Relevant bibliographies by topics / Enamina

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  1. Journal articles
  2. Dissertations / Theses
  3. Books
  4. Book chapters
  5. Conference papers

Academic literature on the topic 'Enamina'

Author: Grafiati
Published: 5 September 2021
Last updated: 29 July 2025

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Journal articles on the topic "Enamina"

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Moustaid, Khadija, Nguyen Dinh An, Bernard Laude, Marie-France Mercier, and Ahmed Sedqui. "Cycloaddition de la C-p-anisyl-N-phénylnitrilimine sur deux énamines cycliques dérivées de la 1,2-dihydro-6,7-diméthoxyisoquinoléine-3-carboxylate d'éthyle. Régiochimie, stéréochimie et évolution des cycloadduits." Canadian Journal of Chemistry 70, no. 3 (1992): 802–8. http://dx.doi.org/10.1139/v92-105.

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Two ethyl-1,2-dihydro-6,7-dimethoxyisoquinoline-3a-carboxylate derivatives were synthesized. These cyclic enamines in which the enaminic carbon atom was bonded with an ester group react regio- and stereospecifically with a diarylnitrilimine. The regiochemistry was specified by chemical and spectroscopic methods. The radiocrystallographic structure of one cycloadduct allows us to determine the stereochemistry of the reaction and to compare it with that of the reaction of a diarylnitrilimine with a 1,2-dihydro-1,2-dialkylisoquinoline without an ester group at the enaminic carbon atom. Keywords:
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Hernández Rodríguez, Marcos. "Organocatálisis asimétrica: una caja de herramientas para construir moléculas." Educación Química 33, no. 1 (2022): 5. http://dx.doi.org/10.22201/fq.18708404e.2022.1.81372.

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<p>El premio Nobel de Química 2021 fue otorgado a Benjamin List y David W. C. MacMillan por el desarrollo de la organocatálisis asimétrica. El propósito de este artículo es explicar de qué se trata esta herramienta sintética, historia previa a la invención de la organocatálisis y los trabajos que iniciaron este campo por la activación vía enamina e iminio descubiertas por los galardonados al Nobel. Adicionalmente, se menciona la catálisis por enlace de hidrógeno y bifuncional. Se ilustra el alcance de la organocatálisis en la síntesis de los antivirales letermovil y oseltamivir y una sug
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Morales-Ríos, Martha S., Oscar R. Suárez-Castillo, Celina Alvarez-Cisneros та Pedro Joseph-Nathan. "13C NMR and crystallographic evidence of push-pull effects in furoindolic β-enamino esters". Canadian Journal of Chemistry 77, № 1 (1999): 130–37. http://dx.doi.org/10.1139/v98-213.

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A series of cyclic enamine derivatives, stabilized through conjugation with an electron-attracting CO2Me group at the β-carbon of the enamine system, has been prepared. The influence of substituents at the vinylogous donor NH2 group on 13C chemical shifts has been investigated, and the results analyzed on the basis of resonance and steric effects on the dipolar charge distribution in the molecule. Intramolecular H-bonding was established for the N-methylated enamines 4a and 4b based on the high-frequency shift of the NH proton and its solvent immutability. Several deuterium-induced isotope eff
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Miesch, Laurence, and Frédéric Beltran. "Tertiary Enamides as Versatile and Valuable Substrates to Reach Chemical Diversity." Synthesis 52, no. 17 (2020): 2497–511. http://dx.doi.org/10.1055/s-0040-1707403.

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Tertiary enamides display versatile reactivity and great stability compared to their enamine congeners. This review covers progress made in the development of new methods involving the enaminic reactivity of tertiary enamides with respect to the synthesis of complex nitrogen-containing compounds. A focus on the preparation of biologically active molecules is also presented. The syntheses reported herein are classified based on their reaction type. In addition, mechanistic insights are given for most of the new transformations.1 Introduction2 [2+2] Cycloadditions3 [4+2] Cycloadditions4 Electroc
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Sukhorukov, Alexey Yu. "Umpolung of Enamines: An Overview on Strategies and Synthons." Synlett 31, no. 05 (2020): 439–49. http://dx.doi.org/10.1055/s-0037-1610741.

