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Journal articles on the topic 'Emulsion Liquid Membranes'

Author: Grafiati

Published: 28 May 2022

Last updated: 31 July 2025

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1

M. Barad, Jaydeep, Mousumi Chakraborty, and Hans-Jörg Bart. "Formation and Stability Study of Nano-Emulsions: BTX- Separation." Open Chemical Engineering Journal 3, no. 1 (2009): 33–40. http://dx.doi.org/10.2174/1874123100903010033.

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The selective separation of aromatics (benzene, toluene and p-xylene, BTX) from aliphatic (n-heptane) is investigated using simple permeation and facilitated transport emulsion liquid membrane mechanism. The separation performances, represented by the permeation rate and separation factor, are analyzed systematically by varying the operating parameters. One of the major obstacles to the application of emulsion liquid membranes to industrial separations is the stability of emulsion globules. In the present study, stability of emulsion liquid membrane is studied by varying different parameters e

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2

Mondal, Suchintan, Bhavna Alke, Aline Machado de Castro, et al. "Design of Enzyme Loaded W/O Emulsions by Direct Membrane Emulsification for CO2 Capture." Membranes 12, no. 8 (2022): 797. http://dx.doi.org/10.3390/membranes12080797.

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Membrane-based gas separation is a promising unit operation in a low-carbon economy due to its simplicity, ease of operation, reduced energy consumption and portability. A methodology is proposed to immobilise enzymes in stable water-in-oil (W/O) emulsions produced by direct membrane emulsification systems and thereafter impregnated them in the pores of a membrane producing emulsion-based supported liquid membranes. The selected case-study was for biogas (CO2 and CH4) purification. Upon initial CO2 sorption studies, corn oil was chosen as a low-cost and non-toxic bulk phase (oil phase). The em

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3

Stevens, G. W., C. Chang, and M. E. Mackay†. "Stabilizing Emulsion Liquid Membranes." Separation Science and Technology 31, no. 8 (1996): 1025–33. http://dx.doi.org/10.1080/01496399608001331.

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4

León, Gerardo, Elisa Gómez, Beatriz Miguel, et al. "Feasibility of Adsorption Kinetic Models to Study Carrier-Mediated Transport of Heavy Metal Ions in Emulsion Liquid Membranes." Membranes 12, no. 1 (2022): 66. http://dx.doi.org/10.3390/membranes12010066.

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Emulsion liquid membranes have been successfully used for the removal of different types of organic and inorganic pollutants by means of carrier-mediated transport mechanisms. However, the models that describe the kinetics and transport of such mechanisms are very complex due to the high number of model parameters. Starting from an analysis of the similarity between the elemental mechanisms of carrier-mediated transport in liquid membranes and of transport in adsorption processes, this paper presents an experimental analysis of the possibility of applying kinetic and mechanistic models develop

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5

Luthfiana, Anisa, Sri Mulyati, Nasrul Arahman, Aulia Cintia Ambarita, and Muhammad Prayogie Aulia. "Cigarette Filter-Based Membranes with Tannin and FeCl₃ Additives for Enhancing the Antifouling Properties of Oil Emulsion Filtration." Jurnal Kimia Sains dan Aplikasi 27, no. 12 (2024): 580–89. https://doi.org/10.14710/jksa.27.12.580-589.

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Industries in Indonesia significantly contribute to the economy by increasing foreign exchange earnings and creating job opportunities. However, industrial activities also negatively impact the environment, particularly water pollution caused by liquid waste containing oil emulsions. This research aims to develop a membrane based on cigarette filters as an alternative to cellulose acetate for separating oil emulsions in water. Cigarette filters were processed into membranes with tannic acid (TA) and ferric chloride (FeCl3) as additives using a vacuum-filtration coating technique. The resulting

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6

Basuki, Kris Tri. "MATHEMATICAL MODELING FOR THE EXTRACTION OF URANIUM AND MOLYBDENUM WITH EMULSION LIQUID MEMBRANE, INCLUDING INDUSTRIAL APPLICATION AND COST EVALUATION OF THE URANIUM RECOVERY." Jurnal Forum Nuklir 2, no. 1 (2008): 63. http://dx.doi.org/10.17146/jfn.2008.2.1.3284.

