyclodextrin concentration) the reaction rate of all substrates but 4 and 5. In the latter two cases, the rate
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Bury, Adrian, Harold A. Earl, and Charles J. M. Stirling. "Elimination and addition reactions. Part 44. Eliminative fission of cycloalkanols." Journal of the Chemical Society, Perkin Transactions 2, no. 9 (1987): 1281. http://dx.doi.org/10.1039/p29870001281.

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Dissertations / Theses on the topic "Elimination reactions"

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Amyes, T. L. "Mechanisms of carboxyl-activated elimination reactions." Thesis, University of Cambridge, 1986. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.383698.

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Yang, Shuo. "Ammonia elimination from protonated nucleobases." Diss., Columbia, Mo. : University of Missouri-Columbia, 2007. http://hdl.handle.net/10355/4977.

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Thesis (M.S.)--University of Missouri-Columbia, 2007.<br>The entire dissertation/thesis text is included in the research.pdf file; the official abstract appears in the short.pdf file (which also appears in the research.pdf); a non-technical general description, or public abstract, appears in the public.pdf file. Title from title screen of research.pdf file (viewed on May 27, 2009) Typescript. Includes bibliographical references.
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Davison, Edwin Christopher. "Tandem reactions involving hydroxylamine-alkyne cyclisations." Thesis, University of Cambridge, 1995. https://www.repository.cam.ac.uk/handle/1810/273122.

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Volta, Luca. "Evaluation of strain effects in elimination and addition reactions." Thesis, University of Sheffield, 1998. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.298198.

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Orme, Christopher Paul. "Hydride complexes of ruthenium(II) : elimination, addition and substitution reactions." Thesis, University of York, 1994. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.241016.

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Florence, Michael R. "The development of a novel protecting group for natural product synthesis." Thesis, University of Edinburgh, 1987. http://hdl.handle.net/1842/13831.

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Zeng, Xiaofeng. "Mechanisms for Solvolytic Elimination and Substitution Reactions Involving Short-lived Carbocation Intermediates." Doctoral thesis, Uppsala University, Organic Chemistry, 2002. http://urn.kb.se/resolve?urn=urn:nbn:se:uu:diva-2565.

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<p>Solvolysis reactions of a range of tertiary substrates in largely aqueous solvents were studied in such respects as β-deuterium kinetic isotope effects, linear free energy relationships and stereochemistry.</p><p>Solvolysis of the fluorene derivatives 9-methyl–9-(2´-X-2´-propyl)fluorene (<b>1-X,</b> X = Cl, Br, OOCCF<sub>3</sub>) involves a very short-lived carbocation intermediate. The fraction of alkene is increased by addition of general bases, which can be expressed by a Brφnsted parameter β = 0.07. The kinetic deuterium isotope effects vary with solvent composition in a way which is no
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Burger, Barbara J. Bercaw John E. "Olefin insertion and [beta]-elimination reactions of permethylniobocene olefin hydride and permethylscandocene alkyl complexes /." Diss., Pasadena, Calif. : California Institute of Technology, 1987. http://resolver.caltech.edu/CaltechETD:etd-01162008-111854.

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Hayes, Roger Nicholas. "A study of some gas phase nucleophilic substitution reactions of carbon, silicon and boron by ion cyclotron resonance mass spectrometry /." Title page, table of contents and summary only, 1985. http://web4.library.adelaide.edu.au/theses/09PH/09phH418.pdf.

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Crumpton, Dawn M. "Mechanistic studies of carbon-carbon and carbon-hydrogen reductive elimination reactions from platinum(IV) complexes /." Thesis, Connect to this title online; UW restricted, 2000. http://hdl.handle.net/1773/8484.

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Books on the topic "Elimination reactions"

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Royal Society of Chemistry (Great Britain) and Open University, eds. Chemical kinetics and mechanism. 2nd ed. Royal Society of Chemistry, 2006.

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Schroeder, Grzegorz. Wpływ cyklicznych polieterów na kinetykę reakcji eliminacji halogenowodorów od niektórych diarylohalogenoetanów w alkoholach. Wydawn. Nauk. Uniwersytetu im. Adama Mickiewicza w Poznaniu, 1987.

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Reakcje beta-dehaloalkoksykarbonylowania. Wydawn. Politechniki Warszawskiej, 1987.