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Umpolung strategies are of considerable interest to organic chemists because they provide alternative synthetic routes to those imposed by the natural polarity of classical synthons. Reverse-polarity reactions of aldehydes, α,β-unsaturated carbonyl compounds, and imines are deeply embedded in the methodology of organic synthesis. In recent years, umpolung of enols and enamines has received much attention as a novel strategy to access α-substituted ketones. Here, state-of-the-art approaches to umpolung of enamine reactivity are discussed, with a particular focus on recent developments in this f
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Vilarrasa, Jaume, Alejandro Castro-Alvarez, Héctor Carneros, and Anna M. Costa. "Computer-Aided Insight into the Relative Stability of Enamines." Synthesis 49, no. 24 (2017): 5285–306. http://dx.doi.org/10.1055/s-0036-1590909.

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Venerable aldol, Michael, and Mannich reactions have undergone a renaissance in the past fifteen years, as a consequence of the development of direct organocatalytic versions, mediated by chiral amines. Chiral enamines are key intermediates in these reactions. This review focuses on the formation of enamines from secondary amines and their relative thermodynamic stability, as well as on the reverse reactions (hydrolysis). Experimental results and predictions based on MO calculations are reviewed to show which enamine forms may predominate in the reaction medium and to compare several secondary
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Corte, Marigorta, Palacios та Vicario. "A Brønsted Acid-Catalyzed Multicomponent Reaction for the Synthesis of Highly Functionalized γ-Lactam Derivatives". Molecules 24, № 16 (2019): 2951. http://dx.doi.org/10.3390/molecules24162951.

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Brønsted acids catalyze a multicomponent reaction of benzaldehyde with amines and diethyl acetylenedicarboxylate to afford highly functionalized γ-lactam derivatives. The reaction consists of a Mannich reaction of an enamine to an imine, both generated in situ, promoted by a phosphoric acid catalyst and a subsequent intramolecular cyclization. The hydrolysis of the cyclic enamine substrate can provide enol derivatives and, moreover, a second attack of the amine on the carboxylate can afford amide derivatives. An optimization of the reaction conditions is presented in order to obtain selectivel
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Sharma, Anamika, Assem Barakat, Hessa H. Al-Rasheed, et al. "Crystal Structure and Theoretical Investigation of Thiobarbituric Acid Derivatives as Nonlinear Optical (NLO) Materials." Crystals 10, no. 6 (2020): 442. http://dx.doi.org/10.3390/cryst10060442.

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Here we report on the crystal structure of three enamine/imine TBA derivatives (1–3). Since the derivatives can take the form of enamine or imine tautomers, theoretical calculations were made to confirm that the former predominates due to higher stability (thermodynamic calculations). The enamines’ form was further corroborated by high activation energy (ΔG≠; which is >60 kcal/mol in all the cases), thus requiring a large amount of energy to pass the barrier (kinetics calculations). Furthermore, 1–3 were found to show high static hyperpolarizability (βtot), thereby making them potential can
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Baradarani, M., RH Prager, and K. Schafer. "The Chemistry of 5-Oxodihydroisoxazoles. XV. Reaction of Derived Ketenimines With Enamines and Enolates." Australian Journal of Chemistry 49, no. 8 (1996): 911. http://dx.doi.org/10.1071/ch9960911.