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MATHEMATICAL MODELING FOR THE EXTRACTION OF URANIUM AND MOLYBDENUM WITH EMULSION LIQUID MEMBRANE, INCLUDING INDUSTRIAL APPLICATION AND COST EVALUATION OF THE URANIUM RECOVERY. Emulsion liquid membrane systems are double emulsion drops. Two immiscible phases are separated by a third phase which is immiscible with the other two phases. The liquid membrane systems were classified into two types: (1) carrier mediated mass transfer, (2) mass transfer without any reaction involved. Uranium extraction, molybdenum extraction and solvent extraction were used as purposed elements for each type of the me

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7

KIRKKÖPRÜ, AYŞEN, RICHARD D. NOBLE, and ANNETTE L. BUNGE. "AMINE PHASE PARTITIONING USING EMULSION LIQUID MEMBRANES." Chemical Engineering Communications 64, no. 1 (1988): 207–15. http://dx.doi.org/10.1080/00986448808940237.

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8

Kostanyan, Artak E., Andrey A. Voshkin, Vera V. Belova, and Yulia A. Zakhodyaeva. "Modelling and Comparative Analysis of Different Methods of Liquid Membrane Separations." Membranes 13, no. 6 (2023): 554. http://dx.doi.org/10.3390/membranes13060554.

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This article is devoted to a brief review of the modelling of liquid membrane separation methods, such as emulsion, supported liquid membranes, film pertraction, and three-phase and multi-phase extraction. Mathematical models and comparative analyses of liquid membrane separations with different flow modes of contacting liquid phases are presented. A comparison of the processes of conventional and liquid membrane separations is carried out under the following assumptions: mass transfer is described by the traditional mass transfer equation; the equilibrium distribution coefficients of a compon

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9

Draxler, J., W. Fürst, and R. Marr. "Separation of metal species by emulsion liquid membranes." Journal of Membrane Science 38, no. 3 (1988): 281–93. http://dx.doi.org/10.1016/s0376-7388(00)82425-4.

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10

Nii, Susumu, Kazuho Tanaka, and Hiroshi Takeuchi. "Application of Ferromagnetic Particles to Emulsion Liquid Membranes." Separation Science and Technology 30, no. 17 (1995): 3253–63. http://dx.doi.org/10.1080/01496399508013143.

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11

Stefanut, Mariana, Adrian Novac, Elisavet Amanatidou, and Carol Csunderlik. "Some Aromatic Amine Transport through Emulsion Liquid Membranes." Separation Science and Technology 31, no. 16 (1996): 2219–29. http://dx.doi.org/10.1080/01496399608001042.

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12

Sarbatly, Rosalam, and Chel-Ken Chiam. "An Overview of Recent Progress in Nanofiber Membranes for Oily Wastewater Treatment." Nanomaterials 12, no. 17 (2022): 2919. http://dx.doi.org/10.3390/nano12172919.

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Oil separation from water becomes a challenging issue in industries, especially when large volumes of stable oil/water emulsion are discharged. The present short review offers an overview of the recent developments in the nanofiber membranes used in oily wastewater treatment. This review notes that nanofiber membranes can efficiently separate the free-floating oil, dispersed oil and emulsified oil droplets. The highly interconnected pore structure nanofiber membrane and its modified wettability can enhance the permeation flux and reduce the fouling. The nanofiber membrane is an efficient separ

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13

Guo, Zhifeng, Huidan Su, Ru Cai, and Xiaoli Ma. "Extraction of dl-anabasine from Alangium platanifolium root using an emulsion liquid membrane." Analytical Methods 7, no. 5 (2015): 1860–65. http://dx.doi.org/10.1039/c4ay02779e.