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Organic chemistry: Block 3: Understanding reactions : Substitution: pathways and products : Elimination and addition: pathways and products : Making drugs. 3rd ed. Open University, 1996.

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Null, Gary. No more allergies: Identifying and eliminating allergies and sensitivity reactions to everything in your environment. Villard Books, 1992.

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Office, General Accounting. Rail safety: States' reaction to proposed elimination of inspection funding : fact sheet for the chairman, Subcommittee on Commerce, Transportation and Tourism, Committee on Energy and Commerce, House of Representatives. The Office, 1987.

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Elimination Reactions. Hassell Street Press, 2021.

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Lefcourt, Michael Aaron *. The Al(℗ rP)(SiH r) complex and the photoreversible oxidative-addition/reductive-elimination reactions Al(℗ rP)(SiH r)<->SiH rAlH. 1989.

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Lee, Jeehiun K., M. Lundberg B. G, and J.A. Smiley C. Stanton D.J. Tantillo N. W. Orotidine Monophosphate Decarboxylase: A Mechanistic Dialogue. Springer, 2010.

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Hagen, A. P. Inorganic Reactions and Methods: The Formation of Bonds to Transition Metals, Oxidative Additions and Reductive Eliminations, Insertion Reactions and (Inorganic Reactions and Methods). Vch Pub, 1997.

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Book chapters on the topic "Elimination reactions"

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Birsa, M. L. "Elimination Reactions." In Organic Reaction Mechanisms Series. John Wiley & Sons, Ltd, 2011. http://dx.doi.org/10.1002/9780470975800.ch10.

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Birsa, M. L. "Elimination Reactions." In Organic Reaction Mechanisms · 2008. John Wiley & Sons, Ltd, 2011. http://dx.doi.org/10.1002/9780470979525.ch10.

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Birsa, M. L. "Elimination Reactions." In Organic Reaction Mechanisms Series. John Wiley & Sons, Ltd, 2011. http://dx.doi.org/10.1002/9781119972471.ch10.

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Birsa, M. L. "Elimination Reactions." In Organic Reaction Mechanisms Series. John Wiley & Sons, Ltd, 2014. http://dx.doi.org/10.1002/9781118560273.ch10.

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Knipe, A. C. "Elimination Reactions." In Organic Reaction Mechanisms 2001. John Wiley & Sons, Ltd, 2006. http://dx.doi.org/10.1002/0470866748.ch10.

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Birsa, M. L. "Elimination Reactions." In Organic Reaction Mechanisms Series. John Wiley & Sons, Ltd, 2012. http://dx.doi.org/10.1002/9781119941910.ch10.

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Knipe, A. C. "Elimination Reactions." In Organic Reaction Mechanisms Series. John Wiley & Sons, Ltd, 2006. http://dx.doi.org/10.1002/0470022051.ch10.

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Birsa, M. L. "Elimination Reactions." In Organic Reaction Mechanisms · 2014. John Wiley & Sons, Ltd, 2018. http://dx.doi.org/10.1002/9781118941829.ch9.

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Birsa, M. L. "Elimination Reactions." In Organic Reaction Mechanisms · 2006. John Wiley & Sons, Ltd, 2010. http://dx.doi.org/10.1002/9780470669587.ch10.

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Li, Jie Jack. "Kemp elimination." In Name Reactions. Springer Berlin Heidelberg, 2003. http://dx.doi.org/10.1007/978-3-662-05336-2_159.

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Conference papers on the topic "Elimination reactions"

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Porto, Caio M., and Nelson H. Morgon. "Quantum Tunneling and Reaction Rates in Selenoxides and Sulfoxides Elimination." In VIII Simpósio de Estrutura Eletrônica e Dinâmica Molecular. Universidade de Brasília, 2020. http://dx.doi.org/10.21826/viiiseedmol202062.