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Reaction of 2-heterocyclisoxazol-5(2H)-ones with bases leads to the formation of ketenimines, which react with nucleophiles in competition with intramolecular reactions. Such reactions in the presence of enamines, enamine anions or enolates are reported. Enamines undergo addition through carbon and nitrogen to the ketenimine in competition with direct addition-elimination to the isoxazolone. Enolates of imines or ketones add to the ketenimine to give a mixture of products: only the reaction with the enolate of cyclohexanone is sufficiently specific to provide a useful new synthetic procedure.
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Darwish, Elham S., Mahmoud A. Abdelrahman, and Abdellatif M. Salaheldin. "Enamines in Heterocyclic Synthesis: A Novel Simple and Efficient Route to Condensed Pyridazines." Zeitschrift für Naturforschung B 66, no. 6 (2011): 597–602. http://dx.doi.org/10.1515/znb-2011-0607.

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An efficient and easy preparation of enamine derivatives, via active methyl and methylene compounds by in situ-generated 1-(diethoxymethyl)piperidine, produced from the mixture of triethyl orthoformate/piperidine/DMF, are described. Some new pyridazinone derivatives have been synthesized from the reaction of enamines with hydrazine hydrate and cyanoacid hydrazide.
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Dissertations / Theses on the topic "Enamina"

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Gonçalo, Erika Rocha da Silva. "bβ-enamino ésteres como precursores de análogos do GABA e de di-hidropiridinas." Universidade de São Paulo, 2006. http://www.teses.usp.br/teses/disponiveis/46/46135/tde-28032007-172228/.

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Nesta tese foi empregada a iodociclofuncionalização de β-enamino ésteres para obtenção de análogos conformacionalmente restritos do ácido γ-aminobutírico (GABA) e de 4-aril-1,4-di-hidropiridinas (DHP\'s). Foram preparados ciclopentanos trissubstituídos a partir de b-enamino ésteres cíclicos, com o objetivo de investigar o mecanismo desta reação. Utilizando ESI(+)-MS/MS, foi possível identificar e caracterizar os intermediários bicíclicos catiônicos, confirmando que a reação se processa através de uma SN2 intramolecular. A biorredução do grupo acetila existente nos ciclopentanos, util
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Tin, Sergey. "Rh catalysed hydrogenation of enamines : factors affecting the rate and enantioselectivity." Thesis, University of St Andrews, 2017. http://hdl.handle.net/10023/10599.

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Kanzian, Tanja. "Reactivity Parameters for Enamine Activated Reactions." Diss., lmu, 2010. http://nbn-resolving.de/urn:nbn:de:bvb:19-121580.

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Pereira, Fernando Luiz Cardoso. "Aplicações sintéticas de β-enamino ésteres." Universidade de São Paulo, 2002. http://www.teses.usp.br/teses/disponiveis/46/46135/tde-19112015-162222/.

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Uma série de β-enamino ésteres foi submetida a reações de iodociclização ou lactonização mediada por iodo, fornecendo como produtos iodo-β-enamino ésteres cíclicos ou β-enamino lactonas, respectivamente. Os iodo-β-enamino ésteres cíclicos obtidos foram submetidos a reações de desidroiodação, fornecendo os correspondentes produtos de eliminação de HI a partir de iodociclos de cinco membros, e ciclopentanos trissubstituídos, a partir de anéis de seis membros. Esta última reação ocorreu por substituição nucleofílica intramolecular, em vez da esperada reação de desidroiodação.
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Buff, Heiko. "Hydrazone als Aza-Enamine in der Nenitzescu-Reaktion." [S.l.] : [s.n.], 2001. http://deposit.ddb.de/cgi-bin/dokserv?idn=963417282.

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Brown, Sean Pomeroy Hsieh-Wilson Linda C. "Iminium and enamine activation: methods for enantioselective organocatalysis /." Diss., Pasadena, Calif. : California Institute of Technology, 2005. http://resolver.caltech.edu/CaltechETD:etd-02242005-174252.

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Troxel, Richard L. "The enamine knoevenagel and Michael initiated ring closure reactions." Virtual Press, 1985. http://liblink.bsu.edu/uhtbin/catkey/426373.