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14

Mok, Young Sun, Won Kook Lee, and Yong Kuk Lee. "Modeling of liquid emulsion membranes facilitated by two carriers." Chemical Engineering Journal 66, no. 1 (1997): 11–20. http://dx.doi.org/10.1016/s1385-8947(96)03147-6.

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15

Wan, Y. "Swelling determination of W/O/W emulsion liquid membranes." Journal of Membrane Science 196, no. 2 (2002): 185–201. http://dx.doi.org/10.1016/s0376-7388(01)00554-3.

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16

Thien, M. P., and T. A. Hatton. "Liquid Emulsion Membranes and Their Applications in Biochemical Processing." Separation Science and Technology 23, no. 8-9 (1988): 819–53. http://dx.doi.org/10.1080/01496398808063141.

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17

Sun Mok, Young, Won Kook Lee, and Yong Kuk Lee. "Modeling of liquid emulsion membranes facilitated by two carriers." Chemical Engineering Journal and the Biochemical Engineering Journal 63, no. 2 (1996): 127–37. http://dx.doi.org/10.1016/0923-0467(96)03097-7.

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18

Draxler, J., and R. Marr. "Emulsion liquid membranes part I: Phenomenon and industrial application." Chemical Engineering and Processing: Process Intensification 20, no. 6 (1986): 319–29. http://dx.doi.org/10.1016/0255-2701(86)80010-1.

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19

Ismuyanto, Bambang. "Utilization of Liquid Emulsion Membranes To Set Aside Nickel Ions In Liquid Waste." Natural-B 1, no. 3 (2012): 235–39. http://dx.doi.org/10.21776/ub.natural-b.2012.001.03.7.

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20

Ferencz (Dinu), Andreea, Alexandra Raluca Grosu, Hussam Nadum Abdalraheem Al-Ani, et al. "Operational Limits of the Bulk Hybrid Liquid Membranes Based on Dispersion Systems." Membranes 12, no. 2 (2022): 190. http://dx.doi.org/10.3390/membranes12020190.

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Liquid membranes usually have three main constructive variants: bulk liquid membranes (BLM), supported liquid membranes (SLM) and emulsion liquid membranes (ELM). Designing hybrid variants is very topical, with the main purpose of increasing the flow of substance through the membrane but also of improving the selectivity. This paper presents the operational limits of some kind of hybrid membrane constituted as a bulk liquid membrane (BLM), but which works by dispersing the aqueous source (SP) and receiving (RP) phases, with the membrane itself being a dispersion of nanoparticles in an organic

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21

Korolkov, Ilya V., Asiya R. Narmukhamedova, Galina B. Melnikova, et al. "Preparation of Hydrophobic PET Track-Etched Membranes for Separation of Oil–Water Emulsion." Membranes 11, no. 8 (2021): 637. http://dx.doi.org/10.3390/membranes11080637.

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The paper describes the separation of an oil–water emulsion by filtration using poly(ethylene terephthalate) track-etched membranes (PET TeMs) with regular pore geometry and narrow pore size distribution. PET TeMs were modified with trichloro(octyl)silane to increase their hydrophobic properties. Conditions for the modification of PET TeMs with trichloro(octyl)silane were investigated. The results of changes in the pore diameters and the contact angle depend on the concentration of trichloro(octyl)silane and the soaking time are presented. The obtained samples were characterized by FTIR, AFM,

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22

Wang, Zirui, Shusu Shen, Linbin Zhang, Abdessamad Ben Hida, and Ganwei Zhang. "Hydrophilic and Positively Charged Polyvinylidene Fluoride Membranes for Water Treatment with Excellent Anti-Oil and Anti-Biocontamination Properties." Membranes 12, no. 4 (2022): 438. http://dx.doi.org/10.3390/membranes12040438.