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Selenoxides and sulfoxides elimination reactions are important, not only to Organic Chemistry synthesis, but also to other areas, as Biochemistry. These reactions were studied, using direct dynamics calculations, at the canonical variational theory (CVT) and small curvature tunneling (SCT) level. The calculated rate constants for the selenoxide reaction were in good agreement with experimental data, 8.83 × 10-5 s -1 and 3.20 × 10-5 s -1 , respectively. The rate constants for the sulfoxide reaction are very small at 37°C, namely 2.43 × 10-9 , and there is also a significant tunneling correction
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Eldeeb, Mazen A., and Malshana Wadugurunnehalage. "Chemical Kinetic Model Reduction and Analysis of Tetrahydrofuran Combustion Using Stochastic Species Elimination." In ASME 2020 Power Conference collocated with the 2020 International Conference on Nuclear Engineering. American Society of Mechanical Engineers, 2020. http://dx.doi.org/10.1115/power2020-16583.

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Abstract In this work, a chemical kinetic modeling study of the high-temperature ignition and laminar flame behavior of Tetrahydrofuran (THF), a promising second-generation transportation biofuel, is presented. Stochastic Species Elimination (SSE) model reduction approach (Eldeeb and Akih-Kumgeh, Proceedings of ASME Power Conference 2018) is implemented to develop multiple skeletal versions of a detailed chemical kinetic model of THF (Fenard et al., Combustion and Flame, 2018) based on ignition delay time simulations at various pressures and temperature ranges. The detailed THF model contains
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Eldeeb, Mazen A., and Benjamin Akih-Kumgeh. "Reduced Chemical Kinetic Models Using Alternate and Stochastic Species Elimination." In ASME 2018 Power Conference collocated with the ASME 2018 12th International Conference on Energy Sustainability and the ASME 2018 Nuclear Forum. American Society of Mechanical Engineers, 2018. http://dx.doi.org/10.1115/power2018-7242.

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This work extends the species sensitivity method of model reduction known as Alternate Species Elimination (ASE) to a stochastic version. The new Stochastic Species Elimination (SSE) approach allows for a linear reduction in the number of species retained in the course of reduction. It improves the computational cost and offers flexibility to the user in terminating the reduction process when an acceptable model size is attained. Larger chemical kinetic models, such as the recent literature model of n-octanol, are approached with the SSE method coupled with multiple species sampling. This furt
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Limpitakis, N. C., and C. Genigeorgis. "Elimination of cross reactions during detection of Salmonella spp., with commercial ELISA kits." In Fourth International Symposium on the Epidemiology and Control of Salmonella and Other Food Borne Pathogens in Pork. Iowa State University, Digital Press, 2001. http://dx.doi.org/10.31274/safepork-180809-1171.

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Wojtyra, Marek, and Janusz Fra˛czek. "A Comparison of Various Methods of Redundant Constraints Handling in Multibody System Simulations." In ASME 2011 International Design Engineering Technical Conferences and Computers and Information in Engineering Conference. ASMEDC, 2011. http://dx.doi.org/10.1115/detc2011-48144.

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When redundant constraints are present in a rigid body mechanism, only selected joint reactions can be determined uniquely, whereas the other cannot. Analytic criteria and numerical methods of finding joints with uniquely solvable reactions are available. In this paper the problem of joint reactions solvability is examined from the point of view of numerical methods frequently used for redundant constrains handling in practical simulations. Three methods are discussed: elimination of redundant constraints, pseudoinverse-based calculations and the augmented Lagrangian method. In each method the
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Zhou, Apeng, Shirin Jouzdani, and Ben Akih-Kumgeh. "Reduced Chemical Kinetic Models of C1 - C4 Alcohols Using the Alternate Species Elimination Approach." In ASME 2019 Internal Combustion Engine Division Fall Technical Conference. American Society of Mechanical Engineers, 2019. http://dx.doi.org/10.1115/icef2019-7114.

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Abstract This study presents four separate reduced chemical kinetic models of methanol/ethanol, propanol isomers, n- and iso-butanol, and n- and s-butanol isomers, derived from a comprehensive chemical kinetic model of C1-C5 alcohols using the Alternate Species Elimination approach. It is motivated by complexity of the detailed model (comprising 600 species and 4100 elementary reactions) and the need for simpler kinetic models for analysis of combustion of smaller alcohols. The reduced models are obtained on the basis of ignition delay time simulations with imposed thresholds on the resulting
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Goldthwaite, Donald, Mohamad Metghalchi, and James C. Keck. "Refinement of Reduced Chemical Mechanisms for the Modeling of the Rapid Compression Combustion of Heptane and Octane." In ASME 2005 International Mechanical Engineering Congress and Exposition. ASMEDC, 2005. http://dx.doi.org/10.1115/imece2005-81368.