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The reaction of the pyrrolidine enamine of cyclohexanone with several malonic acid derivatives gave good yields of the corresponding Knoevenagel adducts when one of the activating substituents was a cyano group. The above enamine, after alkylation at the 2-position with methyl acrylate, gave similar yields of Knoevenagel products. Reaction of the alkylated enamine with lithioacetonitrile gave, after acidification, an annulated product by internal Knoevenagel reaction. The latter product was also obtained by a Dieckmann ring closure reaction. The Michael reaction of the substituted Knoevenagel
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Dourado, Jorge Manuel de Carvalho Marques. "HOMO-raising strategies in aminocatalysis, from Enamine to Tetraenamine." Master's thesis, Faculdade de Ciências e Tecnologia, 2013. http://hdl.handle.net/10362/11087.

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Dissertação para obtenção do Grau de Mestre em Bioorgânica<br>In this Master Thesis two different HOMO-raising strategies in aminocatalysis - enamine activation and tetraenamine activation were studied. For the tetraenamine activation concept, it was rationalized that the condensation between 2-(cyclohepta-1,3,5-trien 1-yl)acetate and the TMS-protected diraylprolinol ether aminocatalyst would provide the desired tetraenamine intermediate. The novelty of this concept was further explored by the studied of the [4+2]-cycloaddition between the tetraenamine intermediate formed and a series of 3-
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Bombonato, Fernanda Irene. "Ciclofuncionalização de &#946,-enamino Ésteres e β-hidróxi ésteres." Universidade de São Paulo, 2002. http://www.teses.usp.br/teses/disponiveis/46/46135/tde-24102007-152630/.

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Nosso grupo de pesquisa vem se dedicado, há vários anos, ao estudo das reações de ciclização eletrofílica de substratos insaturados que contêm um nucleófilo interno (oxigênio ou nitrogênio). Este trabalho teve como objetivo obter derivados de éteres cíclicos de cinco e seis membros diferentemente funcionalizados. Compostos 1,3-dicarbonílicos e ß-hidróxi carbonílicos, contendo dupla ligação em posição apropriada, foram submetidos à reação de ciclização mediada tanto por iodo quanto por dimetildioxirana. De maneira semelhante, ß-enamino ésteres alquenilados foram submetidos à reação de io
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Silveira, Leandro Greff da. "Estudos teóricos da reação de alquilação desracemizante em enaminas quirais." reponame:Biblioteca Digital de Teses e Dissertações da UFRGS, 2005. http://hdl.handle.net/10183/5461.

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Utilizando métodos ab initio no nível RHF/6-311G**, combinado com conceitos do Princípio de Curtin-Hammett e da lei de distribuição de Maxwell-Boltzmann, este trabalho teve como objetivo elucidar os mecanismos implicados na reação de Michael assimétrica via o equilíbrio tautomérico imina/enamina quirais, também conhecida como alquilação desracemizante. Estão descritos novas abordagens e metodologias para uma extensiva Análise Conformacional e Análise dos Estados de Transição para moléculas com razoável número de átomos, envolvendo um alto número de graus de liberdade. Essas novas abordagens e
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Books on the topic "Enamina"

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tr, Taeger Marc, and Martínez Pilar tr, eds. Cocodrilo se enamora. Faktoria K de Libros, 2007.

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Zvi, Rappoport, ed. The chemistry of enamines. Wiley, 1994.

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Rappoport, Zvi, ed. The Chemistry of Enamines. John Wiley & Sons, Ltd, 1994. http://dx.doi.org/10.1002/0470024763.

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Zvi, Rappoport, ed. The chemistry of enamines. Wiley, 1994.

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Zvi, Rappoport, ed. The chemistry of enamines. Wiley, 1994.

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translator, Sanabria Noelia, ed. Cuando un hombre se enamora. Ediciones B, 2014.

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Biondo, Gabriela Anahí. Chaco, una provincia que enamora. En un Feca, 2014.

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1933-, Cook A. Gilbert, ed. Enamines: Synthesis, structure, and reactions. 2nd ed. M. Dekker, 1988.

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author, Traeger Fererico, ed. Lo que no mata, enamora. Editorial Planeta Mexicana, 2012.