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Membrane fouling limits the rapid development of membrane separations. In this study, a blend membrane containing polycationic liquid (P(BVImBr1-co-PEGMA1)) is presented that can improve the antifouling performance of polyvinylidene fluoride (PVDF) membranes. By mixing the polycationic liquid into PVDF, an improved membrane-surface hydrophilicity and enlarged membrane porosity were detected. The water contact angle decreased from 82° to 67°, the porosity enlarged from 7.22% to 89.74%, and the pure water flux improved from 0 to 631.68 L m−2 h−1. The blend membrane surfaces were found to be alwa

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23

Bhagyaraj, Sneha, Patrik Sobolčiak, Mohammad A. Al-Ghouti, and Igor Krupa. "Copolyamide–Clay Nanotube Polymer Composite Nanofiber Membranes: Preparation, Characterization and Its Asymmetric Wettability Driven Oil/Water Emulsion Separation towards Sewage Remediation." Polymers 13, no. 21 (2021): 3710. http://dx.doi.org/10.3390/polym13213710.

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To address the problem of ever-increasing oily wastewater management, due to its directional liquid transport property, membranes with asymmetric wettability can be effectively used for emulsion separation. This study reports the synthesis of electrospun polymer–clay nanocomposite nanofibers, using co-polyamide polymer (COPA) and halloysite nanotubes (HA) as filler. The influence of clay content on the morphological, thermal and dielectric properties of the polymer composite nanofiber was investigated comprehensively to address the material characteristics of the developed system. The surface

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24

Gupta, Smita, Mousumi Chakraborty, and Z. V. P. Murthy. "Removal of Mercury by Emulsion Liquid Membranes: Studies on Emulsion Stability and Scale Up." Journal of Dispersion Science and Technology 34, no. 12 (2013): 1733–41. http://dx.doi.org/10.1080/01932691.2013.767205.

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25

Kaczorowska, Małgorzata A. "The Latest Achievements of Liquid Membranes for Rare Earth Elements Recovery from Aqueous Solutions—A Mini Review." Membranes 13, no. 10 (2023): 839. http://dx.doi.org/10.3390/membranes13100839.

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The systematic increase in the use of rare earth elements (REEs) in various technologically advanced products around the world (e.g., in electronic devices), the growing amount of waste generated by the use of high-tech materials, and the limited resources of naturally occurring REE ores resulted in an intensive search for effective and environmentally safe methods for recovering these elements. Among these methods, techniques based on the application of various types of liquid membranes (LMs) play an important role, primarily due to their high efficiency, the simplicity of membrane formation

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26

Pîrțac, Andreia, Aurelia Cristina Nechifor, Szidonia-Katalin Tanczos, et al. "Emulsion Liquid Membranes Based on Os–NP/n–Decanol or n–Dodecanol Nanodispersions for p–Nitrophenol Reduction." Molecules 29, no. 8 (2024): 1842. http://dx.doi.org/10.3390/molecules29081842.

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Membrane materials with osmium nanoparticles have been recently reported for bulk membranes and supported composite membrane systems. In the present paper, a catalytic material based on osmium dispersed in n–decanol (nD) or n–dodecanol (nDD) is presented, which also works as an emulsion membrane. The hydrogenation of p–nitrophenol (PNP) is carried out in a reaction and separation column in which an emulsion in the acid-receiving phase is dispersed in an osmium nanodispersion in n–alcohols. The variables of the PNP conversion process and p–aminophenol (PAP) transport are as follows: the nature

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27

Chen, Luying, Dooli Kim, and Wiebe M. de Vos. "Enhancing the Separation Performance of Cellulose Membranes Fabricated from 1-Ethyl-3-methylimidazolium Acetate by Introducing Acetone as a Co-Solvent." Membranes 14, no. 9 (2024): 202. http://dx.doi.org/10.3390/membranes14090202.