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Reduced chemical mechanisms for heptane and octane, originally developed by Keck and Hu, have been shown to give excellent agreement with experimental ignition delay times obtained using a rapid compression machine. These mechanisms consist of 20 species and 41 reactions with 10 reactions detailing the initial breakdown sequence of the alkane, 2 global reactions leading to the formation of end products, and the remaining reactions specifying the path to equilibrium products. Until recently, the success of these mechanisms in matching experimental data rested in large part on the fine tuning of
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Xu, Zhengxin, Mianzhi Wang, Jie Hou, et al. "Development and Validation of a Reduced Toluene/N-Heptane/N-Butanol Mechanism for Combustion and Emission Prediction in IC Engine." In ASME 2015 Internal Combustion Engine Division Fall Technical Conference. American Society of Mechanical Engineers, 2015. http://dx.doi.org/10.1115/icef2015-1157.

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The present study proposed a reduced mechanism for a fuel blend of toluene reference fuel (TRF, toluene/n-heptane) and n-butanol for modeling the combustion and soot formation processes of n-butanol/diesel blend fuel. A detailed reaction mechanism for n-butanol, consisting of 243 species and 1446 reactions, and a reduced TRF mechanism, containing 158 species and 468 reactions, were reduced separately and then combined to create a new TRF/n-butanol mechanism. The new TRF/n-butanol mechanism contained 107 species and 413 reactions. A multi-technique reduction methodology was used which included
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Wu, Y., L. Jia, E. J. Anthony, S. Madrali, J. Hill, and L. Hunt. "Reactivation of CFBC Ash by Sonic Energy." In 18th International Conference on Fluidized Bed Combustion. ASMEDC, 2005. http://dx.doi.org/10.1115/fbc2005-78002.

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Hydration and carbonation tests confirm that SESI technology using sonic energy promotes the effective hydration of FBC solids; 70–80% CaO conversion to Ca(OH)2 was easily achievable in a few minutes. In addition, the 75 kW sonic generator, with addition of the grinding medium, was able to produce a highly carbonated residue which could serve as an effective sulphur sorbent or could be landfilled without the current undesirable side reactions such as ettringite production, due to the effective elimination of CaO and Ca(OH)2 in the ash. Over 70% conversion to CaCO3 was achieved in samples that
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Akih-Kumgeh, Ben, and Jeffrey M. Bergthorson. "A Four Component Skeletal Model for the Analysis of Jet Fuel Surrogate Combustion." In ASME Turbo Expo 2013: Turbine Technical Conference and Exposition. American Society of Mechanical Engineers, 2013. http://dx.doi.org/10.1115/gt2013-94813.

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A skeletal chemical kinetic model for jet fuel combustion, comprising four representative fuel components, is presented. The sub model for the three components, toluene, methyl cyclohexane (MCH) and n-dodecane, is deduced from a detailed model for jet fuel surrogate proposed by Wang et al. [Wang et al., 2010]. The reduction is based on a species sensitivity approach, herein referred to as Alternate Species Elimination (ASE). The sub model for the fourth component, iso-octane, is established through semi-detailed kinetic modeling, considering existing reactions and species of the smaller hydroc
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Reports on the topic "Elimination reactions"

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Suria, Sabartanty. Intermolecula transfer and elimination of molecular hydrogen in thermal reactions of unsaturated organic compounds. Office of Scientific and Technical Information (OSTI), 1995. http://dx.doi.org/10.2172/108159.

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Lahav, Ori, Albert Heber, and David Broday. Elimination of emissions of ammonia and hydrogen sulfide from confined animal and feeding operations (CAFO) using an adsorption/liquid-redox process with biological regeneration. United States Department of Agriculture, 2008. http://dx.doi.org/10.32747/2008.7695589.bard.

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The project was originally aimed at investigating and developing new efficient methods for cost effective removal of ammonia (NH₃) and hydrogen sulfide (H₂S) from Concentrated Animal Feeding Operations (CAFO), in particular broiler and laying houses (NH₃) and hog houses (H₂S). In both cases, the principal idea was to design and operate a dedicated air collection system that would be used for the treatment of the gases, and that would work independently from the general ventilation system. The advantages envisaged: (1) if collected at a point close to the source of generation, pollutants would
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