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Missbach, Martin Beat. Untersuchungen über [3+3]-Carbocyclisierungen mit Nitroallylestern und Enaminen. [s.n.], 1990.

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Book chapters on the topic "Enamina"

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Pihko, Petri M., Inkeri Majander, and Anniina Erkkilä. "Enamine Catalysis." In Topics in Current Chemistry. Springer Berlin Heidelberg, 2009. http://dx.doi.org/10.1007/128_2008_21.

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Pihko, Petri M., Inkeri Majander, and Anniina Erkkilä. "Enamine Catalysis." In Topics in Current Chemistry. Springer Berlin Heidelberg, 2009. http://dx.doi.org/10.1007/978-3-642-02815-1_21.

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Waser, Mario. "Enamine Catalysis." In Asymmetric Organocatalysis in Natural Product Syntheses. Springer Vienna, 2012. http://dx.doi.org/10.1007/978-3-7091-1163-5_2.

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Li, Jie Jack. "Stork enamine reaction." In Name Reactions. Springer Berlin Heidelberg, 2003. http://dx.doi.org/10.1007/978-3-662-05336-2_292.

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Li, Jie Jack. "Stork enamine reaction." In Name Reactions. Springer Berlin Heidelberg, 2002. http://dx.doi.org/10.1007/978-3-662-04835-1_280.

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Laue, Thomas, and Andreas Plagens. "Stork-Enamin-Reaktion." In Teubner Studienbücher Chemie. Vieweg+Teubner Verlag, 1994. http://dx.doi.org/10.1007/978-3-322-94015-5_99.

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Laue, Thomas, and Andreas Plagens. "Stork-Enamin-Reaktion." In Teubner Studienbücher Chemie. Vieweg+Teubner Verlag, 1998. http://dx.doi.org/10.1007/978-3-322-94077-3_101.

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Laue, Thomas, and Andreas Plagens. "Stork-Enamin-Reaktion." In Teubner Studienbücher Chemie. Vieweg+Teubner Verlag, 1994. http://dx.doi.org/10.1007/978-3-322-94726-0_99.

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Murphy, John J., Mattia Silvi, and Paolo Melchiorre. "Enamine-Mediated Catalysis (n?→?π*)." In Lewis Base Catalysis in Organic Synthesis. Wiley-VCH Verlag GmbH & Co. KGaA, 2016. http://dx.doi.org/10.1002/9783527675142.ch17.

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Waser, Mario. "Combined Iminium-Enamine Catalyzed Approaches." In Asymmetric Organocatalysis in Natural Product Syntheses. Springer Vienna, 2012. http://dx.doi.org/10.1007/978-3-7091-1163-5_4.

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Conference papers on the topic "Enamina"

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Visser, Susan A., John A. Sinicropi, Edward H. Magin, and Paul M. Borsenberger. "Hole transport in enamine-doped polymers." In Optical Science, Engineering and Instrumentation '97, edited by Stephen Ducharme and James W. Stasiak. SPIE, 1997. http://dx.doi.org/10.1117/12.290244.

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Rezali, Nurul Syafiqah. "The Syntheses Of Fused Cyclic 5/6-Membered Ring Lactams Via Enamine Hydrogenation." In 8th International Conference on Multidisciplinary Research 2019. European Publisher, 2020. http://dx.doi.org/10.15405/epsbs.2020.03.03.87.

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Naimi-Jamal, M., and M. Seyedalikhani. "Enamines Preparation Under Solvent-free Conditions Catalyzed by LiClO4." In The 12th International Electronic Conference on Synthetic Organic Chemistry. MDPI, 2008. http://dx.doi.org/10.3390/ecsoc-12-01256.

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Andrighetto, Rosália, Helio G. Bonacorso, Jussara Navarini, Nícolas Krüger, Marcos A. P. Martins, and Nilo Zanatta. "Highly Efficient Synthesis of CF3-Containing 7-Aminoquinolines From Cyclocondensation Reaction of Trifluoroacetyl Enamine Precursors." In 14th Brazilian Meeting on Organic Synthesis. Editora Edgard Blücher, 2013. http://dx.doi.org/10.5151/chempro-14bmos-r0008-1.