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Cellulose, a sustainable raw material, holds great promise as an ideal candidate for membrane materials. In this work, we focused on establishing a low-cost route for producing cellulose microfiltration membranes by adopting a co-solvent system comprising the ionic liquid 1-ethyl-3-methylimidazolium acetate ([EMIM]OAc) and acetone. The introduction of acetone as a co-solvent into the casting solution allowed control over the viscosity, thereby significantly enhancing the morphologies and filtration performances of the resulting cellulose membranes. Indeed, applying this co-solvent allowed the

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28

Anarakdim, Katia, Gemma Gutiérrez, Ángel Cambiella, Ounissa Senhadji-Kebiche, and María Matos. "The Effect of Emulsifiers on the Emulsion Stability and Extraction Efficiency of Cr(VI) Using Emulsion Liquid Membranes (ELMs) Formulated with a Green Solvent." Membranes 10, no. 4 (2020): 76. http://dx.doi.org/10.3390/membranes10040076.

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The stability of emulsion liquid membranes (ELMs) and their ability to extract Cr(VI) were investigated. The objective of this study is to compare different ELM formulations using combinations of two hydrophilic (Tween 20 and Tween 80) and two lipophilic (polyglycerol polyricinoleate (PGPR) and Span 80) emulsifiers. TOPO (tri-n-octylphosphine oxide) as a carrier and a green solvent (sunflower oil) were used to provide high extraction efficiency of Cr(VI). All these double emulsions were characterized in droplet size distribution, zeta potential, visual inspection with a microscope, and stabili

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29

Acosta, A. O., C. Illanes, and J. Marchese. "Removal and recovery of Cr (III) with emulsion liquid membranes." Desalination and Water Treatment 7, no. 1-3 (2009): 18–24. http://dx.doi.org/10.5004/dwt.2009.438.

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30

YORDANOV, B., and L. BOYADZHIEV. "Pertraction of citric acid by means of emulsion liquid membranes." Journal of Membrane Science 238, no. 1-2 (2004): 191–97. http://dx.doi.org/10.1016/j.memsci.2004.04.004.

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31

Devulapalli, Ramanamurthy, and Francis Jones. "Separation of aniline from aqueous solutions using emulsion liquid membranes." Journal of Hazardous Materials 70, no. 3 (1999): 157–70. http://dx.doi.org/10.1016/s0304-3894(99)00134-x.

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32

Bart, H. J., H. Jüngling, N. Ramaseder, and R. Marr. "Water and solute solubilization and transport in emulsion liquid membranes." Journal of Membrane Science 102 (June 1995): 103–12. http://dx.doi.org/10.1016/0376-7388(94)00280-c.

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33

Ahmad, A. L., Adhi Kusumastuti, C. J. C. Derek, and B. S. Ooi. "Emulsion liquid membranes for cadmium removal: Studies of extraction efficiency." Membrane Water Treatment 4, no. 1 (2013): 11–25. http://dx.doi.org/10.12989/mwt.2013.4.1.011.

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34

Patnaik, P. R. "Liquid emulsion membranes: Principles, problems and applications in fermentation processes." Biotechnology Advances 13, no. 2 (1995): 175–208. http://dx.doi.org/10.1016/0734-9750(95)00001-7.

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35

Thein, M. P., T. A. Hatton, and D. I. C. Wang. "Separation and concentration of amino acids using liquid emulsion membranes." Biotechnology and Bioengineering 32, no. 5 (1988): 604–15. http://dx.doi.org/10.1002/bit.260320505.

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36

Razo-Lazcano, Teresa Alejandra, Moncef Stambouli, María del Pilar González-Muñoz, Dominique Pareau, and Mario Ávila-Rodríguez. "Emulsion liquid membranes for recovery of ibuprofen from aqueous solutions." Journal of Chemical Technology & Biotechnology 89, no. 6 (2014): 890–98. http://dx.doi.org/10.1002/jctb.4329.

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37

Raghuraman, B., and J. Wiencek. "Extraction with emulsion liquid membranes in a hollow-fiber contactor." AIChE Journal 39, no. 11 (1993): 1885–89. http://dx.doi.org/10.1002/aic.690391115.

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38

Hu, Y., N. Zhang, and C. Qu. "Separation of Hydrogen Sulfide from Wastewater by Emulsion Liquid Membranes." Chemical Engineering & Technology 35, no. 2 (2011): 341–46. http://dx.doi.org/10.1002/ceat.201100283.

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39

Reis, M. Teresa A., Ondina M. F. Freitas, Shiva Agarwal, et al. "Removal of phenols from aqueous solutions by emulsion liquid membranes." Journal of Hazardous Materials 192, no. 3 (2011): 986–94. http://dx.doi.org/10.1016/j.jhazmat.2011.05.092.

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40

Kakoi, Takahiko, Masahiro Goto, Aki Kamachi, et al. "Silver-mediated separation of polyunsaturated fatty acids by oil-in-water emulsion liquid membranes." membrane 23, no. 4 (1998): 204–12. http://dx.doi.org/10.5360/membrane.23.204.

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41

Miron, Alexandra Raluca, Aurelia Cristina Nechifor, Abbas Abdul Kadhim Klaif Rikabi, and Szidonia Katalin Tanczos. "SEPARATION OF AROMATIC INTERMEDIATES OF BIOLOGICAL INTEREST USING EMULSION LIQUID MEMBRANES." Environmental Engineering and Management Journal 14, no. 2 (2015): 373–79. http://dx.doi.org/10.30638/eemj.2015.038.

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42

Habaki, Hiroaki, Sakurako Isobe, Ryuichi Egashira, and Junjiro Kawasaki. "Permeation and Concentration of Erythromycin by Supported and Emulsion Liquid Membranes." JOURNAL OF CHEMICAL ENGINEERING OF JAPAN 31, no. 1 (1998): 47–54. http://dx.doi.org/10.1252/jcej.31.47.

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43

Lee, Sang Cheol. "Extraction of succinic acid from simulated media by emulsion liquid membranes." Journal of Membrane Science 381, no. 1-2 (2011): 237–43. http://dx.doi.org/10.1016/j.memsci.2011.07.039.

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44

Teresa, M. "Recovery of zinc from an industrial effluent by emulsion liquid membranes." Journal of Membrane Science 84, no. 3 (1993): 201–11. http://dx.doi.org/10.1016/0376-7388(93)80016-q.

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45

Shen, Jinh-Qing, Wei-Ping Yin, Yong-Xin Zhao, and Li-Jun Yu. "Extraction of alanine using emulsion liquid membranes featuring a cationic carrier." Journal of Membrane Science 120, no. 1 (1996): 45–53. http://dx.doi.org/10.1016/0376-7388(96)00158-5.

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46

KATO, SATORU, and JUNJIRO KAWASAKI. "Enhancement of hydrocarbon permeation by polar additives in liquid emulsion membranes." Journal of Chemical Engineering of Japan 20, no. 6 (1987): 585–90. http://dx.doi.org/10.1252/jcej.20.585.

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47

Wodzki, Romuald, Alicja Wyszynska, and Anna Narebska. "Two-Component Emulsion Liquid Membranes with Macromolecular Carriers of Divalent lons." Separation Science and Technology 25, no. 11-12 (1990): 1175–87. http://dx.doi.org/10.1080/01496399008051846.

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48

Mikulaj, V., P. Rajec, A. Švec, N. H. Cuong, and V. N. Ahn. "A continuous preconcentration of cobalt and uranium using liquid emulsion membranes." Journal of Radioanalytical and Nuclear Chemistry Articles 101, no. 1 (1986): 67–69. http://dx.doi.org/10.1007/bf02039394.

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49

Miesiąc, I., K. Schügerl, A. Hasler, and J. Szymanowski. "Extraction and enzymatic hydrolysis of Penicillin G in emulsion liquid membranes." Journal of Radioanalytical and Nuclear Chemistry Articles 208, no. 1 (1996): 133–44. http://dx.doi.org/10.1007/bf02039755.

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50

Patnaik, P. R. "Reactive extraction with liquid emulsion membranes: The finite reaction zone concept." Reaction Kinetics and Catalysis Letters 68, no. 2 (1999): 347–54. http://dx.doi.org/10.1007/bf02475523.

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