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Ortiz, Maria J., Antonia R. Agarrabeitia, Eduardo Palao, et al. "Exploring BODIPY meso-enamines as singlet-oxygen photosensitizers for PDT." In The 21st International Electronic Conference on Synthetic Organic Chemistry. MDPI, 2017. http://dx.doi.org/10.3390/ecsoc-21-04785.

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Santos, A. F., M. Polido, A. P. Serro, and C. G. Figueiredo-Pina. "COMPARATIVE TRIBOLOGICAL STUDY OF TWO PROSTHETIC DENTAL MATERIALS: ZIRCONIA AND VITA ENAMIC." In BALTTRIB. Aleksandras Stulginskis University, 2017. http://dx.doi.org/10.15544/balttrib.2017.29.

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The purpose of this study was to compare the tribological behaviour of two commercial prosthetic materials – Zirconia and a polymer infiltrated ceramic (PIC) commercially known as VITA ENAMIC – when tested against human molars/premolars. Samples of both materials were prepared and their hardness, wettability and topography were characterised. Antagonist teeth samples were prepared by cutting human molars/premolars to obtain isolated cusps. A wear test was performed during 306,000 chewing cycles, corresponding to 1.5 year of mastication, using a simulator with artificial saliva as lubricant. Th
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Tikhomolova, Alexandra S., Zhanna V. Mamleeva, and Alevtina Yu Yegorova. "Synthesis of New Representatives of Push–Pull Enamines 5-Aryl-3-((dimethylamino)methylene)furan-2(3H)-Ones." In ECSOC 2023. MDPI, 2023. http://dx.doi.org/10.3390/ecsoc-27-16056.

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Costa, Paula Marino, Helena Sandrini Venante, Marcelo Lupion Poleti, Paula Vanessa Pedron Oltramari-Navarro, Thais Maria Freire Fernandes Poleti, and Regina Célia Poli Frederico. "Associação entre Polimorfismos dos Genes AMELX e ENAMEN e Cárie Dentária em Crianças de Londrina-PR." In V Simpósio de Bioquímica e Biotecnologia. Editora Edgard Blücher, 2015. http://dx.doi.org/10.5151/biochem-vsimbbtec-22162.

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Daškevičiūtė-Gegužienė, Šarūnė, Cristina Momblona, Kasparas Rakštys, et al. "Fluorene-based enamines as low-cost and dopant-free hole transporting materials for high performance and stable perovskite solar cells." In nanoGe Spring Meeting 2022. Fundació Scito, 2022. http://dx.doi.org/10.29363/nanoge.nsm.2022.375.

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Isepon, Marielly, ALESSANDRO ZORZI, VICTOR MONTALLI, FRANCISCO NOCITTI, and ANA MONDADORI DOS SANTOS. "AMELOGÊNESE IMPERFEITA ASSOCIADA AO TAURODONTISMO." In I Congresso Nacional de Pesquisas e Estudos Genéticos On-line. Revista Multidisciplinar em Saúde, 2022. http://dx.doi.org/10.51161/geneticon/8153.

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Introdução: Amelogênese Imperfeita (AI) é uma alteração patológica no desenvolvimento da estrutura do esmalte dentário. Em 2016, Neville criou uma classificação considerando padrão de calcificação e sinais radiográficas, sendo 4 tipos principais: hipoplásica, hipocalcificada, hipomaturada-hipoplásica e hipoplásica-hipomaturada. Com padrão de herança variável, os principais genes são: Enamelina (ENAM – OMIM * 606585) autossômico dominante ou recessivo e Amelogenina (AMELX – OMIM * 300391) ligado ao cromossomo X. Taurodontismo é o aumento ocluso-apical da câmara pulpar dos dentes molares, acomet
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